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By A. S. Moore

The Bureau of Mines is doing research and development work on removing acid-gas impurities from synthesis gas made directly from coal. Since conventional gas scrubbers, packed towers and bubble-cap columns, are expensive to construct and difficult to operate with viscous solutions, one aspect of the work was developing a compact, agitated, gas-liquid contactor for use with concentrated absorbents. The efficacy of the agitated contactor for absorbing carbon dioxide in diethanolamine increased with increasing solution rate, turbine speed, diethanolamine concentration, and carbon dioxide concentration in feed gas, and with decreasing liquid-gas ratio. It was unaffected by pressure between 200 and 300 p.s.i.g. and little affected by temperature between 115 and 190° F.

Jan 1, 1961

By Christopher C. Jobes

Computer-assisted control of a mining machine can place the operator in a safe, remote location. A guidance system aids remote positioning of a mining machine by determining its position and heading. The mechanical position and heading system (MPHS) is one of several guidance systems being developed at the U.S. Bureau of Mines. The MPHS uses linear position transducers (LPT's) to provide navigation information during face maneuvers. This report presents an overview of the MPHS theory and implementation, including recent design modifications made for more successful underground testing. This report also presents the experimental setup and procedure for the underground test. The test showed that the MPHS provides reliable and accurate results and can, therefore, provide useful guidance information for face navigation.

Jan 1, 1992

By Ludwig Schmidt

[The use of vapor-tight tanks has proved so effective in reducing the evaporation losses of petroleum that today practically all operators are using this typo of equipment. It has boon shown, however, that vapor-tight tanks should be supplemented with additional measures which will further reduce evaporation. Probably the most effective use of the supplemental measures are found on the small producing leases where the breathing losses from vapor-tight stock tanks materially affect the volume and gravity of the stored oil. The breathing loss from a vapor-tight stock tank that is filled and emptied daily is a negligible quantity. Also, the filling loss, which on the average varies between 0.1 and 0.2 per cent, usually is not of a sufficient quantity to affect materially the value of the crude. However, the combined breathing and filling losses from a vapor-tight tank requiring several days to fill are of sufficient importance to warrant the use of measures in addition to the vapor-tight tanks. The breathing losses are caused by atmospheric variations. Probably the greatest are the changes in atmospheric temperature which cause changes in temperature of the vapors in the tank. During the day, as the temperature increases, the gasoline-saturated vapors in the tank expand and are forced out into the atmosphere. At night the vapors are cooled and contract, drawing into the tank fresh air, which becomes saturated with gasoline vapor and is forced out of the tank during the following day. In Addition to the maximum and minimums temperature variations there are many smaller variations throughout a twenty-four period caused by showers, clouds, winds, and other atmospheric conditions which likewise cause the tank to breathe. The two mist common measures used by lease operators for reducing breathing losses in vapor-tight tanks are, first, operating; lease tanks under pressure, and second, the use of light colored paints anti tank houses. In this report these two methods are discussed together with their adaptability to lease operation. Results of experimental observations are given which show the reduction of evaporation looses where these supplemental measures have been used.]

Jan 1, 1927

By R. H. Thompson

Six different types of blasting caps, mainly of the type used in coal mines, were evaluated to determine both their 1lF and DC characteristics. Two of the caps were of foreign manufacture. All the American made caps had "no-fire" (0.1% firing probability with 95% confidence, as determined by the Bruceton test) levels above 0.04 watts. One of the caps of foreign manufacture had a "no-fire" level of 0.023 watts. A worst case analysis of blasting cap pick up of RF power in coal mines was performed and safe distance curves were generated.

Jan 8, 1973

By A. J. Forney

Recent experiments used catalysts of plate assemblies in synthesizing high-Btu gas and gasoline indirectly from coal. A gas with a heating value of 925 to 943 Bt-: per cubic foot has been prod u la the hot-gas-recycle pilot plant from synthesis gas (3H2+100) with lathe turnings used as catalyst in the first reactor, and assemblies of parallel sprayed plats of nickel in the second. Solid plates made of Raney nickel, and steel and aluminum plates sprayed with Raney nickel or nickel oxide were tested. Those catalysts had very low resistance to gas flow; 90 percent lower than nickel granules used in previous experiments. In a single stage of synthesis thee nickel plates were only partially successful. Although the heating values of the product gas ranged from 856 to 941 Btu per cubic foot, the carbon monoxide content of he gas was above 0.1 percent. Both steel and wrought turnings were tested in single-stage synthesis, but the conversion of hydrogen and carbon monoxide was too low to attain the desired heating value of 900 Btu per cubic foot in the product gas. Assemblies of plates thermally sprayed with fusel iron were tried in an experiment to make gasoline. A gasoline yield of 52 percent (of the hydro¬carbons produced) was obtained using a 1H2-10O feed These sprayed assemblies were in service for 1,500 hours, the longest that this type of catalyst has been used. When a second reactor containing Raney nickel catalyst was added in series with the first reactor, complete utilization of the feed gas was obtained because in addition to the liquid product, a high-Btu gas with a heating value of 800 Btu per cubic foot was made.

Jan 1, 1965

By Barry L. Warner

This program involves testing to determine whether a fire hazard exists when the exposed wood surface area of timber in a mine passageway equals 40 percent of the surrounding strata surface, excluding the sill. Twelve full scale fire tests were conducted in a simulated mine passageways, using kerosene pan fires as the ignition source. The tests included three timber sizes, plus one test with roof lagging, two wood types, plus one test with treated timbers, and two ventilation air velocities. The results show air velocity to be an important factor in the occurrence of flame propagation, and that the 40 percent surface area ratio of wood to surrounding strata appears to b0. a valid criteria for fire safety at 150 fpm, but not at 350 fpm.

Jan 1, 1975

By H. E. Perlee

Autoignition temperatures and limits of flammability of nine halogenated hydrocarbons in atmospheres of air, oxygen, and nitrogen tetroxide were measured in a modified standard autoignition apparatus and limit-of-flammability apparatus previously developed at the Bureau of Nines. Of the nine halogenated hydrocarbons investigates--bromochloromethane, bromotrifluoromethane, bromochlorodifluoromethane, 1,1,2-trichlorotrifluoroethane, 1-bromo-l-chloro-2,2,2-trifluoroethane, dibromodifluoromethane, l,2-dibromo-1,1,2,2-tetrafluoro-ethane, 1,1,1,3,3-pentachlorotrifluoropropane, and l-bromo-2,4-dichloro-1,1,2, 3,3,4-hexafluorobutane--two formed flammable mixtures with nitrogen tetroxide and six with oxygen; none formed flammable mixtures with air. Three of the halogenated hydrocarbons formed no flammable zones with any of the three oxidizing atmospheres. For those halogenated hydrocarbons that supported combustion in oxygen atmospheres, explosion pressures developed during constant-volume burning of mixtures near the middle of the flammable zone were observed to range from about 6 psig for dibromodifluoromethane to 158 psig for 1-bromo-1-chloro-2,2,2-trifluoroethane. In all cases, the calculated burning velocities of these mixtures were less than 8 in/sec.

Jan 1, 1966

By T. Kessler

Spark-source mass spectrometry has been used to determine the amounts of minor and trace elements in coal particles of various sizes, including the respirable range (<5 microns). Fifty-six elements ranging in concentration from 0.1 ppm wt to 5,000 ppm wt have been determined. The investigation of coal and coal ash has shown that the organic material in coal does not interfere with the spark-source determination of the various elements.

Jan 1, 1971

By Frank C. Morris

This report presents the results of a Bureau of Mines study to identify clays found in several petroleum-reservoir rocks in the Tejon-Grapevine area, Kern County, Calif., and to determine the effect of water sensitivity of the clays on the permeability of the reservoir rocks. The clays in the porous rocks were examined in detail, and the clay-mineral types were identified by differential thermal analysis, X-ray diffraction, and optical and dye-staining methods. Fresh-water damage to the permeability of the oil-reservoir rocks was indicated by a study of 125 core samples from productive formations. The study indicated that, although clays were generally less than 5 percent of the reservoir rocks, they swelled in water, particularly fresh water, and nearly blocked the flow channels through which oil flows to the well, effectively reducing the permeability of the formations. The average permeability of rock decreased from 1,600 millidarcys in air to 620 millidarcys in salt water and 120 millidarcys in fresh water. The dominant clays in the oil-bearing sandstones were members of the montmorillonite group. They were associated with smaller quantities of clays found to be in the mica or illite group. None of the cores appeared to contain clays of the kaolinite group. In the lower section of the J.V. sandstone indications of what appeared to be the mineral sepiolite were noted.

Jan 1, 1959

By R. V. Ramani, R. Bhaskar

"While the National Academy of Sciences has stated that gravimetric sampling technology for compliance purposes is adequate, research into various aspects of respirable dust control require data on many other parameters of airborne dust. These, in turn, have created the need to use many instruments, other than personal gravimetric samplers, in mi ne environments for dust measurement. There is a need to evaluate the performance of these instruments under conditions of potential use.As part of research in the Generic Technology Center for Respirable Dust, cascade impactors, gravimetric personal samplers and gravimetric samplers collecting dust using isokinetic sampling principles were employed for dust measurements under identical conditions in a mine airway. During the course of the experiments, 8-stage cascade impactors and gravimetric samplers drawing air isokinetically were located in the center of a mine airway at various stations. Two types of data were examined - concentration of dust and size distribution of the dust collected in the samplers. The data show that the amount of dust collected by an impactor is less than half the amount collected isokinetically. The size distributions of the dusts collected from the two instruments, though comparable, show a consistent difference in median diameters. The cause for this bias is examined.The paper presents and discusses the results of the tests, including the concentrations and size distributions obtained from the two instruments for different experimental conditions. There is a need to document the performance of various dust measuring devices in mine airflow conditions.INTRODUCTIONThe sampling of airborne dust in mines can be done for several purposes. Traditionally, dust sampling has been restricted to the gravimetric measurement of airborne respirable dust to comply with the regulations governing the mining industry. Instruments such as the MRE gravimetric sampler, and personal gravimetric samplers that have collection characteristics similar to the human respiratory system have been in use for the last two decades. Presently available instrumentation for the purpose of regulation have been considered adequate by the Committee on the Measurement and Control of Respirable Dust in Mines (National Academy of Sciences, 1980),"

Jan 1, 1989

By H. P. Greenwald

"INTRODUCTION In the course of its studies of the explosibility of various coal dusts in the Experimental coal mine, the Bureau of Mines has tested coals representing the entire range of volatile content found in the United States. In connection with their work the Bureau's field engineers some¬times meet operating officials who are not impressed by the fact that there is an explosion hazard in mines working low—volatile coals. Actually the difference in explosion hazard between high—volatile and low—volatile coals is one of degree and not of kind. The purpose of this paper is to set forth briefly the experimental evidence that has been accumulated on the explosibility of coal dusts containing 8 to 31 percent volatile matter on a dry, mineral—matter—free basis.There have been numerous dust explosions in mines in which coals were worked that have compositions within this range. Those explosions are listed in an appendix, together with a bibliography of Bureau of Mines papers describing explosion tests in the Experimental coal mine."

Jan 1, 1940

By E. T. Bowers

The Accident Analysis (ADA) computer program was developed at the Spokane Research Center (SRC) to provide a rapid broad-based analysis of mining accidents. Because the Bureau of Mines often needs this type of information for the development of viable research programs the ADA program was written to access and analyze accident data available frog the Labor Department&apos;s Mine Safety and Health Administration (MSHA). This report describes the ADA program, the data it uses, and the potential value it has for planning mining research.

Jan 1, 1987

By J. D. Sargent

Selenium might be described as a paradoxical element, being a metal or a nonmetal, a conductor or nonconductor, amorphous or crystalline, colorant or decolorant, and a hydrogenator or dehydrogenator. Selenium was discovered in 1817 by the Swedish chemist, Berzelius, while studying flue dust from the lead chambers of the sulfuric acid works at Gripsholm, Sweden.

Jan 1, 1954

By G. R. Hopkins

Although many small refineries were dismantled in 1934 the total number of plants, including a few under construction, increased from 604 at the beginning of the year to a new high of 638 on January 1, 1935. The capacity also reached a new record, the total of 4,072,400 barrels of crude oil daily being about 45,000 barrels higher than the previous high of January 1, 1932. The number of refineries increased materially in 1933, following construction in east Texas and the building of many small plants in the Rocky Mountain district and elsewhere. Most of the new plants of 1933 were built to provide an outlet for crude or because the ratio between crude oil and gasoline prices appeared conducive to profits However, low gasoline prices and increased costs in 1934 dispelled the hopes for profits; many plants were shut down, and some were dismantled. The number of operating plants declined from 454 on January 1, 1934, to 435 on January 1, 1935, but the number of inactive plants increased from 137 to a new high of 196 during the same period. As indicated above, new construction was at a minimum in 1934, and on January 1, 1935, only 7 plants were being built.

Jan 1, 1935

By Chas. F. Jackson

This paper is a tabular compilation of data contained in a series of information circulars dealing with mining methods and costs at a large number of mines in the United States and some foreign countries. There circulars have been published from time to time during the years 1929 to 1934 inclusive. From time to time, as enough data became available in these circulars, other circulars and. bulletins have been published in which the data bearing upon different phases of nine operation were summarized, discussed, and analyzed. The present paper is a compilation of data on costs of drifting and crosscutting contained in earlier circulars, .designed to assemble this information in a convenient form for reference without attempting lengthy discussion of details of drifting and crosscutting practice. For such details the reader is referred to the circulars on individual mines.

Jan 1, 1935

By J. S. Tosh

The Federal Bureau of Mines has investigated the equilibrium of the system potassium carbonate (K2C03) potassium bicarbonate (KHCO3) potassium bisulfide (KHS) carbon dioxide (C02) hydrogen sulfide (H2S) water (H20). Partial pressures of hydrogen sulfide, carbon dioxide, and water vapor were measured at 70° to 130° C. over solutions of 20-, 30-, and 40-percent-equivalent potassium carbonate containing from 20 to 3,000 grains of equivalent hydrogen sulfide per gallon of solution. This study was made to obtain equilibrium data for evaluating the feasibility of using solutions of hot potassium carbonate for removing, hydrogen sulfide from gas mixtures. The equilibrium partial pressure of hydrogen sulfide may be correlated with the ratio of the molal concentrations of the solutes (KHC03) (KHS)/ (K2CO3). The relationship is shown graphically for the 30- and 40-percent solutions. Once this ratio is determined, the partial pressure of hydrogen sulfide can be obtained from the curves. The equilibrium data show that effective removal of both carbon dioxide and hydrogen sulfide can be achieved simultaneously with hot solutions of potassium carbonate.

Jan 1, 1960

By J. M. Singer

Quenching distances for flames of methane-coal dust mixtures were determined with air and oxygen-enriched air. Coals used were Pittsburgh, Sewell, and Pocahontas No.3. Quenching distances were greater for flames of hybrid mixtures of coal dust and methane than for methane flames of corresponding stoichiometry. From the data of quenching distances and methane-coal dust concentrations was calculated the quenching equivalence, which is the increase in coal dust concentration required to maintain a given quenching distance value as the methane concentration decreases. These equivalences could be useful in identifying hazardous methane-coal dust mixtures in mines.

Jan 1, 1966

Oil from shales has long been a source of fuel in foreign countries; however, in the fuel economy of the United States this source is classed as a reserve for future needs. In fad, shale oil has never been produced here in quantities necessary to establish oil-shale utilization as a sustained industry. The first known resources of stored energy that man endeavored to utilize were probably wood and water, and from these he directly obtained heat and power, respectively. With the evolution of man came the search for and the development and use of other natural fuel resources, the series progressing through the solid, liquid, and gaseous fuels until today those of one type can be converted into another, depending upon the use for which they are intended. The most important fuels are those that appear naturally in the most concentrated, conveniently obtainable, and usable forms. With the discovery of each new and more concentrated fuel there has been an appreciable increase in the importance of and number of devices for converting these fuels into energy.

Jan 1, 1938

By Gordon E. Fletcher

This Bureau of Mines report outlines the atomic absorption analysis of oilfield brines for barium, calcium, copper, iron, lead lithium, magnesium, manganese, potassium, sodium, strontium, and zinc, using the method of additions. The advantages of using atomic absorption are discussed. The method of additions was chosen to overcome large matrix interferences usually found in brines; techniques of overcoming chemical, ionization, and background interferences are also described. The method was used to analyze several hundred oilfield brines and found to be rapid and reasonably accurate. A solvent extraction method was used to concentrate lead, copper, zinc, and iron in low-level samples.

Jan 1, 1974

This paper describes the sinking and lining of a 14 foot 6 inch finished diameter shaft down to and into the salt of a typical dome of the Gulf States region. The conditions and nature of the strata encountered divide the work into three distinct sections - that in (1) alluvial surface deposits, sunk through by open caisson methods, (2) water bearing rock, directly above the salt, and in (3) salt. ACKNOWLEDGMENT The writer wishes to acknowledge the cooperation of the sinking contractors, The Dravo Contracting Co. of Pittsburgh, Pa., through E. T. Gott, vice-president, in furnishing the data used in this paper.

Jan 1, 1932