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By V. R. Miller

The Bureau of Mines has developed a technique to separate and recover the three major components, Pb, Zn, and Cd, from lead smelter flue dust. This research was conducted as part of the Bureau's effort to reduce environmental conflicts and occupational hazards associated with mineral-processing operations and to recover valuable constituents in emissions and effluents. The laboratory process utilizes sulfation roasting of the flue dust followed by water leaching to extract over 95 pct of the cadmium and zinc. Ninety-nine percent of the cadmium was recovered from solution by cementing with zinc dust, and zinc was electrowon from the resulting solution after purification. Zinc electrolysis was carried out in a 1-liter cell at 35° C with a cathode-current density of 8 A/dm2 in a solution containing 65 g/l Zn++ and 180 g/l H2S04, Current efficiencies of 80 pct were obtained. The leached residue consisted largely of PbS04, which was converted to PbC03 and leached with H2SiF6 to produce PbSiF6 electrolyte. Ninety-five percent of the lead contained in the residue was converted to electrolyte. Lead was electrowon from solutions containing 70 gil Pb++ and 90 g/l H2SiF6 using a lead cathode, Pb02-coated titanium anodes at 28° C, and a current density of 1.6 A/dm2. Current efficiencies approaching 92 pct were obtained. Accessory minerals such as cobalt and nickel were separated into purification residues and liquor.

Jan 1, 1982

By Eliot J. White

The physical properties and clay mineral content of the major oil-producing formations in the Powder River Basin of Wyoming were determined by analyses of cores from 100 wells. Interrelationships were established among permeability, restored water saturation, clay content, and bulk swelling capacity of the crushed sample and used to estimate the susceptibility of the formations to water damage. The ratio of water permeability to gas permeability (kw/ki) offers a convenient scale for semiquantitatively estimating the water sensitivity of sands. The irreducible water saturation was also found to have a similar relationship to the clay mineral content and the water sensitivity of the sands. The average relation of water permeability to gas permeability is different for each sand, as shown by the curves, and the relative positions of the curves indicate the degree of water sensitivity of each sand from which the susceptibility to water damage may be estimated. How accurately these estimates show formation behavior under field operations will not be known until studies of field performance can be made. The water permeabilities of the Muddy, Minnelusa, and Tensleep sands average about the same as the gas permeabilities, and these sands are classified as insensitive. The water permeabilities of the Sussex and Shannon sands, at the other extreme, are much less than the gas permabilities [when average ki is 30 millidarcys (md), kw is 6.1 md], and these sands are classified as highly water sensitive. The sensitivities of the five other sands are between these extremes.

Jan 1, 1962

By J. P. Conway

The yielding-rock-bolt concept, as developed in South Africa, consists of a smooth-bore die or collar fitted to a standard rock bolt. Laboratory testing at the Bureau of Mines Spokane Mining Research Center under slow and fast strain rates showed that extrusion loads can be controlled by varying the configuration of the die bore and that theoretical analysis (using basically Sachs' theory of wire drawing) predicts extrusion loads of the different die-bore configurations. A derived equation, based on this research, can be used for designed die-thread combinations for any desired extrusion load. Dynamic loading resulted in slightly higher loads (15 percent) than static loading. The strain hardening effect, which increases yield and ultimate strength, was partly offset by adiabatic heating of the threads, which decreases strength.

Jan 1, 1975

By J. J. Cummins

The Bureau of Mines heated at 150° to 350° C for 0.5 to 360. days Green River oil shale that had been previously extracted by benzene to provide information on in situ processing conditions, to determine the effect of low-temperature heating on the unconverted kerogen, and to determine the composition of benzene-soluble thermal products. The methods used in determining the composition of the soluble thermal products consisted of fractionation of the soluble material, elemental analysis of the soluble products, fractionation of the polar resins by ion-exchange chromatography, gas chromatographic analysis of [n]-alkanes3 and mass spectral analysis of the branched plus cyclic alkanes and aromatic oils. The methods used to determine the effect of low-temperature heating on the unconverted kerogen remaining in the oil shale heated residues consisted of carbon-hydrogen analysis, volatile material determination, carbon residue determination, and oxidation rate determination. In general, it was concluded that significant increases in the degradation of kerogen to oil occurred between the temperature range of 250° to 350° C; that the composition of the soluble products depends upon the temperature at which they are formed; and that the [n]-alkanes are pyrolytically degraded from the kerogen structure. In particular, the 250° C heating temperature is beneficial to the formation of branched plus cyclic alkanes. Also, the heated and unconverted oil shale kerogen and the soluble thermal products become more aromatic as the temperature increases from 150° to 350° C.

Jan 1, 1974

By P. W. Jeran, S. J. Pepperney, M. C. Irani, F. F. Kopsch

The Bureau of Mines has designed and put into operation a fail-safe control system for use in underground coal mines equipped with methane drainage pipelines. This control system can detect certain unsafe conditions and respond by automatically shutting off the flow of methane from the degasification borehole to the drainage pipeline. Methane flow is shut off when the methane content in the return airways reaches a predetermined level (typically 1.5 pct), when the methane drainage pipeline is ruptured by roof fall, or when there is an electric power failure. The fail-safe control system was designed using commercially available components and a methane analyzer system previously developed by the Bureau. The fail-safe system consists of a unit that combines a shutoff valve and pneumatic valve actuator, and electronic and mechanical equipment designed to detect hazards and effect shutdown. The fail-safe control system was designed to meet regulatory requirements issued by the Mine Safety and Health Administration (MSHA), U.S. Department of Labor, and State regulatory bodies for the safe operation of underground methane pipelines used for mine degasification. MSHA has inspected and tested this system and permitted its use in two mines. The Bureau installed the fail-safe system in two working coal mines, where successful performance has been demonstrated.

Jan 1, 1980

By C. H. Elder, M. C. Irani

Two degasification test boreholes were drilled to depths of 1,238 and 1,212 feet on Bureau of Mines property at Bruceton, Pa., as part of the Bureau's long-range coal degasification program. The holes provided detailed geologic information and geologic sections, which were correlated with regional stratigraphic cross sections prepared by the Pennsylvania Geological Survey. Gas content determinations and coal analyses were made on the Upper Freeport, Middle Kittanning, Clarion, Brookville, and Mercer coalbeds; gas content of the coalbeds ranged from 53 to 165 cubic feet per ton. Formation pressure and gas flow tests were conducted on selected coalbed intervals in borehole 1; formation pressures ranged from 292 to 473 psig. The middle Kittanning coalbed was hydraulically stimulated using very heavy gelled water, but gas production remained low because gel residue and formation water inhibited the flow of gas. Gas contents in the Clarion, Upper Brookville, and Mercer coalbeds were anomalously low owing to the proximity of porous sand- stones which act as reservoirs for gas migrating from coalbeds.

Jan 1, 1977

Provide a simple and effective means of measuring mining-induced pressure changes in coal mine roof and pillars. Approach Develop a reliable, easy to fabricate and install borehole instrument which measures mining-induced pressure changes in pillars and in the mine roof. Ground pressures are monitored through use of aluminum platens coupled with d copper flat jack. How It Works The Bureau's instrument measures mining-induced pressure changes by transmitting strata pressure through the aluminum platens to an oil-filled borehole platened flat jack (BPF). Pressure in the flat jack is displayed on a gage located outside of the borehole. The instrument is in-stalled in the borehole by inflating the flat jack using a hand-held hydraulic pump. In addition, the platens have been designed to allow up to three BPFs to be installed in a single borehole, thus permitting pressure change measurements in more than one direction from a single borehole. Installation pressure is calculated on the basis of the estimated pressure exerted by the overburden and the percent of recovery after intial mining has

Jan 1, 1986

By W. E. Anable

A 180° magnetic deflection residual gas analyzer mass spectrometer with a mass range of 2 to 200 amu was used to study the nature of gases evolved during arc and electron-beam melting of certain reactive and refractory metals. The partial pressure of residual gases over molten Mo, Hf, Ti, and Fe, was found to be similar: Water and hydrogen were evolved from the samples and from the furnace components, carbon dioxide and carbon monoxide resulted from deoxidation of some of the melts. Argon and acetone were residuals in the system, and methane was a decomposed organic compound from the oil diffusion pump.

Jan 1, 1969

By C. Stephan, E. Weiss, J. Trackemas, M. Sapko

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Laboratory (PRL), in collaboration with the Mine Safety and Health Administration (MSHA), the mining industry and seal manufacturers, conducted a series of full-scale experiments within the underground experimental mine at PRL's Lake Lynn Laboratory. The purpose of the experiments was to evaluate the explosion-resistant characteristics of several new seal designs for rapid deployment during mine emergencies. These seals can be deployed in less than 12 hours and are capable of withstanding explosion overpressures in excess of 140 kPa (20psi). These novel seal designs use available mine materials, do not require conventional rib hitching and, most importantly, can substantially reduce exposure time for coal miners during sealing and mine recovery operations.

Compare the dust control efficiency and bit life of surface coal mine drills using standard water injection and water injection with water separation. Approach A research study was conducted to determine if a water separation technique affects wet suppression dust control. Dust control efficiency and bit life of surface coal mine drills were compared during tests using both standard water injection (wet drill bit cutting) and water injection with water separation (dry drill bit cutting). Background Surface coal mine blast hole drills typically generate a substantial amount of dust during the drilling cycle. One method used to control this dust is the injection of water into the bailing air. This is known as wet suppression.

Jan 1, 1988

By A. A. Giardini

This report represents the results of a literature study on boron nitride and related substances. The purpose of the study was to find Information that might be of value for production of a new, hard modification of boron nitride preferably in single crystal form. The report consists of a review of the major developments in boron nitride research, a discussion of the results, tabulations of physical and chemical properties;, conclusions drawn from the study, and a bibliography.

Jan 1, 1953

By R. V. Higgins

A numerical method is presented to calculate the isopressure (isobar) lines and streamlines for an oilfield from the pressure distribution. A knowledge of these lines is useful in the study of the flow of fluids in underground reservoirs, especially for those containing gaseous and/or liquid hydrocarbons. This work was done primarily to enable determination of the shape factors needed in the calculation of petroleum reservoir performance. However, it has application for the flow of water in aquifers, or electricity or heat in odd-shaped geometry. Techniques previously developed were used to calculate the pressure distribution. From this pressure distribution, the isopressure lines were calculated accurately by the method presented in this paper. Then by successively projecting orthogonal lines from one isopressure line to another, the streamlines are determined. From the coordinates of the isopressures and the streamlines, the shape factors can then be determined by a published method. Computer methods are presented to calculate the streamlines and isopressures for any well-spacing pattern existing within a field with multiple wells. The method reproduces the flow net for several well configurations having extensive geometrical variations. Such information provides the petroleum engineer with data from which he can compute oil recoveries for different patterns and thereby maximize the recovery of hydrocarbons from the reservoir.

Jan 1, 1972

By A. J. Barry

Two methods of testing anchorages of headed expansion-type mine roof bolts were investigated by the Federal Bureau of Mines to determine whether they are acceptable for general use. In both methods a load was applied to a tightened bolt with a hydraulic jack. A total of 80 tests, 40 using each method, was conducted in 4 test areas in 3 commercial coal mines. Electric resistance strain gages were used in all tests to indicate true bolt load as the bolt was tightened and when an additional load was applied with the hydraulic jack. The results indicate that: 1. The relationship between the true bolt load and the jack load will vary according to the test method until the two loads become equal. The bolt load-jack load relationship below this point can be determined only with strain gages. 2. The point at which the two loads become equal can be estimated by noting the load when the hardened washer becomes loose in one method, and when the bearing plate becomes loose from the roof in the other. It also can be approximated for either method of testing by noting the load when the first abrupt change in the slope of the jack load-bolt displacement curve occurs. 3. The anchorage characteristics of the test bolt can be determined from the data obtained from either method by examining the slope of the jack load-bolt displacement curve above the point at which the true bolt load is equal to the jack load.

Jan 1, 1960

By Edmond Chin

Mineral production was of minor importance to the country's economy, and Bangladesh was not a ranking world producer of any mineral commodity in 1980. Natural gas was the most important mineral exploited, and reserves were sufficient to allow a significant increase in its use. A greater proportion of the domestic heat and electrical energy needs could be filled by increased production and distribution of natural gas. Also, the export of natural gas was feasible either by pipeline to India or in the form of liquefied natural gas (LNG). Some nonmetallic minerals could be developed, as well as coal and peat, given sufficient capital investment. Bangladesh's strongly agricultural economy made fair progress in 1979.80.1 The major harvest of November-December 1979 turned out to be better than had been anticipated after an early drought left poor planting conditions. Secondary crops (harvested in February-March 1980 and June- July 1980) were excellent. There were prospects for a record harvest in fiscal year

Jan 1, 1982

By Tobias W. Goodman, Joseph Cervik

This Bureau of Mines report investigates the horizontal trajectory of boreholes drilled in coalbeds using the rotary drilling technique. Test holes drilled in coalbeds showed that the path of a borehole in the horizontal plane depends on drilling assembly configuration, drill bit rotation, and coalbed geologic features. An assembly that contained an 18-ft (5.53) long drill collar and two centralizers had the best horizontal stability evidenced by trajectories that deviated less than 16 ft (4.9 m) from a target at 1,000 ft (305 m). Removal of one of the centralizers resulted in a loss of control of hole trajectory in the horizontal plane. Generally, holes tended to turn to the right, presumably because of right-hand rotation of the bit. Deviations from the original bearing line were as much as 200 ft (61 m) or more at a depth of 1,000 ft (305 m).

Jan 1, 1988

Provide an inexpensive, simple means of supporting highly yielding ground In underground mines. Approach The Bureau of Mines developed a high capacity support post made from standard steel pipe which, when using a 60-inch post configuration, has a 45-ton capacity and a yield length of 24 inches. How It Works The post mechanism is a three-piece unit consisting of a top and bottom leg (made from standard steel pipe) and a separate foot bracket. During installation in the mine, the bottom leg is placed on a relatively flat surface on the mine floor and the top leg is placed over it until its flared end contacts an expansion ring attached to the bottom leg. As the roof and floor converge, the flared end of the top leg is forced into the expansion ring, causing the walls of the top leg to be deformed radially and along the axis. The mechanism will yield until the unit bottoms out after about 24 inches of yield.

Jan 1, 1987

The National Institute for Occupational Safety and Health (NIOSH) recommends that occupational exposures to respirable coal mine dust and respirable crystalline silica* be controlled by complying with the provisions presented in this document. These recommendations are designed to protect the health and provide for the safety of workers exposed to respirable coal mine dust and respirable crystalline silica for up to 10 hr/day during a 40-hr workweek over a working lifetime. The information presented in this document demonstrates that underground and surface coal miners are at risk of developing simple coal workers' pneumoconiosis (CWP), progressive massive fibrosis (PMF), silicosis, and chronic obstructive pulmonary disease (COPD). Adherence to the recommendations in this document should prevent or greatly reduce the risk of adverse health effects in workers exposed to respirable coal mine dust and respirable crystalline silica. NIOSH recommends that preventive efforts be focused primarily on reducing worker exposures. Effective health and hazard surveillance and medical screening are also useful components of a comprehensive prevention effort.

Jan 1, 1997

By B. H. Eccleston

The Bureau of Mines, in cooperation with the American Petroleum Institute, studied the effect of fuel volatility and front-end fuel composition on the amount and photochemical reactivity of automobile exhaust and fuel-system evaporative emissions. The study involved six gasolines--the base fuel, three fuels of varied volatility, and two fuels differing from the base and from each other in front-end olefin content. Data were obtained from 16 vehicles operated on a chassis dynamometer using a speed-load-time cycle that approximated a typical urban trip. Tests were made at ambient temperatures of 20°; 45°, 70°, and 95° F, using a climate-controlled dynamometer room. The amount of hydrocarbon emission and its probable photochemical effect, a potential contribution to pollution, is expressed as weight (reactivity equivalent) of a moderately reactive material, ethylene. Emissions of oxides of nitrogen, car-bon monoxide, and aldehydes were also observed. Results showed that reduction of volatility from currently typical levels serves to reduce both the amount and the reactivity equivalent of evaporative losses with a slight penalty by way of higher exhaust emissions. Alternatively, reducing the amount of light (low boiling) olefin in the fuel had no effect on the amount of hydrocarbon pollutant but did significantly reduce the reactivity equivalent of the emissions. Neither volatility change nor chemical changes to the fuel significantly affected the nonhydrocarbon emissions.

Jan 1, 1970

By P. W. Jeran, C. M. McCulloch, Maurice Deul

The natural vertical fracture sys tem in bituminous coalbeds is called cleat. Cleat orientation commonly controls the direction of mining with major development paralleling the face cleat. Previous researchers have categorized the origin of cleat as endogenetic, relating the origin of cleat to compaction and coalification, and exogenetic, relating the origin of cleat to tectonic forces. In the coalbeds studied for this report it was found that tectonic forces were the controlling factor of cleat formation. Face cleats were formed as extension fractures during structural deformation, and butt cleats, as release fractures during erosion and uplift. The face cleat of the Pittsburgh coalbed rotates from N 80° W in north- western West Virginia to N 57° W in southwestern Pennsylvania ; the face cleat maintains a perpendicular orientation to the shifting axial trend of local structures . Cleat orientation in other bituminous coalbeds in Virginia, Utah, Oklahoma, and Central Pennsylvania showed a similar relationship to local structure. Directional permeability of coal is directly related to cleat. Holes drilled perpendicular to the face cleat yield from 2.5 to 10 times the amount of gas released as compared with holes drilled perpendicular to the butt cleat.

Jan 1, 1974

By David R. Hanson

Experimental work performed by the Bureau of Mines in a laboratory environment has shown that the formation of failure zones within certain rock types is accompanied by the emission of significant amounts of radiofrequency (RF) electromagnetic (EM) energy. This radiation was detected using nonresonant, "electrically short," broad-band antennas. Rock types for which emission was observed include granite, quartzite, and taconite; sandstone and marble did not emit measurable radiation. Amplitude spectra of the radiation showed the energy to be concentrated between 10 and 40 kilohertz. These data indicate that emission is directional, but this has not yet been proven. In addition, amplitude of RF emission increases with increasing crack size. Since emission was observed only for brittle quartz-bearing rocks, it appears the formation of piezoelectric fields is a necessary condition for RF radiation. Plausible mechanisms for emission include rapid decay of piezoelectric fields accompanying the sudden stress release at failure and/or the acceleration of an "exoelectron plasma" through the intense local piezoelectric fields. Since emission appears to increase with the scale of failure, and since antennas do not need to be coupled directly to rock surfaces as with conventional geophones, the possibility of developing a portable system to monitor seismically active areas exists.

Jan 1, 1981