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By Rick McGregor, David Blowes, Mike Choi, Ralph Ludwig

The oxidation of sulfide minerals at an ore transfer location in Western Canada has resulted in widespread contamination of underlying soil and groundwater. The oxidation of sulfide minerals has released sulfate [SO,] and heavy metals including cadmium [Cd], copper [Cu], nickel [Ni], lead [Pb], and zinc [Zn] into the groundwater. A compost-based sulfate-reducing reactive wall was installed in the path of the plume in an attempt to reduce the potential impact of the heavy metals on a down-gradient marine inlet. Monitoring of the reactive wall over a 21-month period has shown that Cu concentrations decrease from over 4000 ug/L to less than 5 ug/L. Cadmium, Ni, Pb, and Zn concentrations also show similar decreases with treated concentrations generally being observed near or below detection limits.

Jan 1, 2000

By N. Rajmohan, K. T. Jacob

Presented is a thermodynamic feasibility analysis of extracting base metal chlorides from low-grade, multi-metallic oxide ores using CaC[1]2 as a chlorinating agent in the presence of SO2 and O2. The oxides react to form corresponding chlorides, while CaC[1]2 is converted to CaSO4. The Ellingham diagram is used for comparing the standard Gibbs' free energy change for the sulfation-chlorination reaction of a large number of oxides. Except for alumina, silica and chromia, most of the other metal oxides will be converted to their respective chlorides. The volatile chlorides can be condensed, and the chlorides present in the condensed state can be leached. A process is proposed that uses a nontoxic chlorinating agent and gives an efficient separation of the metallic values from the gangue.

Jan 1, 1993

By J. R. Diehl, R. W. Lai, R. W. Hammack, S. U. M. Khan

Cyclic voltammetry (CV), flotation response, evolved-gas analysis (EGA), and X-ray photoelectron spectroscopy (XPS) were employed to evaluate the major differences in the surface property and surface reactivity of a selected coal pyrite and a mineral pyrite. Surface properties of pyrite were evaluated in terms of flotation response in the presence of both an anionic fluorosurfactant and sodium hydrosulfide. The charge transfer adsorption and oxidation potential of sodium hydrosulfide were evaluated using cyclic voltammetry. Drastic differences in the flotation response have been observed between the coal pyrite and the mineral pyrite. Significant differences in the cyclic voltammograms at pyrite surfaces of these two sources were also observed. Measurements by XPS and EGA were used to determine the oxidation products and the rate of oxidation of the coal-pyrite and the mineral-pyrite surfaces.

Jan 1, 1991

By O. Fernandez, M. Vesely

Abrasive grinding, leading to ultrafine product and "critical size" material buildup inside the mill, is proposed as the cause of high power consumption and low capacity in many fully autogenous grinding processes. Addition of steel balls (hence, semiautogenous grinding) or pebble removal and separate crushing have been used, with different efficiencies, to overcome the problem. Information and data for the conceptual analysis, basic design, and operation of a pebble crusher at the Los Bronces semiautogenous grinding plant is presented along with data showing a production increase of 1000 t/d (1100 stpd) and significant operating costs savings.

Jan 1, 1987

By Michael D. Balen

The plate-glass windows in the bus were cracked and mud-coated. Nevertheless, they afforded an excellent view of the many head-on collisions we narrowly avoided along the route from the Magadan airport to town. Apparently the driver thought the left side of the road was smoother than the right side, for he drove in the wrong lane at all possible times, even in the face of oncoming traffic. As far as we could tell, neither side of the road was any better than the other. Either way, we had to hang on just to stay in our seats. We careened past trucks and pedestrians, nearly always in the face of impending disaster. When the bus finally pulled into the parking lot of the Okean Hotel in Magadan, we had to thank the driver, not only for safely delivering his passengers, but also for the lasting first impression he gave us of the Russian Far East.

Jan 1, 1995

The definition of sustainable development is often taken from the so-called “Brundtland” report, requiring that activities of the current generation not detract from the potential welfare of future generations. Mining is often held up as unsustainable in this regard, since the extracted resource is non-renewable. Yet Brundtland’s definition of sustainable development also requires that the current generation address the disparity in welfare across the globe, a facet of Brundtland’s report that most have ignored. This paper examines the impact of mining on the welfare of the poor, empirically assessing mining’s contribution to this second facet of sustainable development.

Jan 1, 2004

By Walter C. Labys

There has been considerable growth in public enterprise institutions involved in mineral commodity markets. These institutions typically consist of trading organizations (STO1s), regulatory agencies, and mixed agencies. The particular character of these institutions varies according to whether they reside in developing countries, in Eastern Europe (COMECON Countries), in industrialized countries, or in the form of international agencies. The purpose of this paper is to explain recent attempts to assess the growth of public enterprises as well as their impacts on mineral markets and trade. Some earlier analyses of market impact made by the author have been up- dated for four major mineral markets: copper, tin, bauxite and iron ore. Conclusions are drawn regarding the dynamics of market structure changes and their impacts.

Jan 1, 1986

By Richard D. Grove

The on-stream analysis of phosphorus and silica has not been possible by XRF techniques and only recently has some success been indicated with quantitative XRD for P. Yet there has been a recognized need for an on-stream analysis of P and acid insoluble to permit the automatic control of phosphate rock flotation plants which produce some 30-40 million tons of concentrate each year in the southeastern U.S. IMC Fertilizer, Inc., the largest U.S. phosphate rock producer, embarked on a program to develop such an on-stream analysis capability several years ago. Following many months of lab and prototype development, the first commercial installations started in December 1986 and now have completed some 400,000 analyses with surprising accuracy, precision and reliability. The use of these devices in the improved control of the phosphate flotation plant is currently receiving some very serious attention at IMC.

Jan 1, 1989

By Jerome P. Downey

Treatment of tungsten ore at Anschutz Mining Company's Chicote Grande (Bolivia) operation results in a relatively high grade arsenopyrite byproduct stream. Laboratory and miniplant testwork have been performed at Colorado School of Mines Research Institute to examine the technical feasibility of recovering a marketable arsenic product fr an this source. Process selection was constrained by the remote location of the millsite, which demands an uncomplicated, low maintenance operation. As a result of the research effort, a two-stage roasting/condensing process was developed, featuring the use of an indirect heating method. Arsenic was efficiently extracted and the arsenic trioxide (As203) product consistently exceeded the industrial purity specification of 99.5%. Key process parameters have been secured for extrapolation of the process to pilot or small commercial scale.

Jan 1, 1985

By C. Bemelmans, L. Chia, T. O’Keefe

Lead alloys function effectively as oxygen-evolving anodes in copper SX-EW operations, and they are highly resistant to corrosion. However, the presence of an organic (from solvent extraction circuits) in the electrolyte seems to enhance solution line attack. Laboratory tests showed that lead is soluble in D2EHPA, Acorga and LIX 984 to a limited, yet measurable, degree. Lead alloys and various lead phases formed on the anode were tested to evaluate their effect on the corrosion process in organic media. Possible causes for anode corrosion and mechanisms responsible for their initiation are discussed.

Jan 1, 1998

By Boleslaw Tolwinski

This paper presents an algorithm for the de- termination of a production schedule for an open pit mine that satisfies all principal physical and economic constraints required by a realistic mine design. We propose to model the evolution of the mine over time as a sequential optimization problem or, equivalently, as a problem of finding a path with a largest value in a graph. Some preliminary evidence is provided that such a path can be effectively sought by an algorithm that combines a number of heuristic search rules, inspired in part by learning theories developed in Artificial Intelligence.

Jan 1, 1992

By Antti J. Niemi

Radioisotope tracers have so far been used for extraction of residence time distributions of flotation devices. They have also been proven applicable to evaluation of rate coefficients k of industrial flotation. It is now shown how values of k are scaled up on the basis of laboratory data on flotation and chemical conditioning, and of laboratory testing of samples from output of industrial conditioning vessel. Subsequently a model of conditioning and flotation is obtained which may be used for simulation and control of the steady state of the combined process. Discussion extends to modelling, simulation, CAD and opti- mization of flotation plants with re- circulation, and of ore dressing systems which consist of grinding and flotation plants.

Jan 1, 1990

By D. G. Chedgy

Careful consideration is given to the type of cleaning equipment and control systems to be used when selecting circuits for washing fine coal (0.5 mm x 0, or 28 mesh x 0, size fraction). However, desliming, declaying, and sizing procedures required for efficient operation normally are not evaluated in sufficient detail, resulting in disappointing system performance. This paper details desliming and de. watering circuit design that is effective based on recent test data. The circuit maintains control of the 0.5 mm x 0 (28 mesh x 0) (declayed) size fraction with minimal misplaced material and maximized circuit efficiency. A discussion of circuit design parameters and control systems, as well as results from the testing program, are included in this text.

Jan 1, 1987

By H. W. Newcomen, D. R. Brox

Assessments of the stability performance of open pit highwalls have traditionally been based on consideration of surface movement rates. Although generally accepted in industry, this approach presents challenges for establishing appropriate threshold values to allow for safe mining operations and does not address the issue of total strain. Surface movement monitoring data from a limited number of open pit mining operations in North and South America has been evaluated in terms of highwall strain, rock mass quality and inferred mechanism of instability. Threshold strain levels for key stages of highwall stability proposed from previous work have been reviewed and are generally endorsed based on evaluation of additional data. An empirical highwall strain criteria for the assessment of highwall stability performance is postulated based on the observed trends in highwall strain data from the case histories presented.

Jan 1, 2004

By V. K. Karra

Research by various workers has shown compressive comminution to be significantly more efficient than impact comminution. Based on the work being done at Nordberg, wet compressive crushing in cone crushers producing finer and finer products, shows the feasibility for partial substitution of conventional tumbling mills. For further substitution, major challenges are processing of fine feed slurries in cone crushers to realize a significant size reduction of the particles, and understanding the limitation of the gyratory type units in terms of finest product achievable. The paper addresses the challenges involved, efforts at Nordberg, and the implications to conventional comminution flowsheets.

Jan 1, 1989

By S. K. Kawatra, R. A. Seitz

Nonpolar hydrocarbon oils are commonly used in the flotation of minerals to fulfill a number of roles. These roles include reducing overall reagent costs by replacing part of the collector addition, improving coarse particle recovery without reducing selectivity, as well as several others. This paper will cover the types of oils which are available, their physical and chemical characteristics, and the effect of these characteristics on the function of hydrocarbon oils in flotation. In addition, techniques for improving the behavior of oils will be discussed.

Jan 1, 1986

By Ch. Arvanitidis

This paper presents the design solution for an actual case of settlement tanks, for a wastewater treatment plant under construction, actually founded on swelling clay (the nature of which had not been appreciated beforehand) and suffering considerable damage as a result. Two points of interest prompted the use of a numerical model as an alternative approach to the traditional method of analysis: First, the desire to compare the in situ measured deformation and displacement of the tanks with the figures calculated by the numerical model. Second the need to check the validity of the suggested solution as a remedy, i.e. the replacement of a certain thickness of clay by graded material.

Jan 1, 2005

By A. D. Davis, G. A. Zabolotney

A ground-water flow model was developed to simulate the postmining recharge rate from precipitation at the Belle Ayr surface coal mine, which is located in the Powder River Basin near Gillette, WY Wyoming state regulations require that reclaimed lands should provide a rate of recharge that approximates the premining rate. Steady-state calibration and transient simulations showed that the postmining recharge rate through spoil is at least 50 mm (2 in.) per year, exceeding the original infiltration rate of 4 mm (0.16 in.) per year to shallow overburden aquifers. Major reasons for the increase include the flat topography of the reclaimed areas and the decreased spoil density. It is expected that the backfill will disaggregate and settle over time, eventually resulting in a nearly constant recharge rate that is less than 50 mm (2 in.) per year but still somewhat greater than the premining rate.

Jan 1, 1997

By Arpad E. Torma

The electrochemical behavior of a zinc sulfide concentrate during the microbiological leaching was investigated using ZnS-carbon paste electrodes and a cyclic voltametric technique. The effects of Zn2 [ ] , Fe2+, Fe3+ and Cu2+ on the cathodic and anodic currents associated with zinc sulfide leaching in presence and absence of microorganisms, were assessed. The semiconductor nature of zinc sulfide was discussed in terms of ability of microorganisms to obtain their metabolic energy (through removal of electrons) from this high energy gap substrate. The intermediate electrochemical reactions involved in the ZnS leaching were described.

Jan 1, 1989

By F. F. Aplan, D. D. Xu

A novel system for the depression of pyrite and the ash-forming minerals has been developed. A metal ion, including but not restricted to Fe+2, is added to form a hydroxide coating on the pyrite or ash-forming minerals. A polymeric depressant is then added to attach to these re- surfaced minerals. Nearly 200flotation tests with I1 different coals indicate the effectiveness of this system. Many of the important process variables such as the coal source, frother- collector system. grind size and procedure, pH, metal ion, and depressant type and concentration have been studied.

Jan 1, 1995