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By T. A. Gray, L. M. Crayne, P. Glogowski, Trevits. M. A.

Of the 19 major mine fire events (including thermal events) that have occurred in the last 6 years (2000-2005), it is estimated that remotely constructed mine seals could have been used at 65% of the events to control or suppress the fire. Underground observations of seals that have been remotely installed during mine fire events show that they often do not fully achieve mine roof-to-floor and rib-to-rib closure. Unfortunately, the inability to reliably close the mine void has limited or precluded the regular use of this technology. The National Institute for Occupational Safety and Health is conducting full-scale underground experiments at the Lake Lynn Experimental Mine to identify and remedy existing remote sealing technology shortcomings, to develop novel technologies, and to transfer the new or improved technologies to the mining industry. This paper will discuss the remote mine seal testing program and will provide the results of the in-mine experiments. Disclaimer: The findings and conclusions in this report are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health.

From the National institute for Occupational Safety and Health Disasters take many forms and demand quick response from emergency workers. They may include natural disasters such as earthquakes or hurricanes, or they may involve manmade disasters such as technological failures or terrorist attacks. As a member of an emergency response team, you and your team members are at risk of experiencing what psychologists refer to as a traumatic incident—an incident that may Involve exposure to catastrophic events, severely injured children or adults, dead bodies or body parts, or the loss of colleagues, for instance. Traumatic incidents can produce unusually strong emotional reactions that may interfere with your ability to function at the scene or later: You may experience any of the physical, cognitive, emotional, or behavioral symptoms listed below in Table 1. Some people experience emotional aftershocks weeks or months after they have passed through a traumatic event. Others may experience these reactions while still at the scene, where they must stay clearly focused on constantly changing hazards to maintain their own safety and to rescue injured victims.

By V. A. Nieberlein

This paper presents the results of research undertaken to recover titanium and columbium by low-temperature chlorination of low-grade columbium-bearing ilmenite concentrates, and to simultaneously remove chlorinated impurities from the volatile chlorides without resort to distillation. Coke-reduced ilmenite was chlorinated at 400° to 500° C., and the resulting TiC14 was free of most impurities before condensation. A heated purification column was used wherein various packing materials reacted chemically or physically with the impurities which passed through them in the vapor phase. A nearly water-white TiC14 product was obtained directly. The principal impurities in the titanium tetrachloride were: 0.02 percent Fe, 0.01 percent V, 0.05 percent A1, 0.04 percent Si, and 0.07 percent Cb. This is a less pure product than commercial TiC14. Most of the columbium was recovered as crude CbC15, requiring further refining.

Jan 1, 1960

By W. J. Fene, H. B. Humphrey, J. J. Forbes

"INTRODUCTION Loss of life from coal-mine explosions in the United States in 1949 was the lowest in any year since before 1870. Although fatality reports from coal nines before 1910 were incomplete,' the explosion fatalities from single disasters or individual States exceeded the 1949 total in each year as far back as 1870, when the records become fragmentary. Since 1890, the only other year in which fewer than 35 were killed was 1946, with a total of 32. Figure 1 shows the total yearly fatalities from explosions in all coal mines and those in anthracite mines alone since 1870. The fatalities in bituminous coal mines were not completely reported before 1910, but enough reports were issued by major coal-producing States to compile reasonably representative figures back to 1885. Any corrections would be additions to these totals.The reason for the moderate total of 46 explosion fatalities in 1948 and the low total of 8 killed in 1949 is thought to be the serious and careful attention devoted to elimination of coal-mine explosion hazards after the disastrous explosions in 1947. The standards now being observed generally with respect to ventilation, rock-dusting, and inspections for gas are better than those found earlier in even the mines having the best reputations for safety. Exceptions are still numerous, but they are fewer, month by month, because of the pressure of Federal and State inspections and a changing conception of the hazards that should not be permitted underground. The prevailing precautions have not eliminated all ignitions of gas or dust, but they have limited propagation to small explosions and have prevented serious loss of life.The number of ignitions (14) reported for the year was less than the average (24) for the 5 years 1944-48 and only half the average for the fiscal years 1929-44. Another favorable factor is that Bureau of Mines representatives were probably in closer contact with both small and large mines in nearly all coal-mining districts. Inspectors now assigned to individual districts are better able to keep informed on the happenings and the progress of safety in their districts. In 1948, one-fourth of the explosions were in mines that employed fewer than 10 men; this condition was duplicated in 1949."

Jul 1, 1950

By M. R. Geer

The washability examination of a coal establishes the quality of the product that could be prepared by mechanical cleaning, shows how much impurity would have to be eliminated to attain a particular quality of product, indicates what type of cleaning process would be suitable, and tells whether the coal could be cleaned efficiently, The coal-preparation laboratories of the Bureau of Mines make washability examinations of coal for a variety of purposes. Sometimes these examinations are made as an integral part of research conducted on coal-washing problems. Occasionally they are made on coals mined on Government-owned land or on coals destined for use in Government installations. Often they are made on coals from new fields or new beds in existing fields to help establish the characteristics of the Nation's coal reserves. Whatever the original reason for doing the work, the results often are useful later in evaluating deposits or in the design of cleaning plants. Publication of the results of such studies provides for the widest possible usefulness. This report brings together the results of washability examinations made on 1 coal each from Oregon and Idaho, 2 from Wyoming, 5 from Utah, and 11 from Washington. Material of this nature is inherently difficult to summarize. Some of the coals are so clean} despite full-scam mechanical mining, that they could not be improved materially by washing; others present some of the most difficult preparation problems found in the country.

Jan 1, 1961

By O. C. Baptist

The gravitational pressure gradient (GPG) in porous sandstone containing free gas was determined to define the proper GPG to use when calculating the rate of downdip flow of oil in the Sub-Scalez No, 1 sand, Elk Hills field, Naval Petroleum Reserve 1. The GPG was determined at several gas saturations using long, artificially consolidated sandstone models that were mounted vertically in some tests and horizontally, with rotation, in others. Also determined by laboratory and field tests were relative permeabilities, capillary pressure relations; critical gas saturation, water sensitivity, and depletion drive performance. The critical gas saturation in the models having an absolute permeability of 1 to 2 darcys was about 2 percent of pore volume. The GPG with the critcal gas saturation was that due to the weight of the gas-saturated oil. The GPG in the upper part of the models was reduced as gas saturation increased to a value considerably larger than the critical. The exact gas saturation at which the GPG became less than that due to the weight of the oil could not be determined but was estimated to be of the order of 10 percent of pore volume. Tests indicate that the rate of oil production is not permanently reduced by exposure of the sand to fresh water but that the rate of injection of fresh water will be considerably less than that to brine, Methods for determining the factors mentioned above are discussed.

Jan 1, 1967

By Charles C. Boley

The Bureau of Mines dried and carbonized two wood wastes, one softwood (redwood) and one hardwood (oak), using continuous, vertical entrainment techniques previously developed for use with coal. It was demonstrated that these techniques are readily applicable to wood waste and that appreciable changes in the yields of carbonization products can be obtained by varying operating conditions. A limited amount of experimental work was done on briquetting the char-coals. Firm briquets were formed with oak charcoal, although greater quantities of starch binder than used commercially for kiln-produced charcoal were required. Redwood charcoal did not briquet successfully under the test conditions employed.

Jan 1, 1969

By Stephen D. Cramer

The solubility of methane, carbon dioxide, and oxygen was measured in brines at temperatures from 0° to 300° as part of Federal Bureau of Mines research on the corrosion of metals in high-temperature geothermal and mineral processing environments. Solubilities were measured by the technique of extracting pure gas, dissolved at pressures where Henry's law was applicable, from known volumes of brine. The results were smoothed with respect to temperature. The solubility, expressed in terms of the Henry's law constant, reaches a maximum at temperatures ranging from 60° to 100° C for methane and oxygen, and from 160° to 170° C for carbon dioxide. The Henry's law constant increases, that is, gases are salted out of the brines, in the presence of dissolved salts. Salting-out coefficients are strongly dependent upon temperature. The temperature dependence of the Henry's law constant for geothermal brines is different from that for sodium chloride brines owing to the more complex chemistry of the geothermal brines. The solubility of oxygen and carbon dioxide in brines exposed to air saturated with water vapor and at a total pressure of 760 mm Hg is reported for temperatures from 0° C to the normal boiling point.

Jan 1, 1982

By Michael S. Wieland

Recognizing the dynamic nature and possible range of toxic concentrations in the impending fume cloud prior to undertaking explosive blasting can reduce potential hazards and mitigate related incidents. The scaled cloud model was formulated to predict the relevant (major) toxic components in fume clouds released by nonideal mining explosives used for surface blasting. Natural turbulence unceasingly disperses the toxic molecules, widening (inflating) the fume cloud while diluting the concentrations, ultimately rendering nonhazardous conditions. The threshold cloud size depends upon the type and quantity of total explosives used and the cloud's thermodynamic condition. Though the scaled theory works for fume clouds with irregular (odd) shape, an equivalent upright cylindrical form is useful for rendering simple riskhazard scenarios. The cylinder's projection downward on the underlying terrain yields a circular 'shadow' marking the region threatened, thereby permitting a rough estimation of the potential hazards, were the cloud to settle down there. Wind causes the cloud to drift while it expands, so the shadow travels while it grows, until the risk hazard process is truncated at the nonhazardous threshold. The overall relative fume toxicity (RFT) is taken from the traditional Russian RFT rule, which utilizes only the two fume components that tend to dominate the resultant toxicity: carbon monoxide (CO) and total nitrogen oxides (NOx). Tabulated constants that characterize the fume spectrum in the cloud model were resolved for ammonium nitrate (94%) with fuel oil (6%), ANFO-94/6, using a refined thermodynamic work-principle. Comparable results were found with the reduction factor technique, when test results from the underground fume chamber were readjusted to reflect nominal field shooting conditions.

By Isaac A. Zlochower, Kenneth L. Cashdollar

The Pittsburgh Research Laboratory of the National Institute for Occupational Safety and Health conducted a study of the explosibility of various metals and other elemental dusts dispersed in air, with a focus on the experimental explosion temperatures. The data are useful for understanding the basics of dust cloud combustion, as well as for evaluating the explosion hazards in the minerals and metals processing industries. The dusts studied included boron, carbon, magnesium, aluminum, silicon, sulfur, titanium, chromium, iron, nickel, copper, zinc, niobium, molybdenum, tin, hafhium, tantalum, tungsten, and lead. The dusts were chosen to cover a wide range of physical properties - from the more volatile materials such as magnesium, aluminum, sulfur, and zinc to the highly "refractory" (very low volatility) elements such as carbon, niobium, molybdenum, tantalum, and tungsten. These flammability studies were conducted in a 20-L chamber, using strong pyrotechc ignitors. The experimental data obtained included the minimum explosible concentrations, maximum explosion pressures, and maximum explosion temperatures. A unique multiwavelength infrared pyrometer was used to measure the temperatures. For the elemental dusts studied, all ignited and burned as air-dispersed dust clouds except for nickel, copper, molybdenum, and lead. The measured maximum explosion temperatures ranged from -1 550 K for tin and tungsten powders to -2800 K for aluminum, magnesium, and titanium powders. The measured temperatures are compared to the calculated, adiabatic flame temperatures. In general, the dusts whose experimental temperatures were closer to the adiabatic values were those with the finer particle sizes, those that were more easily vaporized, and/or those that were intrinsically more reactive.

This chapter describes the adverse health effects associated with exposure to respirable coal mine dust. Epidemiological studies of underground and surface coal miners in the United States and other countries are discussed. Also discussed are animal studies that add to our understanding of particle deposition and retention in the lungs and associated disease responses. This chapter emphasizes studies that (1) were performed since the passage of the Federal Coal Mine Health and Safety Act of 1969 [P.L. 91- 173], (2) used standardized methods of exposure monitoring and disease classification, and (3) investigated exposure-response relationships between respirable coal mine dust exposure and disease. Several published review articles contain further discussion of health effects studies of coal miners [Attfield and Wagner 1992b; Petsonk and Attfield 1994; Cotes and Steel 1987; Merchant et al. 1986; Morgan and Lapp 1976; Morgan 1975].

Jan 1, 1997

By Sam Friedman

The Bureau of Mines conducted experiments using bench-scale apparatus to explore the effect of large changes in process variables on the yield and composition of the gases produced by passing 800° C steam through a fixed bed of Pittsburgh seam (hvab) coal. The total yield of combustible gases increased throughout the given range for the following variables: Superficial steam velocity increasing from 0.02 to 0.12 fps, pressure increasing from 1,000 to 6,000 psig, residence time increasing from 0 to 60 minutes, and temperature increasing from 800° to 900° C; however, a greater increase in the yield of hydrogen in comparison with the increase in yield of methane reduced the gross heating value of the gas to around 470 Btu per scf at conditions giving the maximum yield. Pressures of 1,000, 3,000, and 6,000 psig at 0.09 fps steam velocity, 800° C, and 60 minutes residence time, respectively, produced methane yields of 20, 24, and 22 percent, based on maf coal, with the gross heating value of the CO2-free gas decreasing from 552 to 520 and to 470 Btu per scf. Methane concentrations in the CO2-free gas were 26, 22, and 14 percent, respectively. Based on the gross heating value of the coal, the percentage of the heating value recovered in the gas was 60, 71, and 87 percent, respectively. The use of tungsten sulfide as a catalyst for converting carbon oxides and hydrogen into methane was explored briefly using both a sulfur-free gas rich in methane and a sulfur-bearing synthesis gas (3H2:1CO).

Jan 1, 1968

By J. E. Zeilinger

This Bureau of Mines report describes the preparation characteristics of the significant coalbeds of Clarion County, Pa. Of the 15 samples collected, 1 was of metallurgical quality as received, 4 could be sufficiently upgraded to provide acceptable products, and the remaining 10 samples could not be upgraded to metallurgical quality because their sulfur contents could not be lowered to meet the standard. For steam or power generation, 1 sample was of low sulfur content as received, 1 sample could be upgraded to low sulfur content, and 10 samples could be upgraded to medium sulfur content. The original sulfur content of the remaining three samples can be appreciably reduced by removal of the sink 1.58 specific gravity material; however, these coals would be classified as medium sulfur coals both before and after removal of the sink material.

Jan 1, 1968

By H. C. George

This report presents a comprehensive tabulation of lifting cost data collected from oil companies in many different fields. These data were collected during the writer's studies of surface equipment and methods of pumping oil wells, in practically all of the important oil fields in the United States and are based on average operating conditions at 57 groups of properties with a total of 4,497 producing wells. Although lifting cost is only a part of the total cost of producing oil, it nevertheless gives a representative cost figure for purposes of comparison.

Jan 1, 1923

By W. M. Myers

[The principle of the application of electrolytes for deflocculation of fine materials in order that impurities may settle out, and the subsequent flocculation of the suspended particles by a different reagent, is well known and has been applied successfully to clays. Flocculation is also applied with success to ore slimes. Thus certain electrolytes, particularly alkalies added to a suspension of colloidal particles cause deflocculation so that, suspension may be-maintained indefinitely. The addition of bother electrolytes particularly acids, on the contrary produce's flocculation and the articles produce's are rapidly precipitated from suspension leaving a clear liquid above: the precipitated mass. Salts of trivalent elements such as aluminum act similarly. Due to its cheapness the double sulphate of aluminum and potassium, ordinary alum, has been used extensively for treating clays. These properties of electrolytes. and. their utilization in the commercial: preparation of clays have been described in publications of the Bureau of Mines.2]

Jan 1, 1927

By R. E. Brown

The objective of this Bureau of Mines study was a laboratory-scale evaluation of the sodium sulfate refining process for removing copper from molten ferrous scrap. Maximum copper removal is achieved in carbon-saturated melts at 1,300° C. Low carbon concentrations and higher temperatures result in a less efficient copper removal and an increased sulfur concentration in the iron. Sodium sulfate refining significantly lowers the concentration of aluminum, manganese, and silicon; however, the copper removal efficiency is adversely affected by the presence of manganese and silicon. Compared with other reagents tested, sodium sulfide-forming slags were found to be the most suitable for both copper removal and sulfur control. The sulfur content of the refined iron was higher in tests conducted in acid-type refractory crucibles. Earlier studies showed that tin, a significant metallurgical impurity, is not removed by the sulfate process. During the present investigation, results showed that chlorination, using organic solid sources of chlorine, reduced the tin concentration to acceptable levels in molten iron.

Jan 1, 1975

By Lloyd A. Morley, Alan M. Christman

Introduction A wealth of information exists which deals with electrical grounding, both from a general viewpoint and from a specifically mine-oriented approach. Many parameters must be investigated in order to thoroughly cover all of the variables which govern the performance of electrical grounding systems. The emphasis of this work on open-pit practices re- presents a new development in the field of grounding research, and an exhaustive review of the relevant historical documentation is especially desirable. Grounding System Purposes What purposes are served by a grounding system? The answer is four-fold and may be summarized as follows. First, it must limit potential gradients between conducting materials in a given area (56). When a phase conductor comes into contact with a machine frame, current flows through the equipment, which tends to become elevated above ground by an amount equal to the voltage on the conductor. If a man were to touch the machine while he was simultaneously connected to ground in some manner, his body would also tend to become elevated in potential, possibly to a lethal extent. Thus, the grounding system should provide a low- resistance path for the fault current to return to the source. The maxi- mum potential to which a man could be exposed when touching a machine frame is equal to the voltage drop along the ground conductors inside the power cable, as shown in Figure 1 (54). The ground conductors, therefore, (page # 96 is missing from the original document)

Jan 1, 1976

By Gregory M. Molinda

The Bureau of Mines conducted an investigation into the occurrence of outbursts of salt known to be responsible for explosions, fatalities, and damage in domal salt mines. The purpose of the investigation was to develop a basis for predicting these outbursts based on geologic and associated physical properties of salt. The investigation was conducted at the Cote Blanche salt mine in southern Louisiana. Because outbursts are the primary mode of methane emission into the mine, more than 80 outbursts, ranging in size from 1 to 50 ft in diameter have been mapped. These outbursts generally are aligned and elongate parallel to the direction of salt layering. More than 200 salt samples, both random and selected, were tested for methane content. It was found that outburst zones are well correlated with high methane content. Detailed mapping also revealed that the zones are well defined, with salt crystal size abruptly increasing upon entry into the zone. The intensity of folding and kinking of the salt layering within the outburst zone also appears to increase. An interbedded sand layer occurring throughout the mine does not appear to be a significant source of methane. However, fine-grained salt may be related to outburst occurrence.

Jan 1, 1988

By R. L. Anderson

Mechanical cleaning of bituminous coal in the United States was begun about 1875, with plants in western Pennsylvania and Illinois. The United States Geological Survey began to record the quantity of washed bituminous coal in 1906; and the series was carried forward to 1923, except that no data were collected, for 1922. This statistical work was transferred to the Bureau of Mines in 1925, and the collection of data on mechanical cleaning was resumed in 1927. Data collected before 1927 include only the coal that was washed at the mines and do not include that cleaned by pneumatic methods at the mines and that cleaned at central washeries operated by consumers.2/ The total bituminous coal washed in 1906 was less than 10 million net tons. In 1927, the first year for which complete figures are available for all types of mechanical cleaning, 28 million net tons of bituminous coal were cleaned in the United States.

Jan 1, 1951

By David M. Hopstock

To help assure an adequate supply of minerals to meet the Nation's economic and strategic needs, the Bureau of Mines is conducting bench-and pilot-scale research using wet high-intensity magnetic (WHIM) separation to recover iron from oxidized taconites of the. Lake Superior region. The advantages and disadvantages of WHIM separation in relation to other separation methods, the most recent innovations in WHIM flowsheet design, and the role of mathematical models in process optimization are discussed.

Jan 1, 1979