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By Jose P. T. Agapito

Several underground coal mines currently operating in the Beckley District of West Virginia are experiencing serious roof and floor problems. A significant portion of the estimated two billion tons of coal resources may be lost as a result of these ground control problems. Preliminary studies by the Bureau of Mines indicated that these problems are due in part to a high horizontal stress field. During this contract study, a field program was conducted to quantify the horizontal in situ stress. A total of 14 overcoring sites (using the Bureau of Mines strain-relief overcoring technique) in five mines were drilled producing 53 data sets. Analysis of the data was done to provide in situ horizontal stresses for each of the five mine, and for the district as a whole. Stress data indicate horizontal stresses far in excess of that predicted by theory and in some cases, up to six times the estimated vertical stress. In addition to the field testing, a detailed computer modeling study was conducted using finite element and boundary integral (displacement discontinuity) methods. Verification of in situ stresses was obtained by the models and analysis of various development geometries, mining methods and remedial techniques were conducted. Recommendations for reducing ground control problems and future studies are presented.

Jan 1, 1980

By Russell R. McLellan

Under the Heavy Metals Program, investigations were conducted at the old Badger dill placer mini in Nevada County California to collect data and information regarding drilling and sampling methods and deposit characteristics. The studies contributed to a team effort by five Bureau of Mines research groups to develop new or improved placer mining technology in the Tertiary gold-bearing channel gravel of northern California. This report describes the techniques used and the results obtained in the sampling and drilling stage of deposit delineation studies that were conducted by the Denver Mine Systems Engineering Group. Sampling included the collection and processing of 400 tons of largo and small volume samples from drill holes, underground workings, surface pits, and blast hole rounds. A total of 355 samples averaging 2,296 pounds per sample provided reasonably accurate data for analysis of the gold distribution. These studies indicate that the bulk of the gold is within 40 foot of bedrock in stacked, lenticular zones of cemented gravel that are largely confined to the relatively narrow, meandering course of the deepest portion of the bedrock channel. Drilling studies involved the testing of three types of truck-mounted drills including rotary, bucket and vibratory, none of which proved to be a completely versatile tool for sampling quickly and reliably both consolidated and unconsolidated gravel.

Jan 1, 2012

By X. Shi, K. S. Kaspnak

"The generation of free radicals from reactions of nickel (Il)-thiol complexes with molecular oxygen and model lipid hydroperoxides was investigated by electron spin resonance (ESR) utilizing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. Incubation of nickel (II) [Ni(II)) with cysteine in an aerobic environment generated hydroxyl (·OH) radical, which then reacted with cysteine to generate a carbon-centered alkyl ( · R) radical. Radical generation was inhibited under a nitrogen atmosphere. Model lipid hydroperoxides, cumene hydroperoxide, and I-butyl hydroperoxide enhanced the yield of these radicals and also generated an alkoxyl (·OR) radical. Radical yield decreased by approximately half under a nitrogen atmosphere. Although histidine did not cause radical formation in the reaction between Ni(II) and cumene hydroperoxide under aerobic conditions, the addition of histidine to a mixture containing Ni(ll), cysteine, and cumene hydroperoxide under the same experimental conditions increased the yield of · R radical but lowered the yield of ·OR and ·OH radical adducts. It thus appears that histidine caused the ·OH attack to be more site-specific. Similar results were obtained utilizing 1-butyl hydroperoxide. Penicillamine or N-acetylcysteine yielded similar results except that under aerobic conditions, reaction between Ni(ll) and N-acetylcysteine without hydroperoxide did not generate a significant concentration of free radicals. Under the same experimental conditions, cystine did not generate any detectable free radicals, suggesting an important role of the -SH group in Ni(II)-mediated free radical generation. The results indicate that free radical generation from the reaction of Ni(Il)-thiol complexes and molecular oxygen, and/or lipid hydroperoxides, may play an important role in the mechanism(s) of Ni(II) toxicity and carcinogenesis. INTRODUCTIONWhile nickel is a well-recognized carcinogen [l, 2]. the underlying biochemical mechanisms remain unclear (3, 4). Recent studies suggest that these mechanisms may involve oxidative DNA damage through free radicals, especially the hydroxyl (•OH) radical [5-13]. The mechanisms of nickel carcinogenicity and toxicity may also involve lipid peroxidation [14-21]. Unlike ferrous ion [Fe(II)], the Ni(II) cation itself does not directly react with 02, H2O2, or lipid hydroperoxides to generate free radicals [12, 21]. However, it has been reported that Ni(II) complexes with certain synthetic oligopeptides, e.g., tetraglycine or glycylglycylhistidine, make Ni(II) reactive with 02. This reaction results in transitory formation of Ni(III) and degradation of the organic ligand via free radical reactions [22]. Such Ni(II)-peptide complexes are also capable of reacting with H2O2 to produce oxygen free radicals [11, 12]. Although the cellular environ¬ment may not contain these particular peptide ligands that are known to render Ni(II) redox active in vitro, it does contain a variety of oligopeptides that are capable of forming Ni(II) complexes at physiological pH, and thus may facilitate Ni(II) redox activity in vivo. These oligopeptides include glutathione (y-L glutamylycysteinylglycine), carnosine (homocarnosine (y aminobutyryl-L-histidine), and anserine ( B-alany1-3-methyl-L-histidine)."

Nov 1, 1995

This appendix is composed of five sections, each of which is tabbed for ease of access. The sections are as follows: ? Fire incident report forms for underground mine fires. There is one form for each incident listed in Table II-1a. They are ordered chronologically with incident numbers corresponding to those in Table II-la. ? Fire incident report forms for surface mine fires. There is one form for each incident listed in Table II-lb. They are ordered chronologically with incident numbers corresponding to those in Table II-lb. ? Journal article report forms. There is one form for each article reviewed. They provide supplemental information to that contained in the fire incident report forms for selected fires. Index 11-14 keys the journal article report forms to the appropriate fire incident report forms. ? Non-reportable incident descriptions for underground mine fires. This is a listing of underground fires for which MSHA regulations do not require formal reports. ? Non-reportable incident descriptions for surface mines. This is a listing of surface fires for which MSHA regulations do not require formal reports. This appendix is intended to be used in conjunction with the tables and indexes contained in Volume II of this report and, as such, should be considered an integral part of Volume II. The indexes in the body of Volume II provide a means of ready reference to the underground and surface mine incident report forms. For those readers with interests other than those indexed, Tables II-la and II-1b can be used to locate specific incidents of interest. Complete incident information can then be obtained from the corresponding report forms in the first two sections of this appendix.

Jan 1, 1980

By L. D. Tracy

This is the third of the series of reports on coal-mine royalties and leasing conditions in Illinois. The results of the study of District VI were published as Serial No. 2726, January, 1926, and those of District VIII as Serial No. 2745, April, 1926, of the Bureau of mines. The counties of Macoupin, Sangamon, and Montgomery, which are three of the principal coal-producing areas in the northern part of District VII, have been chosen for this report because these counties cover an entirely different part of the State than do the two districts already covered. Some leases in, Randolph and Washington counties are included as they are in the southern part of the district, and the data happened to be readily available.

Jan 1, 1926

By Richard O. Kneisley

An empirical method, based on U. S. Bureau of Mines field studies in several Western U.S. coal mines, is presented for sizing gate road yield pillars. Discriminant analysis was used to generate functions separating successful from unsuccessful case studies. These functions relate the pillar width-height and extraction ratios and a pillar development factor to the Coal Mine Roof Rating System (CMRR), and are assumed to establish three criteria that other entry systems, under similar conditions, must satisfy. A program, Pillar Sizer, from user-provided inputs, generates a range of pillar sizes that meets the proposed criteria. Although the analysis is based on a sample consisting primarily of two-entry systems, the derived expressions generate pillar sizes closely agreeing with observed, two-entry and three-entry in situ pillars. It is concluded that the proposed approach should assist mine operators estimate entry system yield pillar dimensions.

Jan 1, 2010

By Charles W. Perdue

This U.S. Bureau of Mines report considers, from a psychological perspective, the perceptual process by which miners recognize and respond to mining hazards. It proposes that if the hazard recognition skills of miners can be improved, mining accidents may be reduced to a significant degree. Prior studies of hazard perception in mining are considered, as are relevant studies from investigations of military target identification, pilot and gunnery officer training, transportation safety, automobile operator behavior, research into sensory functioning and visual information processing. A general model of perception is introduced, and selected concepts from the psychology of perception that are applicable to the detection of mining hazards are reviewed. Hazard recognition is discussed as a function of the perceptual cues available to the miner as well as the cognitive resources and strategies employed by the miner. The development of expertise in responding to hazards is related to individual differences in the experience, aptitude, and personality of the worker. Potential applications to miner safety and training are presented.

Jan 1, 1995

This Bureau of Mines report comprises tables listing the name, location, and other pertinent data concerning certain future fuel-related projects. The tables include information on projects involving the proposed or planned development of fuel resources, as well as the development of storage, transportation, and conversion facilities; the report covers the 26 States east of the Mississippi River. Of the total 594 projects for which information is provided, 492 concern coal mines and electric generating plants.

Jan 1, 1976

By Thomas J. Peters

The King Mountain study area is centered about 120 air km northwest of Blackfoot, and 30 air km north of Arco, Idaho. The study area makes up the southern one-third of the northwest-trending Lost River Range--the highest mountain range in Idaho. The area is predominantly underlain by Paleozoic-age marine limestone and lesser dolostone, with a relatively small inlier of silica-rich, Ordovician-age quartzite. There are vast, unquantified resources of these industrial minerals present; however, special markets need to be developed for these resources which are near enough for transportation costs to be competitive. Five prospects were found in the study area; however, only one, the Elbow quartz silica prospect, contains resources and current claims. There has been no mineral production in the study area.

Jan 1, 1993

By E. R. Maize

[In report of Investigations 3452,5/ baling with roof movement in the Crucible mine, reference was made do to the fact tart timber decay was being studied at the time of writing. This roper, written after completion of that study, describes s the work and summarizes the data obtained. When the study of roof movement as begun at Crucible two ideas were advanced on decay Of timber by some of the officials: (1) That timber decay vas unusually rapid in the Crucible mine, and (2) that timber coated with rock dust decayed more rapidly than those teat were not so coated. There yore no records by which these ideas could be tested, and it appeared wise to make a limited; investigation particularly of the effect of rock dusting on decay, as rock dusting is an important means of preventing coal-dust explosions.]

Jan 1, 1940

By James Westfield

Drilling for roof bolting has created a new dust problem for the coal-mining industry. Drilling is inherently dusty, and control of dust produced by drilling vertical or nearly vertical holes is much more difficult than control of that produced by drilling flat or down holes.4/ Also, the dust produced by roof drilling differs in composition from that produced by drill-fur, or cutting the coal face because it contains a significantly greater amount of free silica and therefore presents a greater potential hazard of silicosis. Roof bolting has been practiced successfully in the mines of the St. Joseph Lead Co. in southeastern Missouri for over 20 years, but it was not until 1947 and 1948 that large-scale roof-bolting experiments were conducted in coal mines.5/ Although the need for dust control in conjunction with roof drilling was recognized from the beginning, the development and acceptance of roof bolting progressed so rapidly during 1949 and 1950 that solution of the dust problem lagged behind other engineering phases of the technique.

Jan 1, 1951

By E. R. Spencer, E. Reeves

National Institute for Occupational Safety and Health (NIOSH) researchers conducted an investigation to quantify sound levels and to determine the amount of sound reduction provided by engineering noise controls installed in a talc processing plant. Baseline sound level and sound intensity measurements were performed at the plant and the measurement locations were recorded for comparison to post-control measurements. Follow-up measurements were then made at the same locations after the initial noise controls were installed. The plant subsequently decided to implement additional noise controls and the researchers returned to conduct measurements for a final analysis of all noise controls. The most significant results showed a sound level reduction in the main mill area from a range of 93-104 dB(A) down to 90-94 dB(A), and a total sound power level reduction of 21 dB(A) for air classifying mill 3.

By A. E. Sands

This report deals with a portion of the research and development work in the field of synthesis gas purification, carried out by the Bureau of Mines at its Morgantown, W, Va., Station in cooperation with West Virginia University. The Bureau's work in connection with gas purification has been performed with the objective of finding effective, low-cost, processes for removing impurities from synthesis gas to protect the catalyst used in the Fischer-Tropsch process for production of liquid fuels. Synthesis gas used for the production of other chemicals, such as ammonia, alcohols, and methane, requires equally rigorous purification. Although present-day practice in the manufactured-gas industry does not require such a high degree of purification, there is increasing interest in the complete removal of sulfur compounds from city gas. Although the gas-purification work at Morgantown deals with several impurities, major effort has been devoted to organic sulfur compounds in gas; this paper represents a progress report on some of the more important studies in connection with those compounds. Because this is a progress report on the Bureau's experimental work, no attempt has been made to cover the work of others on the subject; references to the literature have been restricted to those bearing directly on the work described.

Jan 1, 1950

By C. H. Riggs

This petroleum-engineering report of the Atlanta oil field in BO them Arkansas reviews reservoir conditions and pressure-production history of one of the important Smackover limestone fields in southern Arkansas. The study of the field was made and the report prepared to aid operators in this and similar fields to increase the efficiency of recovery through the application of better engineering practices. A similar study of the Magnolia field in Arkansas by Carpenter and Schroeder was the first of these reports prepared under a joint agreement between the Arkansas Oil and Can Commission and the Bureau of Mines. The increasing demands for petroleum and its products and the steadily increasing cost of discovering and developing oil field; emphasize the importance of conserving known reserves of oil and gas. In recent years vast improvements have been made in the technique of oil recovery, both by better utilization of the natural energy stored in the reservoir and by improved methods of applying external energy to the reservoir system. This report may aid in oil conservation by careful evaluation of the several factors that did or did not contribute the greater recovery in the Atlanta field and by suggesting improvements in production methods and applications.

Jan 1, 1949

By Fredrick L. Johnson

Tungsten is the principal mineral commodity in the Laurel-McGee RARE II area; copper and molybdenum would be recovered as by-products with the tungsten. Indicated and inferred tungsten marginal reserves at the Hard Point Mine (fig. l, no. 10) are 16,000 tons (14,000 t) averaging 1.0 percent tungsten trioxide (W03). The mine is outside the RARE II area, but the geologic structure that it is on extends into the area. Indicated subeconomic zinc, silver, copper, and lead resources at the Lucky Strike Prospect (fig. 1, no. 7) are nearly 6,200 tons (5,600 t) averaging 5.45 percent zinc, 0.5 oz silver per ton (19 g/t), 0.40 percent copper, and 0.32 percent lead. Although tungsten has been produced at the Tiptop Mine (fig. 1, no. 12), resources were not calculated because of the spotty nature of the tungsten mineralization. Additional exploration at the Tiptop and Hard Point Mines could reveal significant resources. The potential for tungsten resources at the Payday Prospect, Tungsten Prospect, and Morhardt Mine is also high. The Pine Creek Mine custom mill, located about 35 mi (56 km) southeast, could process tungsten concentrates from the area. Tungsten production has been recorded from three properties, the Hard Point, Morhardt, ant Tiptop Mines. Output was about 405,000 lb (184,000 kg) of W03, nearly all from the Hard Point.

Jan 1, 1983

By H. H. Yancey

In this information circular is presented a summary of the more important articles that nave appeared in the literature pertaining to the experimental work and to the commercial operation of the froth-flotation and Trent processes as applied to the cleaning of fine coal.

Jan 1, 1933

By Dennis R. Dolinar

In general, the direction of the maximum horizontal stress in the eastern United States is fairly well defined. However, the variation of the magnitudes of the horizontal stresses is not very well understood. Because the horizontal stresses cause severe ground control problems in underground coal and limestone mines throughout the eastern United States a more complete understanding of how the magnitudes vary would be useful for developing mine design strategies to combat horizontal stress related ground control problems. Therefore, in this National Institute for Occupational Safety and Health (NIOSH) study, the variation of the magnitude of the horizon stresses in sedimentary deposits in the eastern and Midwestern United States are examined with respect to two factors, the elastic modulus of the rock and the site depth. Stress measurements from thirty-seven sites are used in the evaluation. Examining the applied excess strains indicates that the eastern United States can be, separated into high and low strain zones. For most of the eastern United States the maximum applied excess or tectonic strain ranges from only 300 to 550 micro strains. However, there is one area, a portion of the Beckley seam in the central Appalachian region where the strains are significantly higher than the other regions. In this higher strain zone, the maximum applied tectonic strains range from 700 to 1,000 micro strains. Regression models for each zone based on the elastic modulus can explain between 83 to 85% of the variation of the maximum horizontal stress. Because one region, the northern Appalachian district, has strains that are about 20% higher than the other regions in the low strain zone, multiple strain models based on geographic regions were developed for the low strain zone that can explain 87 to 91% of the maximum horizontal stress variation with the elastic modulus. Depth was found not to be a significant causal factor in any increase in the horizontal stress even though the site depths ranged from 275 to 2,500 ft. Beyond a theoretical increase, based on Poisson’s effect and gravity, no other increase in the horizontal stress with depth can be justified with this data. The most significant factor controlling the variation of the maximum horizontal stress is the elastic modulus of the rock, not the overburden depth.

By John J. Sammarco

The U.S. Bureau of Labor Statistics reports that the mining industry has the highest average annual fatality rate (31.9 per 100,000 workers) among all major American industry. To address this, a major research program to reduce hazard exposure of miners with computer-assisted mining equipment was initiated by the U.S. Bureau of Mines.1 One application involves the manual process of extracting and hauling coal where operators, in the tight confines of a mine, can be struck or caught by mobile machinery. The approach to remedy this problem uses a guidance system on the haulage equipment so that it follows the machine that extracts coal. This, in essence, involves sensor-based docking of the machines. Sensors that can survive the hostile mine environment of dust, methane gas, and water, play the key role. Computer analysis of the mining machine's movements and empirical machine characterizations were conducted to establish operating requirements and spatial limitations to ensure proper loading of coal into the haulage equipment. These data served in the selection of a sensing system. Various technologies such as scanning laser systems and ultrasonic sensors have frequently been used in other applications but were found unacceptable. However, a near infrared (IR) sensor employing active targets met the requirements. The sensor has a nominal 75° conical field-of-view and a range from 0.1 to 18.0 m. For the single target mode, nominal range accuracy was 4.3% at a distance of 3.56 m. Correction algorithms were generated reducing the error to 0.6%. Airborne dust testing showed less than 0.8% accuracy (worst case) degradation at levels exceeding (by a factor of 7.5) concentrations permitted by Federal law. The sensor can track multiple active targets providing five degrees-of-freedom (DOF) measurements. Using four targets, the nominal range accuracy was 0.4% without correction algorithms. A guidance system for the haulage system to follow the mining machine does not exist commer¬cially. Such a system can reduce fatalities and injuries by current haulage mining equipment, and is a viable alternative to current haulage control.

By K. O. Bennington

The thermodynamic properties of two manganese silicates, pyroxmangite and fowlerite (zincian rhodonite), were experimentally determined by the Bureau of Mines. The standard enthalpies of formation were determined by hydrofluoric acid (HF) solution calorimetry, the low-temperature heat capacities by adiabatic calorimetry, and the high-temperature heat capacities by differential scanning calorimetry over the range 322 to 1,372 K. Data for the standard enthalpy of formation (AH298), the derived standard entropy (S298), and the standard Gibbs energy of formation (AGf 298) are as follows: Pyroxmangite [(Mn0.9554Cao,0446)(Si03)J- AHf298 319.668±0.46 kcal/mol AH298 (from oxides)... -7.215±0.11 kcal/mol 5295 23.785±0.048 cal/(mol'K) AGf298 -301.190±7.96 kcal/mol Fowlerite [(Mno.7o3Zno.0884Ca0.2086)(Sio3)]--AHf298 ?... -329.914±0.419 kcal/mol AH298 (from oxides)... -8.400±0.104 kcal/mol 5598 21.949±0.059 cal/(mol-K) AGf298 -310.716±7.99 kcal/mol These experimentally determined values were combined with data from the literature to calculate the Gibbs energies and equilibrium constants of formation over the temperature range of the measurements. Standard enthalpies, Gibbs energies, and equilibrium constants of formation are given as a function of temperature from both the elements and the constituent oxides.

Jan 1, 1987

By Lloyd H. Banning

With the ever-increasing demand for energy in all forms, electrical energy generated from geothermal resources could become an important energy source in the next few decades. Geothermal fluids, which contain appreciable quantities of dissolved salts and gases, are generally corrosive to materials of construction. Since data on corrosion of materials in geothermal brines is limited, the literature was surveyed through February 1972 to obtain a compilation of information on corrosion resistance of aluminum and its alloys, copper and copper-base alloys, carbon steel and cast iron, stainless steels, chromium-iron alloys, nickel-and cobalt-base alloys, and titanium in heated brines including sea water.

Jan 1, 1973