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By Rolf Andreas Lauten, Guy Kluck

"Formation of scales may have important detrimental effects in many mineral processing applications. A well-known problem is the need for frequent maintenance to remove scale from processing equipment. Another challenge may relate to encapsulation of valuable minerals in precipitating scale. In this work, we explore the ability of some crystal growth inhibitors to prevent or lower the degree of scale precipitation. In many situations pregnant leach solutions contains substantial concentrations of calcium, magnesium, sulfate and carbonate in addition to dissolved valuable elements, e.g. gold, copper, zinc. Together with non-dissolved gangue minerals, some slurries may also contain particulate gold, copper etc. During normal processing of the pregnant leach solution it may be exposed to temperature gradients or similar promoting precipitation of various scales. Valuable minerals may become entrapped in precipitates and thus become inaccessible to the lixiviant. Use of a crystal growth inhibitor may lower the degree of encapsulation of valuable elements.Using a simple model system, supersaturated with respect to gypsum, the effect of some crystal growth inhibitors on the prevention of scale is evaluated in terms of amount precipitated gypsum, the particle size of the precipitated gypsum and the carbon gold loading capacity.INTRODUCTIONGold bearing sulfide ores are often roasted or pressure oxidised prior to leaching. The purpose of this unit operation is to prevent loading the leaching circuit with sulfides that consume cyanide. Pressure oxidation or roasting chemically converts the sulfides into sulfates and at the same time, the pH of the slurry ends up in the acidic range. Typically, lime addition is the preferred means to raise the pH to around 10 where gold leaching takes place. Combination of large amounts of calcium ions from the lime with sulfate ions from the ore induces precipitation of gypsum. Compounds like calcium carbonate may also precipitate if carbonate ions are present in the slurry. Depending upon the composition of the ore, compounds like calcium carbonate and other types of scale may also precipitate on gold surfaces on the slurry particles. A layer of scale on top of exposed gold surfaces will prevent dissolution in the cyanidation that takes place during leaching. Naturally, such a precipitation may lower the gold recovery."

Jan 1, 2016

By S. Masambi, S. M. Bradshaw, C. Dorfling

The presence of iron in base metal leach solutions complicates nickel and copper recovery processes. Leach solutions are commonly purified by precipitating iron as hematite, jarosite or goethite. Fast oxidation of ferrous to ferric is an important step to remove iron by precipitation at low pH values. This study reviews the ferrous oxidation mechanism and reaction rates in chloride media using molecular oxygen. This work contributes to the development of a better understanding of iron precipitation processing steps, which continues to be an important matter in hydrometallurgy. The specific objectives were to investigate (1) the effect of key process variables (acid concentration, copper concentration, and temperature) on the rate and extent of ferrous oxidation by dissolved oxygen and (2) the oxidation mechanism by varying chloride and hydrogen ion concentrations separately. Batch oxidation tests were performed using synthetic chloride solutions containing 45 g/L Fe and 3 g/L Ni at 50 and 80°C, dissolved Cu concentrations (0.3 to 3 g/L) and HCl concentrations (2 to 4.6 M). Regression analysis indicated that the significance of the effect of different variables on the extent of oxidation achieved after five hours decreased in the following order: HCl concentration > Cu concentration > temperature. Increasing the HCl concentration from 4 M to 4.6 M caused the degree of oxidation achieved after two hours to increase from 58.3% to 98.1%. The catalytic effect of dissolved copper on ferrous oxidation was more significant at low acid concentrations. Experimental data suggest that rapid oxidation of ferrous is possible at high HCl concentrations for two main reasons. First, the formation of ferrous chloride complexes allows ferrous oxidation to proceed without the formation of superoxide as an intermediate product (the rate limiting step in dilute acid solutions). Second, the formation of ferric chloride complexes stabilises the oxidation product.

Jan 1, 2016

By A. J. Rigby

The wear mechanisms of the tuyere lines of Peirce-Smith and Hoboken converters are a subject of endless debate and speculation. However, there has been an indication that one of the primary factors in the deterioration of tuyere lines is due to the batch operation of the converting process. The cooling of the brick in the tuyere line during out-of-stack times leads to shrinkage of the brick and resultant opening of the joints. Subsequently, on re-entry of the tuyere line into the bath, the joints become penetrated with matte and re- expansion of the brick is prevented. It is thought that this regular cycle of exiting the batch for slag skimming and replenishment of matte and re-entering for further blowing leads to a gradual “ratcheting” of the tuyere brick lining. If no expansion allowance is furnished between the endplate and the endwall of the lining, then the generation of damaging compressive stress is unavoidable. INTRODUCTION It is generally accepted industry-wide that the integrity of a refractory lined vessel is determined by an inextricable combination of refractory brick quality, the caliber of the lining design and installation, and the severity of the process inflicted upon the high wear areas of the vessel lining. Rigby has summarized the concentrated attempt, over the past several years, to optimize the microstructural, chemical, and fracture properties of the refractories used in non-ferrous pyrometallurgical vessels. Furthermore, lining design concepts involving larger and longer brick and the extent and positioning of expansion allowance in the joints have been extensively trialed. All these efforts have provided some, but not startling, improvements. The simple fact is that a vessel lining composed of bricks with an optimized microstructure and chemical inertness must installed with a well-conceived design to decompress the lining stresses that are generated by the batch operation of copper converters. REFRACTORY QUALITY Converting is conducted by injecting air into the molten matte and white metal for the very purpose of generating iron and copper oxide slags. These slags must be contained by a refractory which, by its mineralogical formulation, is optimized for chemical inertness.

Jan 1, 2019

By S. Konetschnik, Lux Degel, R. Degel, T. Haslinger

UrbanGold and its partners from Mettop and SMS group have developed a novel technology for the recovery of valuables from all non-ferrous metals’ fractions of WEEE (Waste Electrical and Electronic Equipment), with a special focus on low qualities which are commonly landfilled or incinerated. The technology is marketed under the brand name “UrbanGold Flex” to illustrate the high flexibility in respect of plant design and raw material portfolio, allowing also the processing of low grade material and materials with high caloric values. The process of the technology’s centrepiece, a modified and enhanced bath smelting furnace called “HENRI”, was investigated in numerous pyrometallurgical trials as basis for a scale-up towards a capacity of up to 100,000 tons of WEEE-concentrates per year. All relevant facility components have been evaluated in respect of references, fall-back options, as well as exit strategies (alternatives) to minimize risks when establishing a novel technology. A spin-off within the development is the “UrbanGold Compact” technology which can be seen as optimization of state-of-the-art smelters by using an optimized TBRC as primary processing unit. As an UrbanGold Compact plant will be the first industrial scale reference of UrbanGold’s technologies, it is also explained in the publication. As precious metals recovery is of major (economical) importance when recycling WEEE, major attention has been given to minimize the losses of these valuables. These measures, as well as a sophisticated way of utilizing waste heat as far as possible, result in interesting business cases with gross profits of up to 20% or even more. INTRODUCTION Over the past years, the demand of electrical and electronic equipment has increased dramatically with technological progress. Innovations on the technology of electronic devices led to a shorter usage and lifespan and thus boosted the generation of Waste Electrical and Electronic Equipment (WEEE). WEEE is one of the fastest growing waste streams, growing at 3 to 4% per year worldwide and is expected to reach more than 52 million tons per year by 2021. Currently, about 45 Mt of these wastes are estimated to arise worldwide, and the trend is rising (Baldé et al., 2017).

Jan 1, 2019

By Steven Doyle

Presentation Outline ?Introduction to Brunswick Mine ?Mining Needs and Drilling Trends ?Maintenance Program ?Back to Basics ?Results ?Additional benefits Introduction Xstrata Zinc Brunswick Mine ?No. 12 deposit discovered in 1953, pilot mining 1957, u/g mining began in 1964 ?Zinc, copper, lead and bulk lead/zinc concentrates ?Since 2007, a fully owned division of Xstrata Zinc Canada ?Over 132Mt milled 3.4 % Pb, 8.8 % Zn and 102 g/t Ag ?Deposit dips approximately 70 degrees; strike length of 1200 m; currently mining from 250 m to 1125 m depth

Nov 1, 2011

By Sarah Belair, Gauthier Deblonde, Valerie Weigel, Alexandre Chagnes, Gerard Cote

"Niobium and tantalum are strategic metals for electronic and alloys industries. They are produced by pyrometallurgy and hydrometallurgy but most of the niobium and tantalum production processes are not environmentally friendly. For instance, in the hydrometallurgical route, niobium and tantalum separation can only be achieved by liquid-liquid extraction in the presence of hydrofluoric acid by taking advantage of the difference in niobium(V) and tantalum(V) speciation in fluoride-based media. Therefore, the environmental footprint of hydrometallurgical processes for the production of niobium and tantalum could be clearly lowered by replacing HF or NH4F by greener media such as alkaline solutions in which high solubility of niobium(V) and tantalum(V) can be achieved.The development of such new efficient and environmentally friendly hydrometallurgical processes requires a fine description of the physicochemistry of niobium(V) and tantalum(V) in alkaline solutions. Unfortunately, literature data show a huge discrepancy on niobium(V) and tantalum(V) speciation in such media. This paper gives a brief overview of the niobium(V)-tantalum(V) production processes and paves the way to the development of alternative processes in alkaline media by presenting and discussing recent advances in the physicochemistry of niobium(V) and tantalum(V) in these media.INTRODUCTIONNiobium and tantalum are strategic metals since they are used for the production of alloys and super alloys, capacitors and magnets in strategic industries such as electronic, aeronautics and automobile. The main sources of niobium and tantalum are given in Table 1."

Jan 1, 2016

By Q. Ricoux, F. Goettmann, A. Maihatchi

"Electrodeposition processes are widely used in the metallurgical industry to produce, extract and refine metals from various feed materials. However, raw materials used to provide non-ferrous metals often contain high amounts of iron. In the presence of iron, while metals are plated at the cathode, electrowinning processes produce corrosive and highly oxidative ferric ions at the anode that are harmful for the process sustainability. In fact, these ferric ions cause dramatic current efficiency loss, induce high maintenance expenditures to limit the corrosion of devices and it results in the formation of impure and dendritic deposits on the cathode. Consequently, the management of iron in electrodeposition process became a major issue in non-ferrous metals production. Actually, numerous methods have been developed to limit the ferric ion concentration in the electrolyte or, at least, to limit its harmful effect. Many methods aim to limit the iron(III) concentration in the electrolyte, generally by coupling electrowinning to extraction process such as solvent extraction (SX) (Bender & Emmerich, 2015), ion exchange (IX) (Gula, Dreisinger, & Horwitz, 1996) or cementation (Kust, 1979) processes to remove ferric ions. Other routes consist of (i) using the ferric ions oxidant properties to leach raw materials, either directly in the electrolytic cell (Fanta & Tributsch, 1975) or through a secondary circuit (Cain, 1950), or (ii) reducing ferric ions through periodic reversal of direct current to enhance the formation of Fe2+ (Loutfy & Bharucha, 1980). On the other side of the spectrum, papers discuss methods to valorize the iron from by-products of the non-ferrous metal industry, that generates vast quantities of iron containing wastes (A. Agrawal, Sahu, & Pandey, 2004). Many studies on iron electroplating and electrolytic iron production from ores have been carried out (Cain, 1950; Mostad, Rolseth, & Thonstad, 2008), but very few have been conducted on waste or by-products. Therefore, we propose to build on the previous literature review to develop a process for the production of electrolytic iron from by-products.INTRODUCTIONNon-ferrous metals and their alloys are used in a large variety of applications. Aluminum and titanium are used for their strength, light weight and corrosion resistant properties in structural applications. Copper has been used in various applications requiring high thermal and electrical conductivity, as kitchen products and electrical wires. Nickel and zinc are commonly used as plating materials; nickel offers a wide range of working temperature and zinc is used for steel plating. Gold, silver, and platinum group metals are used in electrical/electronic applications, jewelry and chemistry as catalysts."

Jan 1, 2016

By J. P. Harrison, G. F. Gambino

"This paper examines unpredictability in the parameters governing hydraulic fracturing (HF) as used in stress amelioration for underground excavations, with the aim of showing how this unpredictability may affect design decisions. Using uncertainty models that are appropriate to particular levels of information and degrees of uncertainty, this paper demonstrates how these can aid in decision-making related to feasibility assessments of HF arrays for stress amelioration.Cave mining operations produce large underground voids and high stress concentrations around critical mine locations. These stress concentrations increase the potential for rock burst events. Although de-stress blasting has a long history for redistributing high stress concentrations, to improve safety and reliability HF is now being trialled as an alternative.Unfortunately the HF process is extremely uncertain, and so predicting fracture propagation geometry is difficult. Although the major parameters governing HF propagation have been previously identified, no indication has been given regarding the contribution that uncertainty in these makes to unpredictability in the overall HF system. Using simplified models of HF and referencing a recently proposed characterization of unpredictability, we relate unpredictability in the various governing parameters to the effect it has on strain energy density (SED) in the surrounding rock. Within these models we analyse SED as well as the stress intensity factor (KIc) when investigating the effect of parameter uncertainty and its influence on various crack propagation criteria (Sih & Macdonald, 1974). These models are applicable to unpredictability associated with the development of new fractures; the case of pre-existing fractures is the subject of on-going work.The paper will assess in greater detail the various governing parameters, and investigate the appropriate use of other uncertainty models. As a result, we will show how assessment of uncertainty in HF parameters can be used to both guide feasibility studies and determine the optimal allocation of resources to improve the final design."

Jan 1, 2015

By R. Spring

"Soft-sensors are a computer software alternative to inadequate hardware instrumentation. Filters are averaging methods that reduce the noise in any sensor's signal. This paper introduces these topics and places them in a mineral processing context using then-product formula.Soft SensorsAs their name implies, ""soft-sensors"" are computer programs that estimate values for process variables (Tham, 1991). This approach is useful when the appropriate hardware sensor does not exist, is deficient, supplies only infrequent values, etc. For example, in mineral concentrators the traditional magnetic flowmeter/ nuclear density gauge instrumentation for measuring slurry flows costs $5,000 or more per flow and requires frequent maintenance. However, metal assays are commonly available from online X-ray fluorescence analyzers and application of the n-product formula (Taggart, 1945) to these assays conveniently provides software estimates of the flowrates (albeit only when the circuit is in steady-state).Soft-sensors are used by inferential controllers that base their control actions on the process values ""inferred"" by the soft-sensor. Such was the case at Brenda Mines where the rod mill feed tonnage controller used an inferred value of the cyclone overflow particle size (Bradburn, 1976). It was also the case at Brunswick Mining where reagent controllers adjusted reagent addition rates throughout the plant according to the various ore flowrates inferred by an expert system (Spring, 1991). A unique feature of the expert system soft-sensor was its dynamic flow models which compensated for residence times, material transport lags, etc. Thus the soft-sensor values were valid under both steady-state and nonsteady- state conditions."

Jan 1, 1992

By Ngonidzashe Chimwani, David Glasser, Diane Hildebrandt

"Milling circuits play an important role in achieving the desired product; tonnage, size distribution and properties, since they are directly linked to the comminution energy consumption for the whole process. A grinding model with a mathematical simulation was developed for an open milling circuit with a scalped feed from a hydro-cyclone. The circuit was optimized by determining the optimal conditions in terms of energy consumption which would produce a floatable product having a desired size range (i.e. -75 +9 µm) for a platinum-bearing ore. The simulation results showed an operating region comprising the best combination of the ball filling and mill speed to achieve the highest production of a floatable size class, with the minimum energy consumption.INTRODUCTIONBall milling is usually conducted in closed circuits in order to achieve a desired product size without material overgrinding. The technological importance of optimising milling circuits cannot be overemphasised (Toneva and Peukert, 2007). Previous work has brought significant insights into the benefits of modelling milling circuits (Austin et al., 1984; King, 2012; Toneva and Peukert, 2007). However, the ability to model these circuits is dependent on the performance of the classifiers and the fidelity of the grinding mill model used compared to the actual circuit (Toneva and Peukert, 2007). Austin et al. (1984) identified five types of milling circuits as shown in Figure 1 namely; the grinding circuits employing mill in an open circuit, normal closed circuit, reverse closed circuit, open circuit with scalped feed, and, the combined closed circuit. Depending on the presence of the first classifier, the second, or both as well as their corresponding loops (streams), the combined circuit (e) can reduce to; an open (d), a normal closed (b), an open circuit with scalped feed (c) or a reverse closed circuit (a). In the case of an open circuit, the mill is operated without being directly influenced by a classifier. The normal closed circuit does not have the first classifier and therefore the make-up feed is the actual feed stream. Conversely, the reverse closed circuit keeps only the first classifier. The open circuited with scalped feed has only the first classifier but does not have the second one. The overflow stream from the classifier is mixed with the mill product to form the final product for the downstream process."

Jan 1, 2016

By N. P. Hristov, L. V. Kuzev

"A simulation study of the fill factor of a drum mill was conducted using two types of grinding media: balls and tetraballpebs. Each medium was composed of equal number of grinding bodies having equal weight but different shape. The difference was in the density of the two grinding media.Standard spherical grinding bodies (balls), which were used in practice, and equivalent (by weight) grinding bodies in the shape of spheroidal tetrahedrons (tetraballpebs) were studied. The simulation was conducted in a module of a 1.2 m diameter drum mill, whose length exceeded twice the diameter of the corresponding grinding body. The grinding balls had a few percent (3 to 6) higher fill factor than the grinding tetraballpebs in the same shell.Vertical sections of the grinding medium were taken across the studied shell module along its axis. They showed the location of each grinding body in the fill volume. Defects in the packing of the grinding bodies and the contacts between them and with the inner surface of the shell were also show. Differences in the contact points of the balls and the tetraballpebs were noted. For the tetraballpebs, we observed contacts both between the spherical surfaces and with the edges and vertices of the grinding bodies.The topography of the grinding media is shown visually.INTRODUCTIONThe grinding balls have been studied extensively. It is the traditional grinding medium in ore processing industry. The parameter characterising the grinding medium is its density. It is the mass of the grinding medium per unit of volume. The parameter may have a range of values. It depends on:• The physical properties of the material they are made of;• The shape of the grinding body;• The dimensions of the body;• Size distribution of the grinding bodies in the grinding media.In comminution, the fill factor of the mill shell is the process parameter that is representative of the grinding medium. Some publications have indicated the disadvantages of ball grinding. For example, Wu, Xiang, Glen, and Duan (2008) note in the analysis of the mechanism of grinding that the balls are not the best grinding media and disadvantages include among others:• Easy over-grinding resulting from the point contact between the balls;• Attrition surface is the smallest in the grinding media;• Poor selective exposure of minerals resulting from the accidental and often significantly more powerful impact on the feed;• The grinding efficiency drops as the fineness of grind is increased;In the Handbook of mineral processing, Polkin (1950) noted that the shape of the grinding bodies determines the volume of the void spaces therein and therefore the shape affects the grinding efficiency per unit of volume of the grinding medium."

Jan 1, 2016

By K. Hashiba, Y. Z. Liang, K. Fukui, M. Koizumi

"Efficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Development and modification of the rock drills based on test data are timeconsuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved. The objective of our research project is to construct a new realistic numerical model of continuous percussive drilling, which is based on the previous Okubo-Nishimatsu’s model. In this study, the parts of the previous model involved in stress wave propagation and attenuation were modified. The two models were prepared for HD712 hydraulic rock drill mounted on crawler drills and HD210 hydraulic rock drill mounted on drilling jumbos. Stress wave propagation was computed with the discretized one-dimensional wave equation. The calculated results were compared to the stress waves measured on a rod during percussive drilling. In both models for HD712 and HD210, the measured stress waves can be reproduced with the one-dimensional model of the same acoustic impedance as the actual piston, shank rod and rod combined with the CI+spring model as a rod joint. The calculated results indicate that the spring constant in the model of a rod joint needs to be set appropriately depending on drilling conditions. INTRODUCTIONEfficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Components related to the percussive drilling are a drill body, a piston, a shank rod, rods, rod joints, a bit and rock. The piston in the drill body is reciprocated by hydraulic pressure and collides with the shank rod a few thousand times per minute. Stress waves generated by the collision propagate and attenuate in the rods and rod joints, and then reach the bit. The bit penetrates and crushes rock. During percussive drilling, the components mutually affect each other and self-induced oscillation occurs. The number of blows and the rate of penetration are determined by the practical drilling conditions such as hydraulic pressure, thrust force, number of rods and mechanical properties of rock. Development and modification of the rock drills based on test data are time-consuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved."

Jan 1, 2015

By Feng Tianran, Lu Shijie, Shen Zhengchang, Han Zhibin, Tan Ming

"As a kind of non-metallic material, high-purify quartz sand has been widely used in many fields. Flotation is a popular way to process quartz sand. But it is in difficult position for flotation to get high-purify quartz product due to large amount of coarse particles contained in the feed. In this paper, a design principle of special flotation cell for high-purify quartz sand has been put forward base on ore property analysis and laboratory test, and the pilot scale special flotation cell has been developed to meet the requirement of the quartz sand flotation process. The special flotation cell for high-purify quartz sand is featured by middle positioned impeller, false bottom and draft tube, which could decrease the rising distance of mineralized bubble and strengthen the circulation capacity of the lower part of the flotation cell. Hydrodynamic study indicates that high air dispersion degree and strong lower slurry circulation could be produced by pilot scale special flotation cell, which is helpful to create a suitable hydrodynamic environment for quartz sand processing.INTRODUCTIONNatural quartz is a non-metallic mineral, which is widely used as raw material in multiple industry process (Shifu, 2006). High purity quartz, especially containing more than 99.9% silicon dioxide, is characterized by high temperature resistance, small thermal expansion coefficient, highly insulating and so on. The demand of high purity quartz has been rising along with social and economic development, now high purity quartz is widely used in the field of photovoltaic industry, electronic information, communications and aerospace industry.Quartz is a kind of main rocking-forming minerals in the nature. There are seven genetic types, such as natural crystal, quartz sandstone, quartzite, vein quartz, konilite, natural siliceous sand, granite quartz (Baolei, Shuilin, & Dianchao, 2012). The natural crystal is primarily used as raw material to refine high purity quartz, but it is not available for two reasons. On the one hand, the natural crystal is extremely expensive and poor in resources reserves, which can not satisfy the need of large-scale industrial production. On the other hand, the chemical component of natural crystal is instability, it may lead to low stable product performance in large industrial applications, and it is also difficult to achieve raw materials standardization. Therefore, there are a lot of studies to search for other technological methods to obtain high purity quartz from other genetic quartz types."

Jan 1, 2016

By Ramesh Subramanian

Overview Background / History Undergraduate Programs Mining Engineering Chemical Engineering Mechanical Engineering Graduate Programs and Research Student Enrolment (2002 -) Future Plans

Oct 1, 2010

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By A. I. A. Salama, M. W. Mikhail

"The existing methods of block diagram manipulation and vanishing variable for flowsheet simplification used in coal and mineral processing circuit evaluation and optimization cannot be easily implemented on digital computer.The signal flowgraph technique is proposed to represent and simplify determination of the relationship between intermediate or end variable and the feed in the flowsheet. Typical and existing circuits are used to demonstrate the application of the proposed technique which can easily be implemented on digital computers.IntroductionRecently there has been much interest in the analysis and optimization of coal and mineral processing circuits to assist in the pre diction of coal and mineral processing plant performance. The block diagram and the vanishing variable were introduced and utilized in the analysis of plant flowsheet. Although the block diagram approach is useful, it requires manual manipulation of the circuit block diagram which may present difficulties in the situation of complex circuits. Moreover, it may not be easy to implement on a digital computer.In this paper, the signal flowgraph technique is proposed to represent the circuit flowsheet and to simplify the determination of relationships between intermediate or end variables (fractional mass) and the feed for any coal and for any mineral processing circuit comprising size and density separators. These relationships are utilized in the analysis and/or optimization of the circuit. The proposed technique is illustrated by considering typical and existing circuits."

Jan 1, 1987

By H. Deveci, E. Y. Yazici, A. D. Bas

The leach solutions of waste of printed circuit boards (WPCB) may contain a wide range of base and precious metals with different concentrations due to heterogeneity of these wastes in composition. Therefore, selection of a suitable metal recovery method is of practical importance for downstream processing of pregnant leach solutions of WPCB. Sulphuric acid leaching of WPCB in the presence of a suitable oxidant is capable of dissolving base metals as well as precious metals such as silver. In this study, cementation of silver from sulphuric acid leach solutions of WPCB using metallic copper, aluminum and zinc was studied. The WPCB sample was assayed to have a silver content of 694 g/t. A synthetic leach solution containing 20 mg/L Ag in sulphuric acid solution (0.51 M H2SO4) was prepared based on the silver concentration in pregnant leach solutions of oxidative sulphuric acid leaching tests. Total sulphate concentration ([SO4 2-]T) was kept constant using sodium sulphate at 1 M. Metallic powders of copper (-850 +600 µm), aluminum (-425 +45 µm) and zinc (-45 µm) were used in the cementation tests. The effects of metal type (Cu, Al or Zn), dosage of metal powders (above the stoichiometric ratio by up to 2000-fold) and temperature (20-80°C) on the rate and extent of silver extraction from the solution was investigated. The effect of presence of copper on the cementation performance was also tested. Under suitable conditions high silver recoveries (>90%) was achieved using metallic copper and zinc while aluminum yielded the lowest silver recovery (i.e. 40% Ag). The kinetics of cementation by zinc was comparatively higher than that of other metals. Increasing the temperature was observed to significantly enhance both the rate and extent of silver cementation. SEM-EDS studies were performed to characterise the metallic powders after cementation.

Jan 1, 2016

By R. Esteban, D. Runnels, S. Girgin, J. Torrealba-Vargas

"Each mineral processing project requires early testwork to evaluate the economic potential of a deposit. The testwork needs to be efficient and it should provide enough information to obtain key parameters, first for a high level flowsheet selection at the conceptual and PEA stages and then, for later stages, to confirm the flowsheet selection and optimize the metallurgical efficiency of the plant. The testwork should consider all rock types or lithologies present, and carry out testwork for the purpose of sizing the major processing equipment.A successful project requires that the project stakeholders develop an efficient sample collection program to produce enough material for a scoping and pre-feasibility level program. This involves the participation of a team of geologists, mining and metallurgical engineers in the project, as early as possible, to define the deposit characteristics that need to be validated.The project schedule requires a close control of the testwork scope, procedures, and timing, but also the efficient analysis of results to provide indications of red flags that could impact circuit design as early as possible.In some cases, projects are put on hold due to fluctuations of the world economy until the return of more favorable conditions. In that scenario, prior data analysis of former testwork results could reduce significantly the amount of testwork required to restart a project. The paper will also present examples where the analysis of former testwork data was used to reduce the amount of new testwork in addition to presenting examples of latest projects where the above-mentioned test program approach was followed."

Jan 1, 2016

By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985

By B. Hoare, H. M. Hill

"SYNOPSISTailings volumes, disposal systems, effects of dam failures, construction materials, and concentrator process water volumes are discussed. Earth dams and tailings dams are discussed in detail. Some of the fundamentals of soil mechanics relating to earth dams are presented. Brief notes on optimization are presented. The development of a triplex meter for earth dam instrumentation is described. The advantages of the hydro-cycloned dam over the spigotted dam are outlined. INTRODUCTIONThe realistic and responsible recognition of the pollution problem, combined with the grossly increased volumes of waste material from large modern mining operations, has emphasized the demand for safe tailings dams at minimum cost.Tailings may be defined as the waste material from a mining operation after the process of concentration in which the minerals have been extracted for commercial use. The present revenue from the Canadian Mining Industry is slightly over $4,000,000,000 per year and it is estimated that the quantity of tailings produced exceeds 300,000,000 tons annually. In many instances, the volume of tailings from a mining operation is greater than the volume of crude ore mined on account of the small quantity of valuable mineral recovered during concentration, and on account of the ""swell factor"" resulting from the processes of drilling and blasting, crushing, and grinding of the crude ore. Some of the larger mine tailings deposits contain over 200,000,000 cubic yards and the associated tailings dams are among the largest man-ma.de structures in the world."

Jan 1, 1970