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By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By J. Bardinas

"The use of autogenous mills has become widespread, owing to their capacity and favorable capital and operating costs. Optimal operation of these systems is critical, given their high energy consumption and effect on downstream processing. A considerable effort has been spent over the years in the development of advanced control systems to achieve a better performance in this regard. However, despite significant advances, the problem still remains challenging, owing to the nonlinear behaviour of the system with respect to the mill variables, and, the unmeasured ore variability come from the mine.The mill load, in particular, can be seen as a state variable of the mill, which could be important for; modelling and control, and, important insights into the mill behaviour. In this investigation, time series cluster analysis was performed using online mill load measurements in order to identify the different control states of the mill. More specifically, this time series was divided into short non-overlapping segments. A distance matrix was set up for each segment and the information was captured by means of textural features, similar to that used in multivariate image analysis. These wavelet and grey level cooccurrence matrix features could subsequently be used to rapidly identify the normal operating conditions from the feed disturbances in the mill.In principle, the methods and models presented here, once suitably validated and calibrated, could be used in online process monitoring of autogenous mills. They also could serve as a foundation for developing more advanced process control models."

Jan 1, 2016

By A. Warczok

The mechanisms and kinetics of copper oxidation and reduction have been investigated in small scale thermal gravimetric experiments as well as in laboratory pilot scale, packed bed reactors. With blister copper flowing gravitationally down through a packed bed of ceramic particles, counter-current to low oxygen containing combustion gases, the rate of oxidation was found to be very high due to the large surface area created. Similarly, reduction by flowing copper through a packed bed of charcoal lead to rapid de-oxidation. Based on these laboratory measurements, fundamental rate data have been obtained. Modeling of industrial sized packed bed reactors using the laboratory results, opened up the possibilities of developing a new, very intensive, continuous process for copper fire refining. The developed mathematical model together with a computer process simulator, allowed for the design of the industrial-pilot installation to be built and tested at the ENAMI Paipote smelter in Chile.

Jan 1, 2007

By V. S. Sastri, M. Elboujdaïni

"Corrosion rates of silicon brasses, highzinc yellow brass, low-zinc yellow brass, leadedtin bronze and silicon bronzes in both permanent-mold and sand-cast conditions were determined in soft water of pH 3, 5 and 8, and hard water of pH 8 at 70°C by electrochemical polarization technique. The alloys in permanent- mold condition showed greater corrosion resistance than sand-cast condition. Corrosion rates obtained from weight loss measurements showed no observable trend of a difference between permanent-mold and sand-cast alloys.The corrosion rates decreased with increasing pH of the medium. Silicon bronze and silicon brass showed high corrosion resistance while leaded-tin bronze showed the least resistance. Addition of small amounts of aluminum improved the corrosion resistance of silicon bronzes and silicon brasses. Alloys in permanent- mold condition showed greater resistance to dezincification than sand-cast alloys when average pit depth parameter is considered."

Jan 1, 1997

By J. D. Botsford

Westmin Resources Limited's H-W orebody on Vancouver Island is a copper/lead/zinc massive sulphide deposit that has been in production since 1985. The sulphur content of the ore averages 28% and in some stopes is as high as 53%. Several minor secondary sulphide dust explosions have occurred in development headings and cut and fill stopes, but as yet no known explosions have occurred in blasthole stopes. This pa:per reviews the history of sulphide dust explosions in the H-W Mine, factors contributing to the explosions and the preventative measures taken to control them.

May 11, 1988

By H Zorychta

Based on underground measurements made at the Nova Scotia coal mines of the Dominion Coal Company, Limited, this paper presents a comparison between the physical properties of hardwood packs and steel friction props when used for longwall support. The probable loads sup-ported by steel friction props on a longwall face at both the Dominion No. 20 Colliery and the Princess Colliery are delineated, and the results of the tests are presented in graphical form. It is concluded that the steel friction props are more efficient than the hardwood packs that they replaced as roof supports. Introduction AN evolution in the methods of longwall face support is taking place in the Sydney coalfield. Longwall face support had consisted primarily of timber props and hardwood packs. In 1957, however, at the Princess Colliery, Sydney Mines, Nova Scotia, the first longwall was equipped with steel friction props. At the present time, eleven longwall faces are supported on wood and sixteen faces are carried on steel friction props.

Jan 1, 1965

By J. S. De Lury

The metalliferous areas of Manitoba have been described in more or less detail. Since the descriptions were written some new prospects have come to light and considerable mining development has taken place in two or three localities. No attempt will be made in this paper to give an account of recent activities or to describe the several areas in detail. In a general way, geological conditions are similar in all metalliferous areas of the province, a similarity that invites a discussion of the prospects as a whole, the features that are common to all deposits and the reasons for their uniformity. Modern theories of metallogenesis have a direct bearing on such a discussion and an effort will be made to show their application.

Jan 1, 1925

By T. S. Smith, C. C. Rennie

"THE LEAD-ZINC and tungsten mines of Canadian Exploration Ltd are on Iron Mountain, 8 miles south of Salmo, B.C., in the Nelson mining division. Relative location of the mines is shown on the general plan.First recorded lead production was in 1908 from surface outcrops. Small amounts of high lead ore were mined intermittently until 1926. No major lead-zinc production occurred until 1949 when outcroppings on the south side of the mountain were mined and diamond drilling began to prove the existence of a large replacement orebody. Lead-zinc ore has been mined continuously from the Jersey orebodies since March 1949, with monthly tonnage as high as 50,000 tons per month, but currently averaging 30,000 tons per month.Schee1ite-bearing tungsten ore was found in 1942 by H. Lakes in an old adit and open cuts at the north end of the Emerald tungsten orebody. The Emerald tungsten mine was developed by the Federal Government as a Wartime Metals project and operated for eight weeks in the fall of 1943, when the poor demand for tungsten closed the mine. Canadian Exploration Ltd. purchased the mine in 1947 and mined in excess of 100,000 tons in 1947-48 until the demand for tungsten dropped again and interest was centred on lead-zinc. The Federal Government repurchased and reopened the Emerald Mine in 195 L and built a new concentrator. The mine and mill were sold back to Canadian Exploration Ltd. in 1952.Regional Geology and IntrusivesThe host rock for both the lead-zinc and tungsten mineralization is the Laib formation of Lower Cambrian age, which consists of 400 feet of crystalline limestone underlain by beds of argillite, and argillaceous limestone locally altered to ""skarn"" or ""tactite"". The Laib limestone is overlain by black argillite and underlain by the Reno quartzite of Pre- cambrian age. Repetition of folded beds has allowed the interpretation of the large isoclinal fold which repeats the limestone (see general cross-section). Dolomitization and the associated lead-zinc ore have been found only in the right-side-up limestone and are not known in the overturned limestone.Two elongated stocks of granite cut the sediments. The Emerald stock outcrops along the east side of the Emerald tungsten mine and again west of the Jersey workings, while the Dodger stock outcrops only at the north end of the Iron Mountain. The shape and attitude of these bodies are believed to have been governed partly by pre-granite faulting and partly by pre-granite folding of the sediments. Although some forceful intrusion may have occurred the detailed granite surface indicates a gentle stoping emplacement."

Jan 1, 1949

By F. J. Tozer

Canal communication between Lake Erie and Lake Ontario has been one of almost constant enlargement and reconstruction to meet the rapid growth of trade and commerce, and the consequent steady increase in the size of vessels plying the Great Lakes. The original canal was built by the Welland Canal Company. The first sod was turned in 1824 and the first vessel passed through in. 1829. There were 36 lift-locks, built of oak timber, 110 feet long and 22 feet wide, with a depth of water over the sills of 8 feet. The second canal, now known as the 'Old Welland Canal' was built by the Dominion of Canada (1842 to 1850). There were 26 masonry locks, 150 feet long, 26.5 feet wide and with a depth of water over the sills of 9 feet. The walls and banks were raised in 1853 to give a 10-foot draught. The third canal, known as the 'New Welland Canal, built by the Dominion of Canada, was started in June 1874 and the first boat passed through in the spring of 1882. There are 25 masonry lift-locks, 270 feet long, 45 feet wide and with a depth of water over the sills of 12 feet. The walls and banks were raised in 1891 to give a 14-foot draught. This is the canal in use at present.

Jan 1, 1926

By S. Markstrom

The Boliden AITIK copper mine is located 100 kilometres north of the Arctic Circle in northern Sweden. A pre-feasibility study was conducted in 2005 with the aim of increasing the capacity of the existing processing plant. After analysis, options to upgrade the existing plant were abandoned in favour of building a new processing plant, with higher capacity and therefore greater profitability. A new plant could be designed with greater flexibility to make potential future expansions easier. A feasibility study for a new 36 Mt/y processing plant including fully AG grinding circuits and flotation was completed in 2006. The project was approved by the Boliden board shortly thereafter. Construction started in the beginning of 2007 and was completed during 2009. Commissioning of the new plant was undertaken in the first half of 2010. The grinding circuit consists of two lines with each line consisting of a 22.5 MW AG mill and a 10 MW Pebble mill in closed circuit with a spiral classifier. The nominal production level is 2 200 t/h for each grinding line. This paper presents the start-up and operation of the grinding circuit.

Jan 1, 2012

By P. Czaja

The paper presents a patented and copyright protected concept of constructing a shaft lining that goes through rock masses having strong rheological properties and being susceptible to leaching. In the case of salt layers, especially at significant depths (over 900 m) the relative convergence of the heading contour may amount to 40 ?/year. That results in the fact that any other method of securing the shaft lining, e.g. by making it flexible, will not be sufficient to ensure the stability of the shaft reinforcement geometry. In the new shaft lining concept the excessive rock creep into the outbreak inside the shaft diameter will be removed by local and controlled leaching of the shaft cheeks by means of fresh water directed through a porous medium at the contact layer behind the watertight tubing lining. The paper presents the structure of such a lining and an outline of the construction technology. In order to implement such a lining, a typical tubing will be applied. Separate design and manufacturing will be required for the technological rings used to control the leaching process behind the lining.

Aug 1, 2013

By W. Standifird

"Cohesive fracture is a mechanical model widely used for modeling quasi-brittle fracture in rocklike materials. This work discusses use of this model to simulate quasi-brittle fractures generated by injection stimulation during the process of cuttings reinjection in West Africa. Cuttings reinjection is an engineering practice used for disposal of drilling waste. During this process, hydraulic fractures are created at the target formation and milled cuttings are injected with fluid. In practice, this process must remain in compliance with environmental regulations and zero-discharge policies. The purpose of this study is to determine the following factors of injection design for a field in West Africa: (1) pumping pressure capacity required to successfully perform the injection and (2) the injection rate for injection performance and the value of fracture width under injection.A simplified three-dimensional (3D) finite element model (FEM) was built. A poroelastic plastic damage model was used for simulation of the cohesive crack prorogation within the target formation. For simplicity, fracture development in both horizontal and vertical directions was simulated separately. In this way, the computational burden for one calculation was reduced to a reasonably low level, without losing accuracy of the model. Loads of the model include fluid injection and gravity, which balances the initial geostress field. Various values of injection rate were used in these calculations to determine the most reasonable value of injection pressure. The capacity of pressure of a pumping device was determined using this optimized value of injection pressure.Results in values of width and length of fractures created by the injection are presented. Injection pressures at bottom-hole (BHP) corresponding to each value of injection rate are also given. Numerical results for fracture generation and propagation in a horizontal direction were visualized. The pumping pressure capacity required to fulfill the cuttings reinjection work was determined based on the numerical results of optimized injection rates and pressure. The fracture width was determined using the given pumping pressure. The length and height of the fractures was determined using pumping pressure along with the required volume of cuttings waste to be disposed of into the formation.This work presents a case study of 3D finite element modeling of hydraulic fracturing generated by cuttings reinjection. The results of the optimized injection rate and pressure provide a best practice and a useful reference for cuttings reinjection analyses in this region."

Jan 1, 2015

By Jerry Gagnon, Matt Burr, Timothy Ellis, Abbas Mirza, Larry Webb

"The mechanical properties of RSR anode alloys (lead-calcium-tin, 009+ and lead-strontium-tin) were investigated as a function of time with an objective of developing lead anodes for use in high temperature electrolytic processes such as in copper liberator cells and in cobalt and nickel electrowinning. At a temperature of 70 oC, the mechanical properties of rolled RSR lead-calcium-tin (PbCaSn) alloy currently used in copper electrowinning decreased gradually while the mechanical properties of rolled RSR lead-strontium-tin (PbSrSn) decreased relatively quickly and stabilized at low strength levels. Cast PbSrSn started off as the weakest alloy but its properties remained stable with time. Rolled RSR 009+ anode alloy showed improvement in ageing properties over the other alloys tested. However, its mechanical properties did not stabilize in the study timeframe of 284 days. Further investigations are planned to study the effect of alloying elements on mechanical properties of RSR 009+ anode alloy over several years as a function of time at 70 oC. The mechanical properties will be evaluated to determine the time at which they stabilize. Comparative plant trials with rolled RSR PbCaSn and RSR 009+ will also be performed in copper liberator cells and in cobalt and nickel electrowinning tankhouses to determine their mechanical and electrochemical performance at temperatures of 65-75 oC.INTRODUCTIONLead-based alloys are the primary anodes used in the electrowinning of copper, zinc, nickel, cobalt and manganese from sulfate-based aqueous systems. Lead anode technology has evolved over the years migrating from pure lead and lead-antimonial alloys to the present day PbCaSn alloys for copper and PbAg and PbCaAg alloys for zinc electrowinning (Prengaman, Ellis and Mirza, 2010). It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new lead anode alloys and production processes for lead anodes to be used in copper electrowinning, the industry still has some unresolved issues. These relate to the necessity of having higher mechanical properties especially for the lead anodes in liberator cells in copper electrorefining and for cobalt and nickel electrowinning as these tankhouses operate at temperatures of 65-75 oC compared to 40-45 oC in case of copper electrowinning."

Jan 1, 2016

By PETER O. SANDVIK

The Cargill deposit, located 32 km south west of Kapuskasing, Ontario, was discovered by International Minerals and Chemical Corporation in 1975 and has been evaluated through an extensive program of drilling, chemical analyses, metallurgical tests and engineering and economic studies. The Cargill alkalic complex, comprising mainly carbonatite and pyroxenite-amphibolite rocks, was intruded into the rift system of the Kapuskasing magnetic-gravity high. Weathering and leaching under assumed temperate to cool climatic conditions plus faulting, shearing and/ or initial petrographic variations within the carbonatite developed a small, locally confined karst system. This resulted in a thick enriched leached carbonatite zone capped by troughs and sinks, and filled with a residuum of apatite, goethite, clay and other minerals. Residuum thickness ranges from nonexistent on ridges to 170 m in troughs and sinks. Apatite values are 5 to 15% in fresh carbonatite, 20 to 40% in leached carbonatite and 20 to 98% in residuum. A tentative open-pit mine designed for preliminary feasibility studies is estimated to contain 62.5 million tonnes averaging 19.6% P20 5.

Jan 1, 1984

By Nigel Saunders, Zhanli Guo

"Quench sensitivity of heat-treatable aluminium alloys is closely related to the precipitation process taking place during quenching. Faster cooling results in less precipitation of coarse phases during cooling, leaving more solutes in the solution before ageing. An alloy in such state would be of greater hardening potential as larger amounts of hardening phases may precipitate out during ageing. Hence, to understand the quench sensitivity of an alloy, it is essential to understand its precipitation process. Precipitation is a diffusion-controlled process and the diffusion is made complicated by the so-called quenched-in vacancies. These vacancies form during solution treatment, become “excess” when temperature goes down, and annihilate during the following cooling and ageing treatments, making diffusion now a function of both temperature and time. This paper first investigates the formation and annihilation of quenched-in vacancies and their effect on diffusion. The diffusion affected by quenched-in vacancies is considered in the kinetic models to realise the calculation of TTT/CCT diagrams for aluminium alloys. The calculated CCT diagrams have been used to explain the observed quench sensitivity and age hardening behaviour of various commercial alloys. The transformation from GP zones to other hardening phases during ageing is also discussed.INTRODUCTION The heat treatment of aluminium alloys mainly consists of three stages: a solution treatment at an elevated temperature, quenching from this solution treatment temperature to room temperature, followed by an ageing treatment to allow the precipitation of strengthening phases(Davis, 1993).The following statements generally describes how quench sensitivity is observed in heat-treatable Al-alloys: faster cooling results in,(i) less precipitation of coarse phases formed at high temperature during cooling, (ii) more solutes kept in solution before ageing, and (iii) larger amounts of hardening phases being formed, i.e. a greater hardening potential. Thus, the quench sensitivity of an alloy is closely related to its precipitation kinetics."

Jan 1, 2018

By M. Pötsch, W. Schubert

"The kinematic analysis of rock blocks is one part of a block stability assessment. It provides information about a block’s movability, i.e. if a block can detach from the adjacent rock mass and move towards the free space. This paper introduces an analytical method for the analysis of pure rotations of arbitrary finite polyhedral blocks. It enables the engineer to judge a block’s rotatability about a corner or an edge. The method is presented using a graphical and computational method. The application of the method is illustrated with an example. INTRODUCTIONThe kinematic analysis of rock blocks deals with the determination of the movability of blocks. Established methods typically cover: (a) translational motion (John 1968, Markland 1972, Londe et al. 1969, 1970, Goodman & Shi 1985, Warburton 1981) and (b) the specific rotational cases Toppling (Goodman & Bray 1977) and Slumping (Kieffer 1998). Mauldon & Goodman (1990, 1996) and Tonon (1998) introduced rotational kinematic analyses for three-joint pyramids and tetrahedral blocks extending Goodman & Shi’s block theory.All mentioned methods are subject to assumptions that limit the applicability to engineering problems. For example, the kinematic test of daylighting joints or intersections inherently assumes a finite block, which only can be proved by the finiteness theorem (Goodman & Shi 1985). Daylighting of an intersection or plane is not a sufficient condition for removability. Goodman & Shi’s and Warburton’s methods are limited to translational block motion. The methods for block rotations so far address tetrahedral blocks only. They also address only pure rotational modes and neglect the general motion of a rigid body. This paper introduces an analytical method for the analysis of the kinematic rotatability of finite rock blocks. It extends Mauldon's and Tonon's theory of rotatability of tetrahedra to arbitrary polyhedral blocks. A graphical method using the stereographic projection and a computational method are presented."

Jan 1, 2015

By W. G. Hubler

History The Aldermac mine is situated on the Nipissing Central railway near the ' centre of the township of Boischatel, Quebec, and is about ten miles west of Noranda. Aldermac Mines, Limited, is a subsidiary company of Towagamac Exploration Company. The property was staked by Messrs. Alderson and MacKay and McMartin, during the winter of 1922-23. During October, 1925, a copper discovery was made by K. W. Fritzsche, who was in charge of exploration work at that time, the first trench on this discovery averaging 8 per cent copper over a width of ten feet. This led to the discovery of another body 200 feet to the north, with an average of 3 per cent copper over fifteen feet in width. A magnetic survey was then carried out which led to the location of the large pyrite ore-bodies which have been developed in the past few years. Development work was carried on to a depth of 1,125 feet, and approximately three million tons of massive pyrite ore was indicated. Extensive metallurgical tests were conducted in the laboratories of the Mines Branch of the Department of Mines at Ottawa to determine the proper metallurgical treatment and the economic possibilities of the ore. Owing to the comparatively low copper content, and the uncertainty of the copper market, it was doubtful if the mine could be profitably operated for the production of copper alone. Messrs. Alderson & MacKay, however, realized the possibility of utilizing the large tonnage of pyrite as a substitute for native sulphur, 'which in past years has been imported into .Canada for the manufacture of acid and sulphate pulp in paper mills. They therefore organized the Sulphite Research Corporation with the object of developing an economical process of utilizing the pyrite.

Jan 1, 1932

By F. W. Tregarthen

"This paper gives a brief description of the methods used to form and implement the present planned maintenance program. The system is designed to assist plant personnel in their task of controlling a large work-force and maintaining the many and varied types of equipment used in a mining and concentrator operation. The types of reports and methods used in scheduling and work-loading are described. General built-in flexibility is derived from computer assistance to the Central Planning Group."

Jan 1, 1971

By J. -C. Sztuke, M. Cao

ABSTRACT The correlations between froth recovery of coal and air recovery were investigated using a hybrid mechanical flotation column. The particle slurry was fed onto the surface of air-water two phase froths to carry out the tests. Froth recovery was taken as the recovery of particles into the froth product, whereas air recovery was determined by the froth height method. The relationships between froth recovery and air recovery were nearly linear, with greater slopes for more hydrophobic particles. Inside the froth phase, the particles were stratified, with hydrophobic particles concentrated in the upper region and hydrophilic particles in the lower region.

Jan 1, 2013

By B. Haneman, J. A. Gorst, W. Slabbert

"The Bayer process involves the digestion of bauxite in caustic liquors at high temperature and pressure. Typically the digestion section of the plant involves the heating of liquors up to the digestion temperature followed by flashing of the digestion product to atmospheric pressure with the flashed steam used to pre-heat the incoming cold slurry. Despite the heat recovery, the digestion process is a high consumer of energy. The application of tube digestion technology in such plants has resulted in significant improvements in refinery energy efficiency with associated benefits of process simplification and refinery flow sheet capital cost reduction. This paper reviews the potential application of this technology to other metals within the non-ferrous industry.THE BAYER PROCESSA typical Bayer flow sheet is shown in Figure 1. The raw feed material bauxite (containing aluminium hydroxide as gibbsite Al(OH)3 and boehmite AlO(OH)) is digested in caustic liquors (caustic soda is the solvent) at high temperature and pressure. This process extracts the alumina and silica and any carbon present on the ore. The slurry is then flashed down to atmospheric condition allowing for heat recovery from the flashed vapour and producing slurry supersaturated in alumina.Following the digestion process the mud is removed via thickening and then pressure filtration to remove fine particulate and produce a clarified liquor with dissolved alumina in solution. The resulting pregnant liquor is then cooled allowing the alumina in solution to precipitate as aluminium trihydrate Al(OH)3. The precipitated hydrate is then filtered and washed and classified into fine and coarse fractions. The fine material is returned to the precipitation process as seed while the coarse fraction is calcined at high temperature to produce alumina. The filtrate from the filtration process (spent liquor) is then heated by the incoming pregnant liquor before being fed to an evaporation process which produced the strong caustic liquor required in the digestion process. Finally, the mud from the thickening process is washed to recover caustic and then fed to tailings ponds. The washer overflow is then mixed with the digester product to increase super-saturation."

Jan 1, 2012