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By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By Karl Houseley, Dr. Robert J. Chapman

"A gravity concentration process has been applied to ores from the Clogau Mine, north Wales, the Tyndrum deposit, central Scotland and an alluvial ore from Leadhills area of Scotland. In the case of the Welsh ore and the alluvial deposit the gold grains in the concentrate and tailings streams have been characterised in terms of their three dimensions.In the case of Welsh ore, the thickness of a gold grain has been shown to be the single most important factor in determining behaviour in a gravity concentration operation. Six indices were used to quantify the overall geometry of the gold grains and those which incorporate a thickness term have proven to be effective in predicting the destination of gold particles within the concentration circuit. It is proposed that the most simple of these, the Heywoods flakiness ratio, has potential for the control of milling operations as an alternative to the established practice of characterising the size of the mill discharge.The effect of grain geometry on the recovery of fine gold has been studied using Tyndrum ore. The recovery of gold by gravity concentration increased from 20% to 70% when the criteria used to design the milling operation was the prevention of over grinding of gold grains.The destination of alluvial grains in the concentration circuit did not show such dependence on shape, and this has been attributed to the effective classification of all the gold grains in the sample by fluvial action producing a population of similar geometric characteristics."

Jan 1, 1996

By Christopher Boys

"Many water inflows in Saskatchewan potash mines are linked to salt anomalies. Potash ore and three anomalies in the PCS Cory potash mine in the Patience Lake Member of the Prairie Evaporite Formation were studied to understand the processes involved in their formation. Another goal was to find geological indicators of the proximity of anomalies. A geological model that relates the potash to the salt anomalies has been developed.Up to five post-burial facies may be recognized. These range from carbonate-mud collapse breccias to bedded sylvinite, and probably result from post-burial leaching. In this model, the same fluids that caused widespread recrystallization and possibly enrichment of the potash salts, started by dissolving huge cavities in the evaporites. The effects of the leaching were highly variable, indicated by selectively preserved delicate laminae and chevron textures, to deformed and totally dissolved salt beds. In at least two major events, Late Devonian and Cretaceous, collapse structures may have acted as conduits for overlying formation waters to cause pervasive leaching and recrystallization of the Prairie Evaporite Formation.Geological indicators of the proximity of an anomaly may include: a change in insoluble seam color from greenish-gray to mottled brown and greenish-gray, unusual local increases in ore grade, large patches (e.g., >200 cm2) of sylvite-poor potash crosscutting units near the top of the ore wne, and drops in topography > 10 m of the marker seams. Anhydrite was more common in an anomaly than in ore. The local abundance of anhydrite in ore may indicate the proximity of some salt anomalies. Once an anomaly has been encountered, indicators of a major collapse feature may include: stretched clay seams, folded beds, small collapse features (1 m to 20 m), numerous washouts, or split clay seams with injected salt. Any number, or none, of these indicators may be found close to a major collapse feature."

Jan 1, 1993

By Robert Walker

Agenda ? Investment thesis ? Engagement ? Competitive advantages Corporate engagement ?The ESG Services team carries out engagement activity with the companies in the Ethical Funds portfolio on behalf of investors ?Each year about 50 companies (20% of our assets) are placed on our Focus List based on assessment of significance and severity of ESG risks and the extent of our portfolio exposure ?We engage in direct discussions on material ESG issues ranging from climate change to human rights to executive compensation ?This enables the team to gain insight into how management is addressing various risks to the business and encourage positive change where gaps exist

Aug 1, 2013

By W. Yang, R. Rajasingam, B. Tadesse, K. Mohanarangam

Copper electrowinning is a complex electrochemical process that involves the production of LME grade copper from copper rich electrolyte. The process involves the deposition of the copper ions onto the cathode from copper rich electrolyte with the production of oxygen bubbles at the anode. Acid mist is produced by these oxygen bubbles bursting at the electrolyte free surface. It is an undesired by-product of the Electrowinning process which unchecked could result in mist generation higher than the recommended time-weight-average exposure limit. Various approaches to alleviate the problem have been adopted by companies, all with varying degrees of success. All of these have been attempts to treat the symptom acid mist rather than the inherent problem, often proving expensive and, in some cases, ineffectual. In this paper, a new method was developed for acid mist quantification based on ‘total acid mist’ capture above the EW cell under well controlled conditions. With the use of sophisticated diagnostic analytical tools and measurement techniques it was possible to study all the operating variables including current density, flow rate, temperature, etc. independently and their effect on bubble size, bubble velocity, gas hold-up as well as acid mist generation and its droplet size. Results show that total acid mist capture increases with an increase in current density but remains more or less constant between 300–500 A m-2. Total acid mist also shows an increase with increasing electrolyte temperature. These findings are substantiated with the aid of bubble size and gas hold-up measurements with the transparent EW cell.

Jan 1, 2019

By Lee Nichols

The Oil Sand Industry in northern Alberta, Canada, disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called Consolidated Tailings or Composite Tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities. Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are long-term stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface. The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process.

May 1, 2004

By R. J. McLeod

"A new backfill plant was constructed in 1966 adjacent to the mill of Giant Yellowknife Mines. The reasons for the addition were to increase the storage capacity for sand fill, provide facilities for mixing cement with the fill for mine stope floors and provide a system for pumping fill to B -3 raise, a horizontal distance of 4700 feet from the mill. At the same time it was hoped to increase the density of the fill pumped underground.The plant consists of two only steel storage tanks of approximately 400 tons capacity of sand fill each. They are 17 feet in diameter and have conical bottoms. The cylindrical section is 28 feet high and the conical section 14 feet high. Each tank is fitted with water nozzles around the conical sections to remove solids at the required density. The water pressure on the nozzles is 150 lbs per square inch. The cyclones used to produce the sand back fill are located on top of the storage tanks. Five model Dl0B Kreb cyclones are used for this purpose. The vortex finders are 2 1/ 4 inch and the apex 1 1/4 inch. The cement silo or storage tank is located in the same building. It is a steel tank 17 feet diameter by 41 feet high with a conical bottom. The silo holds 250 tons of bulk cement, which is unloaded by air from a bulk highway carrier using 12 to 15 lbs air pressure. The cement is conveyed to the top of the silo, a distance of 70 feet from the ground by 450 lbs. of air.The mixing tank is a rubber lined steel tank 14 feet in diameter by 14 feet high. It is equipped with a Lightning Mixer supplied by Greey Mixing Equipment Ltd. The mechanism is driven by a 40 HP motor. The lower shaft is unsupported and is equipped with two 36 inch diameter axial flow turbine type rubber covered impellers. The backfill is discharged from the storage tank into the mixing tank by a 5"" x 4"" SRL-C pump powered by a 20 HP motor. A level control in the mixing tank regulates the rate of discharge of this pump through a Grinnell-Saunders automatic control valve. The cement silo is situated at such a height above the mixing tank to allow for a Rota-Lock, a small hopper and a cement feeder. The feeder is an Omega gravimetric belt type dry feeder with a Sensogram controller. The capacity of the cement feeder is 20 tons of cement per hour. The cement and backfill are mixed in the mixing tank at whatever ratio is required for the mine stope floors."

Jan 1, 1968

By Rick Steen, Weldon Read, Morrism Tracy T.

Edging for starter sheet blanks used in conventional copper refineries has always been problematic for getting the edging to seal and adhere to the titanium material used for the blank so that copper is prevented from plating under the edging and cause undo problems in getting the copper sheets to separate from the blanks. A method was developed at the Amarillo Copper Refinery utilizing an injection molding process that better adheres the edging material to the titanium that makes the harvesting of starter sheets much easier to the point that robots are now used to strip with and which holds up very well to the unforgiving physical nature of the electroplating process. It is believed that this technology could be successfully utilized for permanent cathodes as well. INTRODUCTION ASARCO LLC (Asarco) was organized in 1899 as the American Smelting and Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co- products (Marcosson, 1949). Grupo México, S.A.B. de C.V acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, molybdenum, selenium and tellurium. Asarco operates three open-pit mines and mills and two solvent extraction-electrowinning (SX-EW) plants all in Arizona plus a copper smelter in Arizona and a copper refinery in Texas. Figure 1 illustrates how the copper metal comes out of the ground at the mine and ends up as a refined product at the refinery. The copper refinery in Texas is known as the Amarillo Copper Refinery (ACR) and is located in Amarillo, Texas. It was built in 1975 to replace 3 other aging refineries and was designed to produce 550,000 tons (500,000 MT) of refined copper per year using conventional starter sheet technology. At the time it was commissioned it was the largest tankhouse in the world at just under 1/2 miles long under one roof.

Jan 1, 2019

Grinding with an electrochemically inert grinding media (i.e. high chrome white iron, or Magotteaux’s Duromax® alloys) shifts the pulp potentials to more oxidising conditions, increases the dissolved oxygen content and reduces the EDTA extractable iron concentration when compared with milling with electrochemically active grinding media (forged steel). These changes in pulp chemistry produce cleaner particle surfaces, reduce reagent consumption and increase concentrate grades and recoveries. This paper presents a robust laboratory test program that is able to not only demonstrates these effects but also provide an indication of the magnitude of the improvements that are possible. While laboratory studies are interesting, the proof is in the pudding! So, the paper provides an overview of plant trials conducted at a number of operations around the world, including: Newcrest’s Cadia Operation, Oz Minerals’ Prominent Hill Mine and Glencore’s Ernest Henry Mine. These successful plant trials clearly demonstrate that selection of the right grinding media alloy will yield savings in grinding media consumption and reagent consumption as well as increases in revenue through improved copper, gold and molybdenum recoveries. INTRODUCTION The key to a successful separation in mineral processing is the preparation of particles with adequate liberation under the correct pulp chemical conditions. While the importance of liberation on flotation separations is generally understood and well documented in the literature (Johnson, 1987; Jackson, Sutherland, Gottlieb & Quittner, 1989; Young, Pease, Johnson, & Munro, 1997; Greet and Freeman, 2000), the importance of pulp chemistry is more nebulous, particularly with regard to the impact of grinding media. Extensive work examining the electrochemical interactions between grinding media and sulphide minerals has been completed (for example, Iwasaki, Reid, Lex & Smith, 1983; Natarajan and Iwasaki, 1984; Yelloji Rao and Natarajan, 1989(a); Yelloji Rao and Natarajan, 1989(b)). Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution, therefore a galvanic couple between the media and the sulphide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulphide minerals thereby affecting their floatability (Johnson, 2002).

Jan 1, 2019

By C. G. Kemsley

THE ore as hoisted is very wet, and difficulty was experienced i~ screening it to remove the fines before going to the secondary crusher. In fact, the fines had a tendency to form balls and roll down the screen, and only a small percentage was removed. Their inclusion with the other ore going to the Symons secondary crusher caused excessive spring action and pounding between the adjustment ring and main frame, resulting in abnormal wear between the two. To overcome this, it was decided to wash the fines through the primary screen, and use an Akins classifier to de-water the screenings, pumping the overflow from the classifier up to the mill and discharging the oversize onto the mill-feed belt.

Jan 1, 1945

By M. Takebayashi, M. Shingu, H. Nagai, T. Nakai, S. Asano

The Toyo Smelter and Refinery, owned by Sumitomo Metal Mining Co., Ltd. (SMM) is located in the coastal zone of Saijo City and Niihama City, Ehime Prefecture, Japan. The refinery has been producing copper, sulfuric acid, and precious metals such as gold, silver, and PGMs. Previously, the process of precious metals recovery was a combination of pyrometallurgy and an electro-refining process with the conventional cupellation for around 400 years. However, this process had some major problems such as non-efficient recovery of valuable metals, high environmental risk by pyrometallurgy, high cost for maintenance of equipment and so on. In order to solve these problems, a thorough hydrometallurgical process for precious metals refining using chlorine leaching technology was originated and developed by Sumitomo and thereafter commercialized in 2004 at Toyo Copper Smelter and Refinery. This new process enabled shorter-term recovery of gold and manpower saving, and occupational safety and working conditions have also been improved. Superiority over the existing hydrometallurgical processes was also confirmed, for example by the achievement of 99.99% pure silver production without an electro-refining process. This paper summarizes the hydrometallurgical technologies for precious metals recovery such as chlorine leaching of copper anode slime for silver recovery, solvent extraction (SX) for gold recovery, and ion exchange (IX) for PGMs recovery. It also presents a unique silver purification process. INTRODUCTION Sumitomo Metal Mining Co., Ltd. (SMM) produces copper, precious metals and rare metals as by-products at the Toyo Copper Smelter and Refinery, and nickel and cobalt at the Niihama Nickel Refinery. Precious metals contained in nickel ore are also separated and refined at the Toyo Refinery after concentration. SMM has been refining precious metals using the pyrometallurgical method. In recent years, we have revamped the separation and refining process of precious metals dramatically by making use of advanced hydrometallurgical and engineering technology developed in the company. In this paper, we introduce the history of development and techniques of this process, and also introduce in detail the technologies of gold refining, PGMs recovery, selenium recovery, and silver refining which have been particularly difficult to achieve.

Jan 1, 2019

By D. L. Johnston

"The avenues and degree of participation by aboriginals in the Canadian minerals industry have changed significantly during the thirty years of the author&apos;s career in that industry.The typical 1950s cycle of mineral industry involvement of a local non-Europeanized aboriginal was as an individual employee. The employment relationship would begin with the best of intentions by both parties of permanence and terminate when the pioneering employee was unable to reconcile the attendance behaviour required by the employer and the social-sharing behaviour demanded by family and friends.Cominco Ltd. has been a mine operator and developer in the North since the 1920s. Cominco&apos;s early experiences with employment of non-Europeanized natives at the Con Mine in Yellowknife, Northwest Territories from 1938 to 1986 was a negative experience from both the employee and employer ends. A series of classic failures in employment of individual aboriginals was a large part of the history. A few Metis or natives from other areas were the permanent aboriginal employees at Con (2010). Racial prejudice was overt on the street in Yellowknife and, it can be assumed, in the workplace, as well.The history of aboriginal employment at the Pine Point, Northwest Territories operation (1964 to 1988) was somewhat better but also frustrating. The mine was equidistant (80 km) from the Dene communities of the Hay River Indian Reserve and Fort Resolution, both on Great Slave Lake. Despite a large aboriginal presence and many well-intentioned efforts, employment of aboriginals at Pine Point never got much beyond ten per cent. These would have been half local and half northern prairie aboriginals. One continuing success story was the railcar loading and covering crew led by Ed McKay, a local aboriginal. This predominantly aboriginal crew did its own recruiting and several are on Cominco pension."

Jan 1, 1995

By J. C. Salas, A. Weishaupt, J. A. Guzman

The origins of the electrorefining process date back to 1869, when the first ER cathodes were produced at Pembrey, South Wales. By the time that Pembrey was closing, Chuquicamata tank house was under construction, initiating in 1915 a long history of electrolytic cathodes production. Initially electrowon cathodes and later electrorefined cathodes were produced. During the history of Chuquicamata tank house, there have been several challenges associated with the quality demanded for electrolytic copper. Among them, the transformation from electrowinning to electrorefining in 1952, the onset of the direct commercialization of ER cathodes and the phase out of wire bars in the 80s, several technological changes including the implementation of permanent cathodes, and certainly the constant increase in complexity of the anodes refined. This paper explores the manner in which Chuquicamata has addressed these challenges and examines its links to process characteristics, which have been necessary to maintain a product quality according to market requirements and a brand, “CCC”, that is widely recognized worldwide. INTRODUCTION Located in the north of Chile, in the Atacama Desert, Chuquicamata is an open pit copper mine that for many years has played a relevant role in the global and local mining industry. Known from prehispanic times, the Chuquicamata deposit was initially developed between 1912 and 1915 by the Chile Exploration Company, the operating company of the Chile Copper Company controlled by the Guggenheim Brothers in the USA (Yeatman, 1916). Officially inaugurated on May 18th, 1915, by the President of Chile who pressed a button in Santiago sending a telegraph signal to the power generation plant specially built in Tocopilla, 1500 km north. It signaled the beginning of generating energy, sending it to Chuquicamata, another 140 km east (“El mineral de Chuquicamata”, 1915), marking the beginning of its industrial operation.

Jan 1, 2019

By S. Caron, M. Bourassa, J. Châteauneuf, L. Tardif

"Since many years, the Yvan-Vézina gold plant custom mills and processes different ore types that show different behaviors. Because of this, cyanidation control is more complex than for a typical milling operation. In 1992, a Cyancor™ on-line « free cyanide » analyzer has been installed for monitoring and optimizing cyanidation. This implementation significantly reduced cyanide consumption for the overall cyanidation process. In order to further reduce cyanide costs, an automatic control strategy has been implemented to decrease fluctuations of« free cyanide » from their set points.This paper outlines the major steps of the project: process control audit, control strategy development, implementation and running-in period. Control strategy features include data filtering modules, adaptive PID algorithm and set points management modules are also presented. Finally, the strategy efficiency is illustrated with load-disturbance responses.IntroductionLocated in northwestern Quebec, the Yvan-Vézina plant has an average capacity of 1300 t/d using carbon-in-pulp technology. In 1991, the Yvan-Vézina gold plant was processing three types of ores (Beauchemin, Mouska and Silidor mines) and a pyrite concentrate (Beliveau mine). A cyanide reduction program was then undertaken to reduce « free cyanide» fluctuations <6>. To reach this objective, the optimum cyanide concentration was determined for each ore, a continuous monitoring method with the Cyancor™ on-line analyzer was developed and a tighter control of cyanide addition was applied. These modifications to the leaching practice significantly reduced cyanide consumption.After a while, it was observed that regulation of « free cyanide » concentrations could still be improved by the use of an automatic control strategy. Yvan-Vézina and CRM began collaborating in 1995 to develop and implement such a strategy. Results show that main disturbances of the circuit (e.g. ore mineralogy and pulp feed rate) can be significantly overcome in order to reduce their effects on the leaching operation."

Jan 1, 1998

By R. Alarcón Sch., R. Abel F.

For many years, copper cathode quality has been a priority for end consumers, since it affects the variety of products that can be obtained from them. From the beginning, physical and chemical quality of the wire bars was controlled, as this product was used to obtain wire rod and other forms of copper by wire drawing. At that time, all the electro refined cathodes were melted and casted as wire bars. Subsequently, in the 80’s, with the introduction of continuous casting furnaces, it was possible to directly produce wire rod from cathodes. From then on, cathodes quality standards were consistently increased, by the introduction of uniform criteria, among which we can identify ASTM and British Standards as well. Also, producers began to use more demanding internal standards than the existing specifications, in order to differentiate their cathodes as high quality products among customers. Today the physical aspect of cathodes, including nodules, cracks, sulfates, or others, is the first element used by end customers to assess their quality. This paper aims to show a brief vision of the evolution of quality specifications for products used to manufacture copper wire. INTRODUCTION From the beginning of refined copper production for industrial purposes, mandatory minimum quality conditions were established. These quality conditions were used as the main element to determine prices and discounts of the respective sales contracts. Reviewing the copper development history, we can appreciate that its quality requirements had been constantly evolved, so that currently refined copper has an extremely high quality standard, that allows its direct use in the production of ultra-thin cables and other products applied in the industry. In each stage, refined copper production has fostered the development of technology used in their treatment. Similarly, cathode processing technology has been evolving to minimize treatment costs in order to generate a wire rod for several uses, ranging from power cables to super conductors. In this sense, to the already known type of fusion processes of the Southwire or Asarco type (capacities over 80 kt / year), wire rod production processes of the Upcast or Rautomead type (capacities between 20-50k t / year) have been added. They immediately deliver oxygen-free wire rods. In both cases, we can conclude that the clients' requirement had evolved from a chemical criteria focus, to considering more subjective aspects, such as visual control as the first stage of inspection.

Jan 1, 2019

By H. Y. Sun, Q. Y. Tan, X. P. Niu, L. Li, Y. Jia, R. M. Ruan

During bioleaching processes of sulfide minerals, the sulfide minerals act as the natural habitats for acidophiles, of which, most are autotrophic iron and sulfur oxidizing microbes. These microbes acquire energy by oxidation of sulfide minerals, and play crucial role in bioleaching processes. In the industrial bioleaching heaps, microbial community and their activity are highly related to engineering configurations, while the optimized industrial operation can help to fast dissolution of aim minerals and acid/iron balance under optimized microbial condition. Microbial community succession and activity formation, the function of microbes to mineral dissolution, the mechanisms to promotion and inhibition of sulfide minerals oxidation, and the industrial instances for microbial community regulation were reviewed. For these instances, promoted microbial activity helped to fast pyrite oxidation for sulfuric acid generation, which realized zero sulfur acid addition to the irrigation solution in the initiation of a bioleaching heaps. High microbial activity by optimized operation parameters improved Cu leaching efficiency during the heap bioleaching process. And also by inhibition of microbial activity, especially the iron oxidizing microbes, the excessive pyrite oxidation can be inhibited, which helped to the acid/iron balance during heap bioleaching. INTRODUCTION Around the world, high grade copper ore are exploited, while barely new high-grade deposits are succeeded, the copper grade of ore deposit is constantly decreasing. The increasing copper demands worldwide requests to process these low-grade ore deposits. Processing of low-grade ores are not economical by usual extraction processes. Heap leaching is a cheaper process for recovery of low-grade ores, and has been applied to extract valuable metals from sulfide minerals worldwide, such as copper, gold, uranium and nickel (Gericke et al., 2009). Heap leaching process has greatly decreased the economic grade and expanded the recoverable ore reserve worldwide (Brierley, 2008). It is usually carried out in the open environments, and could process huge amount of ore (usually in millions of tonnes in one reactor) in the heap reactor (Gericke et al., 2009). For copper sulfide, especially the secondary copper sulfides, heap (dump) bioleaching is successfully applied. Heap bioleaching process is cost saving, and sometimes can be achieved without adding chemical into heaps, by microbial fixing of the atmospheric N2 and CO2, and generating oxidant Fe3+ and sulfuric acid in heaps from oxidation of sulfide minerals. Also heap bioleaching is environment friendly by cycling use of the leaching solution, and without exhaust emission.

Jan 1, 2019

By Arthur Lieu

The mill effluent treatment circuit (Bulk Neutralization (BN)) in the Cameco Key Lake Operation was modified in 2008 to enhance the removal efficiency of selenium (Se) and molybdenum (Mo) from the mill process water. This modification was completed in part due to increased knowledge of the effects these elements have on biota. In addition, legacy effects from the historical operation of the Key Lake mill in regards to Se and Mo were shown to have an effect on the regional biota in the downstream receptors. This was a challenging initiative as there was no off the shelf technology available and the removal process had to be incorporated into an existing (brownfield) process. These modifications have resulted in significant reduction in the concentration of these elements in the Key Lake mill effluent. The removal efficiency for Se and Mo in the modified circuit has increased to 95% and 75%. As a result, concentrations of Se and Mo are now consistently less than 0.4 mg/l and 0.02 mg/l. In addition, the Se and Mo precipitates formed were extensively studied to ensure long-term geochemical stability in the Key Lake in-pit tailings facility. This presentation will provide additional detail on the hydrometallurgical removal mechanisms and process modifications required in the Key Lake BN circuit to remove these elements to trace levels.

Aug 1, 2010

By G. E. Agar

"The distribution of gold in the grinding-classification circuit of an operating gold plant was determined by assaying the size fractions of samples from each of the streams. This analysis identified the streams with the maximum potential for gravity recovery of gold and revealed that there was up 110 seventy-five times as much gold in the primary cyclone underflow as in the concentrator feed.Laboratory jigging and tabling tests were done on samples from two of the streams to determine what the recovery might be with a gravity circuit and to show that a high grade concentrate could be produced. A numerical simulation procedure was used to calculate a material balance for a circuit that included gravity separation on the primary cyclone underflow. The numerical simulation optimistically indicated that as much as 84% of the gold might be recovered in a reasonable grade of concentrate even though the recovery in batch bench scale tests was only 14%.Incorporation of a gravity separation device would reduce the inventory of gold in the grinding-classification circuit.INTRODUCTIONMany gold concentrating plants include a gravity concentration operation while others do not and the reasons that some do and some do not is not clear. Some of the advantages and disadvantages of gravity circuits are discussed by Penman (Penman 1987) without clear cut resolution. Penman's comments elicited an interesting response from Lloyd (1989) who produced a simple way to determine if the addition of a gravity concentration circuit would enhance the recovery of gold. Lloyd's method does not consider the cost of running the circuit so it only partially answers the question. There are reports in the literature (Wells and Patel 1991, Matwijenko 1988) that as much as 60% of the entire production comes from a gravity circuit when it is used, and that the grade of the concentrate produced often exceeds 65% gold, an assay that far exceeds most Merrill-Crowe precipitates that are sent to refining. In at least one instance (Hood 1984) a range of recovery from 40-50% was indicated from laboratory test work and the plant subsequently realized recoveries in the range of 26-40%. Despite these favorable numbers other plants use gravity separation when as little as 20% of the gold is recovered in the gravity concentrate (Carter 1992)."

Jan 1, 1993

By R. Sharma, I. Miskovic, S. Miskovic

Solvent extraction (SX) is a widely used method for the extraction of copper from pregnant leach solutions or other ionic solutions in hydrometallurgical applications. About 17% of total refined copper production worldwide is produced using SX followed by electrowinning (EW). Conventional SX units, such as mixer-settlers, consume a large amount of extractant, offer poor process control and yield low extraction efficiency. Extraction efficiency is poor due to low specific interface area, crud formation, emulsification, and slow phase separation stage. Micro solvent extraction (micro-SX) is a rapidly developing technology that provides an opportunity for improved process control, higher extraction efficiency, lower residence time and, as such, has a potential to reduce the environmental footprint of SX operation. In this research, extraction of copper ions in an acetate buffer media is investigated using D2EHPA with kerosene as a diluent. Chemical factors such as extractant concentration and ionic concentration of aqueous phase are varied to determine the optimum conditions. Subsequently, the extraction efficiency and reaction time of new micro-SX reactors are compared against previous bulk SX studies. Extraction in the microfluidic reactor was observed to be faster with a residence time more than an order of magnitude lesser than bulk SX. This study forms a prelude for developing new modular micro-SX units which will enable continuous, effective, and safe operation on a large scale. In future studies, numerical and analytical models validated through this work will help eliminate rigorous experimentation and enable faster design and fabrication of micro-SX units. INTRODUCTION Conventional industrial solvent extraction (SX) units such as mixer-settlers, extraction columns present various disadvantages. Low specific interfacial area, crud formation, and emulsification in industrial reactors lead to long extraction times and severely hamper extraction efficiency (Priest et al., 2011; Chen et al., 2017). Microfluidic extraction considerably improves upon the current extraction practices by (1) creating a large surface to volume ratio that enables rapid mass transfer across the interface, (2) better process control, and (3) easier separation of phases (Kashid, Renken, & Kiwi-Minsker, 2011; Ciceri, Perera, & Stevens, 2014). These factors establish micro-SX as a crucial mode for process intensification. Although, a micro SX unit has significantly low processing volume than conventional extraction methods, their throughput can be increased via massive parallelisation (‘numbering up’), which is an area of active research (Darekar, Singh, Mukhopadhyay, & Shenoy, 2016a; Kriel, Woollam, Gordon, Grant, & Priest, 2016).

Jan 1, 2019

By M. E. Austin

Many numerical models for the tubular solid oxide fuel cell (SOFC) exist, with various degrees of sophistication. However, the question of what physics must be modelled, and what can be neglected has not been resolved. A parametric model is proposed and analyzed to quantify the influence of thermal phenomena such as reaction heat generation, cathode channel convective cooling, and thermal radiation with participating media. Currently, a three-dimensional model is used to simulate the conditions of an anode supported cell in the centre of a tube bundle. The interconnect and nickel foam spacers that bridge adjacent cells in series and parallel, respectively, are neglected thus enabling a domain consisting of a 45o azimuthal section of the tube. The conservation equations for mass, energy, and species transport are solved using commercial computational fluid dynamics software, and radiation heat transfer is also modelled using a Discrete Ordinates method. Finally, temperature-dependent material properties and reaction rates are used. The model predicts lower overall temperatures than models that do not include radiative heat exchange and more moderate temperature gradients than those that ignore participating media radiation. Further, different regimes are identified, from convection dominated heat transfer to radiation dominated heat transfer. The results can be used to aid in the selection of appropriate models for a given fuel cell operating regime.

Jan 1, 2005