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By M. Morales, J. Yianatos

"In this work, an alternative approach to evaluate the flotation performance along a flotation rougher row is presented. The collection zone as well as the froth zone performances were separately evaluated. For this purpose, sampling for metallurgical balances along with sampling of top-of-froth (TOF) grades in each cell of a flotation row were employed. The modelling of the rougher circuit consisted of using TOF grades for evaluating the collection zone recovery, because they are a good representation of the bubble loading, which identifies the true flotation process, as shown in previous studies for shallow froths. In addition, the feed characterization, size-by-liberation, allowed the identification of the mineral distribution and its evolution along the circuit. The latter result was obtained by fitting the recovery profiles as well as the TOF grades down the flotation bank. The flotation rates and the maximum recoveries in terms of size-by-liberation (size classes: -45 µm, +45-150 µm, +150 µm, and liberation classes: -20%, +20%-80%, +80%) were then estimated. The results were in good agreement with those reported in literature by other authors and showed the new approach allows flotation kinetics to be characterized in industrial circuits.INTRODUCTIONMineral recovery in industrial flotation circuits is a function of the mineral characteristics, such as particle size distribution and liberation (Trahar, 1981, Jameson, 2012), and operating conditions such as air flowrate, pulp flowrate, solids percent and reagent conditioning (Jameson 1977; Klimpel, 1980; Mehrotra and Kapur, 1974). The cell type and size (self-aerated or forced air) and the circuit arrangement (single cells or banks of cells in series) are also relevant factors. Sampling of circuits (e.g. rougher, cleaner or scavenger) are commonly carried out using standard automatic samplers for metallurgical balance assessment. However, the flotation plants are generally not provided with proper accesses for local streams, which hinders the recovery estimations and the flotation rate characterization."

Jan 1, 2018

By Ari Kokko

Metso has a long history supplying boilers for high ash coal firing. These boilers are based on circulating fluidized bed (CFB) technology. CFB?s biggest benefit is fuel flexibility ? it can burn fuels from high moisture content to high ash content. Metso has delivered tens of CFB boilers burning waste or high ash coal starting on 80?s. Some of the boilers have been in operation twenty years meaning that there is a long term experience from these plants available. This feedback includes boiler performance and maintenance issues of the boiler. Metso is also delivering coal washing plants to improve coal quality, i.e. reducing ash content of the coal. The idea to combine coal washing plant and CFB boiler was made up two years ago in Metso. Up-coming legislation of coal washing and restrictions for washery reject land-filling in India are good drivers for this kind of concept. Pre-study of this kind of concept led to the conclusion that coal washing process can be fine-tuned so that reject?s calorific value is only 1100 kcal/kg and that was set as a target for boiler design. Metso shipped 200 tons of washery reject to its own research center located in Tampere Finland. First a wide range of fuel characterization tests were done in lab-scale and after that one week test run in 4 MW CFB pilot boiler was done. Test run proved that 1100 kcal/kg can be fired without any support fuel with special boiler design. Test run results gave a good set of data regarding combustion efficiency, emission performance and boiler dynamic behaviour when burning this kind of fuel. These results are introduced in this paper. This paper introduces also the CFB boiler concept for washery reject firing including boiler plant, fuel and ash handling systems and flue gas cleaning system. Power plant can be integrated with coal washing plant so that boiler size matches with washing plants c

Sep 1, 2012

By Xin Tan

In this paper, two types of low-grade complex zinc oxide ores (sandstone and limestone ores) from Yunnan province, China were investigated. A large number of argillaceous and alkaline gangue makes it infeasible to treat the ores with heap leaching. Although wet metallurgy can be considered, the lower efficiency of liquid-solid separation, the high cost, and low revenue limit this technology to be put into practice in large-scale. In order to solve this problem, a new technology combining mineral processing method with metallurgy technique is studied to process this refractory ore that consists of sandstone ore with 5.84 per centZn and limestone ore with 6.50 per centZn. The results of the tests showed that zinc can effectively be recovered from two types of the ores by using the new technology, and the acid consumption can be remarkably reduced. For sandstone sample, 82.96 per cent Zn was recovered by flotation and final Zn recovery by flotation+ hydro-metallurgy can be up to 78.17 per cent from the ore. In addition, for sandstone, acid consumption can be reduced from 270kg/t by direct acid, leaching to 76.92kg/t by flotation + hydrometallurgy combination. For limestone sample, 85.90 per centZn was recovered by flotation and totally 80.95 per cent Zn can be recovered by new technology which is a combination of mineral processing and metallurgy. Besides, H2SO4 consumption can be reduced from 450kg/t for sandstone originally to113.79kg/t after using new technology. One merit of this new process technology is that the zinc sulfides and oxides can be recovered without desliming in the flotation cells at the different stage and make sure the concentrate products as a good feed for hydrometallurgical technology. This study provided pretty good technical support for tapping low-grade refractory zinc oxide ores. Keywords: low-grade zinc oxide ores, limonite, non-desliming beneficiation, flotation + hydrometallurgy combination

Sep 1, 2012

By G. V. Kalabin

"The paper supports applicability of satellite imagery at regional and local level for rapid quantitative assessment of natural environment in zones of activity of mining complex enterprises. Exacerbation of environmental problems during mineral mining and processing associated with their scale and geography of field distribution through the vast territory of our country requires constant monitoring of natural environment status, which necessitates engagement of space surveillance nowadays. It is proposed to use the monitoring of land cover and land use at regional and local level for the environmental assessment of a particular production or complex productions. You must establish the dependence of NDVI change trend with the magnitude of anthropogenic impact on the source or multiple sources of environmental pollution a particular area.. We present the results of studies of vegetation remote sensing methods in a number of territories placing mining enterprises. INTRODUCTION Ensuring a healthy environment is necessary both in untouched areas and disturbed. The condition of the developed territories should be monitored with particular attention, since the restoration of the disturbed territories requires great efforts and financial costs. More narrowly, the health of the environment (Zakharov V.M. and etc.,2001) means its quality ensuring the health of man and other species of living organisms, which includes two aspects (Zakharov V.M. and etc, 2000): - ensuring an environment conducive to human health as a biological species: - maintaining the health of the natural environment, i.e. its constituent species of living organisms and plants. The consequence is the disturbance of natural ecosystems, which determines the quality of the environment, favorable for human habitation and the state of health of the population in total determine the status of the territories where enterprises for the development of georesources are located and allow them to be ranked according to the degree of environmental danger. Without knowledge of the trajectory of ecosystem successions, it is impossible to offer adequate requirements for the technologies used to ensure the implementation of the preserved natural potential after the removal or reduction of man-made stress."

Jan 1, 2018

By Mohammad Kor, David Beattie, Agnieszka Mierczynksa-Vasilev

The selectivity of polymer adsorption in mixed mineral systems is the basis for polymer depression of gangue minerals in flotation. Effective polymer depressants not only reduce gangue mineral recovery, they also have minimal effect on the recovery of the value phase, presumably through targeted adsorption on the gangue phase, and minimal uptake on the value phase. Traditionally, polymer depressant design has been guided by single mineral phase adsorption tests, with affinity and maximum adsorbed amount determined for gangue and value phases separately. However, there is a need to determine the actual extent of adsorption on the gangue phase while in the presence of the value phase. In this work, we report on the development of in situ atomic force microscopy (AFM) imaging for determination of polymer depressant coverage and morphology on mixed mineral surfaces. Our group has previously used AFM imaging on single minerals to connect adsorbed layer characteristics with bubble-particle attachment and flotation outcomes. Two sample types were used to test the methodology: (i) a mixture of two crushed/ground minerals encased in resin; and (ii) a composite mineral sample containing macroscopic regions of three different mineral phases. The samples have been used to probe the selective uptake of two modified dextrin polymers (octenyl succinate anhydride dextrin). AFM images acquired in situ (while all surfaces are immersed in the same polymer solution) of each mineral phase have revealed the natural selectivity of the polymer for the mineral surfaces. In all cases, the polymers adsorb on the all mineral surfaces present, but to a varying extent.

Jan 1, 2014

By Vladimir F. Skorokhodov, Nikolay N. Melnikov, Svetlana P. Mesyats

"Among the problems of the civilization development, a problem of interaction between man and natural environment can be highlighted. In the twentieth century the human transforming activity had got scales of geological processes and defined the contradiction between the goal to increase the quality of human life and possibilities of the natural environment. Last twenty-five years after the World Summit on the Environment (1992) indicate that the development of civilization is still based on receiving super profits from the natural resources exploitation. This statement is confirmed by economy globalization rates, growing contradictions between consumption and production, depletion and degradation natural environment. A new technological order is formed at the time of growing world population, technological capacities, organizational complexity, from one side, and global scales of geo-resources consumption, on the other side. Sciences, determining the further civilization development, should take on the task to change the social worldview, since the preservation of human population consists in remediating and maintenance of biosphere functions as a regulator of ecological balance. The new worldview in the geo-resources exploitation is based on the Ecological strategy of mining development, which consists in reducing mining-induced loading on natural environment while increasing efficient mineral production and processing, and providing for a comprehensive solution of tasks on mineral deposit development. One of strategic trend of mining development is to increase complexity and completeness of useful component extraction from ore and mining deposits while reducing wastes and decreasing their stockpiled volumes. The implementation of the ecological strategy has shown that the future is determined by reduction of the environmental impact while improving the efficiency of mineral mining and processing.INTRODUCTION The global nature of environmental problems caused by the scale of consumption of natural resources, huge amounts of waste, and intensive man-made impact on the environment requires a revision of the strategy for the natural resources development. Many existing technologies are ineffective in achieving the ultimate goal. Direct output in the raw materials - the end product technological chain rarely exceeds 10%, which implies a huge amount of work to move the soil. In addition, the feature of scientific and technological progress at the present stage is the growth of power-to-weight ratio."

Jan 1, 2018

The present study investigates the nature of gold mineralogical distribution and association in a Cu-Au flotation circuit (1.6 g/t Au, feed head grade). The approach used in this study involves a combination of bulk gold assay and quantitative X-ray diffraction (QXRD), on a size-by-size basis, followed by QEMSCAN analysis on the -75+53 µm, -53+38 µm and -38+20 µm size fractions. The QXRD and QEMSCAN analysis showed that gold mineralogy is complex and fine-grained in the flotation feed, particularly in the -38+20 µm size fraction. Gold and pyrite concentration follow each other closely, suggesting gold-pyrite association. Quartz as the major gangue mineral shows a bi-modal distribution with respect to particle size. The identified gold particles were completely locked (~94 %) in pyrite as fine inclusions and 6 % locked as complex aggregates (-75+53 µm size fraction) whereas in the -38+20 µm size fraction, the identified gold grains occur as fine inclusions (~1-3 µm) within pyrite and silicates. However, in the intermediate size fraction (-53+38 µm), 75 % of the identified gold grains (10-22 µm) were over 90 % liberated and 25 % associated and locked in pyrite and complex aggregates (~2-4 µm). The identified gold grains in the -53+38 µm size fraction occurred as native and electrum with varying silver concentration between 8 and 20 % by weight. In the -38+20 µm size fraction, a gold telluride was also identified. Based on the mineralogical analysis of the feed, possible flotation strategies are discussed. Optimizing the flotation of pyrite is suggested as the primary Au recovery strategy. Keywords: flotation, pyrite, gold, liberation, QXRD, QEMSCAN

Sep 1, 2012

By Kaustubh Joshi, Pradip, Beena Rai, Venugopal Tammishetti

"Rapid depletion of high grade iron ores coupled with the increasing demand for the blast furnace grade iron ore in recent times has shifted the research focus on the development of appropriate technologies for the utilization of low - grade alumina rich iron ore slimes. These slimes are currently being dumped into tailing ponds owing to their high alumina content. Typical constituent minerals present in the Indian iron ore slimes are hematite, goethite, gibbsite and kaolinite. Considering the fine particle size distribution (<37 microns) in the slimes, selective dispersion-flocculation seems to be one of the most appropriate process which has been explored by us. We present our successful results on a natural iron ore slime sample obtained from one of the mines in India. We have been able to achieve a concentrate assaying >67% Fe, and <3% Al2O3 and 2.8% loss on ignition (LOI) from the slime sample assaying 60.4% Fe, 7.7% Al2O3 and 5.45% LOI with an Fe recovery of 62-69% simply by adjusting the pulp pH. We have scaled up the process to a semi batch scale as a prelude to commercialize it for the beneficiation of low grade iron ore slimes."

Jan 1, 2014

By S. K. Pan, M. P. Srivastava, N. Prasad

"Dalli mines of Bhilai Steel Plant, India is fully mechanized iron ore mine having wet processing system. It has a capacity to treat 5 Mt of ROM. In processing circuit of Dalli mines, scrubbing, wet screening and classification operation is being carried out. Average slime generation for the last five years is about 14% of ROM. As the mining has reached to the lower benches, fines generation is more. As a result, very fine and heavy particles, which settle fast, are being discarded with the slime to tailing pond. These heavy and faster settling particles were causing jamming in the thickeners.Laboratory investigations were carried out at Research and Development Centre for Iron and Steel (RDCIS) to suggest a suitable scheme to recover high quality fines so that the availability of thickener can improve. The slime samples were first treated in a floatex density separator. The concentrate obtained from the floatex density separator was treated in hydrocyclone. Laboratory investigations indicated that the slime with 49% Fe, 12.7% silica and 10.7% alumina can be upgraded to 62.1% Fe, 3.3% silica and 2% alumina with 36% material recovery. Based on the laboratory studies ,a system was installed at Dalli minesThe general arrangement of the system is shown in Fig. below."

Jan 1, 2003

By P. Knüpfer, B. Babel, M. Rudolph, F. Perez Maldonado, U. A. Peuker, L. Ditscherlein

"In heterocoagulation processes for the separation of mineral particles, the most famous being froth flotation, the main characteristic of separation is a differing wettability of the constituents to be separated. This most crucial property in the economically important process of flotation is often only and incompletely, quantitatively described in terms of contact angles against water. A water contact angle larger than 90° is referred to as hydrophobic and hydrophilic vice versa. Looking at Young’s equation shows that it is actually the surface energy of the solid in interaction with the surrounding phases and their surface energies (or surface tensions for liquids) which describes whether there will be hydrophobic/hydrophilic hydration interactions leading to attraction or repulsion. This, we have previously published for various more or less hydrophobic minerals in correlation to their flotation response, i.e. flotability (c.f. Rudolph & Hartmann, Coll.Surf.A 513, 380-388). In the same paper we also discussed the heterogeneity of wettabilities as assessed with the novel method of inverse gas chromatography. Furthermore we have also reported on hydrophobic force distributions as assessed with atomic force microscopy which are as well due to wettability heterogeneities (c.f. Fritzsche et al., Coll.Surf.A 459, 166-171).In this paper we present wettability distributions of different substrates and particles with various surface roughnesses/shapes and degrees of hydrophobization as assessed with iGC, AFM and dynamic sessile drop analyses. We are putting the results in context in unifying models and present methodologies helpful to make use of the fundamental information and their impact on the actual industrial separation process in fundamental process models. Besides froth flotation we also emphasize the impact on selective hydrophobic flocculation process."

Jan 1, 2018

By Ji Hoe Kwon

Hindered-settling column process has been used for the separation of mineral particles for many years. In this study, a model based on DEM (Discrete Element Method) was used to simulate the movements of particles in a settling column separation process. DEM model is capable of describing the motion of particles and calculating the impact forces between particle and particle, and particle and wall contact under various operating conditions. Drag force, rotation induced Magnus lift force, contact force and the gravitational force acting on individual particles were considered for establishing the mathematic models. The overall motion of the particles in water is satisfactorily simulated by the DEM, and the result shows good agreements with the result of lap-scale experiment.

Jan 1, 2014

Three high-grade limestone ores (CaO content over than 53 %) with different geological origin have been characterized for the synthesis of aragonite precipitated calcium carbonate. Limestone ores examined in this study showed different crystal particle size that cause difference in disintegration degree and surface area of the synthesized slaked limes. The limestone ore with smaller crystal particle size showed higher disintegration degree and also yielded slaked lime with smaller surface area, which is good for the synthesis of aragonite precipitated calcium carbonate. The synthesis of aragonite PCC using the limestone with a small crystal particle size was yielded needle-shaped aragonite with the aspect ratio of about 14. Keywords: limestone, lime, slaked lime, precipitated calcium carbonate, aragonite, accelerated carbonation

Sep 1, 2012

By Baidyanath Mandal

Technology in the solid-liquid separation industry has evolved rapidly during the last fifty years and from the beginning, DIEMME Filtration has played a very important role in this evolutionary process by developing innovative solutions, which are used for a diverse range of industrial applications. Since the last decade, we find more and more examples of filter presses employed in the mining & mineral processing field, where high performances in terms of productivity, dewatering capacity and mechanical strength even in extreme working conditions are required. Mainly the requirement of such high quality equipment comes from the Process, however in few cases the reason could be linked with the environment. For stringent process applications like Mineral Concentrates dewatering & leached Slurry Filtration, it requires a high quality & extremely reliable equipment. In these applications, since many years industries are achieving the desired result by using Diemme Filter Presses. Also, recently, due to stringent environment practices are been applied globally, industries needs equipments which could dewater a high amount of residues / tailings with minimal moisture content in the filtered cake. In comparison to all the conventional dewatering equipments, Diemme Filter Presses are most efficient for these kind of product & applications. Diemme Filtration is a highly professional & technological company with several decades of experience in designing equipment for mineral processing. We take up each project as separate & design and manufacture equipment based on individual process or project requirement. This presentation will be focused on the Solid-Liquid separation technologies & equipment Diemme Filtration offers to the mineral processing Industries. It consists of Diemme?s History, Global Network, Technologies & Expertise, R & D Capabilities, Manufacturing Range, Some Applications & results on different mineral processing. Keywords: solid-liquid separation, filtration, dewatering, filter press

Sep 1, 2012

By John A. Herbst

Professor A.M. Gaudin and his students at MIT were dedicated to understanding the fundamentals of mineral processing and as a consequence were constantly searching for better quantatative descriptions of size reduction, liberation and mineral separations. I have had the good fortune of meeting Professor Gaudin and working with many the modeling pioneers who followed him. I have observed first hand the refinement of mineral processing models as they increased in realisticness moving up the steps of the pyramid (see figure below) from pure empiricism to the current pinacle of physics based models. During this journey our industry benefited significanbtly as model prediction errors were reduced from ± 20% to ± 1%. Unit operation and plant simulations improved in accuracy and speed of calculations.

Sep 1, 2012

By N. P. Haran

A detailed study was undertaken to beneficiate sub-grade iron ore sample from Kenojhar District, Orissa, India containing 57% Fe (T), 7.7% SiO2, 4.8% Al2O3, 4 % L.O.I. 0.4% TiO2,1.3 % Mn and traces of S(T) to make it suitable for the user industry. The mineralogical study indicated that it predominantly consists of haematite with subordinate amounts of goethite and clay. Quartz, Cryptomelane / Psilomelane, Pyrolusite, Gibbsite, Feldspar and Muscovite mica were present in very minor to trace amounts. The Denver grind ability tests indicated, that the sample could be categorized as ?medium soft to medium.? The Bond ball mill work index was determined to be 14.19 kwh per short ton. The beneficiation process involved classification followed by tabling of the classified sand, ground to minus 48 mesh size. The table slimes were subjected to Wet High Intensity Magnetic Separator (WHIMS). The developed process yielded a composite concentrate from tabling and WHIMS operations assaying 65% Fe(T), 2% SiO2, 1.8% Al2O3, 2% Mn and 0.9% LOI with a recovery of 60.1% Fe (T), amounting to 52.5 wt.% yield. To meet the size specifications for pellet making, it was further ground. Dewatering studies were also carried out on the ground combined concentrate and rejects. The thickener area of ground combined concentrate using 0.02 kg/t of Sufloc A 1115 flocculant was 0.02 m2/tonne of dry solids per 24 h. And for the combined rejects using 0.12 kg/t of flocculant, it was 0.035 m2/tonne of dry solids per 24 h. The moisture content, in the pressure filtration cake, in the ground combined concentrate product was 10.0%, and productivity was 506.7 kg/m2h. Thus, by thickening and filtration of process products, 90% of water used in the process could be recovered. The study highlights the development of a simple and cost effective flowsheet with almost complete water recovery for a subgrade iron ore sample. Keywords: tabling, WHIMS, thickener, filtration

Sep 1, 2012

By K. Kiangi

On installing the Metso Superior MK 54x75? primary gyratory crusher in Nkomati mine the crusher experienced severe power spikes greater than 1000kW which subsequently led to the crusher tripping under load while processing some of Nkomati?s MMZ ores. Likewise significant losses in throughput were also experienced while processing some of Nkomati?s MMZ ore types. Interestingly the crusher was capable of processing the PCMZ ores without experiencing any power spikes or losses in throughput. Investigations into the challenges faced by the crusher while processing Nkomati?s MMZ ores were conducted using the DEM model in conjunction with the fast breakage model present in Metso?s High Fidelity Simulator. The intentions of the study were to establish the most suitable operating conditions or cavity design that would potentially enhance the performance of the crusher. Likewise an understanding of the effects the feed conditions (size distribution and hardness) had on the crusher?s performance was established. Ore characterization tests were conducted on Nkomati?sPyroxenite, Diabase, Calc silicate and quartzite ores which were from Nkomati?s MMZ ore body. The ore characterization tests conducted were drop weight tests, slow compression tests and elastic modulus tests. Four simulations were conducted used the existing cavity design with various open side settings (OSS) and throws. This established the effects of changing the crusher?s operating conditions on its performance. Four additional simulations were conducted on two cavity designs with reduced volumes. This established the effects of changing the crusher?s cavity design on the crusher?s performance. Thus through the simulations a better understandings of the impact of the crusher design, operating conditions and feed conditions on the crushers performance. Furthermore an analysis of the crusher?s performance was made which was used as a basis for comparisons with the base case simulation. Keywords: crusher, discrete element method, simulation, ore characterization

Sep 1, 2012

By Zhiyong Gao, Ruiying Fan

"Crushing and grinding are the prerequisite processes in many industries, such as minerals processing and powder technology. During crushing and grinding, minerals will cleave or fracture along the directions by broken the interlayer bonds (e.g., ionic bonds), generating some commonly exposed surfaces. The broken (or dangling) bonds at the generated surface makes the surface more active and determine the reactivity of the surface. In this work, the population of broken (or dangling) bonds on commonly exposed surfaces of fluorite mineral (a chosen model mineral) was calculated. Based on the calculated broken bonds information, the anisotropic surface reactivity of fluorite such as surface energy, surface relaxation, dissolution, wettability, surface charge and adsorbability, were discussed. The results show that the surface broken bonds density, which is positively related to the surface energy, can be used to predict the cleavage nature, surface relaxation degree and surface stability of fluorite crystal. The distribution characteristic and the number of broken (or unsaturated) bonds of surface active atoms (like Ca for fluorite crystal) can be used to predict and explain the anisotropic wettability, surface charge and adsorption mode and strength of organic molecules on different commonly exposed surfaces. It is easy to conclude that the calculation of surface broken bonds can serve as a fast and accurate way to start the mineral chemistry studies. These findings will be helpful to the mineral/material chemistry research in related interfacial science communities.INTRODUCTIONGrinding for mineral liberation is a prerequisite for a successful flotation separation. Also grinding for size reduction is a prior process for a favorable powder technology. During the grinding process, the minerals / materials will cleave and fracture along certain crystal directions with relatively weak interlayer chemical bonds1 to form a number of common exposed surfaces. Exposed surfaces are the outer boundary of a solid substance. In the mineral / material block, the bonding orbital of the atoms is filled with electrons and the atoms are in a steady state. Atoms on these exposed surfaces appear to show dangling bonds (or broken bonds) by losing chemical bonds to adjacent atoms in the previous block. Therefore, surface broken bonds serves as an initial property of a fresh surface. The lattice arrangement and crystal orientations causes differences in the number of dangling bonds on each exposed surface, i.e., anisotropic surface broken bonds2. The anisotropic dangling bonds enable the exposed surfaces to show varying degrees of surface reactivity (including surface energy, surface charge, surface relaxation, dissolution, wettability and adsorption behavior), known as anisotropic surface reactivity."

Jan 1, 2018

By Ashiwani Kr Gupta

The floatability of coal is affected by the presence of dissolved inorganic ions in plant process water. Water quality is characterized in terms of conductivity, hardness, turbidity and composition of oil. These quality indices are correlated with coal flotation performance for three different water named, ?R&D laboratory tap water?, ?process untreated water? from West Bokaro wahsey-2 Tata Steel, India and ?process treated water? after passing laboratory developed treatment process. The study clearly indicated that a significant quantity of clean coal is being lost due to poor process water quality used in the flotation process. The laboratory investigations showed that if these dissolved salts and suspended solids are reduced to even 50%, a clean coal yield improvement by minimum 5%~10% at the same ash level could be expected. Therefore, the conventional practice of water recycling though a thickener or a tailings pond needs a complete re-look. The water treatment process for recycled water has also been discussed for improving the process water quality as well as enhancement in flotation performance efficiency.

Jan 1, 2014

By U. M. J. Boin, E. V. Verhoef

Pyrometallurgical reactors constitute a key processing component in the total primary and industrial/recycling resource cycle, being involved both in primary smelting, converting and extraction, as well as the reprocessing of scrap, from aluminium cans to end-of-life automobiles. Therefore the pyrometallurgical reactor?s role in achieving sustainability is the central theme discussed in this paper since optimising their operation minimises waste, residue and offgas (NOx, dioxin, CO2) and maximises product quality and therefore efficiency. To effectively control the overall resource cycle, one needs to take a systems modelling approach of the whole cycle, seeking to also understand the dynamic process behaviour of the individual components of the cycle, and then especially the part that contributes most to the chemical conversion, namely the pyrometallurgical reactor. This paper highlights the role of pyrometallurgical thermodynamics in the whole resource cycle and specifically places equilibrium thermochemistry in the context of process dynamics where large, variable inventories are recycled or maintained within the system. This paper will therefore review the semi-empirical dynamic modelling tools, which are used to model complex systems with the specific goal of developing dynamic predictive models, which also include slag-alloy chemistry, towards controlling the recycling in a feed forward manner. To illustrate the primary production of metals, high carbon ferrochrome and Ni-Cu-matte smelting will be presented as a brief case study. Also fundamental studies in blast furnace and waste incineration kilns will be given. It also will show how the distributed nature of the chemistry of melts in the case of primary extraction, and industrial (recycling) materials such as recycled end-of-life vehicles, have a significant impact on the process outcomes and model predictions. It is therefore argued that the fundamental thermodynamics and kinetics in metallurgical reactors play a final crucial role in modelling the closed material cycle, but only when it is used in conjunction with process systems theory based on reconciled data for parameter estimation and model calibration. System models for aluminium and car recycling will be given as well as a dynamical system model that describes the interconnected material flows for Ag, Au, Bi, Cu, Fe, Ni, Pb, PGM, Sn and Zn for a study on lead-free solder.

Jan 1, 2003

By V. K. Gupta

Several approaches to the estimation of the size discrete breakage rate and distribution parameters (kj and bi,j ) of the batch grinding kinetic model are available in the literature. Analysis of a large amount of data available in the literature and our own data on several pure minerals and complex ores has shown that it is not always possible to obtain correct estimates of the two sets of parameters using known approaches as several widely different combinations of k and b parameters can sometimes simulate the batch grinding data reasonably accurately. It has been found that there are two main reasons: (i) all size classes are not well represented in the data and (ii) functional forms used for estimation of the two sets of parameters are sometimes chosen somewhat arbitrarily (especially in the case of complex ores), though they are actually uniquely related through size continuous breakage rate and distribution functions. A suitable experimental methodology has been described and demonstrated using some synthetic data and actual experimental data. A mill function approach, which does not require making any assumptions about the functional forms for k and b parameters, is also described and demonstrated. This approach is promising, but requires further development.

Sep 1, 2012