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By Michael MacMillan

AI is already changing how mining companies are seen, judged, and trusted. This paper discusses “reputation engineering,” a structured way to build trust in a world where AI systems summarize and evaluate everything a company says publicly. Using mining examples, emerging AI search trends, and real communication work, the paper explains why the next 12–18 months are a crucial window for action. It also provides a practical framework to help mining companies improve their visibility, accuracy, and consistency across both human and machine channels.

Feb 22, 2026

By A. Moergeli, Philip Sander, John Reilly

"SUMMARY While the basic elements of risk management, including probability, consequences, risk registers, mitigation measures, etc., are now well understood, the process to include correlation, dependencies and linkage of risks and risk scenarios is less well defined and not well understood. To perform accurate and complete risk analysis and risk management, it is necessary to include correlation, dependencies and linkage between risk events, as well as risks that may occur multiple times. In this way, owners and contractors can more accurately determine risk-based costs, risk impacts and risk mitigation strategies. This paper will outline methods to deal with correlation, dependencies and linkage and will consider risks that may occur multiple times. Practical result comparisons – with or without these elements – will be presented. INTRODUCTION We believe the reader is familiar with basic concepts of risk, risk management and mitigation and the use of probabilistic cost-risk processes versus deterministic ones (Reilly et al. 2015; Sander et al. 2015). The probabilistic approach, compared to the simpler and more common deterministic approach (unit prices times unit costs plus a contingency), offers more useful information with respect to the range of probable cost as well as cost “drivers” and better quantifies the effects of risks, opportunities and variability – which improves understanding, leading to a better potential for profit (or loss) for contractors and added value for owners. In this context, a valid and sufficient quantification of correlation, dependencies and linkage of risk events, plus the impact of risks that may occur multiple times, is essential. Components of Cost Estimates – Base Cost, Risks and Other Uncertainties The components of cost that need to be correctly addressed in an estimate include (Moergeli et al. 2015): •,Base costs – the costs that will result if “all goes according to plan” (Reilly 2004) •,Risk costs – the resulting costs of threat and opportunity events, if they should occur •,Escalation costs – costs resulting from normally expected inflation with variability •,Other uncertain costs – costs that result from other events, normally external to the project team’s control, which may include unanticipated events, politically related changes and “black swan” events (Talib 2007)"

Jan 1, 2016

By Xuchen Fan, Chenyang Zhou, Yuemin Zhao, Liang Dong, Chenlong Duan

A gas–solid fluidized bed using magnetite particles is an effective methodology for coal beneficiation in the field of dry coal cleaning. Broadening the size range of magnetite used in the bed decreases medium preparation cost. In this study, a tapered fluidized bed was used to investigate a magnetite particle size range of −0.5 + 0.074 mm. The results showed that a tapered fluidized bed effectively strengthens mixing of magnetite with a wide size range (−0.5 + 0.074 mm). The results of beneficiation experiments indicated that with increasing tapered angle, separation efficiency increased and then decreased. The highest separation efficiency was obtained at a tapered angle of 10°. The optimal results showed that the ash content of the concentrate decreased from 31.82% to 12.33% with a probable error of 0.11, which indicated that a tapered fluidized bed was efficient to improve fine coal beneficiation performance.

By E. Nickel

"Bi- and multilateral banks as well as export credit agencies in the OECD countries, but also numerous commercial banks, last year committed themselves to compliance with the World Bank’s standards. These environmental and social guidelines, also known as the Safeguard Policies, are the strictest international standards in the area of financing of major investment projects. The Safeguard Policies are procedural and quality guidelines by means of which socially and environmentally relevant impacts can be taken into account in the planning and implementation phase of a project. Objectives of the Bank Safeguard Policies are to ensure that environmental and social issues are evaluated in decision-making, to reduce and manage risk of projects and programs, and to provide a mechanism for consultation and disclosure of information. They are often referred to as the "10+1 Safeguard Policies," since ten of the guidelines address environmentally and socially relevant issues, while one guideline is exclusively concerned with public participation ("Public Disclosure"). In the presentation, the transparency of risk management measures and emergency response plans in pipeline projects will be discussed as an indicator of sustainability. The discussion is to be carried out on the basis of the results of an evaluation of several major pipeline projects, which have been financed at least in part by multilateral banks over the past few years. The controversies surrounding some of these projects due environmentally and socially relevant impairments connected with the investments have also been addressed by the Extractive Industry Report of the World Bank. Pipeline construction was the investment type chosen for the examination to be presented here, since pipelines frequently start in remote, unspoiled regions, and their routes often cross various natural zones and areas with various social structures. The question of safety during construction and operation of the line is always central to these projects; not only for the responsible authorities but also for other societal groups involved, such as environmental associations."

Jan 1, 2005

"Tell us how you got involved in mining?I was first exposed to mining at a young age, as a consequence of my dad and his passion for the industry and rock collecting. Even though he graduated with a degree in mining engineering from Washington State University, my dad spent most of his career working as a structural engineer for the Boeing Company. At the time, Boeing supported a range of employee activities and clubs, including one devoted to mineral prospecting, small-scale dredging and rock hounding. My dad was extremely active in the Prospectors Club, where as a family, we spent a good part of my youth tramping around the Pacific Northwest digging for mineral specimens and panning for gemstones and gold. On my mother’s side of the family, I had relatives that mined in Dawson City and Fairbanks, AK which left a family legacy of sorts. I loved the stories that my dad and a close buddy of his, who was a geologist, would tell about various operations and towns, as well as the wild times at the annual Northwest Mining Association (NWMA) meeting in Spokane, WA. My first recollection of ever being at a commercial operation was during a tour of the Bunker Hill Mine with my dad when I was 7 or 8 years old; this had to have been shortly before the May 1972 fire at Sunshine. That visit of the mine and processing facilities made a permanent impression on me. While I always knew there was something special about the Silver Valley, I began to understand why. To this day, I still get the same feeling when I visit historic mining districts like Leadville, Morenci, Virginia City, Butte, Silverton and Barkerville. During our summer excursions to Helena, MT to dig sapphires, we would usually make visits to Butte and watch mine operations inside the Berkley Pit and surface activities at the Kelly and Mountain Con. In high school, I did well in math and science and began entertaining thoughts of pursuing a degree in engineering. Above all, I wanted to go to a college in the West that had a good academic reputation, where I could also play football. As a 6-ft, 190-lb nose guard, my options for a Division I scholarship were pretty slim, and there weren’t that many technical schools in the Northwest that were Division II that offered athletic scholarships. As fate would have it, I was unexpectedly contacted by Marv Kay, a legendary coach at the Colorado School of Mines (CSM), and was recruited to play ball. Fortunately, I had a couple of high school friends who were already attending CSM, and I had just secured a summer internship with Asamera Minerals in Wenatchee, WA. It was as if all the stars had aligned, and, with the support of my parents, I made the decision to attend Mines. Despite the stress of getting through CSM during a period when the mining industry was in freefall, it was a great decision to attend Mines, and I’m thankful for all the opportunities, friendships, and faculty mentoring I received as a student"

Mar 1, 2019

By Yunxing Cao, Xinsheng Zhang, Bingbing Meng, Shuaifang Guo, Li Wang, Junsheng Zhang

During the initial process of mining a longwall working face, it is often found that the roof will not collapse readily, which increases the risk of later roof collapse disasters. Explosive and hydraulic fracturing are common roof weakening techniques; however, they have certain limitations. In the present study, CO2 fracturing was used for roof weakening during the initial mining phase in the Changcun coal mine, China, which is a novel strategy. First, by analyzing the lithological characteristics of the working face and applying combined beam theory, the breaking spans of the top coal, immediate roof, and main roof were determined before weakening. An F-35 CO2 fracturing device with a rated pressure of 270 MPa was used, which provides fracturing energy equivalent to 0.968 kg of TNT. The fracture radius of the main roof was studied by ANSYS/ LS-DYNA combined with the hanging roof-breaking theory to determine the optimal layout of CO2 fracturing drills. The results show that the breaking spans of the top coal, immediate roof, and main roof were reduced by 3.99 m, 7.66 m, and 22.03 m, respectively. The main roof collapsed as the working face advanced, eliminating the chance of later roof collapse disasters. Compared with hydraulic fracturing and explosives, CO2 fracturing is safer and more practical, giving it significant application potential.

Nov 23, 2023

By HASSAN E. EL-SHALL, AYMAN A. EL-MIDANY, KERRI-ANN A. HUE

Modifying the hydrophobicity of clay is necessary to accommodate large mycotoxin molecules such as zearalenone (ZEN). In this study, tricaprylmethylammonium (TCMA) chloride and common corn oil were used to modify clay. The results indicate that more than 90 percent of ZEN could be removed using clays modified by TCMA and corn oil at acidic and neutral pH due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clay-forming layers. The removal percentage depends on the pH and amount of clay used. Complete removal can be achieved at acidic pH and small clay amount.

By K. E. Yassin, A. Yehia, M. Amar

Phosphate ores are the source of many commodities, such as phosphorus element, P2O5 and fertilizers. Discarding a large percentage of fine phosphate particles produced as slimes during phosphate ore processing represents a severe environmental problem, besides making the beneficiation process uneconomical. The phosphate industry is interested in a process that is efficient, with high grade and high recovery; ensures economical feasibility, with low operating cost; and is environmentally sound, with low toxicity. Numerous investigations have been conducted to try to find better processing techniques and reagents. However, reagent requirements and recovery limitations may be so high that the end does not justify the means. Reagents of biological origin are of special interest because they offer specific interactions with minerals, reduced operating costs, environmental acceptability and flexibility in adaptation. Recently, there has been a growing interest in using microorganisms as flocculants for mineral fines and as flotation collectors. 

By Kathy Kalenchuk

To develop strategic and tactical strategies to manage seismic hazard in a safe and economic manner, it is necessary to understand the spatial and temporal distribution of mine wide seismogenic behavior. Global mine-scale numerical stress modelling provides a means to forward predict seismic susceptibility thereby facilitating informed decision making for the development and implementation of strategic and tactical risk mitigation measures. To make forward predictions of hazard susceptibility using global stress models with reasonable confidence, it is necessary to rigorously calibrate numerical stress models to the observed history of ground reaction. This paper demonstrates quantifiable methods for calibrating numerical models and developing probabilistic prediction criterion using seismic data. The appropriate applications of model inputs (including boundary conditions, constitutive models and material parameterization) specific to global mine-scale modelling are also discussed. Lastly, this paper demonstrates how the calibration process adds value not only to informed decision making, but also to the improved understanding of site geomechanical conditions; including enhanced identification of geotechnical domains and mechanical indicators required for seismic mechanism domaining.

Apr 26, 2022

By M. Heger, V. Lund, P. Mongeon, D. Bogunovic, V. Kecojevic

The U.S. coal mining industry consumes a significant amount of energy, primarily diesel fuel and electricity. The continuous global increase in energy demand, high energy prices and environmental issues related to carbon dioxide emission represent a substantial challenge for the mining industry. This paper presents the result of research on development of an integrated data environment system for analysis of energy consumption in a surface coal mine. A case study on an operating surface coal mine is carried out to demonstrate the practical application of the developed system. The research work presented here may be used by mining professionals to help provide the answers to the crucial questions of when, where and how much energy is being used. This developed system represents a framework for efficient management of energy consumption.

Jan 1, 2009

By Justin Carl, Aliuddin Mohammad, Gordon Evans, Steven Bealby, Carlton Ray

"The District of Columbia Water and Sewer Authority (DC Water) is implementing the $2.2-billion DC Clean Rivers Project (DCCR) to control combined sewer overflows (CSO) to the Anacostia and Potomac rivers and Rock Creek, and to provide flood relief to the Bloomingdale and LeDroit Park neighborhoods in the District of Columbia. The long-term control plan complies with the requirements of a Federal Consent Decree entered into by DC Water, the District of Columbia and the United States, as represented by the U.S. Environmental Protection Agency and the Department of Justice. The Northeast Boundary Tunnel, a design-build project, will store combined sewage and deliver it to a system of downstream tunnels and ultimately to the Blue Plains Advanced Wastewater Treatment Plant (Blue Plains), where it will be treated. In addition, the Northeast Boundary Tunnel (NEBT) is a major project associated with the mayor’s task force to alleviate extreme flood events in Bloomingdale and LeDroit Park. The Northeast Boundary Tunnel Utility Relocations (NEBTUR) design-bid-build (DBB) project is an accelerated component of the Anacostia River System, as shown in Fig. 1. During dry weather conditions, the entirety of the sewage in the combined system is conveyed to Blue Plains.During storm events, when sewer pipe capacity is exceeded, the flow, which is a mixture of sewage and stormwater runoff, overflows into receiving waters through outfalls. There are a total of 47 active CSO outfalls along district waterways.The influx of storm runoff into the combined sewer has an additional impact on the communities of Bloomingdale and LeDroit Park. The sewer system is outdated and undersized. In these neighborhoods, when the capacity of the sewer is exceeded, localized flooding occurs and backups into adjacent residences are prevalent. In any given year, there is a 50-percent chance that flooding will occur in these neighborhoods."

Jan 9, 2017

By Gang Yang, Manchao He, Chengzhang Gao, Jun Zhang, Yayun Li, Jun Yang, Shilin Hou, Ben Liu, Yajun Wang, Jianning Liu

To explore the mechanism of roof directional breaking in gob-side entry formed automatically without coal pillars, the numerical simulation was used to study the deformation movement of roof, the deformation evolution of roadway, and the stress distribution of roadway under roof directional breaking and non-roof directional breaking. Based on the results, the deformation movement of roof is divided into three stages: the goaf roof collapse stage, the basic roof deformation stage, and the basic roof stability stage. The goaf is filled with gangue due to the broken expansion characteristics of the collapsed rock under the roof directional breaking. Due to the supporting force of gangue, the deformation of the basic roof under the roof directional breaking is smaller than that under the non-roof directional breaking, which reduces the influence of the deformation of the basic roof on the deformation of the roadway roof and improves the integrity of the roadway. At the same time, roof directional breaking cuts off the stress transfer path of partial roof, which weakens the peak stress convergence on the arc side, transfers the peak stress convergence to deeper, and improves the stability of roadway. Finally, a field test was carried out to further verify the accuracy of the numerical simulation. The field test results are in good agreement with the numerical simulation results. The roadway deformation is small and meets the requirements of safety production. It is proved that roof directional breaking plays a positive role in improving the stability of the roadway.

Dec 22, 2022

By A. Yadav, B. Behera, G. S. P. Singh

The size of chain pillars in the Indian geo-mining conditions is primarily decided in accordance with the regulatory provisions. These provisions are of little help for deep longwall workings, exceeding the cover depth of 360 m. Furthermore, these provisions are primarily meant to support pillars in bord and pillar workings. They may not be suitable for the chain pillars owing to a significant difference in layouts and functional requirements. Hence, it is imperative to develop a method to evaluate the stability of the chain pillar considering the complex loading and geo-mining conditions. To this end, a machine learning-based model was developed in this study to assess the stability of the chain pillars under high depth of cover considering the field-representative conditions. The data for this work was generated by conducting a parametric study using a field-validated numerical model. The strength and deformability parameters of the caved, fractured, and continuous deformation zones were established by calibrating the numerical model outcomes against the site-specific field observations. The developed ML model was used to evaluate the influence of pillar width, pillar height, cover depth, abutment angle, face length, coal strength, moduli ratio of the roof and floor strata to the coal seam, and the elastic modulus and unit weight of the overburden on the chain pillar stability. An interesting finding of this study showed that the factor of safety of the chain pillar increased with the increasing abutment angle, which may be indicative of the confining effect of the abutment angle on the pillar. Eventually, the ML model was verified by comparing its outcomes with the calibrated numerical model for a typical longwall working from Indian geo-mining conditions.

Oct 18, 2023

By Hakan Uyguçgil, Beril Bayraktar, Adnan Konuk

In mining, which is one of the industries with the highest risk of occupational accidents, a primary goal is to enhance safety through the thorough investigation of accidents using reliable methodologies. In this research, the data from 13,653 accidents reported in the Karadon Hard Coal Enterprise between 2000 and 2011 were analyzed and compared using the life-table and Kaplan-Meier methods. Accident records were classified and analyzed into four categories: environment-related, equipment-related, person-related and other accidents. Findings in terms of survival time indicate that environmentrelated and person-related accidents had the highest risk in Karadon, with equipment-related accidents having the lowest. This study established the reliability of using survival analysis methods to investigate occupational accidents in the mining sector. Given that environment-related and person-related accidents occur in a relatively short period, such as one year after starting work, it is recommended that research be done to improve workplace and occupational safety measures and broaden the training given to miners. Additionally, it is determined that increasing the use of automation and mechanization in underground coal mines, combined with developing a thorough equipment safety training program to raise awareness of the danger, can help prevent person-related occupational accidents caused by the interaction between equipment.

Feb 1, 2024

By William C. York-Feirn, Jeffrey H. Kravitz, David Stalfort

"Mining is an inherently risky business. Over the years, major mine disasters have resulted in the deaths and injuries of thousands of miners in the United States. These disasters also resulted in innovations in approaches to mine design, operations and the training of miners and mine rescue teams. The U.S. Congress responded to these disasters with new laws designed to create mandatory safety and health standards as a means to eliminate fatal accidents; to reduce the frequency and severity of nonfatal accidents; to minimize health hazards and to promote improved safety and health conditions in the nation’s mines.Following a mine emergency preparedness and response holistic gap analysis in 2012, the U.S. Mine Safety and Health Administration (MSHA) identified the need for the development of risk and readiness assessment models for MSHA and the mining industry. MSHA’s objective was to evolve existing theoretical concepts for risk and readiness assessment into simplified tools that can be applied by the mining industry for use at operational levels. In 2012, MSHA hired ABS Group, a recognized industry leader in safety risk management and a wholly owned subsidiary of the American Bureau of Shipping, to develop self-assessment models to help meet this objective.In September 2012, MSHA chartered a project to supply the coal mining industry with a pro-active toolset for mine operators to:1. Self-assess the risks associated with underground coal mining operations in order to prevent major mine emergencies.2. Assess the preparedness of mine operators to respond to an emergency.3. Measure the readiness of mine rescue teams and responsible persons to execute emergency plans.MSHA’s objective was to evolve existing theoretical concepts for risk and readiness assessment into simplified tools that can be applied by the coal mining industry for use at operational levels."

Jan 10, 2018

By Joseph J. Yancik

An exchange of coal mine specialists was made with the USSR under an "Agreement on Exchanges and Cooperation in Scientific, Technical, Cultural, and other Fields for 1972-73," which was signed by President Nixon and Chairman Breshnev on April 11, 1972.* This exchange, in the field of coal mine safety and scientific research in hazard control technologies, was one of 16 technical exchanges covered under the above agreement. A six-man USA delegation visited the Soviet Union from September 9 to September 21, 1973. The delegation visited four deep mines, three in the Donets Basin and one in the Moscow Basin, a State Safety Research Institute, a Mine Research Station and associated Research and Design Institute, two Research and Design mining equipment institutes, and a Trade Union-sponsored health sanitarium. In Moscow, the delegation received a briefing on the Soviet coal industry from First Deputy Minister Vladimir Fedanov. A similar briefing was given to us on the Donets coal basin by the Deputy Minister S. Saratikyanz of the Ukrainian Coal Ministry. Lengthy technical discussions were held with the mines staff and research personnel at the institutes we visited. In addition, we had detailed discussions with key staff members of two combinats "Donetskugol" and "Tulaugol." In all these meetings, principal topics were matters of safety related to hazards associated with face mechanization, coal transport, methane gas control measures, gas outbursts, coal and rock outbursts, fire fighting add control, explosion suppression and control measures and other related hazard factors. There was also much discussion on miner training, miner's attitudes toward safety and accident prevention practices, and preparation and enforcement of safety rules and regulations. The delegation was very warmly received and constant attention was given to our needs. Our numerous questions were answered with candor although quite often in not as much detail as we would have liked.

Jan 1, 1974

By R. L. Grayson

In 2010, MSHA began holding hearings on a new coal mine respirable dust rule, which proposes a 1.0 mg/m3 standard, a separate 0.1 mg/m3 quartz standard, and the use of single-shift samples for compliance. Small mines largely comprise the ?hot spots? where dust diseases of the lungs increased dramatically over the past decade. This paper presents findings on the feasibility of small mines? compliance with the proposed new 1.0 mg/m3 standard. It gives probabilities of noncompliance by MSHA district, seam height, and selected ?hot spot? counties. Because silicosis and respirable quartz dust appear to be the primary issues related to a recent doubling of the prevalence of dust diseases of the lungs, multiple regression models for prediction of the average total quartz content of compliance samples are given. These findings have significant implications on the need for better dust control methods.

Jan 1, 2012

By J. DuCarme, A. Smith, M. Reyes

"A magnetic proximity detection system is mounted on a mobile mining machine to prevent underground workers from being pinned or struck by machine motion. The system generates magnetic fields around the machine to determine safe working distances. The minerworn component measures the magnetic field in order to approximate location. Large masses of steel, such as those from mining equipment, can alter the magnetic field distribution. This affects the locational accuracy of the system, thus adversely impacting worker safety. To examine this problem, U.S. National Institute for Occupational Safety and Health researchers developed a method and test system to study the influence of a steel mass on the magnetic field distribution. The results show that a steel plate can strengthen the magnetic field perpendicular to the generator by up to 40 percent. Furthermore, they show that the degree of the influence on the field distribution is a function of distance. The results from this study can be used to further develop and improve the performance and reliability of electromagnetic proximity detection systems used in underground mining applications.IntroductionOn average, 250 miners are injured every year, and 43 miners were reported to be killed by striking or pinning accidents involving continuous mining machines in the United States between 1984 and 2015, according to the U.S. Mine Safety and Health Administration (MSHA, 2015). Continuous mining machines are large mobile machines used to mechanically cut coal in underground mines. These machines weigh approximately 60 t (132,000 lb) each. Although modern continuous mining machines can be remotely controlled, operators still need to be close to the machine primarily because of the low visibility and wide blind spots of the underground working environment.The MSHA promulgated a final regulation in 2015 that requires the use of proximity detection systems on all continuous mining machines except fullface machines. MSHA has approved five such systems to be intrinsically safe for use in underground coal mines: (1) Strata Worldwide’s HazardAvert System, (2) Frederick Mining’s Model 200 HazardAvert Detection System, (3) Nautilus International’s Coal-Buddy System, (4) Matrix Design Group’s M3- 1000/Joy Global SmartZone Gen 1 and (5) Matrix Design Group’s IntelliZone/ Joy Global SmartZone Gen 2."

Jan 6, 2018

By Kathleen Lagnese, Srikanth Muddasani, Kashi Banerjee, Carla Robinson

"Mine water generated from underground coal mining operations contains both dissolved and particulate solids. Dissolved solids primarily consist of sodium, calcium, magnesium, potassium, chlorides and sulfates. When discharged to a receiving stream without treatment, these constituents create a potentially toxic environment for aquatic life.A case study is presented to discuss how a centralized treatment plant treats mine water from six locations to meet discharge limitations for chlorides. Located in West Virginia, this facility consistently achieves less than the National Pollutant Discharge Elemenation System (NPDES) permit limitation of 218 mg/L chlorides in the discharge while generating almost zero liquid waste. The dissolved solids concentration in the influent ranges between 5,000 and 10,000 mg/L, with chloride concentrations of 1,000 to 2,000 mg/L and sulfate concentrations of 2,000 to 6,000 mg/L.The mine water is treated using advanced treatment technology to produce clean water for discharge or reuse. The treatment process comprises aeration, softening, filtration, reverse osmosis (RO) reject softening, evaporation, crystallization, final effluent remineralization and sludge dewatering. The solid waste generated in the treatment process is landfilled on site. The leachate is sent back to the facility’s thermal treatment process. Because no liquid waste leaves the property, this plant is termed a zero liquid waste (ZLW) facility.The advanced water treatment system was built to meet a new 218 mg/L regulatory limitation imposed by the West Virginia Department of Environmental Protection for chlorides discharged to surface waters. The system is designed to treat a maximum flow of approximately 795 m3/h (5 million gpd) of mine water. The treatment process utilizes RO membrane treatment to achieve the effluent criteria, and evaporation and crystallization technology to manage the RO concentrate from the water treatment process. As a result, the system produces clean water for discharge while generating zero liquid waste. The effluent water can be used for industrial purposes or discharged to a receiving stream. A water impact index (WIIx) study indicated that discharge of this high-quality water into the Monongahela River watershed may improve the water quality for downstream water users. The waste produced in the treatment process, including softening sludge and salt, is disposed of in an onsite landfill. Currently, the plant is treating at an average flow of 490 m3/h (3.1 million gpd) of mine water with an average influent chloride concentration of 1,530 mg/L and an average effluent chloride concentration of 11 mg/L."

Jan 1, 2014

By B. Cousins

Copper, nickel, zinc and other ?penalty? metals are found with gold together in nature, and have a similar chemical affinity for cyanide used in leaching operations4. As a result, solutions that come from the heap leach pads contain a significant concentration of penalty metals along with the desired gold. In solution, gold and cyanide form the complex Au(CN)2- that is readily adsorbed onto activated carbon. Penalty metals as individual metal ions also load onto activated carbon and, depending on the concentration of cyanide and the pH of the solution, can form various cyanide complexes. Some of these complexes can also load onto carbon while some are significantly inhibited from loading. Copper, for example, can form the dicyanide complex Cu(CN)2-, the tricyanide complex Cu(CN)32-, and the tetracyanide complex Cu(CN)43-. At a low pH and a low concentration of cyanide, the dicyanide complex predominates. At a higher pH and a higher concentration of cyanide, the tetracyanide complex predominates. Without excess cyanide, however, individual copper ions can remain present. Activated carbon is used in gold extraction because it is highly selective for gold and less so for other metals, such as copper3. However, copper has the ability to adsorb (?load?) onto activated carbon and block the adsorption of gold when it is in the dicyanide form and in a high enough concentration. When copper is in the tetracyanide form, copper loading is significantly inhibited, allowing for the maximum gold recovery. In order to ensure the tetracyanide complex is formed, a combination of both available cyanide and elevated pH must be present. In the South Area of Newmont Mining Corporation?s Gold Quarry mine in Carlin, Nevada, copper and nickel loading becomes a problem when certain acid generating zones of the heap are leached. Copper, nickel, zinc and other penalty metals become leachable and the lower pH uses up more of the cyanide and creates carbon loading conditions for the metals. This decreases the carbon?s ability to extract the gold from solution, decreasing the recovery and increasing the concentration of gold in the barren solution that leaves the carbon columns. In this study, operational data from March through to May of 2007 is presented to show how Newmont developed a quick fix to lower pH and elevated metal concentrations that were causing low gold loadings on activated carbon at their South Area Leach (SAL) heap leach operations. Laboratory tested were also conducted to examine the chemical kinetics of metal loading and the individual effects of increased cyanide concentrations. THEORY Copper I ions form four different complexes with cyanide in solution: the monocyanide species CuCN, the dicyanide species Cu(CN)2-, the tricyanide species Cu(CN)32-, and the tetracyanide species Cu(CN)43-. The species are formed from the following reactions: [Cu)(?+-+ K1 (1) Cu ß2 (2) --+?+23)(3CNCuCNCu ß3 (3) --+?+34)(4CNCuCNCu ß4 (4) ] where K1 equals 1019.50, ß2 equals 1024.03, ß3 equals 1028.65, and ß4 equals 1030.35. Along with these complexing reactions, hydrogen cyanide and water also dissociate in solution, as per the following reactions: [H?+-+ KH (5) OHOHH2?+-+ KW (6)] where KH has a value of 109.24 and KW has a 1014 value2. These six chemical equations compete with each other, with domination of one over the others dependent on the CN- and H+ concentrations. Each complex also has different properties when it comes to its loading behavior on activated carbon. The dicyanide copper complex and the monocyanide copper complex have an affinity for adsorption onto activated carbon that is greater than the affinity of gold cyanide for adsorption. They also have a lower solubility in water, which enhances adsorption. The tricyanide copper complex and the tetracyanide copper complex are water soluble and have an affinity for loading adsorption on activated carbon that is less than the affinity of gold cyanide for loading adsorption1. There are three prime reasons for this phenomenon. First, the extra cyanides mask the metal ion more, which blocks the main adsorption characteristic of the complex. Second, the complexes are also larger, making it harder to physically fit into the active sites on the carbon. This helps make the latter two complexes kinetically inhibited from adsorption, freeing carbon active site to load with gold cyanide complexes. Third, it is also important to consider the expressions of the mass and charge balance. These balances describe all the overall concentration of copper and cyanide in solution, as well as marking overall charges of the ions in solution4. This is important because significantly changing the charge from positive/neutral to more negative is another reason for activated carbon to reject adsorbing the higher cyanide complexes. The speciation of copper and other penalty metal cyanide complexes in solution is dependent on the pH. At lower pH values, increased hydrogen ions (H+) can out-compete metals for cyanide ions. Lower free cyanide in the system leads to the lower cyanide species of copper cyanide predominating, with a noticeable concentration of the free metal, monocyanide and dicyanide species of copper cyanide. At higher pH values, hydrogen ions are significantly reduced, reducing the kinetics of HCN formation. More free cyanide remains in the system, allowing for more complexing. With this higher amount of cyanide in the system, the tetracyanide species of copper cyanide predominates, also with a noticeable concentration of the tricyanide species of copper cyanide. Higher copper concentrations, however, require more

Jan 1, 2009