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By R. H. Lien

The Bureau of Mines, U.S. Department of the Interior, has developed a flue gas desulfurization process as part of its goal of minimizing the undesirable environmental impacts associated with energy and mineral-processing plants. This process, known as the citrate process, involves absorption of sulfur dioxide (SO2) in a buffered solution of citric acid. The S02-loaded solution is regenerated by reaction of the S02 with hydrogen sulfide (H2S) to form elemental sulfur. As an adjunct to the citrate process, bench-scale research has shown that S02-loaded citrate or glycolate solutions can be regenerated by countercurrent contact with steam (stripping) in packed towers. Concentrated S02 is produced by condensing the steam from the stripper product. Thus, steam stripping provides strong S02 gas for liquefaction, sulfuric acid production, or reduction to elemental sulfur. Stripping steam requirements were determined for treatment of 0.25-, 0.50-3 1.0-, and 2.0-pct-S02 waste gases. Steam requirements decreased with increasing S02 concentration n the simulated waste gases. For example, 5 grams of steam per gram o S02 was required to remove 90 pct of the S02 from a simulated copper smelter gas (2.0 pct S02), while 30 grams of steam per gram of S02 was needed for 90 pct S02 removal from a simulated coal-fired powerplant gas (0.25 pct S02).

Jan 1, 1979

By Jack C. White

As part of an investigation of the production of alumina by the nitric acid leaching of kaolinitic clay, the Bureau of Mines designed, built, and tested a fluidized-bed system for the calcination of aluminum nitrate nonahydrate to alumina, while recovering nitric acid. The calciner consisted of an 8-in-square by 36-in-tall vessel containing 18 in of fluidized solids. Molten aluminum nitrate, sprayed directly into the fluidized solids, formed sandy, granular alumina by growth of successive layers on fluidized particles. Solids were fluidized in a dense bed at temperatures of 250° to 500° C with steam, air, or mixtures thereof. Decomposition of nitrate ranged from 4 to 10 pet during single-pass steam or air fluidization, respectively. Alumina dust losses and low throughput are significant unsolved problem areas.

Jan 1, 1982

By A. F. Jolly

As a part of ongoing research into the sulfidation partitioning of selected complex minerals, the U.S. Bureau of Mines conducted research designed to selectively recover Cu from sulfidized chalcopyrite (CuFeS2). Ferric chloride (FeCI3) solutions leached >90 pct of the Cu and <20 pct (sometimes < 10 pct) of the Fe in the sulfidized concentrates. Cupric chloride (CuCI2) leaches were even more selective, solubilizing essentially 100 pct of the Cu and < 5 pct of the Fe. In contrast, leaching non-sulfidized CuFeS2 with either FeCl3 or CuCl2 showed that somewhat more Fe than Cu dissolved. These studies demonstrate that Cu is substantially more leachable from sulfidized CuFeS2 than from nonsulfidized CuFeS2? The Cu-and Fe-bearing constituents generated as sulfidation products, CuS (covellite) and FeS2 (pyrite), respectively, are differentially dissolved. The solubility of Fe from pyrite in sulfidized CuFeS2 is much lower than the solubility of Fe from complex nonsulfidized sulfide where Fe and Cu are bound in the same crystal lattice. Thus, the Cu dissolves selectively, producing a high-Cu filtrate from which Cu can be recovered by cementation or by electrolysis. Flotation of CuS-FeS2 mixtures indicates partitioned phases can be physically separated if effective liberation can be achieved. Magnetic separation tests yielded less promising results.

Jan 1, 1991

By Michael J. Gallagher

Diamond-bit performance data accumulated by the Bureau of Mines in core-drilling limestone and dolomite show that the physical characteristics of the diamonds and the sizes and types of bits used are economically significant. An analysis of the data establishes one trend of particular significance to those engaged in core drilling: Bits set with small, low-quality drill bort are the most economical. Detailed analysis of the factors that affect diamond-bit performance, such as size and quality of diamonds, sizes and types of bits, percentage of core recovered, and physical characteristics of bit matrices are assessed in the tables, bar charts, and discussion.

Jan 1, 1958

This part of the final report treats some problems related to coal mine carrier frequency communication systems using the trolley wire/track transmission line. This work was undertaken for a brief period of time during the summer of 1972 to help understand, quantify, and improve some of the trolley wire carrier system behavior observed and/or predicted. Calculations and estimates of transmission line characteristic impedance, inductance and capacitance per unit length, mine motor loading effects, parallel line effects, and connection impedances are presented in Chapter I. Chapter II treats the design of r-f isolators for reducing the undesired and troublesome r-f loading that mine motors present to the trolley transmission line. Chapter III treats a diversity method for combatting standing wave nulls. I. CALCULATIONS RELATED TO TROLLEY WIRE COMMUNICATIONS A. ESTIMATION OF INDUCTANCE AND CAPACITANCE PER UNIT LENGTH OF TROLLEY LINES To estimate the L and C per unit length of trolley lines, we use the eccentric line model of Section G of this Chapter, "Characteristic Imped¬ance Estimates for Mine Trolley Lines." The capacitance per unit length for an eccentric line is given by (1)

Jan 1, 1974

By S. R. B. Cooke

Certain saturated and unsaturated fatty acids and a variety of resin acids were used as collectors for specular hematite, magnetite, and goethite. Vacuum flotation tests were used with each collector and mineral to delimit the fields of flotation and nonflotation as functions of concentrations of collector and of hydrogen ion. The experimental results of these tests lead to the following conclusions. The respective fatty and resin acids exhibit characteristic fields of flotation and nonflotation for the three iron oxides. The fields are somewhat similar, and specular hematite apparently is the most floatable mineral. The insolubility of some of the organic acids may seriously restrict flotation at low pH, although the saturated fatty acids, caprylic and capric, collect minus-100, plus-150-mesh specular hematite only in acid pulp. The presence of a lower "critical pH" is explained on the basis of the dissociation and hydrolysis of dilute soap solutions.

Jan 1, 1959

By G. A. Brady

Seven samples of Pennsylvania anthracite from the Bottom Ross bed were analyzed and tested to obtain data on cleaning characteristics, proximate and ultimate analyses, specific gravity, grindability, heating value, and ash softening temperature. Ash content of the samples varied irregularly from 9.0 to 34.4 percent, the range being narrowed to an upper limit of 14.8 percent ash by removing impurities dense enough to sink in a medium with a specific gravity of 1.90. Ash content of the sink material with specific gravity greater than 1.90 ranged from 56.4 to 80.4 percent; corresponding specific gravities were 2.095 to 2.534. Volatile matter contents were indicated to be higher for the ash-forming minerals than for the pure coal substance in the various specific gravity fractions of a given sample. Specific gravities of anthracites with compa¬rable ash contents but from different locations in the bed varied as much as 0.06. The grindability index increased significantly with increasing ash con¬tent of specific gravity fractions from all the samples.

Jan 1, 1968

By Franklin D. Cooper

This chapter includes tables for 1979 that were not available in time for publication in the 1978-79 Minerals Yearbook, but it does not include corresponding tables for 1980. The value of raw nonfuel mineral output in 1980 was estimated at $24.8 billion, 8.5% above the 1979 value. Of the 21 metal commodities produced, quantitative output increased for 11 and decreased for 10. The values for 10 metals were up, 10 were down, and 1 was unchanged. Among the 47 non-metallic commodities produced, 14 showed quantitative increases, 32 declined, and 1 was unchanged. In terms of value, 32 nonmetallics increased, and 15 declined.

Jan 1, 1981

By Berenice B. Mitchell

THE STATISTICAL tables in this chapter present, country by country, the mineral production of the world in 1949-50. The figures are on a mine basis, unless otherwise indicated, except for cement, coke, and steel, which are measured at the processing plant. The tables are essentially a retabulation, by countries, of the 53 commodity world tables appearing in the various chapters of this volume. For lack of comprehensive information, data for the following minerals are excluded: Andalusite, aplite, asphalt, boron, bromine, calcite (optical), calcium chloride (natural), carbon dioxide, clay, columbium (niobium), diatomite (kieselguhr), dumortierite, emery, garnet (abrasive), gem stones (other than diamonds), germanium, greensand, grindstones, helium, indium, iodine, kyanite, lithium, magnesium compounds (other than magnesite), meerschaum, mineral pigments, monazite, natural gas, natural gasoline, oil shale, olivine, perlite, pumice, quartz crystal, radium, sand and gravel, selenium, sillimanite, sodium salts (other than common salt), stone, strontium, sulfur (byproduct), tantalum, tellurium, thallium, topaz (industrial), tripoli) uranium, vermiculite, wollastonite, and zirconium. In addition, a few minor geographic areas for which no statistics are available, are also omitted from the tabulation; it is believed that no significant quantities of minerals are mined in any of these areas. The statistics in these tables were derived principally from questionnaires sent, in cooperation with the United States Department of State, to the governments of each country. Supplementary sources were United States consular reports, the Imperial Institute&apos;s Statistical Summary of the Mineral Industry of the British Commonwealth and Foreign Countries, other official publications of various countries, the United Nations Statistical Yearbook, the Year Book of the American Bureau of Metal Statistics, Minerais et Metaux, business magazines, and company reports. Where official data were not available, esti-

Jan 1, 1953

By Wallace W. Roepke, Jon I. Voltz

"The Bureau of Mines determined coal-cutting forces and primary dust generation of four styles of radial gage bits as used on end rings of continuous mining machines. Direct comparisons for reference were made with two widely used conical plumb-bob types having 60° and 90° (nominal) included tip angles. The cutting forces for all of the gage bits were similar to those of the 60°-tip plumb-bob bit. All bits except the RAD-3 gage bit generated similar amounts of primary total dust at shallow cutting, but during deeper cutting, the amounts varied and the gage bits produced as much as 2-1/2 times the dust produced by the 60° bit. This seems atypical since past experience has always shown differences in dust generation at shallow cutting. The specific energy was more like that found previously with other bits, since the values were spread at shallow cutting but became nearly similar at deeper cuts. The 90° bit and the RAD-3 gage bit are not recommended for use except in extremely difficult cutting conditions where dust and forces are of secondary importance. The choice among the remaining four bits can be made on the basis of dust, energy, forces, or cost, as circumstances dictate. INTRODUCTIONThe Federal Coal Mine Health and Safety Act of 1969, with revisions in 1977, was enacted to ensure more healthful and safer working conditions for miners. The Bureau of Mines coal-cutting research facility at Twin Cities (MN) is examining fundamental aspects of the cutting system, including generation of primary dust causing pneumoconiosis in miners and ignition of methane by the frictional impact of cutting bits used on continuous mining machines (CMM's). The cutting system is defined as the cutter-mineral interface area with all its variables, e.g., forces, speed, cutter geometry, bit-mounting geometry, and wear. It has become obvious over the past several years that the cutting system directly affects the economics and design of the ""total system,"" which is defined as all areas of the operation, from the mine face to the preparation plant, which support the mineral recovery by cutting tools to obtain a salable product."

Jan 1, 1983

By Michael J. Griffin

Science involves the study of the nature and behaviour of natural things and the knowledge we obtain about them. Scientific endeavour leads to the unfolding of new knowledge and adjustments to our understanding and our behavior. To indicate that we ‘know’ something may merely mean we do not feel able to, or that we do not wish to, disagree with others who claim to know; or it may mean we have either heard about it, or studied it, or understand part of it, or accept that it is true, or have seen evidence to be convinced of its veracity. What do we ‘know’ about the health effects of vibration? There are many unknowns in the field of human responses to vibration. Not all would agree on what is known and what is unknown. This paper seeks to summarize what we know that we know, what it is sometimes claimed that we know, and what we know that we do not know about the relation between exposures to vibration and our health. It also speculates on what we do not know that we do not know. Hand-transmitted vibration What we know we know We know that exposures to hand-transmitted vibration result in various disorders of the hand, including abnormal vascular and neurological function. Not all frequencies, or magnitudes, or durations, of hand-transmitted vibration cause the same effects. What we may claim to know To enable exposures to be reported and compared, they are ‘measured’ and ‘evaluated’ using defined (e.g. standardised) procedures. This involves identifying what is to be measured and specifying how it is expressed by one (or a few) numbers. Summarising a vibration exposure in a single value involves assuming the relative importance of components within the vibration (e.g. different magnitudes, frequencies, directions, and durations), so standards define ‘weightings’ for these variables. The importance of the weighted values may also be suggested, allowing ‘assessments’ according to a criterion (e.g. the probability of a specific severity of a specific disease). Standards for the measurement and evaluation of hand-transmitted vibration define a frequency weighting and time dependencies that allow the severity of vibration exposures to be assessed and the probability of finger blanching to be predicted 1. What we do not know We do not know that the frequency weighting in current standards reflects the relative importance of different frequencies and axes of vibration in producing any specific disorder. We do not know whether the energy-based daily time-dependency inherent in A(8) reflects the relative importance of vibration magnitude and daily exposure duration. Consequently, the relation between A(8) and the years of exposure to develop finger blanching, as in an appendix to ISO 5349-1 (2001), is not well-founded. We do not know, or at least there is no consensus on, the full extent of the disorders caused by hand-transmitted vibration (e.g. vascular, neurological, muscular, articular, central), or the pathogenesis of any specific disorder caused by hand-transmitted vibration, or the roles of other factors (e.g. ergonomic factors, environmental factors, or individual factors). We know that acute

Jan 6, 2006

By Larry G. Stolarczyk

This report deals with the creation of an efficient method to determine if command, control, communication and monitoring (3cm) equipment in coal, metal and non-metal mines is susceptible to Radio Frequency Interference (RFI) from the Medium Frequency (MF) radio communications system. A qualitative and quantitative RFT test plan was developed for in-mine and laboratory evaluation of the equipment. The laboratory testing was accomplished using the TEM Test Chamber. Detailed information on the Test Plan and the TEM Test Chamber is included. During in-mine testing of the MF System some underground equipment malfunctioned when the transmitter&apos;s radiating antenna was in close proximity. Electromagnetic Compatibility (EMC) testing was done on three levels; Component (circuit or box), subsystems and system. Nine tables are included which show the results of testing various equipment for RFI.

Jan 5, 1986

By G. E. Walden

The Bureau of Mines is currently engaged in a continuing investigation of the thermodynamic properties of certain inorganic compounds. As a part of this investigation, the heat contents of bismuth and cerous chlorides were measured throughout the temperature ranges of 370° to 630° K. and 370° to 1,200° K., respectively. Equations representing heat contents as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate heat contents at selected temperature intervals ranging from the ice point to 650° K. for bismuth chloride and to 1,200° K. for cerous chloride; also, the heats of fusion of both compounds were calculated at their respective melting points. EXPERIMENTAL Materials The cerous chloride used in this investigation was supplied by the National Carbon Company of Cleveland, Ohio. A chemical analysis indicated Ce 56.57 percent and Cl 43.39 percent. No attempt was made to purify the compound or identify impurities since the analysis showed only about 0.04 percent total impurities. Reagent grade bismuth chloride was used without additional purification.

Jan 1, 1961

By Wallace W. Roepke

The Bureau of Mines has a well-established health and safety research effort directed to fundamental studies of the mine cutting system. This report describes the ignition danger of using cutting bits with flat wear area on still-intact carbide inserts.

Jan 1, 1983

By T. W. Beck

The National Institute for Occupational Safety and Health (NIOSH) conducratory and field tests to evaluate the effectiveness of dust collector bags for reducing dust liberation and operator exposure from a roof bolter’s dust collection system. The laboratory tests evaluated the bag’s effectiveness to contain dust and the effect on canister filter loading in both a bag and bagless condition. The dust emissions from the collector’s exhaust were also measured in each condition during laboratory testing and show that nearly 100% of the test dust fed into the collector was captured by the dust bags. Loading and pressure drop on the dust collector’s canister filter is greatly decreased when using the bags, enabling longer periods of drilling without filter removal/cleaning. The field results showed that, even though dust standards were met, respirable dust in exhausted emissions was reduced around the bolter. Laboratory and field results show that benefits from use of the bags are realized in all areas of operator exposure.

By H. J. Heinen

Excellent gold recovery was demonstrated in a laboratory-scale leaching test on waste material from an open-pit mine in northeastern Nevada. An injection system of leaching was applied in which the sodium cyanide solution was introduced into the interior of the dump at selected points. Dissolution of gold from the waste material, which assayed 0.06 ounce gold per ton, was readily achieved because the gold occurred as submicroscopic particles in a porous host rock. Gold recovery of 80 percent was obtained in 11 days from material crushed to 1 inch in size, and recovery was 90 percent after 21 days.

Jan 1, 1969

By Donald O. Capstick

In 1481, U.S. Bureau of Mines personnel conducted a survey of mines, prospects, and mineral resources in the Table Mountain RARE II area. There are no mines or active prospects in the study area. One prospect in the study area, the Waterfall Prospect, is estimated to contain 480 tons (440 t) of indicated subeconomic tungsten resources averaging about 0.18 percent tungsten trioxide (W03). Other tungsten occurrences are at the Stevens Prospect, just northwest of the area. Stone and sand and gravel deposits in the area are not considered to be resources because equal or better quality material is available closer to major markets. INTRODUCTION The 4,400-acre Table Mountain study area is 13 mi (21 km) southwest of Bishop, California, on the eastern flank of the Sierra Nevada range. The John Muir wilderness adjoins the study area on the southwest (fig. 1).

Jan 1, 1982

By E. G. King

THIRD-LAW entropy data for zirconium-containing compounds are sparse. Kelley a lists entropies at 298° K. for the oxide, tetrachloride, nitride, and silicate, as well as for the metal. The present paper presents heat capacities between 51° and 298° K. and entropies at 298.15° K. for the zirconates of the alkaline-earth metals-calcium, strontium, and barium. The authors believe magnesium zirconate does not exist as a stable compound at room temperature. Entropies of formation from the constituent oxides also are given. MATERIALS The materials used in this investigation were synthesized and analyzed in the Berkeley Laboratory of the Bureau of Mines. Calcium zirconate was prepared by heating an intimate mixture of reagent-grade calcium carbonate and pure zirconia for 30 hours between 1,200° and 1,300° C. and for 32 hours between 1,400° and 1,500° C. As part of the heating schedule, the sample was ground and mixed seven times. Periodic analyses and minor adjustments of composition were made. Analysis of the final product gave 31.19 percent calcium oxide (theoretically 31.28 percent) and 68.67 percent zirconia (theoretically 68.72 percent). The X-ray diffraction pattern agreed with that in the ASTM catalog.

Jan 1, 1960

By E. C. Perkins

This report describes a ferric chloride trap, based on formation of a low-melting sodium chloride-ferric chloride mixture of near-eutectic composition, and its use in chlorination of impure titaniferous materials. The trap is placed in the hot gas stream between the chlorination reactor and the condenser. Virtually all of the iron is removed by the trap. The condensed titanium tetrachloride is free of suspended solids and contains only a trace of iron. Four examples are given of the use of the ferric chloride trap in chlorination of impure titaniferous materials. INTRODUCTION In the Kroll process, ductile titanium metal is produced by reducing titanium tetrachloride with magnesium metal.4/ In commercial practice, titanium tetrachloride is produced by chlorinating titaniferous materials in the presence of carbon.2/ In 1957 most producers were using rutile, and virtually all plants were designed for its use. About four-fifths of the domestic consumption of rutile was imported from Australia. The Bureau of Mines, under provisions of contract DMP-116 with the General Services Administration, studied electrosmelting of domestic ilmenites and titaniferous magnetites to produce high-titanium slags with pig iron as a byproduct. Under the same contract, chlorination studies also were being made of these slags. Smelting was done at the Northwest Electrodevelopment Experiment Station, Albany, Oreg., and chlorination at the Electrometallurgical Experiment Station, Boulder City, Nev.

Jan 1, 1958

By E. G. King

In continuation of the study of thermodynamic properties of the common interoxidic compounds of ferroalloy elements, this report gives the results of low-termperature heat-capacity measurements and entropy evaluations of the monotungstates of sodium, magnesium, and calcium. Previous reports4 5/ of this laboratory dealt with low-temperature heat capacities, entropies, and heats of formation of the sodium vanadates. Heat-capacity measurements of the monotungstates of sodium, magnesium, and calcium (Na2W04, MgW04, and CaW04) were conducted throughout the temperature range 51° to 298° K. The entropies at 298° K. were evaluated and then combined with entropy data for the elements and oxides to obtain entropies of formation. This information is an essential part of the data needed for thermodynamic appraisals of chemical reactions of these substances. No similar data for any tungstate are to be found in the literature.

Jan 1, 1961