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By Charles W. Merrill

The U.S. Treasury stocks of silver have been reduced at such a rapid rate to meet industrial and coinage requirements that they face exhaustion in 3 or 4 years. Alleviation of the silver problem will require increasing supply or reducing demand. This paper examines possible long-range resource development and research programs and improved secondary recovery. The possible reduction or elimination of silver in coinage and development and introduction of substitutes in the arts and industry are also discussed.

Jan 1, 1965

By Y. Miron

Previous studies at the Bureau of Mines outlined the hazards of ammonium nitrate-fuel oil (AN-FO) mixtures in the presence of pyrite-bearing ores. The recent trend in the mining industry to strengthen AN-FO by the addition of aluminum metal raised the question regarding the effect of aluminum in AN-FO in the presence of pyrite-bearing ore. Laboratory work, similar to that done previously, demonstrated that the temperature of a self-sustaining reaction in the presence of AN-FO ore-aluminum is not lower than that for a comparable AN-FO-ore mixture. However, as might be expected from known thermochemical data, once initiated, the resulting reactions between AN-FO, aluminum, and pyrite are much more vigorous than those observed for AN-FO and pyrites alone. The temperature required to produce a self-sustained reaction for the combinations tested in this study is 250°±20° F while in the previous Bureau study, reactions were noted, in some instances, at 150° F. The different pyritic ores may be the cause of this variation.

Jan 1, 1976

By L. C. IlsLey

The observations made by Bureau of Mines engineers of permissible equipment installed in about 40 mines have indicated a chance for improvement in designs calling for the use of bolts , screws , studs , etc. , especially with respect to bolt sizes and protection from mechanical injury .

May 1, 1931

By E. P. Youngman

The rapidly growing demand for titanium pigments has aroused new interest in actual and potential sources of supply of titanium- bearing ores , which only a comparatively few years ago were almost unmarketable . This paper , which supplements a general circular entitled " Titanium" ( Information Circular 6365 ) , represents a summary of current trade literature and Government reports , together with some hitherto unpublished material that has accumulated in the files of the Bureau of Mines . The purpose of this pamphlet is simply to indicate the commercial possibilities of the deposits , and the discussion is confined almost entirely to the three commercial ores , ilmenite , rutile , and magnetite ( titaniferous iron ore ) .

Oct 1, 1930

By L. C. IlsLey, H. H. Clark

In various publications relating to safety in mining the Bureau of Mines has called attention to the hazards attending the use of openBame lamps. An open-flame lamp is a potential source of danger in any coal mine. It may start a fire in a dry mine or an explosion in a gaseous mine. The type of open-flame oil lamp now used in mines is the product of long evolution; its principal merit is simplicity. That such a light is unsafe in an atmosphere containing gas (methane) is evident, and Sir Humphrey Davy immeasurably increased safety in coal mines when he found means of protecting a lamp flame so that it would not readily ignite gas. The safety lamp, however, gives less light than the open-flame lamp, is not as simple in construction, is more cumbersome, and must De carried in the hand .. Consequently, some miners are reluctant to abandon the open-flame lamp for the safety lamp, and risk their own lives and the lives of their fellow workers with the one rather than to be hampered by the other. When small electric bulbs, with their clear, white light, and small electric storage batteries became available, the advantage of combining these elements for a miner's lamp seemed manifest. The combination looked simple and safe, but was soon found to have elements of danger and weakness peculiar to itself. The Bureau of Mines showed, in 1911, that the breaking of a miniature electric bulb in an inflammable mixture of gas and air might ignite the mixture, so that only the fragile glass of the lamp bulb might stand between the miner and injury or death. There Was also a possibility that sparks from the small battery would ignite gas, and the accidental spilling of the contents of a battery on the miner's clothing or skin was a possible source of injury. The first portable electric miner's lamps that were carried in the hand, or with the battery strapped to the back and the light carried on the head, were exceedingly crude and were designed without appreciation of the sources of danger. The possibility, however, of producing a safe and practical miner's lamp by the proper combination and design of the elements available promised to increase safety so greatly that the Bureau of Mines attemr>ted to stimulate better design and construction by careful investigations and the establishment of an approval system that would be an assurance to the miner and an advantage to the maker of the lamp. As a result various manufacturers submitted types of lamps, cords, and bulbs for test and cooperated with the bureau in efforts to so improve the safety features of these devices that the lamps would P&$ specific tests for approval.

Jan 1, 1917

By S. K. Ash

In arriving at economic losses in coal mining due to accidents, a statistician is confronted with many difficulties on account of the lack of information relative to nonfatal accidents. For comparative purposes the ex¬ perience of those countries, States, or companies that keep complete records can be drawn upon and an extimate can be arrived at whereby one State can be compared with another, or one mine compared with another in the same district. Such a comparison for the United States has been compiled by the United States Bureau of Mines. It will be observed in Table 1 that the cost per ton for accidents in the State of Washington for the year 1927 is higher than for any other State, with the exception of Georgia and North Carolina, with a small combined tonnage of 130,089 tons. (The figures for coal production in Table 1 are taken from Bulletin 319, 1930, of the United States Bureau of Mines.) The reasons why the cost of accidents in Washington might be higher than the average are on account of physical conditions such as steep pitches, faults, igneous intrusions, highly explosive coal-dust, extremely friable coals, presence of gravel and water, very gassy coal beds, rugged topographic conditions, inherently bad roof and floor, thick beds, and heavy cover. The nature of the coal beds requires the use of preparation machinery. The mines are often deep, and topographic conditions are such that long and fast haul¬ age becomes necessary. All of these factors not only tend to cause high cost of production, which is manifested largely in a. lower than average daily pro¬ duction, per man, but..they.also affect to some degree a tendency toward a higher than average cost for accidents.

Nov 1, 1931

By W. W. Adams, T. D. Lawrence

"The National Safety Competition conducted by the Bureau of Mines, United States Department of the Interior for the promotion of safety in mines and quarries, has just been closed for seventeenth consecutive year. Enrollment covered more plants than in any previous contest. Moreover, a larger volume of employment was represented than in the contests of previous years, and several new plants were enrolled for the first time. Six safety trophies are awarded annually in these competitions one to the leading plant in each of six groups. An anthracite, mine in Pennsylvania, a bituminous-coal mine in West Virginia, a metal mine in Tennessee, a nonmetal mine in Virginia an open-cut mine in Minnesota, and a quarry in Alabama won the 1941 trophies.To be eligible to win a trophy, a mine or quarry must have had at least least 25 men working under ground or in the pit for not loss than 100 days. The number of man-hours worked must total 30,000 or more. Mines or quarries having no accidents during the year are rated according to the number of man-hours worked. If there are no plants with accident-free records, the mines and quarries in each of the six groups are rated according to their accident-severity rates; the plant having, the lowest rate is declared the winner.The Sentinls of safety trophies presented to the winning mines and quarries in the six groups were donated by the Explosives Engineer magazine to promote safety in the mineral industry. They are held by the winning companies for 1 year or until won by other mines and quarries."

Jul 1, 1942

By Kenneth D. Winters

This Bureau of Mines report presents a Fortran IV computer program for the structural analysis of (1) protective canopies used in underground mines to protect equipment operators from roof falls and (2) rollover protective structures (ROPS) used in surface mines to protect equipment operators during vehicle overturn accidents. The program, entitled PLASTIC CANOPY, permits rapid and inexpensive calculation of the ultimate strength and deformation characteristics of a canopy for a variety of static loading conditions. The structure is modeled as a series of interconnected beam and/or plate elements. Stresses in, and displacements of, each structural element are computed and printed out at the yield strength of the canopy, at several intermediate load levels between the yield and ultimate strength of the canopy, and at the ultimate strength of the canopy. Other features of the program include prediction of buckling of a beam member under combined axial compression loading and bending, plotting of the input geometry of the structure, and plotting of the deformed shape of the loaded structure. Program description, input instructions, program listing, and four example problems are included.

Jan 1, 1979

By James P. Bennett

In this Bureau of Mines study, portions of four acidproof bricks (two red shale and two fireclay) were exposed to 20 wt pct RCI at 900 C for periods of 30 days. Three different techniques were selected to deter-mine volume expansion of these materials after exposure. Linear expansions ranging from about 0.02 to 0.12 pct were noted from Ta pin and dilatometer measurements. The use of strain gages to measure expansions was not successful. The red shale and fireclay brick with the lowest apparent porosities had the lowest expansions. Expansion data obtained by direct measurement of samples exposed for 30-day periods or by dilatometric measurement of autoclaved samples ex-posed for 2 h were comparable. This suggests the use of an accelerated autoclave exposure procedure for determining volume expansion effects of ceramic materials in acid environments.

Jan 1, 1985

By M. E. Volin

The Smuggler is one of the mines in the Aspen district, located the central part of Pitkin County, Colo. It was first examined in July 1943 by C. R. Wilfloy, former mining engineer of the Bureau of Mines at Salt Lake City, Utah, in, company with the lessees, R. D. Rohlfing of Aspen and J. W. Vanderwilt of Denver. The purpose of this examination was to sample a mineralized breccia zone that appeared continuous along the contact between the Leadville and Weber formations. These preliminary samples showed that the zone contains low but significant amounts of lead and zinc and that the minerals are partly oxidized and thus not easily concentrated. The mine was examined again in May 1946 by the senior author and William Herron, one of the present lessees of the property. This examination reviewed the previous sampling and recommended investigations by the Bureau of Mines. Sampling and drilling investigations were conducted by the Bureau from October 1946 to February 1947 and again from August 1947 to April 1948. Aspen is the center of a famous mining district that produced over $102,000,000 in silver and lead ores from 1880 to 1918, when a dispute closed down the mines (fig. 1). All of the workings below the Cowenhoven tunnel in Smuggler Mountain and the lower Durant tunnel in Aspen Mountain have been flooded since that time. The Cowenhoven portal now is caved, and Smuggler Nos. 1 and 2 tunnels are the only accessible workings in Smuggler Mountain. The only operating mine is the Midnight, situated 4 miles south of town at an altitude of 9,700 feet.

Jan 1, 1950

By Joan C. Biordi

The Bureau of Mines used molecular beam-mass spectrometry to determine the microstructure of a 10.1% CH4-2l.2% 02-67.6% Ar-1.1% CF3Br inhibited flame and its uninhibited analog, both stabilized at 32 torr on a cooled flat-flame burner. Composition profiles of atomic, radical, and stable species and temperature profiles for both flames were obtained and compared. Kinetic analyses of the profiles yielded values for the rate coefficients of several elementary methane flame reactions and information on the reactions of formation and decay of the observed halocarbon species. CF3Br is judged to decay by thermal decomposition as well as by abstraction reactions, and the fluorocarbon chemistry occurring in the inhibited flame is due primarily to CF2 radical reactions. Rate coefficients and mechanisms for reactions of the inhibitor-related species are given.

Jan 1, 1978

By Lucien Eaton

This paper describing the mining practices at Mine No. 1, Menominee Range, Mich., is one of a. series being prepared by the Bureau of Mines on mining practices, methods, and costs in the various mining districts of the United States. It is felt that the publication of this information will be of interest and value to the mining industry at large and especially to operators whose mining conditions are similar to those described. ACKNOWLEDGMENTS The author is indebted to the superintendent, engineer, and mining captain of Mine No. 1 for much of the information presented.

Jan 1, 1929

By John A. Johnson

[Tests were conducted at the Mount Weather testing adit of the Bureau of Mines4/ on the effectiveness of spraying water along the outside of the drill steel as compared with standard wet-drilling practice. The spray equipment used in the tests was designed primarily for the control, in quarries, of dust from dry drilling with solid type drill steel. EQUIPMENT Spray equipment is made in sizes to fit different drill steel but is alike in design, the only difference being in the diameter of the ring and the number of spray holes. The device is made of cast steel and has a coating of Stellite on the inside edge that comes in contact with the drill steel. It looks like a garden spray, except that the spray holes point in only one direction.]

Jan 1, 1939

By W. P. Haynes, J. W. Mulvihill, G. B. Taylor, S. Katell

Capital and operating costs have been estimated for separating methane and hydrogen in gas - separating plants designed to produce 90 million scf per day of product gas containing a minimum of 90 percent methane . After a preliminary literature review of various separation techniques , three different processes --moving - bed adsorption using active carbon , oil absorption , and liquefaction -- were chosen for the cost estimates . Three different methane feed gas concentrations , 5 , 20 , and 50 percent ( cases 1 , 2 , and 3 , respectively ) , were chosen as representative methane concentrations for the separation estimates . Capital and operating costs were lowest for the moving - bed adsorption process in all three cases investigated . Operating costs declined from $ 0.24 to $ 0.06 per 1,000 cu ft of product gas , and capital costs declined from $47,490,800 to $7,411,200 as the percentage of methane in the feed gas increased from 5 to 50 percent .

Jan 1, 1964

By Henry P. Wheeler

Natural gas was first stored underground in Welland, County, Ontario Province, Canada, in 1915.3/ The following year natural gas in the United States was first stored underground successfully in the Zoar field near Buffalo, N, Y. Only three additional storage fields were in use in the United States in 1930, but by 1940 the number had increased to over 30, and since that time growth has been more rapid. At least 80 fields, with a combined storage capacity of 440,828 MM c. f ., were being utilized by 1949.4 / In May 1952, 142 storage projects having a capacity of 915,000 MM c.f. were in operation .5/ These fields are distributed from New York to California--from Michigan to Texas. In the Appalachian region alone, there are 101 storage fields with a combined capacity exceeding 526,000 MM cu. ft. Why Natural Gas is Stored Natural gas is stored in order to be readily available to meet the needs of consumers.

Jan 1, 1952

By C. H. Riggs

This report of a petroleum-engineering study of the Flat Rock oil field, Osage County, Okla., describes the geology, reviews the production history, and estimates remaining oil reserves. The Flat Rock field in the southeastern corner of Osage County approximately 6 miles northwest of Tulsa. Okla., was discovered in November 1904. The field was one of the first of many Bartlesville-sand fields developed in eastern Osage County during the early part of the 20th century. Although substantial oil reserves remain in the pressure depleted sands in some parts of the field, their economic recovery by water flooding will require careful consideration of the many factors involved.

Jan 1, 1954

By K. K. Kelley

This work is both a revision and an elaboration of Bureau of Mines Bulletin 371, which was published in 1934 and included data available to October 1933. During the intervening years, a large number of new experimental, high-temperature, heat-content data have become available through continuous, systematic efforts of the Pacific Experiment Station of the Bureau of Mines and the Laboratory for Inorganic and Physical Chemistry of the University of Groningen (Netherlands), coupled with various individual investigations at many institutions. In addition, calculations from spectroscopic and molecular constant data have been extended and applied to a wide variety of gaseous substances. This bulletin purposes to collect and correlate all available high-temperature heat-content and specific-heat data for inorganic sub-stances and to formulate tables and algebraic expressions for their representation. It is hoped in this manner to remove some of the tedium of thermodynamic calculations for industrial metallurgical research workers and engineers who often have available only an inadequate library in this field. It is expected also that this bulletin will have value to those teaching courses in metallurgical and chemical thermodynamics.

Jan 1, 1949

By Victor E. Kral

"SUMMARYFollowing a magnetometer survey on the McCoy iron deposit, a trenching and drilling program was carried out by the Bureau of Mines in August 1944.This deposit is 32.3 miles southwest of Battle Mountain in the McCoy Mining District, Lander County, Nevada, and lies on the east flank of the Fish Creek Mountains at an altitude of 5,400 feet, about 1 1/2 miles south of the gold camp of McCoy.Total production from the deposit has been 400 tons of magnetite, mined by hand and shipped to the west coast for ship's ballast.Bureau drilled two holes to a total depth of 92 feet and excavated 12 feet of trenches. Both holes were drilled in the same ore body and engineered magnetite ore 14 and 11 feet thick. Trenching was used successfully to show the lateral limits of the ore.Magnetite ore bodies were found to occur as replacements of a limestone bed in quartzite. They outcrop near and parallel to the exposure of a diorite entrusting that forms a long westward-trending ridge. Although magnetic outcrops can be traced for 5,000 feet trenching definitely proved the ore bodies to be disconnected to have little or no lateral extent beyond their outcrops. Only two ore bodies more than 10 feet thick were found; one of these is the inaccessible to and the other was drilled by the Bureau."

Jan 1, 1947

By C. C. Anderson, H. H. Hinson, H. J. Snhroeder

"INTRODUCTION The Eunice field is one of a group in southeastern New Mexico producing oil and gas from so-called limestone-type reservoirs in which the productive strata are dolomite or dolomitic limestone ordinarily, wells in reservoirs of this type show wide differences in their productive characteristics, indicating erratic variations in porosity and permeability. Often there is a large difference in total footage of actual ""pay"" penetrated in neighboring wells and the vertical distribution of the ""pay"" within the productive strata varies. In the Eunice field there are few easily recognizable geologic markers to indicate true structural conditions of the oil-productive section, due to horizontal and vertical gradation in chemical compositions and lithologic characteristics of the strata. Geologic markers are found some distance above the oil-producing zones in this field and consequently they indicate only the general structure. Furthermore, no direct relation has been found between the general structure and the accumulation of oil within the reservoir.Many problems in well-completion and production practice have been met in the Eunice field because of erratic variations in porosity, permeability, in vertical distribution of ""pays,"" and the apparent departure from ordinarily accepted relations of oil accumulation to structure. A detailed study of the position and characteristics of the oil- and gas-producing zones aids production procedure. The methods employed in studying the Eunice field, discussed in this paper, may be applicable to other limestone-type reservoirs."

Jul 1, 1939

By Halagowder Devaraj, Mostafa Sheykhnazari, Veer P. Bhavanandan

"A sensitive colorimetric assay for detecting mucins and glycoproteins rich in 0-glycosidically linked saccharides is reported. The method combines the susceptibility of N-acetylgalactosamine terminating 0-glyco idically linked saccharides to P-elimination with the Morgan-Elson reaction for N-acetylhexosamines with free reducing ends. All mucin and mucin-type glycoproteins but none of the serum-type glycoproteins tested resulted in characteristic color production. All mucins tested gave linear responses in the range 5 to 200 ""g and the assay was also adapted to the microscale involving the use of 96-well microtiter plates. The microassay in which the volumes of samples and reagents are scaled down 2.5-fold was particularly useful in monitoring of mucins, in the presence of other glycoconjugates, in large numbers of samples obtained during fractionation procedures. Cesium chloride, cesium bromide, potassium thiocyanate, and various detergents do not interfere with the colorimetric determination. Guanidine hydrochloride, cesium triftuoroacetate, and B-mercap- . toethanol decreased color by 30 to 45%; however, the interference was not serious to prevent the use of the method for detection of mucins in their presence. The use of the method for the specific detection of mucin during fractionation by gel filtration and density gradient centrifugation of cystic fibrosis sputum samples is demonstrated. Mucins are an important class of biomacromolecules whose structure-function relationship is poorly understood (1,2). The investigations of mucins are hampered by difficulties in purifying these very large size molecules which appear to avidly bind other components of the mucus (3,4). One of the problems during purification is the specific detection of mucins. For example, during the various purification steps, the fractions containing mucins are typically detected by assaying for neutral sugars (hexoses) (5,6), for sialic acids (7), or for periodate oxidizable saccharide units (8). However, these methods are not entirely satisfactory because neutral sugars, sialic acids, and periodate-oxidizable saccharides are also components of other glycoconjugates. In addition, the neutral sugar and sialic acid measurements are also subject to interference from high levels of proteins and nucleic acids."

Jan 1, 1990