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By C. Özgen Karacan

Methane emissions from the active face areas and from the fractured formations overlying the mined coalbed can affect safety and productivity in longwall mines. Since ventilation alone may not be sufficient to control the methane levels on a longwall operation, gob vent boreholes (GVB), horizontal and vertical drainage boreholes, and their combinations are drilled and used as supplementary methane control measures in many mines. However, in most cases, the types of degasification wellbores chosen are decided based on previous experiences without analyzing the different factors that may affect this decision. This study describes the development of an expert classification system used as a decision tool. It was built using a multilayer perceptron (MLP) type artificial neural network (ANN) structure. The ANN was trained using different geographical locations, longwall operation parameters, and coalbed characteristics as input and was tested to classify the output into four different selections, which are actual degasification designs that US longwall mines utilize. The ANN network selected no degasification, GVB, horizontal and GVB, and horizontal, vertical and GVB options with high accuracy. The results suggest that the model can be used as a decision tool for degasification system selection using site- and mine-specific conditions. Such a model can also be used as a screening tool to decide which degasification design should be investigated in detail with more complex numerical techniques.

Jan 1, 2009

By Walter W. Fisher

Cement copper was flash roasted in a vertical tube furnace to convert the copper to acid-soluble oxides as part of a postulated process for refining cement copper by oxidation roasting, acid leaching, and electrowinning. The results of the study showed that the oxidation was a linear function of oxygen concentration between 0 and 20 percent, but above 20 percent oxygen there was no further increase in oxidation. Therefore, air was the optimum oxidizing atmosphere in this flash roasting system. The oxidation followed a parabolic rate law as the roasting temperature was increased from 400° to 800° C. Extrapolation of the data, based on the parabolic law, indicated that at 400°, 500°,600°,700°, and 800° C, the roasting times required for complete conversion to soluble oxides were 75, 37, 21, 7.7, and 4.6 seconds, respectively. Cyclic-roasting test results did not substantiate the predictions obtained through data extrapolation.

Jan 1, 1973

By A. W. Hall

Cylindrical plastic scintillators were investigated for efficiency in detecting neutron-induced prompt gamma rays. Scintillator performance was compared on the basis of half-resolution and peak-to-trough ratios for gamma spectra obtained from Co-60 (1.17 and 1.33 MeV), Th-228 (2.62 MeV), and PuBe (4.43 MeV). Various sizes of Pilot Chemical scintillators (types B, F, M, and Y) were tested. The best half-resolution, 7.7 percent for PuBe, was achieved with a 5-by 5-inch Pilot Y?scintillator and dual photomultipliers. Comparison with sodium iodide (NaI) scintillators and the use of plastic scintillators for on-stream analysis of sulfur in coal is discussed. Plastics were found to be unsuitable for on-stream analysis of materials having complex prompt gamma ray spectra; however, they could conceivably be used for those yielding Simpler spectra.

Jan 1, 1974

By John Gross

"Introduction.Southern Illinois and Kentucky are credited with approximately 90% of the fluorspar production of the United States. A small amount of high-grade acid, spar is obtained from the ore by band sorting; the greater part, however, is recovered by jigs and tables as gravel spar containing approximately 85% calcium fluoride. In the jigging and tabling operations, galena is recovered, and enough silica and calcite are removed to raise the calcium fluoride content of the gravel spar to 85%. However, the removal of silica and calcite results in a large loss of spar. With increasing depth in the mines, zinc sulphide, sphalerite, is encountered in increasing quantity and the removal of this has become a serious problem. While the sphalerite can be fairly well removed from the spar by present milling methods, a marketable zinc concentrate can not be made. The experiments described below were made on fluorspar ore from Southern Illinois, by the mining experiment station of the U. S. Bureau of Mines, at Rolla, Mo., in cooperation with the Missouri School of Mines and Metallurgy.The ore tested contained. 7.3% lead, 27.9% zinc, 35.7% calcium fluoride, 9.5% silica and 4.7%. calcite.Tests and Results. In some preliminary tests it was noticed that a portion of the finely crushed ore adhered strongly to the sample pans, and upon investigation it was found that the adhering material was practically clean spar. By utilizing this property of adhesion 46.8% of the spar was recovered as a product containing 98.3% calcium fluoride. This suggested the possibility of using electrostatic separation."

Jul 1, 1921

By Sidney Katell

This study estimates capital investment, operating costs, and selling prices for four underground bituminous mines producing coal with annual production ranging from 1.06 to 4.99 million tons. It is assumed that the mines have a 20-year life. Wages and union welfare payments are considered as of November 12, 1973, under the Bituminous Wage Agreement of 1971, and costs for material and equipment are based on 1973 indexes. Initial capital investment ranges from $12,540,700 for the 1.06-million-ton-per-year (MM tpy) mine to $44,720,500 for the 4.99 MM tpy mine. Total capital investment ranges from $21,850,700 to $75,693,500 for the same mines. Corresponding selling prices for the coal range from $8.76 to $7.53 per ton, assuming a 12-percent discounted cash flow rate of return after Federal income taxes.

Jan 1, 1974

By E. K. Kleespies

The Bureau of Mines determined the kinetics of the reaction of titanium-iron alloys with titanium trichloride dissolved in sodium chloride to provide a basis for understanding the reactions occurring in metallurgical processes involving reduction of the metal halides or alloy refining in fused salts. The rate of the heterogeneous reaction was determined between titanium-iron alloys and titanium trichloride to elucidate the effects of alloy composition on the rate. Measurements were made in an inert atmosphere with a high-temperature thermobalance using high-purity reactants. The rates of the reactions were about 1 x 10-5 g Ti/cm2-sec, and the reaction was phase-boundary controlled. Titanium alloys of the body-centered cubic beta structure reacted faster than those with the hexagonal close-packed alpha structure. The inter-metallic compound, TiFe, reacted very slowly, whereas TiFe2 was inert. Alloys containing above 89 atomic percent iron gained weight by reacting with titanium species in the salt solution and depositing titanium in the alloy. The effect of TiCl3 concentration on the reaction rate was determined from 2 to 12 weight-percent TiC13 and at various alloy compositions. At high iron contents, above 50 atomic percent, the TiC13 concentration effect was small. At lower iron contents, the TiC13 concentration effect was greater for beta-crystalline alloys than for alpha-crystalline alloys. The temperature dependence of the reaction between titanium alloy containing 8.7 atomic percent iron and titanium trichloride was measured over the temperature range 1,062° to 1,220° K, and the energy of activation was 7.7 kilocalories for the reaction.

Jan 1, 1967

By Van H. Manning

PETROLEUM INVESTIGATIONS. The work of the petroleum division of the Bureau of Mines during the period of the war was under the supervision of Chester Naramore, chief petroleum technologist. In its petroleum investigations the bureau cooperated freely with other Government bureaus and acted as a source of information on petroleum matters. COOPERATIVE WORK ON INTERALLIED PETROLEUM COMMISSION. On July 15, 1918, Mr. Naramore and W. E. Perdew, chemical en- gineer of the bureau, left for London to act as representatives of the United States Fuel Administration and the United States Shipping Board on the Inter-allied Petroleum Commission. Numerous con- ferences were held with representatives from France, England, and Italy on specifications and requirements of the various allied Govern- ments for petroleum products, and for this purpose meetings were held in London, Paris, and Rome. EXAMINATION OF PETROLEUM FACILITIES IN FRANCE. The storage facilities and the transportation system in France were studied, and recommendations based on the information gained were made to the director of the oil division of the Fuel Administra- tion and to the chairman of the Shipping Board. Refinery plants in France were inspected, as well as filling stations and shipping facilities from ports in France and Italy to the various fronts and the petroleum base of the American Expeditionary Force at Romorantin. France. At the request of Ambassador Sharp, a re- port was prepared on the advisability of developing the petroleum resources in France.

Jun 1, 1919

By Frank J. Susko

The U.S. Bureau of Mines has developed a computer model to describe a flotation process. Coal data from conventional flotation has been converted to a simple, two-parameter kinetic model developed by Reuter and van Deventer (1,2)3. Each set of coal data was represented by two constants, a and ß, and an average flotation rate. The success of the model was demonstrated when the calculated and experimental recoveries showed good correlation. The two-parameter model allows complex data to be defined much more efficiently than traditional knowledge-based models.

Jan 1, 2010

By H. S. Kalman

A table of factors, for rapid, accurate calculation of the volume of pure helium in cylindrical steel containers, is presented. By use of the table the volume of helium in a container, at base conditions of 14.7 psia and 70° F, can be calculated from the observed pressure and temperature of the helium and the known internal volume of the container. The table covers a pressure range from 0 to 4,500 psia in 10 psi increments and a temperature range of 0° to 120° F in 2° increments. The calculation of volume requires a single multiplication, using a factor from the table and the known internal volume of the container. A discussion and evaluation of the accuracy obtainable and a derivation of the formula used (which takes into account compressibility of helium, thermal expansion of steel containers, and the stretch of steel due to internal pressure) are presented. An example showing how the table can be used is given also.

Jan 1, 1963

By H. S. Kalman

A table of factors, for rapid, accurate calculation of the volume of pure helium in cylindrical steel containers, is presented. By use of the table the volume of helium in a container, at base conditions of 14.7 psia and 70° F, can be calculated from the observed pressure and temperature of the helium and the known internal volume of the container. The table covers a pressure range from a to 4,500 psia in 10 psi increments and a temperature range of 0° to 120° F in 2° increments. The calculation of volume requires a single multiplication, using a factor from the table and the known internal volume of the container. A discussion and evaluation of the accuracy obtainable and a derivation of the formula used (which takes into account compressibility of helium, thermal expansion of steel containers, and the stretch of steel due to internal pressure) are presented. An example showing how the table can be used is given also.

Jan 1, 1963

By Stephen A. Swan

Bureau of Mines researchers have collected and evaluated rollover protective structures (ROPS) f or more than 10 yr. ROPS and falling object protective structures (FOPS) are required on specified mining machines under regulations of the Mine Health and Safety Administration (MSHA). Both ROPS and FOPS are required on mining machines used in surface coal mines and surface areas of underground coal mines (30 CFR 77.403 and 7 7.4 13a), and ROPS are required on mining machines used in metal and nonmetal mining operations (30 CFR 55, 56, and 57.9-88). This illustrated manual provides mine safety personnel, MSHA inspectors, and original-equipment manufacturers with guidelines and a check- list for inspecting ROPS being used in the field. The manual discusses specific requirements of the MSHA regulations and minimum inspection and maintenance checks for ensuring compliance with those regulations. An easily reproducible checklist is provided as an aid to the inspection of ROPS.

Jan 1, 1985

By Susan E. Brink

The first step in determining whether Mn can be recovered by in situ leaching is to develop and test a selective lixiviant. Two column leach tests and one core leach test Were conducted by the U.S. Bureau of Mines on Mn oxide ore using aqueous sulfur dioxide (SO2) as the lixiviant. The column tests showed that aqueous S02 could selectively dissolve available Mn oxides from calcite-rich ore in a heap leach system. However, the core test showed that calcite gangue side reactions can have pronounced negative effects on the likelihood of successful in situ leaching of a calcite-rich ore with aqueous S02. Petrographic and geochemical analyses showed that both Mn (IV, III) oxides and calcite were dissolved. The abundance of dissolved Ca caused precipitation of gypsum. Acid consumption by calcite dissolution caused a rise in pH that caused the SO/S species to shift to S032-(sulfIte), which hindered reductive dissolution of Mn oxide. Gypsum precipitation did not affect complete leaching of the rock fragments in the column tests; however, it plugged the natural permeability in the core. Manganese recoveries were high for the column tests and low for the core test.

Jan 1, 2010

By Fred N. Kissell

Methane concentration peaks were measured by the Bureau of Mines at coal mine working faces during entry development. The statistical distribution of peaks was found to be normal or log normal depending on how well the methane was being mixed into the ventilation airstream. A normal distribution indicated good mixing, whereas a log-normal distribution indicated that mixing was poor. In addition, the "highest" peaks over selected intervals were found to fit a type I extreme-value distribution, a result similar to that obtained while mining longwall faces.

Jan 1, 1974

By R. W. Dalzell, Fred N. Kissell, J. L. Banfield, M. G. Zabetakis

Methane concentration peaks were measured by the Bureau of Mines at coal mine working faces during entry development. The statistical distribution of peaks was found to be normal or log normal depending on how well the methane was being mixed into the ventilation airstream. A normal distribution indicated good mixing, whereas a log-normal distribution indicated that mixing was poor. In addition, the "highest" peaks over selected intervals were found to fit a type I extreme-value distribution, a result similar to that obtained while mining longwall faces.

Jan 1, 1974

By Arthur B. Johnson

The Bureau of Mines investigated the concentration characteristics of high-clay sylvinite ores from four potash companies operating in the Permian Basin near Carlsbad, N. Mex. These ores, containing 13 to 22 percent K20 and 3 to 7 percent clay slimes, cannot be effectively processed by current commercial flotation methods because of their high slime content. A solution to this problem was shown to be the use of two-stage moderate scrubbing conditions and washing of the ore as opposed to strenuous attritioning. Bench-scale physical beneficiation techniques for recovering potash minerals and the development of ore-dressing systems by flotation resulted in obtaining acceptable product grades and recoveries. By using a coarse grind, emphasis was placed on production of premium granular and coarse products. Flotation results showed that concentrates of 58.7 to 60.4 percent K20 with recoveries of 71.0 to 83.4 percent 0f the K20 values can be obtained.

Jan 1, 1971

By John M. Gomes

Two molten salt systems were evaluated as electrolytes for the repetitive recovery of tungsten from tungsten oxide (W03) made by calcining commercial-grade ammonium paratungstate. Using a sodium chloride-sodium fluoride-potassium aluminum tetrafluoride electrolyte at 800° C, 1 pound of 99.8 percent tungsten was recovered for each 2.7 kilowatt-hours of energy consumed. The metal contained 1,100 ppm carbon, was in dendritic masses of spherical grains, and had an apparent bulk density of 5.41 g/cm3. T ngsten of 99.9 percent purity was won from a sodium pyrophosphate-sodium tetraborate-sodium chloride electrolyte at 1,000° C; 6.0 kilowatt-hours of energy was consumed for each pound of metal recovered. The metal contained 120 ppm carbon, was in dendritic masses of hexagonal acicular crystals, and had an apparent bulk density of 7.25 g/cm . Each metallic impurity--aluminum, calcium, copper, iron, nickel, and silicon--in the two tungsten products was 16 ppm or less.

Jan 1, 1966

By R. E. Lindstrom

Electrooxidation techniques were investigated on a bench scale by the Bureau of Mines to determine the applicability of the process for extracting molybdenum and rhenium from low-grade molybdenite concentrates. Parameters affecting the extraction, such as pulp density, power consumption, reagent requirements for pH control, and electrolytic cell configuration, were studied. Molybdenum and rhenium extractions of 98 to 99 percent were achieved from several concentrates containing 4.76 to 28.6 percent molybdenum and 180 ppm to 1,000 ppm rhenium. Optimum results were obtained by maintaining pH values between 5.5 and 7.0 during electrolysis and allowing the final pH to rise to about 8.2. Reagent consumption was 4 to 6 pounds of sodium carbonate per pound of molybdenum extracted. The power consumption declined from a range of 12 to 25 kilowatt hours per pound of molybdenum extracted with immersion electrodes to 9.7 kilowatt hours with a bipolar flow-through cell; however, molybdenum extraction was independent of cell configuration.

Jan 1, 1973

By R. E. Coleman

The molecular species occurring at the mineral-reagent interface of the galena-aqueous potassium ethyl xanthate system was studied by developing a technique for using an attenuated reflection method in conjunction with standard infrared spectroscopy procedures. Lead ethyl xanthate was detected from the infrared spectra of all galena surfaces treated in the pH range of 7 to 11. At pH 8.5, lead ethyl xanthate formed as a film chemically bonded to the galena surface. A solvent extraction sampling method was employed with infrared spectroscopy to obtain quantitative data on the lead ethyl xanthate removed from the galena surface. The data showed that between pH 7 and 11 thy quantity of lead ethyl xanthate physically adsorbed decreased as the pH was decreased; in the same pH range, the quantity of free lad ethyl xanthate in the aqueous medium remained constant, and the amount of unreacted xanthate varied.

Jan 1, 1966

This chapter presents data on occupational exposures from several sources. Data from compliance samples obtained by MSHA inspectors are presented in table 6-1 for coal mine dust and silica dust, and in tables 6-2 through 6-6 for metal fumes. Since these samples were taken for compliance monitoring rather than as part of a survey of the industry, it is difficult to predict how well they indicate actual exposures for all mining operations. In the coal industry, 7.8% of all respirable dust samples during 1986-1995 were above the permissible exposure limit (PEL). Of silica dust samples obtained during the 10-year period, 23.7% were above the PEL in coal, 16% in metal, 10.8% in nonmetal, 9.1% in stone, and 7.6% in sand and gravel. Of metal fume samples, silver samples showed the largest percentage above the PEL-approximately 48% of samples in both metal and nonmetal. Tables 6-7 and 6-8 present data on noise exposures from the MSHA "dual threshold" survey, which was published in the Federal Register [61 Fed. Reg. 66347 (1996)] as part of a proposed rule change for occupational noise exposure in mining. This study examined a group of samples obtained during 1991-1995 and compared the percent of samples that were above two separate specified limits. The first limit was the current noise standard, a time-weighted average of 90 dBA, calculated to include only exposures at 90 dBA and above. The second limit was a time-weighted average of 85 dBA, calculated to include exposures at 80 dBA and above. Tables 6-8 and 6-9 refer to musculoskeletal overload conditions examined in the National Occupational Health Survey of Mining (NOHSM) [NIOSH 1996]. Table 6-8 shows the operational definitions for each condition; table 6-9 shows the percentage of the workforce potentially exposed, by commodity. Across all commodities, a large proportion of workers were exposed to musculoskeletal overloads due to positioning of the neck and back; positioning and motion of the forearms, arms, and shoulders; heavy lifting; and positioning and movement of the lower limbs. The recorded overloads were defined in the survey and did not exceed any NIOSH, MSHA, or OSHA guidelines for musculoskeletal overloads. Further information on this survey appears in appendix A.

Jan 5, 2000

By Thomas M. Barczak

This U.S. Bureau of Mines study evaluates factors that influence longwall support and strata interaction. The longwall system is composed of an immediate and main roof structure and three supporting foundations: longwall panel, powered roof supports, and gob waste. The main roof forms a structure that is generally supported by all three foundations, while the immediate roof acts as a beam that cantilevers from the coal face to the powered support. In most cases, shield loading involves a complex interaction of both main roof and immediate roof behavior and is a combination of loads produced from convergence of the main roof and displacements of the immediate roof caused by deformations of the cantilevered roof beam. Since the shield stiffness remains constant for all leg pressures and main roof convergence is irresistible in terms of shield capacity, the shield must be able to control the behavior of the immediate roof or floor structure for shield loading to be sensitive to setting pressures. If the goal is to minimize total shield loading, any active setting force must be offset by reduced passive shield loading to justify the active setting loads. Field data sumest that the typical reductions in passive loading do not justify the required increases in setting pressure in some applications.

Jan 1, 2010