Search Documents

By Robert B. Schluter

The Bureau of Mines investigated separating copper-nickel mattes to recover a copper-rich fraction suitable for processing by conventional copper metallurgical processes and a nickel-rich fraction suitable for processing in a hydrometallurgical nickel circuit. Distribution of cobalt and precious metals between the copper and nickel fractions was also determined. A matte containing a nominal 65 pct Cu, 9 pct Ni, 4 pct Fe, and 20 pct S was separated into a copper fraction that comprised 80 pct of the matte weight and contained 70 pct Cu and <1.5 pct Ni, plus a nickel fraction that contained 40 pct Ni and 30 pct Cu. Recoveries of copper and nickel into their respective fractions were 90 pct and 87 pct. These results were obtained in a laboratory flotation cell at a matte grind of 90 pct minus 500 mesh and a pH of 12.4, using 1.7 pounds DPG (diphenylguanidine) per ton of matte as collector and frother. Magnetic separation was used to remove metallic iron-nickel alloy from the copper fractions. Distribution of cobalt was about 70 pct to the nickel fraction and 30 pct to the copper fraction. Silver reported predominately to the copper fraction, while Au, Pt, and Pd were essentially entirely recovered in the nickel fraction.

Jan 1, 1982

By Ivette E. Torres

Of the 15 selected non fuel mineral commodities detailed in table 12, only 3 indicated increases in worldwide consumption in 1992. As in 1991, decline in consumption levels of the selected commodities can be attributed to reduced levels of use in the former U.S.S.R. and Eastern Europe. Of the remaining 12 commodities, 2 magnesium and cadmium, stayed relatively the same, while the other 10, including iron and steel, all recorded decreases. Global consumption of iron ore is estimated to have fallen about 3.5 % or about 30 million tons. This is a greater decline than what was estimated for production of iron ore, which is down only 2.7% or nearly 26.5 million tons, suggesting an addition to stocks. The consumption trend for iron and steel has been declining since 1989. This has mainly been due to the continued drops in use in the former U.S.S.R. and Eastern Europe. Even as the European economy begins to turn upward, there may only be a slight increase in consumption of iron, steel, and cement, considering the high cost of construction needed to modernize factories and buildings in Eastern Europe. Many feel that the economies of these countries are limited by the current status of their industries.

Jan 1, 1994

By J. M. Gomes

The Bureau of Mines investigated electrolytic techniques for preparing diborides of the group IV B metals. TiB2, ZrB2, and HfB2 were electro-deposited from their respective oxides dissolved in borate-chloride-cryolite electrolytes. Titanium diboride was also electrodeposited from rutile (Ti02) dissolved in a Na2,B4O7-Na2C03-Na3A1F6-NaC1 electrolyte at 1,050° C; 14 kW-hr were required to produce 1 pound of TiB2. Major impurities in the TiB2 produced in a 10-deposition cycle experiment, in weight-percent, were Al, 0.2; Cr, 0.3; Fe, 0.1; V, 0.3; C, 1.4; and 0, 1.0. Zirconium diboride was electro-deposited from zircon (ZrSiO4) dissolved in a Na2B407-NaOH-Na3A1F6-NaCl-NaF electrolyte at 1,050° C. The ZrB2 produced in a 10-deposition cycle experiment contained the following impurities in weight-percent; Fe, 0.1; Si, 0.5; C, 0.3; and 0, 0.6. Energy required to produce 1 pound of ZrB2 was 9.3 kW-hr.

Jan 1, 1975

By E. G. King

Sodium-aluminum and calcium-aluminum silicates are important rock-forming minerals. While many of them are of only theoretical interest, several are of practical importance--as ceramic raw materials and as potential future sources of aluminum. Heretofore, thermodynamic data for these minerals were incomplete; and in many instances missing data were difficult to estimate reliably. This has seriously hampered thermodynamic calculations pertaining both to the natural formations of these minerals and to their decomposition in sintering and fluxing reactions. This paper reports the results of the Federal Bureau of Mines measurements of low-temperature heat capacities of four crystalline silicate minerals--dehydrated analcite (NaAlSi2O6), hexagonal anorthite (CaA12 Si208), lawsonite (Ca2Al2Si2080?2H20), and leonhardite (Ca2Al4Si8C24?7H2O). It augments previous similar measurements of related minerals, which were summarized recently.4 The measured heat-capacity data were used to derive entropy values for the four minerals at 298.15° K. Some relations between these entropy values and those of other similar minerals were discussed. These relations illustrate the difficulty of estimating entropy values of tertiary (or higher) silicates.

Jan 1, 1961

By C. M. Frost

Crude shale oil produced during in situ retorting by the Bureau of Mines at Rock Springs, Wyo., was refined by three schemes. In the first, the crude oil was fractionated to raw naphtha and 400° F+ residuum. The residuum was hydrogenated over cobalt molybdate catalyst at 815° F and 1,100 psig. The blended raw and 160°-400° F hydrogenated naphthas were hydrodenitrified and then catalytically reformed. The 400° F+ hydrogenated oil was catalytically cracked. In the second scheme, the crude was hydrogenated over nickel-tungsten catalyst at 800° F and 1,500 psig. The hydrogenated fractions were processed by methods used in the first scheme. The third scheme resembled the second but, prior to hydrogenation, the crude was "hydrostabilized" over cobalt molybdate at 500° F and 500 psig. Yields of reformate and cat-cracked gasoline as volume-percents of the crude, and research-method octane numbers (with 3 ml TEL) for the three methods were as follows: First method, 32 pet reformate, 90 octane; 19.5 pct cracked gasoline, 99.2 octane. Second method, 29 pet reformate, 81.1 octane; 21.3 pct cracked gasoline, 99.6 octane. Third method, 28.2 pet reformate, 86 octane; 28.7 pct cracked gasoline, 95.9 octane.

Jan 1, 1974

By T. G. Carnahan

The Bureau of Mines conducted laboratory-scale weathering research on a leach residue containing elemental sulfur and mixed metal sulfides. Experiments were performed to determine pH and impurity element concentrations in the effluents as functions of time and to determine the effects on effluent concentrations of mixing the residue with dolomite tailing material. Four 800-day tests were conducted simultaneously. Soluble metal concentrations, especially zinc and copper, were excessive in the effluents from washed and unwashed samples of the residue. Concentrations of up to 20 g/l of Zn and 12 g/l of Cu were obtained. The pH values of the unwashed and washed residue effluents at the completion of the experiments were 2.8 and 1.9, respectively. Sulfuric acid from oxidation of pyrite caused the pH decrease. Mixing unwashed residue with dolomite tailing to maintain a near-neutral pH minimized the heavy metals content in the effluents. The pH in the dolomite tests increased slowly after the first 360 days and attained values of 7.8 and 8.2, respectively, for tailing containing 1 pct leach residue and for tailing devoid of leach residue. Dissolved zinc and copper did not exceed 0.10 g/l of Zn and 0.001 g/l of Cu.

Jan 1, 1982

By John A. Organiscak

Enclosed cabs are a primary means of reducing equipment operators? silica dust exposure at surface mines. The National Institute of Occupational Safety and Health recently performed a laboratory study to evaluate which factors on an enclosed-cab filtration system are most significant. The various factors evaluated were intake filter efficiency, intake air leakage, intake filter loading, wind infiltration, use of a recirculation filter, and the use of an intake pressurization fan. The result of this laboratory testing has shown that the two most important factors for an effective filtration system on an enclosed cab were the efficiency of the intake filter and the use of a recirculation filter. A higher-efficiency intake filter considerably increased the quality of the intake air that was delivered into the enclosed cab. It also was determined that air leakage around the intake filter notice-ably reduced its air cleaning effectiveness. The second key factor is the use of a recirculation filter, which was shown to improve the air quality in the enclosed cab by six to 12.7 times more than the intake filter alone. The reason for the significant improvement was that the cab air was constantly drawn through the recirculation filter, thus continually filtering the dust out of the air.

Jan 1, 2010

Accurately measure time of detonation and explosive detonation velocity in a blasthole for analysis of explosive performance and delay intervals. Approach A blasthole-monitoring fiber optic probe was developed consisting of filer optic cable to carry the fight and a sensor to detect and convert the light signals into electrical signals. Events can then be recorded on an oscilloscope, tape recorder, digital computer, or start-and-stop timer. This method is simpler to use and more immune to electronic noise than existing resistance techniques. The fiber optic material,, are inexpensive and easy to obtain, and the recording devices, such as storage oscilloscopes, arc available or easy to obtain. The probe provides the mining industry, explosive manufacturers, and those studying blasting, with a practical alternative to complex and expensive coaxial cable reflectometry, resistor strings, or resistance wire methods for determining explosive and detonator performance. How It Works The fiber optic cable is a plastic light guide consisting of sixteen 0.01-inch-diameter optic strands having an overall outside diameter of 0.087 inch. The receiver module incorporates a photodiode to detect the signal and an integrated circuit receiver for signal amplification into one package about 1/2 by 5/8 by 7/8 inch.

Jan 1, 1989

By L. D. Gehi, A. W. Khair, M. Ahmad

"Bit wear presents problems to mining operations because it affects both productivity and economics. Most bit research deals with energy requirements and energy dissipation mechanics for ideal fragmentation during the cutting process.Mechanical cutting leads to dust generation. Past studies involving dust generation due to bit wear concluded that dust concentrations increased considerably after a 7% bit weight loss: leading researchers recommend that the bits be changed at that point.Bit wear is affected by three factors: machine operating parameters in-situ mining conditions and rock properties. Operating parameters such as the depth of cut tool material spray position and the drum's rotating velocity are very important and have a definite impact on bit wear.During the mining process the amount of rock in coal and the strength of that rock is important as abrasion and adhesion take affect. Diffusive wear or deformation becomes dominant only when the temperatures exceed critical. Temperatures rise as a function of drum velocity rock properties and the cutting tool itself.Miner bit surveyIn this study, 15 mines were surveyed, and of those six responded for nine seams. The survey reflected a wide range of information about coal production and bit consumption from continuous miner sections. Also used bits were collected to get first-hand information to analyze wear."

Nov 1, 1995

By A. M. Stubbs

The Bureau of Mines has devised a procedure to selectively extract and recover chromic oxide (Cr203) from waste high-temperature shift catalysts that contain approximately 6 pct Cr and 62 pct Fe, both in oxide form. The Bureau&apos;s procedure consists of roasting the waste catalyst with sodium hydroxide (NaOH) or sodium carbonate (Na2C03) followed by water leaching. The chromium from the leach liquor was recovered utilizing an oxidation-reduction reaction with pH adjustment to form a hydrous chromic oxide (Crp3oXHp) precipitate. The roast-leach procedure produced chromium extractions greater than 89.7 pct, with product recovery in excess of 99 pct from the leach liquor. The costs of the NaOH and Na2C03 roast processes, including sizing and equipment-related recommendations, were determined by the Bureau&apos;s Office of Process Evaluation. The economic evaluation indicates that producing a Crp3 product, at the present time, is not competitive with the present-day cost of imported chromites. The estimated average operating cost for both processes was $5.44/1b of recovered Cr203 concentrate. However, this procedure offers a potential alternative to the disposal of this waste through landfiIl.

Jan 1, 1988

By R. V. Ramani, P. M. T. White, D. Sutton

5.1 Incorporation with the Master Design Simulator Figure 1 diagrammatically illustrates the interaction between the various sub-systems that go to make up the total Master Design Simulator. As a total system, all sub-systems will be scheduled as needed by the controlling program. The data require¬ments for each will be made available either by providing common storage in core or by outputting data to external storage devices such as magnetic tape, disk, drum, etc. The incorporation of the Geology and Reserves sub-system into the total system involves the establishment of an interface through which data may be readily dissemminated in either direction. This interface will be provided by a geological data library in which all information available from the sub-system is stored and can be readily accessed by the main program and/or other sub-systems. In Figure 7, the information flow between the Geology and Reserves sub¬system and other sub-systems is shown. 5.2 Independent Function Geology and Reserves sub-system is capable of functioning as an independent unit or in direct communication with another sub¬system. This is possible by either continued use of the data library or by redirecting output to other peripheral devices separate from the total system libraries. (Figure 8).

Jan 1, 1974

By L. Prosser, A. Iannacchione, G. Esterhuizen

The potential for roof falls in underground mines remains a clear and present danger for mine workers. An investigation of ground conditions in nearly 50% of the nation’s underground stone mines found that the state of roof stability is primarily determined in a limited and subjective manner. These large opening mines, with roof heights typically of 7 m or more, make physical observation difficult. Although some mines use monitoring techniques to gain additional information on roof stability, this practice is usually short-term and localized to address ground conditions in a particular section or part of the mine. A methodology to assess the risk for a roof fall is proposed in a preliminary fashion based on engineering judgment acquired from extensive underground stone mine experience and examination of related literature. The proposed method utilizes an observational technique to identify the risk of roof falls in three categories. Case study scenarios provide a realistic picture of model implementation. Providing the mine level decision maker with an accurate assessment tool to ascertain the level of risk related to ground conditions is expected to reduce mine worker injuries and fatalities. Moreover, the presences of danger can be overcome with a clear picture of quantified ground conditions.

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

C. 7 Emergency Rescue Hoists There is a need, especially in mine development areas, for portable, on-call, man-rated equipment capable of lifting men through several hundred feet. Wire rope climbing equipment as shown in Figure 37 appears particularly suited to this need. It is portable, weighing approximately 100 lbs. , is currently man-rated for numerous above ground applications and can be electric or air powered. Commercial units currently have a lifting capacity of 1000 lbs. , and can be fitted with bosun&apos; s chairs. Lifting speeds are in the 20-30 FPM range and the equipment is not depth limited. In a situation where miners are unable to climb to the top of a shaft this equipment could rapidly be anchored to the top of the shaft and lowered to them by hand. Since the self contained unit is controlled by the person travelling in the shaft he would be able to negotiate shaft obstruction himself. This would not be possible with other forms of easily deployed free-hanging equipment. Typical manufacturers of this type of equipment are Ohio Hoist Mfg, Co, 321 South Beaver St. Lisbon, Ohio 44432 216-424-7283 Sky Climber Inc. 17311 South Main St. Gardena, California 90248 213-321 -6414

Jan 1, 1976

By C. B. Manula, R. L. Sanford, R. A. Rivell

The large amount of computer code required for this simulation model dictates that reasonable limitations be placed on some of the input variables. The program permits the following maximum sizes: 1. Ten mine car stations 2. Twenty track intersections 3. Three hundred mine cars 4. Eight motors 5. One hundred profiles 6. Twelve intersections between stations 7. Forty-five profile changes between stations 8. Thirty station pairs (routes) These may be changed by the user providing the particular computer in use has available core storage. Major Array Descriptions This section is a detailed description of four of the major arrays used in the rail haulage simulator for data storage and logical control. Other arrays are used; however, they may be considered sub¬servative to the major ones. These major variables are explained on the following pages. Motor Control Array (XXXDEF). The first 99 locations in this array are arranged according to and are developed by data input. Unit conversions are made at input time which include: 1. Tons to pounds. 2. Rolling resistance in pounds/ton to percent/100. 3. Miles per hour per second (mphps) to feet per min. per minute. 4. Miles per hour to feet per minute. The following information is stored for each motor at the array

Jan 1, 1974

By G. B. Atkinson

The Bureau of Mines, in cooperation with McDermitt Mine, investigated a method for recovering mercury metal from mercury sulfide flotation concentrate by a hydrometallurgical technique. This preliminary report shows the feasibility of leaching mercury with a cupric chloride solution and electrowinning mercury from the solution. Proposed chemical reactions are shown in equations 1 through 3: 2CuC12 + HgS + 2CuCl + HgC12 + S°; (1) electrolysis HgC12 ?Hg + C12; (2) 2CuC1 + C12 ? 2CuC12. (3) A bench-scale leaching-electrowinning apparatus capable of treating 2.36 kg of sulfide concentrate in 11 days was operated continuously. An acid chloride solution containing, in grams per liter, 70 Ca, 60 Cu, 30 Fe, and 80 Hg was used as both leachant and electrolyte; 99.5 pct of the mercury was solubilized from the sulfide concentrate. Electrolysis of the leaching solution recovered mercury metal at an average current efficiency of 32 pct and an average energy consumption of 1.2 kwhr/lb Hg. Results from a preliminary economic evaluation indicated that a plant producing 31,500 flasks of mercury per year would have a capital cost of $3.7 million and an operating cost of $62 per flask of mercury.

Jan 1, 1983

By Christopher Mark

Since it was first introduced, the Coal Mine Roof Rating (CMRR) has been widely accepted as a tool for geologic characterization and mine planning. This paper discusses the application of the CMRR to another practical ground control problem. Extended cuts (cuts greater than 6 m (20 ft) in length) are commonly used with remote control continuous miners. Extended cuts can greatly increase productivity, but they have been associated with a number of fatal roof fall accidents. When extended cuts are attempted in weak roof, the roof may collapse before it can be bolted, causing hazardous conditions. Until now, it has not been possible to predict where conditions may not be suitable for extended cuts. In this study, data on the CMRR and extended cut experience were collected at 36 mines in 7 states. It was found that when the CMRR was greater than 55, deep cuts were routine in nearly every case. When the CMRR was less than 37, extended cuts were almost never taken. Between 38 and 55, extended cuts were feasible sometimes but not others. The data also shows that extended cuts are less likely to be stable if either the entry span or the depth of cover increases.

By C. P. Lazzara, R. A. Franks, G. F. Friel, J. C. Edwards, J. J. Opferman

A series of four coal combustion experiments was conducted at the National Institute for Occupational Safety and Health&apos;s (NIOSH) Pittsburgh Research Laboratory (PRL) in the Safety Research Coal Mine (SRCM) to evaluate the response of fire sensors to a small 0.61 m square smoldering coal fire which transitions to flaming combustion in the presence of diesel emissions. An optical path smoke sensor alarmed earlier than a point type diffusion mode ionization smoke sensor which alarmed prior to a CO alert value of 5 PPM above ambient. The presence of steady state diesel emissions resulted in a decrease in the optical smoke sensor analog output voltage signal by less than 1.4 pct for the three coal fire experiments in which a diesel engine was operating, whereas the ionization smoke sensor output decreased between 10.8 and 26.7 pct after the initial surge of the diesel engine. A commercial diesel discriminating fire sensor did not alarm for a fire in the one experiment for which it was used. The results of the experiments demonstrated that an optical path smoke sensor might be used to detect a coal fire under the experimental conditions considered of starting a diesel engine followed by a slowly developing coal fire.

By Edward A. Barrett, Lynn L. Rethi

Recent studies have shown that miners performing construction, maintenance, and repair (CMR) work activities in the conduct of their jobs incur from 39 to 65 percent of all reported injuries in the mining industry, The number is particularly high at surface aggregate operations; however, the problem exists at all mining locations and commodities. To address this issue, an interactive, (3-D) slides training exercise, Hazard Recognition Training Program for Construction. Maintenance and Repair Activities, was developed. The purpose of the exercise is to teach work& to recognize CMR hazards in the workplace and to deal with them using accepted safe work procedures. It was field tested using a total of 340 persons from surface mining operations in six states. The subjects were tested before and after the training intervention to determine if objectives of the instruction were achieved. Results indicated that 7 1 percent of the participants showed improvement in ink test scores. Following the posttest, subjects responded to a seven question Likert scale. These questions related to the validity of the exercise and the utility of the training program. More than 93 percent of the miners reported that they "learned something new from the training" and over 94% said they "would use these practices to work more safely".

By D. S. Colby

The productive capacity of natural-gasoline and cycle plants in the United States as of January 1, 1952 was 811,596 barrels per day, an increase of 163,691 barrels per day since the last survey on January 1, 1950. The rate of growth during these 2 years has been 12 percent per year s only slightly below the maximum rate, recorded from 1948-50. This survey, for the first time, presents capacity data on a barrel rather than a gallon basis. Also, for the first time, a break-down of capacity by products has been obtained. The combined LP-gas producing capacity of plants and fractionators equaled 382,790 barrels per day, 47 percent of the total industry capacity tor all products. During January 1952, LP-gas and natural gasoline and other products were each produced at the rate of 76 percent of the January 1 capacity.

Jan 1, 1952

By Frank G. Horino

The Bureau of Mines studied the uniaxial compressive strength of model rock pillars as a function of the angle and spacing of noncohesive planes of weakness. The model pillars were prepared from NX 2-l/8-inch diameter drill core of limestone, sandstone, and granite, and the planes of weakness were diamond saw cuts ground flat and smooth. The angle of the planes of weakness, measured from the horizontal, varied from zero to 57° in approximately 15° increments. When two planes of weakness were used, the thickness-to-diameter ratio of the wafer was 1/4, 1/2, and 1, Approximately 400 model pillars were tested in uniaxial compression. The results indicate that the uniaxial compressive strength of model pillars decreases rapidly as the angle of the plane of weakness increases from 30° to 57°, and that the spacing of these planes of weakness has only a minor effect on the strength. The effect of the number of horizontal planes of weakness, with a spacing of 1/4 and 1/2 of the diameter, upon the compressive strength of model pillars was also investigated. These results indicate that as the number of planes of weakness increases the compressive strength of the pillar decreases. Normalizing the data provides useful estimates of model pillar strengths for any rock type.

Jan 1, 1968