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By James L. Hendrix

A study was made of the United States Bureau of Mines' chlorine-oxygen leaching process for complex sulfide concentrates. The investigation sought to determine the kinetic order and IT mechanisms involved in the reactions betweens sphalerite, and galena with chlorine. The influence of copper on the extraction rates was also studied. It has been shown the rates of reaction of chlorine in aqueous solutions with sphalerite and galena are both zero order at 373K with the rate limiting step being the chemical reaction. Addition of cupric chloride increased the extractions of both lead and zinc.

Jan 1, 1980

By Rees D. Groves

The Bureau of Mines conducted research on reactions of copper sulfide minerals with chlorine in an aqueous system. Selected samples of covellite, chalcopyrite, chalcocite, bornite, and pyrite were leached with aqueous chlorine solutions. The mineral samples were sized on to minus 100- plus 325-mesh, individually mixed with precleaned sand and leached in an enclosed percolation column. Each mineral was leached in stages to achieve about 90 percent mineral dissolution. The chlorine leaching solutions were produced by reacting sodium hypochlorite with hydrochloric acid within the closed system. The study showed that when the mineral dissolution was complete, the reaction products (copper, iron, and sulfur) were in their highest oxidation states and a stoichiometric amount of chlorine was consumed. Although elemental sulfur formed as an intermediate product, it was oxidized to sulfate during the leach.

Jan 1, 1973

By Stephen C. Brown

The major developments of the world's Mineral economy in 1955 were the continued rise in production and consumption of practically all major minerals. the sharp increase in output of the fertilizer minerals in response to demands for greater food output, the cutback, in new investment for steel capacity in Europe and Japan, Europe's continuing decline as a producer of primary minerals, and the emergence of nuclear power as an economically competitive factor in the energy economies of the United States and Western Europe. In resource development, discovery of new natural gas deposits in the North Sea and the continued development of Australia's bauxite and iron ore resources, making this country a major source for these commodities, were significant.

Jan 1, 1967

By W. Beckering

IN CHARACTERIZING tars obtained by the low-temperature carbonization or North Dakota lignite, infrared spectra have been an invaluable aid in both qualitative and quantitative examination. Quite early it became evident in the tar-research program of the Bureau of Mines, U.S. Department of the Interior, that the small number of published spectra available for hydroxy aromatics would be inadequate for comparative purposes when dealing with the wide range of compounds present in coal tar; therefore, compiling a catalog of spectra was initiated as a continuing part of the tar program. As these spectra should be valuable to other investigators in this and related fields, they are being presented in this report. This group or spectra (figs. 1-98) represent 97 compounds, largely phenolic materials. The major problem of this project has been the availability of materials for examination. Samples have been obtained from commercial and private laboratories or synthesized at the Bureau of Mines Lignite Experiment Station, Grand Forks, N. Dak.

Jan 1, 1959

By Masami Hayashi

Cost evaluations were made for five processes for producing 100,000 tons of electrorefined copper per year from a chalcopyrite concentrate. The processes were (1) conventional smelting with all furnace gases vented to the atmosphere; (2) conventional smelting with converter gases routed to an acid plant and reverberatory gases vented to the atmosphere; (3) conventional smelting with converter gases routed to an acid plant and reverberatory gases to a citrate system plant; (4) conventional smelting with all furnace gases routed to a citrate system plant; and (5) a modified smelting process in which the concentrate is roasted before being charged to the reverberatory furnace, with roaster and converter gases routed to an acid plant. The total fixed capital costs of the plants were estimated as (1) $56.7 million, (2) $77.4 million, (3) $87.2 million, (4) $73.9 million, and (5) $77.0 million, respectively. Total S02 removal from stack gases as sulfuric acid or sulfur for each process was (1) none, (2) 66 percent, (3) 99 percent, (4) 98 percent, and (5) 78 percent. Assuming no credit for byproduct sulfur or sulfuric acid, total operating costs per pound of electro-refined copper produced were estimated as (1) $0.081, (2) $0.103, (3) $0.119, (4) $0.111, and (5) $0.103, respectively.

Jan 1, 1974

By David B. Doan

This regional report covers 1993 mining and related activity in approximately 40 countries and territories of Canada, Latin America, and the Caribbean Basin. These countries of the Western Hemisphere, as with the United States, are endowed with a great variety of minerals, including metals, industrial minerals, and energy minerals. For most of these countries, such mineral production helps form foundations for their economies and earns export credits including hard currencies. Table 1 depicts an overall view of Latin America and Canada's production of its major mineral commodities in 1993; subsequent tables show the role of Latin America and Canada in world mineral production, trade, and import dependency on minerals from Latin America and Canada by the United States. Overall, the picture emerges of a rich mineral diversity throughout the hemisphere, attracting increasing interest and investment, and complementing the mineral resources of the United States.

Jan 1, 1995

By J. G. Stuart, A. W. Cipkins, R. H. Thompson

Preliminary safe distances for blasting wiring from typical electromagnetic sources are presented. The distances are for underground coal mines and electromagnetic sources in the frequency range below 10 MHz. The distances are based on measurements performed at 3 locations in each of 3 coal mines. The measurement apparatus, measurement procedure, measurement results and the rationale used in the calculation of the safe distances are all described. The safe distances presented are dependent on the measurement results and their interpretation. More measurements are clearly necessary to establish the validity of the suggested distances.

Jan 1, 1985

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) spin trapping methodology has been used to study the reactions of manganese dusts with glutathione, employing a-{4-pyridyl-1-oxide)·N-tert-butyl-nitrone (PBN) and 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as spin traps. The results show evidence for the glutathionyl radical formation in the reactions of both MnO2 and manganese (Ill) acetate with glutathione. Based on these experimental observations, we hypothesise that the mechanism of neurotoxic effects of manganese might be due to the fact that the generation of glutathionyl radicals depletes the glutathione pool and reduces the glutathione shield against free radical products of dopamine metabolism and manganese induced reactive oxygenated species. IntroductionExposure to manganese compounds often occurs as the result of foundries and mining operations (1. 2). Other significant sources of environmental manganese include coal-fired power plants and burning of residual and crude oil (3, 4). Lately gasoline combustion has also started to contribute since manganese (methyl cyclopentadienyl manganese tricarbonyl. 0. 125 g/gallon) is being used instead of lead as an antiknock ingredient in automobile fuels (5. 6). Although manganese is an essential element in certain biological processes it is toxic in excessive amounts. The manganese toxicity is mainly associated with the nervous system (7-9). Symptoms frequently observed in manganese poisoning or manganism are disorientation, memory loss, anxiety, compulsive laughing and crying, mask-like faces, akincsia rigidity and tremor (10). In spite of numerous investigations to understand the mechanism of manganese induced injury. it has not been possible to localize the initial chemical lesion responsible for altered physiology and ultimate cell death. This may perhaps he the reason for failure in developing a successful therapy for manganese intoxication."

Jan 1, 1990

By Roger J. Morrell

The Bureau of Mines conducted drag cutting experiments in hard, abrasive rock in an effort to extend the capabilities of an experimental kerf-core mining machine. The basic kerf-core mining machine cannot be used in hard, abrasive rocks because of the high wear experienced by the kerf cutters. These experiments were conducted in an effort to develop a method of preweakening the rock ahead of the kerf cutters in order to reduce the high cutting loads and hence the higher wear rates experienced by the cutters. The two "preweakening" techniques studied were indenting with mechanical wedges and single and double slotting with diamond saws. The best cutter force reduction achieved with mechanical indenting as 70 pct, whereas double slotting achieved force reductions of up to 99 pct. Conceptual designs of preweakening systems that could be retrofitted onto the basic kerfing cutterhead were developed for both the indenting and the slotting techniques. A high-energy impactor with wedge bit was used for the indenting method, and high-pressure water jets were used for the slotting method. A preliminary technical and economic analysis was performed for both of these full-scale systems to illustrate the methodology and to point out the important technical and economic factors that must be considered.

Jan 1, 1987

By M. J. Ferrante

Enthalpy and entropy increments above 298.15° K were determined for cop-per sulfate between 298° and 1,000° K and for copper oxysulfate between 2980 and 1,146° K by the method of copper-block drop calorimetry. Enthalpies, entropies, and heat capacities are tabulated for both compounds. In addition, free-energy functions are tabulated for the sulfate. Equations representing the enthalpies are given for each compound.

Jan 1, 1972

By Paul W. Jeran

This Bureau of Mines report has been prepared to provide a means whereby mineworkers without specific geologic training can recognize and record the existence of potentially hazardous geologic features encountered in coal mines. Each geologic feature described in this report has been implicated in roof failure. Through the recording of the observations of mineworkers, based on this report, a geologic map of mine workings and the associated ground control problems can be compiled. From such maps, the trends of changes and features can be determined and projected ahead of mining. The face crew can be alerted to a potential problem and what to look for as the face is advanced.

Jan 1, 1983

By Gary P. Sames

The Bureau of Mines recently initiated a study of geologic features that contribute to roof instability in western U.S. underground coal mines. The purpose of the study is to provide information for use in ground control planning and safety hazard reduction in that region, where mining activity has been increasing. Hazardous geologic conditions were surveyed in selected underground coal mines in Utah and Colorado, and both depositional and structural features were identified as potential ground hazards. Although the conditions found do not differ in kind from hazardous geologic conditions in the Eastern United States, they do differ in intensity of occurrence and relative importance. Three depositional features dominate where unstable roof occurs in western underground coal mines: paleochannel deposits, crevasse splay deposits, and flood basin deposits. Three structural features identified as hazardous, but not so widespread or common as the depositional hazards, are faulting, jointing, and igneous intrusions. This survey establishes a foundation for future studies aimed at reducing and preventing ground control accidents in western coal mines.

Jan 1, 1988

By J. H. Wiggins

In 1919 the United States was threatened with a shortage of gaso- line. In spite of this well-known fact, a detailed field investigation has shown that in one stage only of handling crude oil the volume of gasoline that evaporates is equal to one-thirtieth of the country's yearly gasoline production. This loss occurs during the few days that the oil is stored on the leases before being taken by the pipe line, and in 1919, in the Mid-Continent field alone, it amounted to 122,100,000 gallons. Large as it is, it is only a part of the loss on the lease. Investigation has further shown that the gasoline in crude oil evaporates from one-half to six-tenths as rapidly as the same gaso- line after being distilled and stored, all evaporative conditions being the same. Many wastes in the oil fields are called "necessary." By this is meant that the cost of preventing the waste is greater than the gain through saving. Evaporation losses have fallen heretofore in this category, but now they must be considered unnecessary. In other words, it is no longer economical for any handler of crude oil to permit losses through evaporation. In accordance with its purpose of seeking to conserve mineral resources, the Bureau of Mines investigated the loss of gasoline by evaporation in the storage and handling of petroleum. Inasmuch as most producers had not decided that their losses justified cor- rective measures and no evidence was available on the comparative losses in various stages of handling the oil, the investigation was limited to determining by experiment and observation the nature and magnitude of evaporation losses, where the greatest losses are, and the factor controlling evaporation.

Jan 1, 1922

By W. H. Rinkenbach, C. A. Taylor

"Among the recently patented detonating compounds that have been suggested as substitutes for the commonly used fulminate of mercury is the normal lead salt of trinitroresorcin, or styphnic acid. As no data concerning its use or practi¬cability were available, a study of its properties was made in the explosives laboratory at the Bureau of Mines experiment station at Pittsburgh, Pa. This paper embodies the results obtained.Normal lead trinitroresorcinate was first prepared and patented*** by Herz; it probably found some use during the World War, but no record of its performance is available,Preparation of Lead Trinitrpresorcinate.In his patent specifications, Herz states that the normal salt may be obtained in a quantitative way by precipitating a multiple of the equivalent weight of the lead salt of a strong inorganic acid - such as lead nitrate - in the presence of a weak organic acid - such as acetic acid - by heating with a Teak solution of the alkali-metal salts or alkaline-earth salts of trinitroresorcin. Herz gives the following example: 245 grams of dry trinitroresorcinand 290 grams of crystalline sodium carbonate are dissolved in in 18.8 liters of boiling water, to which 77 c.c. of glacial acetic acid is added. The toiling solution is mixed with a boiling solution of 650 grams of lead nitrate in 1.4 liters of water, stirring rapidly; and the mixture is boiled for two minutes, after which it is cooled quickly with constant stirring. The precipitated crystals are then filtered off, washed several times with cold water, and dried."

Oct 1, 1923

By L. D. Tracy

For many yeirs natural gas has been the principal fuel used in the he·1 ting furnaces in those mills located in the. Pi t-c;s. b.urgh district· \7hich manufacture bolts ., nuts, rivets, pick$, mattocks and srr.&11 for6ine;s. For a nUI.1"'.::>er of years the steady supply of this fuel has been more or less interrupted owing to the increased4and f·or d9mes tic use and to the increasing difficulty in securing an ad.eq_ua te c.1mount of natural gas. This condition has led a number of the steel compa.nies to substitute -oulvsrized coal a.s a fuel for the.furnaces. Elaborate irista.llations have been made for pulverizing tne coal ar!d _ coriveyi16 i -c to the fur:waces. • Soon after the furnaces ·-:commenced .. to operate ·,Vi th :pulverized coal, large quanti ties O::f.' fine dust beg.::in to accumulate on the platforms over the fu:rna. ces, the. roof trusses, on the outside of the va.rious· pip·e ·line electric cables a.i.1.d even on the roofs of the buildings. Some of tha comi:,a.n:;.0s, becomin·g alarmed, requested the Bureau of ;Unes to rr.c1ke an investigation to ascertcliin the.· licibili ty of this dust to cause an explosion.· Nhi le conducting this inves ti ga ti on,· an explosion· occurr-2! d in a.nothe:2 nill ·,7hich caused he death of one man and severely burned t;io others. Eleven sc1nrcles of the dust (which for convenience has been termed "mill d.ust 11 ) from various locations in the different mill' buildings were taken and submitted to chemical analyses, microscopic examination and also to flame and explosion tests. From the chu,1ica.l analyses it was found that· the volatile matter in th..:: dusts xanged -from 6.3 per cent to 23,54 per cent, fixed carbon from 50.88 per cent to 67.08 per cent and ash from 32.29 per cent to 32.16 per centw

Dec 1, 1919

By S. M. Runke

[The coarse-grained granitic pegmatities of the United States have long been a source of many important industrial minerals, because of this, they have been studied intensively by geologists, mining engineers, end metallurgists. These studies have amassed a rather astounding array of published and unpublished information. Correlation of geological studies between individual pegmatites, as well as between major districts, has brought fort come semblance of order to the knowledge of the structure and mineralogical composition of those highly complex and irregular deposits, making it possible to classify certain pegmatites and pegmatitic zones into several grouts of associated minerals, based upon the presence or absence of the minor minerals of beryllium and lithium. This classification or trouping of minerals, with the methods that have been developed for recovering certain of these minerals, possible a systematic approach to the winning of many of the industrially important minerals from pegmatite rock by u single integrated process.]

Jan 1, 1952

Determine the effectiveness of remining operations in reducing contaminant load (acidity, iron, and sulfate) of discharges emanating from abandoned surface and underground coal mines. Background Until the implementation of remining initiatives, most States had regulations that held the operator remining an abandoned site responsible for preexisting acid mine drainage (AMD) discharges. For example, if a mining. company wanted to remine an area hydrologically connected to an existing AMD discharge, the company became responsible, as soon as the site was activated, for treating that discharge to meet effluent standards. If the mining operation improved the quality of the discharge, but the discharge failed to meet effluent standards, the company was held accountable for perpetual treatment. Because of this regulation, most mine operators avoided abandoned sites with minable coal reserves and AMD discharges. However, changes in remining legislation allow coal companies to be released from treatment liability as long as the post-remining pollution load does not exceed the pre-remining level. If remining can improve water quality through improved mining and abatement techniques, abandoned mine land (AML) areas that previously were liabilities could become

Jan 1, 1994

Identity the difficulties of establishing vegetation on mining-related wastes resulting from adverse chemical, physical, and biological properties; describe the ecological and soil factors affecting the relationship between mycorrhizal fungi (soil microorganisms) and plants; and evaluate the feasibility of establishing vegetation on mine waste by introducing mycorrhizae. Problems in Revegetation Successfully using vegetation to stabilize a situ disturbed by mining-related activities depends on knowing the chemical, physical, and biological characteristics of the site prior to, or at the time of, stabilization. The primary objectives of mine land reclamation are to minimize environmental degradation and to facilitate the re-establishment of a functional plant-soil system. Mining disturbances can significantly alter the physical, chem¬ical, and biological characteristic of a site, thus affecting plant establishment, survival, and growth. The physical disturbance caused by the removal and replacement of soil and overburden, together with the waste material from ore processing, affect the chemical, physical, and biological process within the disturbed soil or waste. Additionally, variability in soil properties results from differences in climate, topography, vegetation, and parent material of the site.

Jan 1, 1993

Establish a procedure for reliably determining cation exchange parameters at an in situ mining site. The Problem Predicting the movement rates of pollutants from waste disposal sites requires reliable measurements of cation exchange parameters since cation exchange can retard pollutant movement. Reliable measurements of these parameters are also required for predicting the length of time needed to restore groundwater quality after in situ mining. Cation exchange is otten the controlling mechanism for the replacement of leach solution cations by the cations in the returning ground-water. Unfortunately, laboratory measurements using core samples are of minimal reliability. The uneven clay distribution at most sites produces a high variability in laboratory results. In addition the flow pattern in the laboratory tests is different from that in the field. Approach Bureau of Mines research has developed a field-test procedure that is quick and yields reliable and representative data. A corresponding data analysis procedure was also established in order to verify the' applicability of the computer simulation model of cation exchange used in the analysis, and of the general analysis procedure, with actual field data.

Jan 1, 1986

The U.S. Bureau of Mines (USBM) has developed a test procedure to compare the initiating strength of detonators by using adjustable-sensitivity liquid explosives. Various tests of detonator strength are currently used by the industry, but many of them do not quantify the ability of detonators to initiate detonation reactions in an explosive charge. The USBM used mixtures of nitromethane and ethylene diamine, the sensitivity being "fine-tuned" by 2-nitropropane. Military standard J-2, commercial No.6, and commercial No.8 detonators were evaluated using three test configurations: (1) axially immersed in the test explosive, (2) tip just touching surface of the explosive, and (3) immersed transversely in the explosive. Markedly different results were obtained for these three configurations, indicating that the directional effects are important. This explains why different detonator strength tests do not correlate well with each other. Some tests, such as the sand bomb and underwater, measure the total energy out-put, while other tests, such as the plate dent, test measure the energy in the axial direction. The USBM's test data indicate the importance of conducting the experimentation in the manner in which the detonator is actually intended to function.

Jan 1, 2010