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By I. V. Kubrakova, O. A. Tyutyunnik, M. L. Getsina, A. M. Asavin

An analysis of noble metals (NM) in natural samples is most problematic. Determination of their traces in geochemical samples, in part, for the purpose of deposit evaluation, is a difficult analytical task. A number of international standard reference materials of rocks and ores, in which NM content is certified, is estimated at a half dozen. For example, in the International proficiency test for analytical geochemistry laboratories (GeoPT), which is held by the Department of Earth Sciences (The Open University, United Kingdom), the data for gold and platinum are observed very rarely, and the results obtained in different laboratories differ on 1-3 orders of magnitude. It is caused by low contents of NM in nature, by a variety of their complex and mineral species, as well as by a complicated matrix composition of platinum-containing objects. Among these objects are ferromanganese ores, enriched strongly with Fe, Mn, Ni, REEs - the elements hampering a precise determination of NM due to a complexity of instrumental inter-element correction. The absence of the reliable methods of NM determination in these ores drastically limits the possibility of deposit evaluation.

By Andrea Koschinsky

Recent technological breakthroughs in the fields of ceramics, medicine, aerospace engineering and electronics (semi- and superconductors) are constantly creating new uses and an ongoing increasing demand for a variety of rare valuable trace metals. These so-called high-tech elements such as hafnium (Hf), titanium (Ti,) niobium (Nb), tantalum (Ta), zirconium (Zr), molybdenum (Mo), vanadium (V) and the rare earth elements (REE), many of them of strategic importance, occur inter alia at elevated and potentially economic concentrations in marine ferromanganese nodules and ferromanganese crusts, making those deep sea deposits potential future resources of these metals. As these metals are mostly present in the lattice of the manganese and iron phases, which are strongly intergrown, rather than in separate mineral phases within the nodules and crusts (Koschinsky and Hein, 2003), reductive dissolution of the host phases is a prerequisite to release and dissolve the valuable metals. To evaluate the association of these rare valuable metals with their mineral carrier phases, sequential leaching experiments were carried out on selected samples in a first step in our project.

Jan 1, 2011

By Robert Corcoran, Piotr Jasiobedzki, Roy Jakola, Michael Jenkin

Vast mineral resources of copper, zinc, cobalt and gold have been identified off the coast of Papua New Guinea at depths exceeding 2,000 meters. Accessing them in a cost effective manner and without destroying the marine habitat requires overcoming numerous technical and operational challenges. Although there are a number of deep-sea mining operations underway worldwide, the depths encountered are significantly less than will be required to mine these ore deposits. To date, only the oil industry has developed technologies for successfully accessing reserves at depths of 3,000m.

By Brian D. Bornhold

A comprehensive multi-disciplinary marine geological survey of northwestern Graham Island, Queen Charlotte Islands, British Columbia, Canada was conducted by Offshore Survey and Positioning Services Ltd. of Vancouver, B.C. on behalf of the Geological Survey of Canada; Energy, Mines & Resources Canada, Pacific Geoscience Centre, Sidney, B.C. Canada during October 1984 and July 1985. The aim of the survey was to map both the surficial geology and geomorphology in order to identify and evaluate the nature of the nearshore sedimentation and recent tectonics including stability (slumps and scarps) seafloor faults (frequency and displacements) and both the classification and consistency of soil type boundaries and properties. Data was acquired by utilizing conventional indirect applied marine geophysical techniques including side scan sonar, precision echo sounding and complimentary soil sampling. During October 1984 a total of 320 line kilometres of data including 180 soil samples were acquired. During July 1985 a total of 300 line kilometres of data were acquired including 150 soil samples.

Jan 1, 1985

By Alexander Malahoff

Accumulation of cobalt -rich ferromanganese crusts on Pacific seamounts located off-ridge in the Hawaiian EEZ, represents a complex process that involves geologic aging of the seamounts, geographic transportation- of the seamounts on the Pacific plate during the past 80 million years, and geochemical history of the oceans for that period. A comparative study of the building and erosion processes of the young Loihi Submarine Volcano, located south of the Island of Hawaii , and the 80 million year old Cross Seamount, located west of Hawaii , shows that both edifices show wide armchair-shaped talus chutes and intervening ridges of exposed dikes. The similarity between the observed mass wasting process on Loihi and Cross suggests that the slopes of submarine volcanoes are geologically unstable from the time of their origin on the seafloor through their entire geological history. The slopes of Cross are covered by coalesced ferromanganese crust covered talus, steep exposed dike faces, and crust covered dike ridges. A study of the stratigraphy of the crusts shows a range of thicknesses and number of unconformities present. The thickest crusts, up to 8 centimeters, are found preserved within the larger coalesced slabs along the shallower slopes of the talus chutes and along the crests of the ridges between water depths of 400 and 1800 meters. The platinum content was used in stratigraphic correlation between the crusts in the coalesced slabs and those collected from ridges with the PISCES V submersible. In the samples studied, the highest platinum content of 0.7 ppm

Jan 1, 1991

By H. Shimoda, K. Tamaki, K. Iizasa, M. Watanabe, K. Okamura

Modern Kuroko-type deposits occur in submarine calderas of island-arc fronts and back-arc rifts in Japan. They occur primarily on or adjacent to caldera boundary faults. Hydrothermal sulfides in the Myojinsho submarine caldera are one of Kuroko-type deposits, but their occurrence is different from other deposits found within the area 200 km2 around the Quaternary volcanic front of Izu-Ogasawara arc.

Aug 24, 2006

By M. Geoghegan

Under the provisions of the U.N. Law of the Sea Convention Ireland is likely to have mineral rights to an area of continental shelf some six times its present land area. Apart from the major potential hydrocarbon basins which are currently the focus of active commercial exploration, little is known about the mineral resources of this vast area. In recent years a variety of mineral resources however have been identified from the coastal region. These include Sand and Gravel aggregates, Calcaraeous Algae (Lithothamnion), Heavy Mineral Sands and Coal deposits. The potential also exists in the coastal zone for buried placer deposits and base metal deposits. Several million cubic metres of gravel and hundreds of millions of cubic metres of sand have been identified by the Geological Survey of Irelands (G.S.I) Marine Unit off the east coast. The greater part of these deposits lies within the 10 metre depth contour and are easily recoverable. Irish aggregate needs at present are well supplied by onshore Pleistocene glacial deposits. Commercial interest in offshore deposits is in supplying coastal areas which are locally poor in aggregate and major coastal construction works. The possibility of supplying the large British and Continental European Market nearby also exists.

Jan 1, 1988

By Fredrik Søreide

Several potential marine mineral deposits of various types have been identified within the Norwegian EEZ. The Norwegian University of Science and Technology has recently designed and built a new remotely operated vehicle (ROV) system for scientific investigations of the deep-ocean and seafloor. A program to locate and investigate the most interesting of the identified marine mineral deposits using the new ROV system is underway. The ROV has been designed for detailed survey and sampling tasks. Although initially built for a major marine archaeology project, the design is equally suited to locate and investigate marine mineral deposits. The ROV is equipped with a high precision multi-sensory package that consists of various high quality cameras and lighting systems (together with state-of-the-art video and photo mosaic systems), several sonar systems, magnetometer and various other sensors. The ROV is also equipped with a 7-function manipulator arm and an excavation system. Internal collection baskets are used to store material for retrieval to the surface. A closed-loop control dynamic positioning system is used for detailed positioning of the ROV. Position data and other information are stored in a digital data management system. The ROV will also be used together with a specially developed remotely operated tool (ROT). The size and shape of this benthic lander can be adjusted before it is carefully lowered to the seafloor. The ROV can be docked on a moving platform on the ROT, to do detailed scientific investigations. The ROT can also be equipped with a separate sensor and system package, including drilling, excavation and coring units. This paper will present the new remotely operated system and the planned projects in Norway.

Jan 1, 2004

By Stanley R. Riggs

Onslow Bay is a broad, shallow, high-energy shelf system bounded by the Cape Lookout and Frying Pan shoals. It is generally a sediment-starved shelf system dominated by hardbottoms with a scattered and discontinuous veneer of mobile Holocene sediments. Phosphate-rich beds of the Miocene Pungo River Formation crop out in a belt 150 km long and up to 50 km wide across the continental shelf in Onslow Bay, North Carolina. Previous research has demonstrated that a few of these beds contain vast quantities of potentially economic phosphate resources that occur in the surface and shallow subsurface sediments. Onslow Bay contains five phosphate-bearing beds predicted to include up to 20.7 billion tons of in-place phosphate concentrate with total sediment grades ranging up to 22.9% P2O5 and adjusted average concentrate grades of 29.8% P2O5. These phosphates are lithologically and chemically similar to phosphates currently being mined in the nearby Aurora phosphate district in North Carolina. Various lithologies of the Pungo River Formation and associated rock units of Oligocene and Quaternary age crop out on the sea floor to form extensive hardbottom habitats that dominate almost 100% of Onslow Bay. A large proportion of these hardbottoms appear to be sea floor deserts, whereas others are virtual oases with rich associations of benthic organisms. These important differences in benthic community structure appear to be greatly influenced by one or more of the following variables: 1) geologic framework (geologic formation, hardbottom composition, morphology, and spatial orientation relative to dominant currents and waves), 2) texture, movement, and accumulation of surface sediments, and 3) flow rates and chemical composition of discharged submarine groundwater.

Jan 1, 1992

By Dwight D. Trueblood

The Benthic Impact Experiment (BIE) is designed to address the effects of sediment redeposition prior to the commencement of commercial mining. The experiment is being conducted in collaboration with Russian scientists from the Yuzhmorgeologiya Association aboard the R/V YUZHMORGEOLOGIYA. Sediment resuspension and subsequent redeposition during manganese-nodule mining is predicted to be one of the primary impacts on benthic communities living on the abyssal seafloor. The redeposition thicknesses that will cause significant faunal mortality in the deep sea are unknown. Sediment redeposition could adversely affect abyssal benthic communities through entombment, or through starvation caused by food dilution and obstructed feeding. This spring NOAA conducted the main portion of the BIE experiment, blanketing the experimental area with varying thicknesses of sediment using the Deep Sea Sediment Resuspension System (DSSRS). The DSSRS was conceived by NOAA scientists, designed and built by Williamson and Associates, and is the critical piece of equipment used to generate the controlled sediment redeposition environment on the 4800-m deep abyssal plane. The DSSRS consists of an 1800-kg sled, 4.8 m long, 2.4 m wide, and 2.2 m high. The sled was towed and powered using an 8,000-m, 26-mm single conductor cable having a 3,000 VAC capacity. As the sled was towed across the bottom, mud was ingested through two rear-facing, 45-cm wide intakes using two 7.6-horsepower pumps, and discharged 10 to 20 m above the bottom through two 20-cm diameter riser hoses. Each pump was instrumented with optical backscatter sensors providing real-time information about the discharge concentration.

Jan 1, 1992

By Valcana Stoyanova

Deep-sea mining of polymetallic nodules are expected to produce serious impact on benthic ecosystem due to removal of nodules, sediments and associated fauna by means of collector, and subsequently, by the resettlement of sediment plume which may affect seabed biota outside mining tracks through blanketing, smothering and feeding interruption. The scale and magnitude of the exact impact of commercial operations is not known at present, but its assessment strongly required acquisition of the adequate environmental baseline information. During the past two decades, IOM carried out a total of 20 research cruises in the eastern part of Clarion-Clipperton Zone (CCZ) with purpose to obtain essential data and information on polymetallic nodules and to prepare for future development their deposits. Whilst evaluating the nodule coverage at particular station from both seafloor photographs and box-core recoveries it was ascertain that the ground-truth data plotted against the photo data indicated substantial differences between two methods. Understanding of this phenomenon has not only the methodology meaning related to the efficiency of the using photoprofiling techniques during exploration of nodules, but also it could be of environmental importance because the similarity between natural sediment blanketing occurrence in studied area and expected re-deposition and blanketing of sediments which will be disturbed during mining operations.

Jan 1, 2011

By H. I. Chesalova, M. Ye. Melnikov, A. M. Asavin

The discovery of iron-manganese ores on the surface of underwater mountains was made more than a half century ago. During this time the basic ideas about the thermodynamics of the processes of hydrochemical reactions in the sea water have been developed by scientists and are revealed in geochemical and mineralogical differences between the deposits from the seamounts and the nodules of the sea bottom. The distribution of the dissolved metals, oxygen, carbonic acid and organic matter in the overlying ocean waters of seamounts in the deep ocean to depths more than 5,000 m has been studied in some detail (e.g. J.R. Hein, P. Halbach. G.B. Baturin, Ye.M., S.I. Andreev, L.I. Anikeyeva, [1-6]). In recent years scientists from YUZMORGEOLOGY have completed detailed geological survey work on the Magellan Seamounts in the Pacific Ocean. The results of drilling the ore body and geophysical and photo surveys have also been described [4]. Previous ideas about the general covering of seamount surfaces with iron-manganese crusts have been changed based on ground-truth surveys. This study examines the complex concentric-zone or spotty arrangement of the most densely covered sections, the strong dependence of the thickness of crust on the geomorphologic features, and the potential influence of the underlying substratum. One established geochemical heterogeneity in the composition of ores, also frequently inversely proportional power dependence on directions was observed. The development of a numerical model of the formation of the ore crust on the seamounts is currently a high priority.

Sep 24, 2006

By Hunsoo Choi, Sung Rock Lee, Ian J. Graham, Ian C. Wright

This is a part of the joint KIGAM-GNS-NIWA 3-year study of ferromanganese modules in the Campbell Nodule Field, east of Campbell Plateau to determine age distribution, growth rates and geochemical evolution in relation to geographic setting. The petrography, chemistry, inferred genesis, and 10Be/9Be dating of the nodules were described in the science report of GNS (Chang et al., 2003a, 2003b; Graham et al., 2003a) and presented at UMI (Chang et al., 2003c; Graham et al., 2003b). The morphology and distribution of ferromanganese nodules were also published in detail (Wright et al., 2005). This presentation is only concentrated on the mineralogy and chemistry of the nodules.

Aug 24, 2006

By Jelena Milinovic, Sofia Martins, Anna Lichtschlag, Sven Petersen, Fernando J. A. S. Barriga, Bramley Murton, Adeline Dutrieux

"The active TAG hydrothermal mound is one of the largest and better studied. Due to its size (one of the largest, known so far, in the Atlantic Ocean) and concentration of specific economic valuable elements, it might be considered for future exploitation due the increasing demand for raw materials. However, the discovery of several large inactive sulfide mounds, some partially buried under sediments may relieve this pressure. Exploration for such occurrences can, together with geophysical exploration tools, be accomplished by mineralogical and geochemical studies of those sediments.INTRODUCTION AND GEOLOGICAL SETTINGThis study reports the results from sediment samples collected during the Meteor M127 cruise on the TAG hydrothermal area in 2016. The Trans-Atlantic Geotraverse (TAG) hydrothermal field (Mid-Atlantic Ridge, 26°08’N) is located 2.4 km east of the main rift valley at depths of about 3650 m. The TAG hydrothermal field stands as an example of a massive sulfide deposit on a low-spreading ridge associated with an active detachment fault (Humphris et al., 2015).Associated with the TAG hydrothermal field are metalliferous sediments/deposits that can reach several meters in thickness (Metz et al., 1988). These sediments/deposits can be formed by hydrothermal plume fall out (buoyant and nonbuoyant), massive wasting of hydrothermal edifices (sulfide mounds and chimneys) and authigenic mineralization (Gurvich, 2006). By studying the grain size, mineralogy and geochemistry of the sediments it is possible to identify each type of sediments and find their proximal or distal distribution. The location of the gravity cores studied here is distributed along sediment ponds near inactive hydrothermal mounds [Three mounds area (B)], actively venting low-temperature mound [Shimmering mound (A) and Mir zone (D)] and an area of sediment accumulation [Central area (C)] (Rona et al., 1993) (see Figure 1)."

Jan 1, 2017

By Elizabeth McIsaac, Wylie Spicer

"In July 2016 the International Seabed Authority (the “ISA”) released a first working draft of its mineral exploitation regulations as well as the standard contract terms for mineral resources in the Area, for which stakeholder input was sought in late 2016. In January of 2017 the ISA released a discussion paper on environmental matters related to these draft regulations. The ISA is now in the process of further developing its draft exploitation regulations and standard contract terms to ensure that seabed mining is carried out in an environmentally sound way for the common benefit of mankind.As the regulator of the “Area”, the ISA can draw lessons from onshore mining regulators and offshore petroleum regulators for their experiences in legislative drafting to smoothly and safely oversee project development, implementation, and closure. However, one of the unique challenges that the ISA faces in regulating private industry is its status as an international organization and not a sovereign nation, which results in a significantly different legal relationship between the regulator and the regulated. The result is that the exploitation contract is the sole legal connection between the mining proponent and the regulator for the exploitation phrase of the project.Accordingly, in the regulatory development process, the ISA must carefully consider which rights and obligations are set out in the exploitation contract versus the regulations. This decision will dictate the flexibility the ISA will have to modernize the conduct required of mining proponents in response to changing best practices in the industry, technological progress, and advances in the understanding of the marine ecosystem. As the first working draft of the exploitation regulations sets out an initial contract period of twenty years, it is crucial for the ISA to carefully consider the rights, obligations, and procedures it agrees to in the exploitation contract, as unilateral amendment will not be possible after contract execution."

Jan 1, 2017

By Felix Lehnen, Peter Kukla, Mirjam Rahn

"Significant uncertainty is associated with predicting future trends in deep-sea mining projects, especially when attempting to assess markets for associated products such as ships and collectors. In order to help European Original Equipment Manufacturers (OEMs) to appraise the future market share of deep-sea mining equipment, a methodology was developed that allows to assess and predict equipment turnover. This study presents a market analysis, which evaluates the scale of the potential market for deep-sea mining equipment for seafloor manganese nodules (SMnN) and seafloor massive sulfides (SMS) based on six key drivers: (i) the worldwide deposit potential of SMnN and SMS deposits, (ii) the profitability of deep-sea mining projects, (iii) the metal market of seven associated metals (Cu, Zn, Au, Ag, Co, Ni, Mn), (iv) the current legal and environmental situation in the Area, (v) investment and maintenance costs, and (vi) a competitor analysis.Figures for the different key drivers are based on public reports and expert interviews. Large uncertainties as well as contrasting views and expectations resulted in different options (scenarios) for the future development of the deep-sea mining market. Several scenarios were developed and based on the future number of “mining projects” in the short-term (2022-2041) and the long-term (2042-2061). The number of such mining projects has been calculated based on the combined analysis of the different key drivers.In the scope of this study, the definition of a “mining project” is a deep-sea mining operation for SMnN or SMS lasting for 20 years. This operation includes the purchase of a set of deep-sea mining equipment consisting of a mining support vessel, a vertical transport system and the seafloor mining equipment, in line with other work within the EU FP7 project “Blue Mining” (GA No. 604500)."

Jan 1, 2017

By D. S. Cronan

Studies on polymetallic manganese nodules and Co-rich crusts in the EEZ's of the Cook, Line, Ellice and Phoenix Islands between 0-20°S show that Ni and Cu reach their greatest combined abundances of over 2% between 2-8°S on the southern margin of the equatorial zone of high biological productivity, as a result of biological fluxing of Ni and Cu to the nodules at and just below the CCD. By contrast, Co reaches it greatest abundance of 0.6% south of 8°S in nodules on non-biogenic clays well below the CCD where little biological Co supply is likely. Nodule abundances are greatest (up to 30kg/m2) in the Co-rich area in part due to AABW flow, giving highest overall metal quantities per sq meter in the nodules there, particularly of Co. There are approximately 110 x 106 tonnnes of combined Ni plus Cu plus Co expressed as Ni equivalent in Cook Islands EEZ nodules, approximately 12 x 106t. in Phoenix Islands ones, and approximately 1.4 x 106 t. in Ellice Islands ones, in areas of greater than 5kg/m2 nodule abundance. In the Co-rich crusts, Co averages about 0.7% and crust thickness about 1.6cm, both related to metal fluxes in and adjacent to the 02 minimum zone in association with which both maximum thicknesses and Co grades occur. Within the Cook Islands permissive area there are about 930 x 103 t. of Co and 630 x 103 t. of Ni in crusts, in Phoenix Islands crusts there are about 69 x 103 t. of Co and 55 x 103 t. of Ni, and in Ellice Islands crusts there are about

Jan 1, 1989

By Fernando JAS Barriga

The world-class Neves-Corvo deposits were intersected by drilling in 1977. They occur in the (Carboniferous) Iberian Pyrite Belt (IPB), Western Europe&apos;s largest stock of base metals (see Bamga, 1990, in Dallmeyer RD, & Martinez E, eds, Pre-Mesozoic Geology of Iberia, Springer-Verlag). Massive and stringer sulfides in the area sum up to about 200 Mt (109 kg), in five main orebodies (Neves, Corvo, Graca, Zambujal and Lombador). They include unique, extremely high grade copper and tin ores ( - 33 Mt Cu ores, -7.5% Cu, and -4 Mt Sn ores, -2.6% Sn, - 12.5% Cu). Also present are -50 Mt polimetallic ores (-6% Zn, 1.2% Pb, 64 ppm Ag). The remaining are relatively low grade pyritic massive and stringer sulfides (Cu < 2%. Sn < 1%, Zn equivalent < 4%). The geological setting is one of bymodal submarine volcanism, with predominant felsic, explosive volcanism and associated sedimentation (detrital and chemical), which took place on a shelf-facies, quartzite-phyllite basement (of Upper Devonian age). The plate tectonic setting has been the object of much debate. Current interpretations favour that the IPB volcanism took place in a tensional fore-arc region, associated with oblique subduction and collision (Silva et al., 1990, same volume as above). At Neves-Corvo there are many different ores, that may be grouped in four main types: fissural (at the base), breccia, massive (intermediate) and "ruban6 " (at the top). Fissural ores seem to correspond to stockworks in contrasting types of host rocks (gray to black shale, sericitic, chloritic and graphitic, and light gray volcanic rock). Massive ore may contain significant shaly gangue, at the base of individual orebodies, and silica-rich (cherty) varieties towards the top. The more sulfide-rich varieties predominate, and are usually well banded.

Jan 1, 1993

By J. Bruce Gemmell

ODP Leg 158 drilled seventeen holes into the active TAG hydrothermal mound and underlying stockwork, 26°N, Mid-Atlantic Ridge. Drilling in five different areas, including a high-temperature black smoker complex and a lower-temperature white smoker vent field, revealed the multi-stage depositional history and character of sub-seafloor mineralization and alteration. The upper portion of the mound consist of massive pyrite and pyrite breccias which are underlain by pyrite-anhydrite breccias and then by quartz-pyrite breccias. Quartz-pyrite breccias grade down into silicified wallrock breccias. Chloritised basalt breccias occur at depths greater than 100 m. Several stages of quartz-pyrite±chalcopyrite veins occur in the stockwork zone and lower portions of the mound, whereas anhydrite±pyrite±chalcopyrite veins occur within the upper parts of the mound. Recovery of unaltered basalt near the edges of the mound has constrained the extent of the stockwork zone to a pipe-like feature 80 meters in diameter. A detailed sulfur isotope investigation of sulfides and sulfates within mound and the underlying stockwork zone has revealed the overall range of sulfide d34S analyses to be 0.35% to 10.27%. Anhydrite has a tight range of d34S values 20.55% to 21.56%. There are distinct differences in d34S values between the different textural types of pyrite (massive sulfide, breccia clasts, disseminations associated with alteration, and veins). The massive sulfide and breccia clasts have a similar distribution of d34S values (6%-8%), however the d34S values of the disseminated pyrite associated with the alteration are distinctly heavier (8%-10%). Vein sulfides have the lightest d34S values (5%-7%). Sulphur-isotope values at TAG are, in general, the heaviest reported for unsedimented mid-ocean ridge deposits.

Jan 1, 1998

By Tetsuo Yamazaki

Natural methane hydrate has been scientifically studied as a global carbon reservoir. However, in Japan, it?s potential as an energy resource has been industrially highlighted, because there are few domestic oil and natural gas resources in Japan, but many potential deposition areas for methane hydrate in the sea around Japan. Less CO2 discharge from methane compared with coal, oil and conventional natural gas for the same calorie value is considered an advantage for its use as an energy resource. Because methane hydrate is distributed at shallow depth in sediments on the ocean floor, accidental leakage of methane may occur while we utilize methane hydrate. Methane itself has a considerable impact on the greenhouse effect, if it reaches the atmosphere. Therefore, it is necessary to estimate its behavior in the environment after leakage if we want to use methane hydrate as energy resource. The mass balance after leakage of methane on the seafloor and in the water column can be studied through the analyses of natural cold seepages and hydrothermal activity.

Jan 1, 2004