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By H. Nakazawa, A. S. Malicsi, K. J. Reid, P. J. Ryan, I. Iwasaki, P. W. Weiblen

Precious metals are commonly believed to be recovered along with sulfide minerals in flotation, but a few neutron activation analyses showed that the recoveries of gold and silver were unexpectedly low. Reasons for low recoveries of platinum group metals remained unresolved due to interferences in the analyses. Electron microprobe, scanning electron microscope, and scanning Auger microprobe analyses have identified nickel arsenide minerals in the ore and confirmed a close association of platinum group metals with the arsenide minerals as minute inclusions. These results indicated a need for re-evaluation of flotation procedures that have so far ignored special problems related to arsenide minerals. The electrochemical and flotation behaviors of nickel arsenide and their application to the flotation recoveries of precious metals from copper-nickel bearing Duluth gabbro are presented.

Jan 1, 1987

By Lawrence Neal Post

Introduction Synthetic soda ash production began to decline in the late 1930s. This was due to high operating costs and waste disposal problems. Since soda ash was used as a major component in manufacturing glass, an alternate method of producing that chemical was necessary. A process to produce soda ash from trona was developed by FMC Wyoming Corp.'s predecessor, as well as an economical way to obtain trona. Existing trona operations are located about 40 km (25 miles) west of Green River, WY. Five operators presently mine trona in this area. FMC's property has 153 km2 (59 sq miles) leased. Its eight shafts reach 488 m (1600 ft) deep to the uniform trona deposit. The seam ranges in thickness from 2.4 to 3.6 m (8 to 12 ft). History Egyptian tombs, dating from 4000 to 3000 BC, contained mummies preserved by an embalming process using soda ash. For many years, soda ash was produced by burning marine plants, then dissolving the soluble material (sodium carbonate) from the ashes. The name soda ash is derived from this method of production. In 1791, Nicola LeBlanc developed black ash, or salt cake, from salt, sulfuric acid, coal, and limestone. This process remained in use until 1863, when Ernest Solvay developed a method for producing soda ash from salt, coke, and limestone with ammonia as a catalyst. This Solvay process was widely used. And, in the 1930s, there were 17 plants in the US alone. High plant operating costs and waste disposal problems, however, necessitated finding an alternative to the Solvay process.

Jan 10, 1985

By X. Wu, E. Topuz

Booster fans have been extensively used in underground mines throughout the world. In the United Kingdom, S. Africa, Germany, and other countries, many non-coal and coal mines employ booster fans. These fans help to reduce air leakage, to provide an improved flow distribution and to reduce the overall cost of mine ventilation. Although booster fans have not been used in coal mines in the United States, a recent survey indicated that many coal mines would install booster fans if they were allowed to do so. With the inclusion of coal mines, the use of booster fans in underground mines is expected to increase substantially in order to maintain air quality and quantity requirements. Several techniques are used, with varying degrees of success, in determination of booster fan locations in an underground ventilation network. These techniques include linear programming, critical-path crashing, CPM together with cutset operations, the out-of-kilter method, and simulation techniques. This paper provides a brief comparison of these techniques, and reports on ongoing research for an improved methodology for the determination of booster fan locations.

Jan 1, 1987

By André Vervoort, Jef Caers

Compound lognormal distributions serve as new generalized distribution laws for analyzing and estimating ore value distributions or related properties such as the average ore grade. These models are an alternative to the well known lognormal distribution. They are the translation of general geological constraints on the genesis of the deposit cumulated in suitable statistical properties. In this paper a maximum likelihood framework is established for estimating the parameters of such laws or parameter functions thereof. It is shown that under certain conditions maximum likelihood estimation is accurate and efficient in estimating the mean value even when relatively few samples are available. The method is based on a numerical maximization of the likelihood function of these models given the data. Confidence limits on these estimates are set up using resampling techniques such as the bootstrap. By this a complete methodology is presented for inference on ore grade distributions such as is shown in an example of gold data from the Merriespruit mine (South Africa) and the diamond size distribution of the Bougban deposit (Guinea).

Jan 1, 1996

By Marie-Antoinette Dziurla, Barrie Johnson, Åsa Kolmert

Acidophilic bacteria are well known for their role in accelerating the oxidative dissolution of sulfide minds, such as pyrite. Other acidophiles, however, are able to catalyze dissimilatory reductive reactions. Bacteria that reduce ferric iron to ferrous, and sulfate to sulfide, were isolated from ARD-impacted environments and immobilised onto porous beads made of recycled glass. Column bioreactors containing colonized beads were constructed and peacolated with synthetic and actual ARD, and evaluated for their capacities to promote iron or sulfate reduction, and pH amelioration. Iron reduction did not require strictly anoxic conditions in bioreactors, and rates of up to 800 mg Fe3+ reduced/(l*day) were achieved, with a conversion efficiency of up to 98%. Using mixed populations of acidophilic fungi and iron-reducing bacteria, the bioreactors were capable of promoting iron reduction using paper pulp as sole carbon and energy source. Reduction of sulfate in pack bed bioreactors was observed with acidic wastewaters of pH 3 and above, though average rates of 300 mg sulfate reduced/(l*/day) were less than those recorded for circum-neutral pH systems. Bioremediation of ferric iron-rich ARD was assessed using coupled iron-reducing and sulfate reducing bioreactors.

Jan 1, 2000

By I. Tsolas

Sustainable development is becoming increasingly more important for the mining industry and therefore mining companies should be able to measure their progress towards sustainability. Greek Public Power Corporation (PPC) S.A. is a company which produces lignite in open cast mines in Western Macedonia and in Peloponnesos. The present paper uses operational data kindly offered by PPC S.A. to derive sustainability indicators by means of Data Envelopment Analysis for three large scale lignite open cast mines of PPC (i.e. Main Field, Kardia Field and South Field mines). It also examines three environmental parameters related to the contribution of these mines to sustainable development; namely, the annually produced volume of waste masses, the annually produced quantity of ash from the lignite combustion and the annual volume of pumped water. The calculated sustainability indicators were keeping constantly better during the last years of the different periods for each one of mines studied here, showing that the mines met their goals from both economic and environmental aspects during the last years of their operational periods studied. The contribution of open cast lignite mines studied here to sustainable development can be monitored by the derived indicators analyzing annual mine operational data. The derived indicators can serve as tools to detect where improvements can be made, though another potential use of these indicators can also be during the preparation of feasibility studies or environmental impact studies using necessary benchmarking data.

Jan 1, 2007

By George A. Desborough, Stephen J. Sutley, Reinhard W. Leinz, Paul H. Briggs

The mode of occurrence of metals in mine wastes is investigated using sequential extractions. Metals are extracted from some or all of seven operationally-defined phases: water-soluble, ion-exchangeable, carbonate, amorphous Fe-oxide, crystalline Fe-oxide, sulfide, and silicate. The quantity of metals extracted from each phase varies with particle size. The presence of jarosite (potassium end-member formula, KFe3[SO4]2[OH]6) influences the selection of the procedure for extracting the crystalline Fe-oxide phase. Anglesite (PbSO4) and cerussite (PbCO3) are extracted as several phases. Extraction results can be explained only in part by X-ray diffraction (XRD) mineralogy because of lack of specificity of the extraction procedures, relatively high XRD detection limits, and the presence of 40% XRD-amorphous matter in each waste. The increasing chemical strength of the sequentially applied methods provides a basis for judging metal availability, water-soluble metals being most available and silicate-bound metals being least available.

Jan 1, 2000

By L. E. Krys, K. D. Harrison, S. M. Nordwick, C. G. Anderson

Since 1984, nitrogen-species catalyzed pressure leaching has been utilized at the Sunshine Mining and Refining Company for the recovery of precious metals from a refractory sulfide concentrate, The process operates without the use of cyanide. The plant is now the only industrial-scale commercial application of this technology. Since the inception of the process, changes have been implemented to improve efficiencies and throughputs. Two of these changes, the replacement of nitric acid by sodium nitrite and a concentrate regrind, have recently been implemented. This paper will discuss the outcomes of these recently patented plant-process changes. In particular, a comparison between the previously used method and the new leach method is made. Also discussed is the potential applicability of the process to other materials. A companion publication (Anderson, Harrison and Keys, 1996) indicates possible mechanisms responsible for the success of these process changes.

Jan 1, 1997

By Mahesh C. Jha, Frank J. Smit

Column flotation and selective agglomeration are promising advanced physical cleaning processes that can be developed for preparing premium quality coal-water slurry fuel from coal fines. Such a fuel could either replace oil or natural gas in certain industrial and utility boilers or else could be burned in advanced combustors currently under development. These applications require coal cleaned to sulfur and ash contents below 258 g/GJ and 430 - 860 g/GJ (0.6 lb/million Btu and 1 - 2 lb/million Btu), respectively, to meet clean air emission requirements. A highly loaded slurry must be produced in order to avoid derating the boilers, and the total cost of the fuel must be below $2.37/GJ ($2.50/million Btu) in order to penetrate the market by the turn of the century. Achieving these technical and economic goals depend critically on the selection of suitable feed coals. This paper describes the identification and evaluation of 18 coals and final selection of six coals from different regions of the United States as potential feedstock for preparation of premium fuel. The work is being performed under a cost-shared DOE project.

Jan 1, 1995

By Laurel E. Burns

Alaska is in competition with the rest of the world for exploration dollars. Providing a "seed package" of airborne geophysical data for the state's numerous mining districts encourages companies to begin more detailed exploration in more areas than they could have afforded on their own. When data are already available, the initial risk decreases for people involved in exploration. Airborne magnetic and electromagnetic data help ge¬ologists and geophysicists determine what rocks and structures are present under overburden and vegetation. These data form a fundamental package that exploration companies want before intensively exploring most regions. Individual mining companies have conducted their own geophysical surveys during the past several decades. However, these data are not available to other companies. The companies able to afford geophysical surveys have less money for ground exploration after purchasing expensive, private geophysical data. Therefore, they are not able to explore as many places as they might. Additionally, since data are not shared with other exploration companies, the proprietary surveys do not foster intercompany competition to move projects forward. Individual prospectors and small companies can not afford their own geophysical surveys. "It is more often than not the grassroots exploration efforts of the smaller operator that leads to significant discoveries," said Klaus M. Zeitler, senior vice president for development and exploration at Teck Exploration. Acquiring and releasing the geophysical data to the public produces several benefits. The increased explo- [ ]

Jan 1, 1998

By Douglas J. Piper

On reflection of certain overall circumstances which have pervaded the gold mining industry, it appears useful to point out some specifics which the writer hopes will improve the potential for success in the application of hydraulic dredges to gold mining activity. I will, prior to entering into that discussion, comment briefly on rule of thumb for the application of the three types of equipment. The three are bucket line, bucket wheel and drag line dredges. From a standpoint of high volume movement over a short distance, between 50 and 300 feet, the drag line dredge is historically the most cost effective type of machine to be utilized if bulk excavation is the single driving consideration. It is typical for this sort of equipment to operate in the 10 to 30 cents per cubic yard range, however, cost of operation is not the sole consideration. Typically the drag line mixes and remixes the material which it excavates. In the event that gold recovery is the object of the exercise, a strong potential for loss of the valued mineral exists. Additionally, drag lines do a poor job of bottom cleaning, particularly if there is a ridged or creviced bottom which must be cleaned and in some cases partially removed to assure recovery of the highest percent of valuable ore. The bucket line dredge has, until recently, been considered an extremely cost effective device. However, the high cost of manufacture of this type of equipment has mitigated against its use in the majority of

Jan 1, 1992

By A. K. Bakshi, K. J. Shoop, Komar S. Kawatra, T. C. Eisele

Slurry rheology can have significant impact on the performance of autogenous grinding circuits. A viscous slurry can act as a cushion and retard impact forces between the media and the ore, which reduces grinding efficiency. On the other hand, a dilute slurry will not be viscous enough to hold slurry in the impact zone of the media, which will lead to inefficient use of impact energy. An unfavorable rheology can also lead to overgrinding or centrifuging of the slurry inside the mill. Slurry rheology also affect classification, with higher viscosity increasing the cut size. In this article, the causes of the rheological effects on autogenous grinding and hydrocyclone classification have been discussed. Both plant and pilot scale data from autogenous grinding have been provided to show the effects of viscosity on specific energy con- sumption and other breakage characteristics of the ore. It is shown that: (1) high viscosity, produced by low temperature and high fines content, significantly increases the specific energy consumption and the production of critical size material in an autogenous mill; (2) In hydrocyclone operation, increasing the viscosity causes the d50(c) size to become coarser.

Jan 1, 1998

By J. Hanna, J. Jung, I. J. Anazia

Electrothermal production of elemental phosphorous (P4) generates substantial amounts of highly toxic phossy water and sludges. Because of their high phosphorous contents and lack of reliable processing technology, large tonnages of these hazardous wastes have accumulated from current and past operations. To date, the sludges are stored in ponds or above ground in special containment vessels at various locations around the country. Two samples of electric furnace phosphorous sludge (obtained from the Tennessee Valley Authority (TVA) in Muscle Shoals, AL and FMC Corporation in Pocatello, ID) were investigated using physical separation techniques to recover the elemental phosphorous and to render the residual material nonhazardous. The techniques tested include sizing, froth flotation and dispersed air oxidation. Flotation and sizing produced concentrates containing 69% - 90%P4, with recovery in the range of 60% - 87%. Dispersed air oxidation of the fines and tailings products was effective in the removal of an additional 10% - 15% of the P4 in the sludge.

Jan 1, 1993

By P. D. Nora, M. G. Ranade

A statistically designed pot grate-kiln test program was conducted to determine the agglomeration process variables necessary for increasing the low temperature disintegration resistance (LTD) and reducibility (R40) of magnetite-based Empire acid pellets. The ASTM tumble index and compression strength were to be maintained at an acceptable level. Six process variables - bentonite addition level, preheat time and temperature, firing time and temperature, and cooling rate - were investigated within the constraints of the Empire plant. The bentonite addition level and firing temperature had the largest effect on pellet properties. The results of this program were verified during a plant trial. The target firing temperature at the Empire plant has been decreased for increasing the LTD and R40 of commercially produced Empire pellets.

Jan 1, 1987

By B. E. Davis, D. A. Stanley, C. E. Jordan

A prototype expert advisor was developed by the U.S. Bureau of Mines to systematically offer advice on the control of a Florida phosphate operation. The PC based system receives input from remote sensors for circuit parameters such as feed rate, reagent addition, and pH and from operator entered information such as the quality of the concentrate and tailings in each of the coarse, fine, and amine flotation circuits. The computer evaluates the information using rules obtained from industry representatives and Bureau flotation experts. Recommended actions and questions are displayed to quickly guide the operator to a problem within the flotation circuit and suggest a solution. This process control system could provide more uniformity among the flotation operators and also serve as a trainer for new operators. In addition, it represents a step toward fully automated systems for phosphate flotation.

Jan 1, 1990

By Changhong Huang, Y. J. Wang

This paper describes the formulation of mine ventilation network optimization as a standard nonlinear programming problem and the solution of the problem using the generalized reduced gradient (GRG) method. In general, the GRG method is regarded as one of the most effective and efficient methods for solving large-scale nonlinear programming problems. The variables considered in the network optimization include air quantity, regulator pressure loss, and fan pressure for each branch. Each of the variables is constrained by lower and upper bounds. This facilitates proper assignments of ventilation requirements and provides a great flexibility to include various situations encountered in mine ventilation. The objective of the network optimization is to minimize the overall air power consumed by or supplied to the network; whereas the constraints are, in addition to the variable bounds, the two fundamental network laws: Kirchhoffs voltage law and Kirchhoffs current law. A computer program has been developed based on the GRG method for the network optimization. An example of network with 18 branches, 8 regulators and 3 fans is included for illustration.

Jan 1, 1993

By R. Weinstein, R. Snoby

There are many advantages to upgrading coal with dry jigging technology. The most obvious is the lack of process water, which eliminates the need for fines dewatering and slurry confinement. Dry jigging eliminates the clean coal moisture penalty associated with wet processing. Particulate emissions are virtually nonexistent due to inclusions of fabric dust collectors on all modern dry jig plants. Due to the environmentally kind nature of dry jig plants, installation permits are often measured in days, not months. Coupled with all these advantages there has been a fundamental advance in dry jigging efficiency. All of these advantages have renewed the coal industry’s interest in dry jigging. But, air jigging isn’t right for every application. There are limitations due to particle size, particle shape, moisture, and near gravity content. This paper explores the evolution of dry jigging; reviews parameters important for determining the suitability of dry jigging; compares historical performance data as measured by imperfection, against results from modern dry jigging technology; and presents actual data from modern dry jig installations.

Jan 1, 2006

By Solomon S. Katz

As more and more computer software is written for geological mapping applications, the users of the software are discovering the problems of transferring data between the programs, maintaining correct data and integrating maps produced last week with those produced today. One way to deal with these situations is by using a geographic information system (GIs). Last September the USGS and National Academy of Science held a 5-day GIs symposium on integrating technology and geoscience applications (USGS, 1988). It was followed in October by GEOTECH '88 (Peters and Krajewski 1989) which had a session exclusively for GIs applications in the Geo-Sciences. Editorials in Geobyte (Leonard, 1986, 1988) suggested that geographic information systems will be the next major computer programs to be adopted by the mineral industries. As far- back is 1985, the Computer Oriented Geological Society (COGS) printed An Introduction to GIs in their newsletter (Katz, 1985). About 20 years ago, a revolutionary idea occurred in the world of business data processing. It was the idea that all related data be stored in a standard format, in a single place and that all related computer application programs would use the same data.

Jan 1, 1989

By Y. Topkaya, R. E. Johnson, B. R. Palmer, R. B. Bhappu, J. Brent Hiskey, Gürses Öner

Currently there is considerable interest in applying in situ leaching technology to recover copper from oxide ores. In many instances, the distribution of copper mineralization in these deposits is fracture controlled. Laboratory core-leaching experiments have demonstrated that leaching response is sensitive to the dissolution of copper from and the formation of channels along main fractures. Solution short- circuiting can be a major limitation of this technology. This paper describes the application of macromolecular polymers to achieve flow-profile control during leaching. Pre- and post-leached fractures were characterized by computerized tomography (CT) analysis.

Jan 1, 1993

By D. E. Munson

To assure the safety of a radioactive-waste repository, the performance of the repository must be predicted far into the future. The Waste Isolation Pilot Plant (WIPP) Program is responsible for developing the technology for such performance predictions in bedded salt. An important technology-development activity concerns the, fielding of very large-scale in situ tests to determine the time-dependent deformation of underground openings in salt as a basis for validation of the predictive technology. This technology is necessary to predict repository seal performance and final closure times of rooms and may be of value to the salt and potash mining community, as well.

Jan 1, 1992