Search Documents

By D. C. Seidel, W. K. Tolley

Supercritical water alters the structure of common sulfide minerals by partially removing sulfur from the mineral structure. This discovery has been applied to the treatment of pyritic gold ores to improve precious metal recovery without generating or utilizing environmentally sensitive products such as S02, chlorine, or cyanide. Pretreating pyrite concentrates in supercritical water under mildly oxidizing conditions provided by certain metal oxides or oxygen improved gold leaching using thiourea. The pretreatment differs from chlorination or roast pretreatments in that elemental sulfur rather than sulfuric acid is the major product. A pyritic ore containing 58 g/mt Au was pretreated with oxygenated supercritical water at 24 MPa and 400°C, then leached with 20 g/L thiourea. With pretreatment, gold recovery was 90%; by contrast, gold recovery was below 10% without pretreatment.

Jan 1, 1990

By S. K. Sharma, D. A. Stanley

The US Bureau of Mines is investigating the fundamentals of the flocculation process. The objective of this study was to determine the effects of various physico-chemical parameters, namely, shear rate, polymer dosage, and polymer concentration, on floc growth and to determine the applicability of a model for predicting polymer flocculation behavior. A rapid in-line particle size analyzer was used to follow the progress of both the floc growth and the breakage as a function of time. A genetic algorithm (GA) was used to determine the unknown parameters in the model and to fit a curve to the experimental data. The results showed that the model reproduces the experimental data with only reasonable accuracy and that it was relatively insensitive to the parameters. Results of the flocculation study showed that increases in the polymer dosage had a greater effect on the time required to reach the maximum floc size than on the floc size itself: It was also determined that, given all the above parameters, the degree of slurry mixing during the flocculation process had the greatest bearing on floc growth.

Jan 1, 1995

By Monica Pavlik, Thomas Wildeman

Water from the Forest Queen mine adit near Silverton, Colorado drains into a natural wetland. Because the pH of the water averages 5 and the iron concentration averages 18 mg/L, it was thought that the wetland might naturally treat the water. Of most concern with respect to the aquatic environment is zinc whose concentration averages 0.60 mg/L. Starting in October 1997, the surface waters, ground waters in the peat substrate, and the sediments in the wetland were sampled and analyzed four times over the course of four months. The adit water primarily remains as surface water where Fe, minor amounts of Al, and no Zn are removed. After the adit water enters the peat, then it is found that the pH rises to 5.8-6.5 and sulfate is reduced. The removal of Zn and A1 is caused by these two changes. However, Fe in its reduced state is quite soluble and may be remobilized in the reduced environment of the peat.

Jan 1, 2000

By P. R. G. Brandão

In this investigation, the differences in the absorption spectra of etheramines, fatty amines and condensates, mostly present as acetates, from several suppliers are characterized by means of infrared spectrometry. Sharp differences were observed in the absorption spectra of three types of amines and derivatives. Etheramines show a characteristic and well-defined peak at 1,114 cm-1. This peak is due to the ether C-O group and differentiates etheramines from the other classes. The absence of such a peak indicates that the species is not an etheramine. The distinction between condensates and fatty amines is made by the presence of a sharp peak around 3,200 cm-1. This peak is probably due to the proximity of the N-H amine groups and C=O carbonyl groups in the amide portion of the condensate's molecule and by different and better-defined bands in the 1,800- to 1,500-cm-1 range. The flotation performance of these amines was evaluated by means of the laboratory-scale flotation of an itabirite ore. The etheramines proved to be the most effective collectors for this system. Monoamines presented better performance than diamines for the ore under investigation.

Jan 1, 2002

By Michel David

Once a mineralized body has been delineated, drilled and estimated from surface samples, it often happens that before the final go-no-go decision is taken, an underground sampling program is decided, very often via a ramp which hopefully will be later used to extract the ore. The cost of such a program can be close to a million dollars. On other occasions, when a property changes hands and is reexamined maybe 20 years after the original drilling program, a "check sampling" program is carefully, designed to make "sure" that the old assays are "correct". One may fear poor sampling practice in old days, or deliberate highgrading by promoters. Again one may be talking of resampling cost which may be in the six-figures range. Other similar situations include the drilling of a few large diameter holes to ascertain the validity of a majority of small diameter drill holes, or auger drilling, or back-rimming. In uranium checking radiometric information is also a problem related to the above ones.

Jan 1, 1979

By R. Frenette, A. W. Mo, H. A. Hamza

Fine particles present major technical and economic problems to those who deal with solid/liquid separation processes. In the coal industry the problem is compounded by the large amounts of produced fines such as those present in Western Canadian coals. Flocculants in the form of high molecular weight water soluble polymers are commonly considered an effective solution for the enhancement of the separation process. These reagents are relatively expensive especially when considering a low-price commodity such as coal. Optimization of the use of these reagents is therefore an operational necessity. Six polymers were evaluated as to their effectiveness in flocculating a fine coal tailing. Results were compared with those for a reference flocculant, in-use at that time in the washery. It was shown that, in general, flocculants significantly improve the solid/liquid separation process. The ranking of the flocculants as to their effectiveness in settling and filtration indicated that the best flocculants for settling were not necessarily the most effective for filtration. Flocculants that showed the best filtration improvement were generally cationic and those best for settling were anionic.

Jan 1, 1988

By R. J. Sawyer

*An earlier version of this paper was presented at the IMM meeting, "Use of Cultivated Carbon in Extraction of Gold and Other Metals," held in London in January, 1983, and was subsequently published in Trans. IMM (Sect. C: Mineral Process. Extr. Metall.) in December, 1983. Reprinted with permission of The Institution of Mining and Metallurgy, London. INTRODUCTION This paper describes the development of the processing route for the Alligator Ridge Mine which commenced operation in 1980. It also reviews the modifications which have been made to improve operating efficiency during the three years that the mine has been in production. Alligator Ridge is located 70 miles Northwest of Ely, Nevada. The mine is a joint venture between Amselco and Nerco with Amselco acting as operator. The deposit consists of micron sized disseminated gold imbedded in siltstone. Although definitive conclusions have yet to be drawn as to the age and origin of the deposit, it is probable that it is young by geological standards, perhaps only 5 million years old. It is likely that the gold was brought to the surface by hot springs. As the superheated solutions rose through the porous siltstone, they redeposited minerals in the rock, forming the present ore bodies.

Jan 1, 1984

By A. G. Journel

Few Earth Scientists realize fully the assumptions they are making, willing or not, when pooling into a same histogram data coming from different locations and considering such histogram as an estimate of a probabilistic distribution. First they need the hypothesis of stationarity in space; second the presence of spatial auto-correlations implies that data be unequally weighted according to their relative locations and the degree of spatial continuity of the underlying phenomenon. The novel technique of indicator kriging allows construction of local or global histogram which can be considered as unbiased estimators of precisely defined probabilistic distributions, full account being given to the underlying continuity. Such estimates of local distributions can be used in mine planning for estimation of local recoverable reserves.

Jan 1, 1982

By Hajime Miki, Michael J. Nicol

Relatively simple techniques have been developed which enable the electrochemistry of sulfide minerals to be studied with particles varying in size from above 100 pm to less than 1 pm. Both oxidative and reductive processes have been studied wing the minerals pyrite, arsenopyrite and chalcopyrite. It has been shown that it is possible to completely oxidise or reduce the minerals during a single voltammetic sweep. The resulting voltammogram produces peaks which are characteristic of each mineral and can be used to qualitatively identify the minerals. In the case of chalcopyrite, it has been demonstrated that the charge involved in the anodic oxidation can be quantitatively related to the amount of copper dissolved. Quantitative information can be obtained using peak fitting techniques. Interesting differences in the behaviour of the minerals in sulfuric and hydrochloric acids have been observed, particularly in the case of pyrite for which a second major peak is obtained which has been attributed to the oxidation of elemental sulfur in the presence of chloride ions. The technique offers the possibility of providing mineralogical information of individual particles based on an electrochemical voltammetic finger print.

Jan 1, 2005

By M. S. Janssen

The development of a design equation for, and the testing of, a constant- flow airlift pump IS described. The predictions of the new airlift model agree with the results of experiments carried out using riser diameters between 0.025 and 0.300 m, submergence depths between 5 and 10 m, suspension densities between 1000 and 1650 kg/m3, and a solids dg of 70 to 100µm. The predictions o the model also agree with data from the literature for submergence depths that reached 130 m. This airlift model was employed to simulate the pulp flow through a series of tanks, each of which was fitted with an airlift pump to transfer the suspension to the next tank. Particular attention was paid to the riser diameter, submergence of the airlift pump, and control of the air supply to the airlift pump during the simulated operation of a series of tanks. The results of the simulation highlight some design parameters that could affect the efficiency and operation of a plant that employs airlift pumps to transfer suspensions.

Jan 1, 1989

By Hassan El-Shall, Rosana M. Macedo Borges, Ponisseril Somasundaran, Regis Stana, José Renato B. Lima, Patrick Zhang

The phosphate fertilizer industry is a large activity in Brazil because the soil has a phosphorous deficiency. The phosphoric acid that is produced is extensively used in the production of fertilizer. It is produced by reacting phosphate carbonaceous rock with sulfuric acid, generating phosphogypsum as a by-product. In 1991, there were about 29 million tons of phosphogypsum stored in Brazil. This has increased to an estimated 280 million tons in 2001. While the phosphogypsum is used in the cement industry and also in agriculture, the quantity used is much less than the production rate, and the stockpiles are still increasing. The radioactivity of this waste may not allow its continued use as a construction material and some other uses. However, Brazilian phosphogypsum contains a smaller quantity of radioactive materials than is reported for phosphate rocks from other countries. One important reason is the geological origin of the Brazilian apatite. All the large deposits being currently mined are igneous, not sedimentary, as is the majority of the phosphate rock produced around the world. An extensive study is being conducted to characterize the phosphogypsum generated in two production facilities in Sao Paulo state to develop safe uses for this waste and determine the environmental impact caused by the present method of phosphogypsum disposal.

Jan 1, 2002

By E. J. Meets, C. F. Meyer

Bord and pillar mining at shallow depth (400 m approx. maximum) is widely used in South African coal mines. One of the problems encountered in extracting coal in this manner is the ventilation of advancing bord and pillar headings. The traditional ventilation methods of force, exhaust and overlap (force/exhaust) are reasonably effective but tend to be both cost and labour intensive. Ducting often restricts the available free area of roadways thus impeding the transport of coal and other materials inbye the coal production section. Due to the above facts, ductless fans are currently being used to minimize the amount of ducting required in advancing sections. Two different types of fans are used, namely, vortex fans and the so-called `jet' fans. Vortex fans were developed from the fan blade design used for vertical take-off aircraft. The fans have the capability of delivering air over distances of about 30 m in the underground situation without any ducting attached to it. Jet fans are standard axial flow fans fitted with outlet reduction pieces which increase the velocity pressure at the discharge to such an extent that the air delivery distance is improved to almost match that of vortex fans. The paper describes some applications of both these fan types in advancing bord and pillar sections.

Jan 1, 1993

By K. A. Natarajan, J. M. Modak, B. Saha

Nonliving waste biomass consisting of Aspergillus niger attached to wheat bran was used as a biosorbent for the removal of copper and zinc from aqueous solutions. Copper and zinc uptake by the biomass obeyed Langmuir isotherms. The binding capacity of the biomass for copper was found to be higher than that for zinc. The metal uptake, expressed in milligrams per grain of biomass, was found to be a function of: •the initial metal concentration (with the uptake decreasing with increasing initial concentration), •the biomass loading (with the uptake decreasing with increasing biomass loading) and •pH (with the uptake increasing with increasing pH in the range of L5 and 6.0). The metal uptake was significantly affected in the presence of a co-ion. The uptake of copper by the biomass decreased in the presence of zinc and vice versa. The decrease in metal uptake was dependent on the concentrations of metals in the two-component aqueous solutions. The effect of copper on zinc uptake was more pronounced than the effect of zinc on copper uptake.

Jan 1, 1997

By J. A. Herbst, T. I. Martinovic, Y. C. Lo

This study was concerned with the application of a computer simulation methodology to optimize the performance of mills grinding iron ore concentrate prior to pelletizing. The methodology involves batch and plant testing, modeling and computer simulation. The analysis of grinding performance was carried out and capacity increases were predicted in the context of detailed population balance models developed for the plant ball mills. Model developnent and plant confirmation were performed using data obtained in a series of batch tests and three plant tests. From experimental data and computer simulation it was found that ball size, percent solids and classification all had a significant effect on mill throughput. Based on the findings of this study, a 12-152 increase in capacity was predicted to be available by a proper combination of ball size charge and optimum percent solids. These predictions have been confirmed by plant tests in which the recommended operating changes have been made.

Jan 1, 1990

By H. Bernatowicz

The Nucoalyzer (On-Line Nuclear Analyzer) is a new method recently made comercially available for monitoring the elemental composition of a process stream. Applications for the Nucoalyzer include grading ore on a conveyor belt before or after it has gone through primary crushing, monitoring the slurry being transported in a pipe to the concentrator, and monitoring the stream of concentrate or the tailings from the concentrator. The Nucoalyzer may also be used at the smelter to monitor elements in the feed that include copper, sulfur, iron and silicon where a uniform feed is desired. The advantage of the Nucoalyzer over most other techniques are (a) it performs the measurement directly on the process with no sampling necessary, (b) the analysis can be performed on streams of particulate and slurries, and (c) the system does not have to make contact with the material it measures. These Nucoalyzers are operating at coal fired power plants and several more are about to be placed in service. This paper discusses the principles of operation of the Nucoalyzer, our experience in the field, application of minicomputers to data reduction, and potential applications in the ferrous and non-ferrous industries.

Jan 1, 1982

By Gill G. Geesey, Michael R. Hankins, Paul L. Wichlacz, Anita Gianotto, John G. Jolley, Randy B. Wright

Thin films of copper [2.0 nm on germanium internal reflection elements (IREs) and 3.4 nm on germanium discs] were exposed to 10% gum arabic (aqueous solution) , 2% alginic acid (aqueous solution), 1% bacterial culture supernatant (BCS, simulated seawater solution) and 0.5% Pseudomonas atlantica exopolymer (simulated seawater solution). The IRES were monitored in situ, in real time using fourier transform infrared/cylindrical internal reflection/attenuated total reflection spectroscopy as a function of time at ambient conditions. The discs were characterized (pre- and post-exposure) by X-ray photoelectron and Auger electron spectroscopies. Ancillary graphite furnace atomic absorption spectroscopy was used to monitor the removal process of the copper thin film from the germanium substrates. Results indicate that Cu was oxidized by gum arabic, alginic acid and BCS. Furthermore, Cu was removed from the Cu/Ge interface by all four polymers. The Cu was found associated with the polymer solutions.

Jan 1, 1989

By G. A. Doyle

Until the suspension of conventional operations in 1996, the White Pine Mine was the second-largest active underground copper mine in the United States, underlying an area of approximately 30 km2 (13 sq. miles) in the Upper Peninsula of Michigan. The mine operator intends to initiate in-stope solution copper mining by circulating a solution (lixiviant) of mine water, sulfuric acid and ferric iron through rubblized ore. As planned, the solution would be retired in the mined-out stopes following completion of the solution-mining activities. Investigations into the fate of the retired solution indicated that the solution, through time, would change from an acidic, metal-rich solution to a near-neutral, reducing solution containing much lower concentrations of metals. Investigations included reaction-path modeling (EQ3/6) and laboratory and in-mine tests. The combination of neutralization and reduction will result in precipitation of most metals, primarily as metallic sulfates, chlorides and sulfides.

Jan 1, 1997

By R. D. Miller, D. W. Steeples

Application of shallow, seismic reflection to problems associated with mineral exploration, mine planning, abandoned-mine detection and environmental evaluation has been successful in many geologic settings. The increased dynamic range of recording equipment and the decreased cost of processing hardware and software have made shallow, seismic reflection a cost-effective means of imaging geologic targets significant to mining operations. Seismic data possess sufficient resolution in many areas to detect faulting with displacement of less than 3 m (10 ft) in coal seams as thin as 2 m (6.5 ft) at depths of 200 m (655 ft). Subsurface voids associated with abandoned mines at depths of less than 20 m (65 ft) can he detected and mapped. Seismic reflection has been successful mapping disturbed subsurface associated with dissolution mining of salt. Complex geologic features associated with deposition of various hydrothermal minerals have been mapped with high-resolution seismic reflection at depths from 80 m (260 ft) to more than 300 m (985 ft). Faults in sulfur-hearing cap rock over salt domes have been accurately located, allowing improved efficiency of the dissolution mining process. Shallow, high-resolution seismic reflection has the potential to enhance the economics and safety of mine operations.

Jan 1, 1996

By D. K. Sengupta, T. K. Rout, A. R. Prasad, B. P. Singh

The filter cake from the vacuum drum filters of a uranium ore processing plant still contains some leach solution. If the filter cake is not efficiently washed the associated leach solution is lost. Therefore, it is necessary to produce a filter cake that is permeable enough to allow efficient washing. The dewatering characteristics of the solid-liquid system must be improved to obtain flocs with sufficient strength to withstand the suction pressure of the filtration system. To facilitate efficient filtration with minimum cake moisture, studies were undertaken to improve the dewatering characteristics of the cake using different types of flocculants and surfactants. In these studies, flocs were formed with anionic, cationic or nonionic flocculants. The best performance was obtained with a low cationic high molecular weight flocculant. The filtration parameters, namely, capillary suction time, cake resistance, cake permeability and final moisture content of the filter cake, are improved by using a combination of flocculant and nonionic surfactant.

Jan 1, 2002

By G. F. Friel, J. C. Edwards, C. C. Hwang

In the implementation of a mine fire alarm and location strategy, the Interpretation of the fire signature Is Important. Smoke and CO are the two dominant fire signatures, and many mine fire detection systems utilize sensors which respond to smoke or CO through a diffusion mode or a mechanical pump mode. The fire signature may be modified during its transport along airways and at crosscuts. The modification occurs through dilution of the contaminants. In this Investigation, computer codes were employed to compute the effects of contaminant dilution on the contaminant signature when a straight flow passage has one dead-end crosscut. The model predicted the airflow within always and the entrainment of contaminants into the crosscut from the airway. One application of the model is to determine the most suitable location for CO detectors for early mine fire detection.

Jan 1, 1995