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By Ö Yilmaz

In this study, the behaviour of rock mass subjected to blasting load is investigated using three dimensional finite difference numerical modelling. In the analyses, Mohr-Coulomb failure criterion has been used for the characterisation of the rock mass strength. Stresses acting on the borehole boundary have been simulated by an exponential function which reaches its maximum within a short time and then falls to zero value in a considerable time period. The strain rate effect on the mechanical properties of rock material has also been taken into account in the analyses. Four different explosive-rock mass combinations have been studied to investigate blast induced damage zone. It has been observed that proposed equation for the dynamic compressive strength of rock material fits very well to general suggestions. Results have shown that blast damage analysis model recommended with this study is successful.

Aug 1, 2013

By P. R. A. Andrews

"Talc ore from Bakertalc, High water, Quebec analyzing about 60% talc, previously dry ground to about 95% minus 53 µm was beneficiated in an 11.4 kg/ h pilot-plant flotation circuit. A concentrate of 95.9% talc (necessary for paper-grade) was obtained at a recovery at 75.3% by employing 53 g/t of Dowfroth 250 collector at pH 9.2; further cleaning increased the grade to 97.2% talc at a recovery of 57.5%.Flotation of fresh ground 60% minus 44 µm ore at a feed rate of 18.6 kg/ h produced a grade of 96.4% talc with a recovery of 78.2%, using Aerofroth 70 collector a six carbon-branch chain alcohol, at pH 9.2.The similarity in the concentrate grade and recovery between pre-ground and fresh-ground ore indicated that it was not neces¬sary to grind to 95% minus 53/2m to achieve comparable selectivity. A grind of 60% minus 44 pm corresponds to 100% minus 300 µm.Flotation retention times obtained with fresh ground ore indicate 33 min. for combined rougher/scavenger, and 15 min. each for the first and second cleaners.Talc-magnesite flotation separation is explained in terms of physico-chemical forces, with reference to surface charge and adsorption mechanisms."

Jan 1, 1989

By M. J. Merwin

Heat treated seamless tubular products are processed in a fashion that can be easily modified to produce dual phase microstructures, through the implementation of intercritical soaking prior to quenching. Dual phase steels are known to possess low yield strength compared to tensile strength. The steel line pipe market is interested in low yield-tensile ratio materials for application in reel barge pipe laying operations. In the current work compositions of commercially produced material already in use for the line pipe market were examined and dual phase microstructures were successfully developed. The microstructure and properties of the materials were found to be stable over the range of intercritical temperatures employed. Tempering temperature and, somewhat unexpectedly, small chemistry differences were found to have the largest influence on properties. Excellent toughness performance was observed in samples tempered at temperatures in excess of 550°C. Tempering in this temperature regime produced materials with strength suitable for application as API X60 line pipe. A difference in tensile strength between steels of similar chemistry was observed, and is not fully understood at this time. Welding performance was considered through simulation of three regions of the heat-affected zone. Neither intercritical temperature, nor tempering temperature, were found to have a significant influence on the heat-affected zone properties. The peak temperature achieved in the thermal cycle was the only significant factor. The hardness of the heat-affected zone was found to increase continuously with increasing peak temperature. While toughness was found to be low for both partially-transformed and coarse-grain heat-affected zones, the toughness of the fine-grained heat-affected zone was substantially better. Based on the results found in this laboratory study, a limited production trial is expected.

Jan 1, 2005

By Harold Hopkins

THE Wright-Hargreaves mine is one of a group of seven mines long active in the Kirkland Lake district, Ontario. Detailed geological reports and maps covering the area have been published by the Ontario Department of Mines (1,3)t. Though all these mines work several productive veins there is one vein which is common to all and is known as the North Vein of the camp?not that it is the most northerly vein mined, but it is the more northerly of the two major veins of the camp. At the Wright-Hargreaves mine there are in all ten important producing veins, and most of them have a N.60°-65°E. strike and in general a steep southerly dip. It is a common belief that most of these veins lie along faults but it will be shown that whilst this is true of some of them it is not true of all, and also that a vein may lie in a fault along part of its course and elsewhere fill a fracture in line with the fault, this being a consequence of rotational movements that took place during faulting. The paper describes the history of faulting at this mine in particular, makes observations on the principal pre-ore fault, and describes the method used in solving the movements on the post-ore faults. Other details of geology are not discussed except to mention here that our main veins lie almost entirely in the syenite porphyry stock except on lower levels close to the east boundary of the property, where the North vein leaves the porphyry to enter the greywacke.

Jan 1, 1940

By J. Dufour

Although the recovery of nitric and hydrofluoric acids from stainless steel pickle liquors has been solved by several methods, such as solvent extraction, acid retardation, evaporation or pyrohydrolysis, metals (mainly iron, chromium and nickel) are usually obtained as a waste or by-product that has to be disposed. Alternatively, the treatment requires a high liquor flow to be economical, as is the case for pyrohydrolysis. A new process has been developed for metals recovery, that produces metal oxides with a low fluoride content. This new technique is based on a selective precipitation mechanism, which produces nickel hydroxide with a purity of 90%, separate from a mixture of iron and chromium oxides and hydroxides suitable for recycling. The reaction mechanism is based on the precipitation of fluoride compounds of iron and chromium, K2FeF5 and CrF3. For this purpose, free fluoride must be added as potassium fluoride. Also, solid fluoride compounds are hydrolysed, releasing free fluoride. A part of the fluoride is recycled to the selective precipitation operation and the remainder is fed to the acid recovery stage. Nickel does not react in this operation; it remains in solution giving a high separation yield.

Jan 1, 2006

By C. Zangerl, T. Strauhal, S. Perzlmeier, M. Holzmann

"In high mountainous regions, deep-seated rock slides are often observed in foliated metamorphic rocks such as paragneisses, micaschists and phyllites. Given that comprehensive investigations of deepseated rock slides are extraordinary costly and therefore are rare, most studies are related to investigations in the surroundings of infrastructures and human settlements. In the framework of this study there is an excellent opportunity to gain new insights in the fundamental processes and mechanisms of slowly moving deep-seated rock slides from a case study in the surrounding of a large dam reservoir in Austria. New fundamentals for comprehensive slope stability analyses and hazard assessments and sound prognoses focussing on the long-term stability and deformation behaviour of slopes under changing boundary conditions (e.g. impounding of a reservoir) and/or concepts for mitigation measures can be obtained. Within this contribution, geological field surveys, deformation monitoring, geophysical and drilling data were analysed and presented. Based on the compiled and analysed data, some key-properties of the rock slide will be presented, whereby special attention will be given on the geometry and internal structure, the slope kinematics, as well as hydrogeological and geomechanical aspects.INTRODUCTIONIn high mountainous regions, deep-seated rock slides are often encountered in highly foliated metamorphic rocks such as paragneisses, micaschists and phyllites (Agliardi et al. 2012). Critical situations may occur when deep-seated rock slides fail in a rapid manner characterised by very high sliding velocities, and/or when they develop into long run-out rock avalanches. However, many rock slides in foliated crystalline rock masses either do not move at high velocities nor do they accelerate seriously and form extremely rapid slides. Displacement rates in the range of a few millimetres or centimetres per year are common for this type of rock slide (Bonzanigo et al. 2007, Tentschert 1998, Watson et al. 2007). Nevertheless, some case studies show an activity behaviour characterised by acceleration phases reaching velocities of even metres per day. However a slope collapse is not expected and these slopes decelerate to much lower base activities. The trigger for these phases can be manifold and include heavy rainfall and snow melt, initial reservoir impounding and water level fluctuations, changes in the slope’s equilibrium state due to antecedent slow deformation processes, ongoing erosion processes along the toe of the slope, and others (Zangerl et al. 2010)."

Jan 1, 2015

By X. M. Zhou, T. Wu, He X. N.

"In order to study the support effect of concrete in the surrounding rock of a metal mine, the concrete and surrounding rock were comparatively studied. Firstly, the general situation of the ultra-kilometer deep shaft in Xincheng, surrounding rock and geological conditions are introduced. Secondly, the experimental scheme of material mechanical properties of surrounding rock and shaft lining concrete based on same standard dimension and shape are examined, and the mechanical tests of rock and concrete based on different shapes and sizes are carried out. The study shows that the compressive strength value and elastic modulus of the rock cube are 1.28 times and 1.78 times that of the cylinder, and the Poisson's ratio is 0.77 times. The dimensional effect law of the concrete cube and cylinder test data is consistent with the rock law. However, the test results of the concrete are less discrete than the rock; the test also shows that the strength and elastic modulus of the concrete lining of the main shaft of the Xincheng are much smaller than the surrounding rock that is also used as the concrete aggregate, which indicates that the support of concrete lining in the surrounding rock shaft behaved weakly. Based on the development of the modern NATM rock support theory, it is suggested that the mechanical test standard of artificial support materials should be unified into the mechanics test standard of natural rock, which will help to improve the accuracy and practicality of scientific calculation of geotechnical engineering.INTRODUCTIONConcrete and rock mass are usually attributed to a class of materials called frictional materials or geotechnical materials, of these two kinds of materials, the first is man-maded and the second is natural. The attentive scholar can find that there are many differences in the test criteria for the mechanical properties of the two kinds of materials among different industries or departments, reflecting the differences in their sources, tradition, and the application thoery of material strength among them.There is a situation wordwide, that there are many testing standards of the same material mechanical parameters such as elastic modulus, compressive strength, etc. The cube with a side length of 150 mm is adopted as a common sample in the architecture department in China, while a cylinder with a diameter of 50 mm and a height of 100 mm is as a standard specimen in geotechnical department.Knowing that mechanical parameter values are strongly affected by the the size, shape of specimen and loading rate etc, that is to say the mechanical parameter values of the same material are completely different when obtained from different test with different standards. However, such a problem has been long neglected in geotechnical engineering."

Jan 1, 2019

By W. W. Bake

INTRODUCTION IN IN JUNE, 1943, the main pillars of the Beattie Mine glory hole failed, allowing over a million yards of wet clay and debris to flow into the mine, completely filling all workings to within seventy feet of the 3rd level. The resulting Job of clearing these workings and rehabilitating the mine represents a unique and hazardous operation, seldom, if ever, previously encountered in Canadian mining. The purpose of this paper is to describe one phase of this operation -that of cleaning and rehabilitating the mine from the 6th to the 9th level -to outline briefly the events which led up to this work and to describe the techniques and costs involved. It will be noted that such costs, methods, and performance figures as are dealt with in this paper refer only to work in the internal shaft and adjoining workings from the 6th to the 9th level, previous work having been done under other supervision and management. The Beattie mine is in Duparquet township, northwestern Quebec, twenty miles northwest of the town of Noranda and twenty-three miles southeast of the town of La Sarre. The mine and the town of Duparquet, which it?supports, are accessible by highway from Noranda throughout the year. Production at the Beattie mine began in May, 1933, and up to June, 1943, twenty-one million dollars in gold and silver had been recovered from five and a half million tons of ore.

Jan 1, 1951

By S. Jeon, T. H. Kim

"Understanding the frictional properties of discontinuities is crucial to ensure the stability of underground structures. In particular, the frictional behavior at depth depends on the complex interaction among mechanical, hydrological, thermal and chemical characteristics and their coupled effects. In this study, a series of triaxial compression tests were carried out to investigate the behavior of rough shear surface of synthetic rocks. The frictional behavior showed little variation at different confining and water pressures. The test results were analyzed using Coulomb’s failure criterion. In addition, numerical analysis was carried out using PFC2D to simulate the test.INTRODUCTIONUnderstanding coupled behavior of rock at depth is of great importance in design, construction and operation of underground structures such as a disposal facility of radioactive waste, hot dry rock geothermal system and oil reservoir. In particular, many uncertainties are involved in characterizing deep rock mass deformation in the designing process and interactions among fluid flow of groundwater, high temperature and stress disturbance should be considered. Many independent studies have been carried out to investigate the thermal, hydro, mechanical and chemical coupled effects in numerical and experimental methods. They include the researches by Lockner, Summers, Moore and Byerlee (1982), Jafari, Amini Hosseini, Pellet, Boulon and Buzzi (2003), Tembe, Lockner and Wong (2010), Lee, Lee and Jeon (2012), Indraratna, Premadasa, Brown, Gens and Heitor (2014)."

Jan 1, 2015

By Finch. J. A., C. Perez, J. M. Ortiz, G. Cortes, A. B. Yañiez, F. Coddou, P. Morales, H. Elgueta

A campaign to perform characterization tests in a TankCell®-300 flotation cell installed at Chuquicamata Codelco's concentrator was conducted. The campaign included integrated gas dispersion measurements (gas velocity radial mapping and single point gas holdup and bubble size) and determination of frother concentration. Cell streams were sampled to assess metallurgical performance at the same time. The experimental program was designed to establish the bubble surface area flux operating range and its effect on performance, and the effect of using longer residence times and of a device designed to enhance mixing in the collection zone (FlowBooster(TM)). The gas dispersion results and their relationship to metallurgical performance are discussed.

Jan 1, 2009

By Jan Butra

Longstanding mining of copper deposits in the Legnica-Glogow Mining Basin, Poland has accumulated broad experience concerning the impact of geological and mining conditions on seismic and rockburst hazard. Methods of rockburst prevention for deep copper mines have been developed based on gathered data. Methods of rockburst hazard evaluation and rockburst control constitute a set of rockburst prevention measures. Due to their nature and location within the production process, prevention methods can be passive or active. Active methods of rockburst prevention consist of the liquidation of stresses in the areas where they are concentrated through controlled generation of rock-mass tremors and rockburst by blasting works (group extraction blasting, release blasting in the rock mass and pillars able to accumulate the stress, as well as in the roof and floor). Group blasting works as a basic method are very effective in copper mine conditions. Provocation of dynamic events makes it possible to control the timing of their occurrence. In Polish copper mines, all blasting works are made during the absence of miners in the mining fields. Daily distribution of both the number of recorded strong seismic events and volume of energy released, confirm the advisability of using this kind of rockburst hazard prevention. The rockburst hazard prevention methods developed over 40 years of copper deposit extraction are economically reasonable and offer sufficient effectiveness under high rockburst hazard conditions.

Aug 1, 2013

By W. J. Dick

THE purpose of this paper is to point out, briefly, the importance of the coal mining industry of Alberta and to stress the economic factors that hinder its development; also to offer suggestions relating to the major problems of the industry. The minor problems will not be dealt with in detail, because, if the major problems are taken care of, it is felt that the industry itself can take care of ,he remainder. COAL MINING NO LESS IMPORTANT THAN GOLO MINING The large increase in metal mining development in all provinces of Canada, excepting Saskatchewan, Alberta, and the Maritimes, has had the effect of focussing public attention on this branch of the industry. The fact, also, that this development came at a time of depression has been of immense benefit to Canada as a whole. On account of the necessity and consequent demand for gold, with its attendant increase in price, through government action, from $20.67 per ounce to $35.00 per ounce, it is safe to say that the public of Canada have become, today, gold mining conscious. While everyone admits the great value. of the gold mrn111g industry, nevertheless, the equal value to Canada of certain other industries must not be lost sight of. The coal mining industry, in particular, is worthy of greater public and government support than has been accorded it in the past. It would seem unnecessary to stress this matter to a meeting of the Canadian Institute of Mining and Metallurgy, but unless certain facts are brought to your attention, there is danger that the coal mining industry will not be developed to the extent its national importance deserves. Too many public men and men in authority are unaware of the value of coal mining.

Jan 1, 1936

By Dharmendr Kumar, Pradip, Beena Rai, Venugopal Tammishetti

"Due to rapid depletion of high grade Indian iron ores, there is a need to utilize low grade fines and slimes. However, these fines and slimes, in their current form, cannot be utilized in steel making due to their high alumina (6-10%) contents. Several beneficiation strategies such as gravity separation, magnetic separation, flotation and selective flocculation are currently being explored for the upgradation of low grade fines and slimes. In our previous work density functional theory simulations were employed to come up with selective flocculants for beneficiation of iron ore slimes. Our simulation results suggested that starch and guar gum are more selective towards iron minerals than other minerals present in the sample. Grinding of iron ore fines becomes necessary in some cases to achieve adequate liberation for removing alumina impurities in Indian iron ores. We have thus investigated effect of grinding of iron ore fines on its selective flocculation-separation.In the present work, we have taken natural iron ore fines from one of the Indian iron ore mines and ground it to -400 mesh (<37 microns) in dry and wet conditions. X-ray diffraction study confirmed the presence of minerals hematite, goethite, gibbsite and kaolinite in the sample. The fine ground samples were used in selective dispersion-flocculation study with corn starch and guar gum flocculants. It is interesting to note that even though the dry and wet ground samples possess almost similar particle size distributions, significant differences were observed in yield and grades of the concentrates thus produced. These differences may be arising due to the coating of alumina containing minerals on iron minerals. We have also studied the effect of addition of dispersant while grinding. Our study suggests that grinding conditions determine the efficiency of the separation process."

Jan 1, 2016

By M. H. Moys, C. Bhondayi, Eric Tshibwabwa

"The relationship between froth bubble size as represented by intra-bubble impact distances (IID) and flotation performance is investigated. Experiments using an artificial ore comprising of limestone as the floatable component and silica as the gangue material were carried out in pseudo-steady-state circuit. A method to measure IIDs developed by Bhondayi and Moys (2014) was then used to measure froth bubble sizes as a function of froth height, superficial gas velocity and feed rate (pulp residence time). Samples for flotation performance evaluation were also taken. Results indicate that as froth height increases, the average IID values increase resulting in a decrease in limestone recovery while the grade increases. Increasing gas rate results in lower IID values that are accompanied by high recovery and low limestone grade. The effect of feed rate on both flotation performance and average IID values depended on froth depth and gas rate. Average IIDs largely remained the same at the two feed rates investigated.INTRODUCTIONIt is regarded as obvious that froth bubble size distribution (FBSD) will have an effect on plant grade and recovery. As the average FBSD decreases, the bubble surface area flux will increase making possible an increase in recovery and a decrease in grade. The opposite trend will be involved if average FBSD is increased. However: no method for measuring FBSD has been available, so these trends have not been studied in any detail. Bhondayi and Moys (2014) developed a novel technique to measure or estimate froth bubble sizes. Although they established a potential to use this method in understanding froth performance, no data have been presented to assess the correlation between the estimates of bubble sizes and actual flotation performance. In this work experiments are done to establish how the change in froth phase bubble sizes affect flotation performance. Flotation performance will be evaluated using recovery and grade. How water recovery to the concentrate changes with changes in bubble sizes will also be evaluated. It is known that water recovery is approximately inversely proportional to the square of the overflowing bubbles sizes. It will be interesting to establish how the rate of change of bubble sizes changes with water recovery."

Jan 1, 2016

By A. Mcdonald, F. W. Breaks, T. F. Morris, S. A. Averill, D. C. Crabtree

Abstract-Gahnite, a zinc-bearing spinel, is a resistate mineral that may be used as an indicator mineral of polymetallic deposits in high-grade metamorphic terrain. The Ontario Geological Survey recently completed surficial mapping and sampling programs in the Separation Lake area of northwestern Ontario and Kinniwabi Lake area of northeastern Ontario in which gahnite was recovered from samples of surficial sediments. Ternary plots of the composition (ZnO, MgO, FeO[t]) of gahnite recovered from these surficial studies reveal three distinct groups: Group 1 is characterized by low (< 1 wt%) MgO values; Group 2 by higher (>1 wt%) MgO values; and Group 3 by higher FeO(t) values than Groups 1 and 2. The composition of in situ gahnite recovered from volcanogenic massive sulfide mineralization, Zn-rich Sedex-type mineralization and peraluminous rare-element mineralized granite and pegmatite also was determined. The composition of the gahnite obtained from surficial samples was compared with that of in situ material. Gahnite from the peraluminous rareelement granite and pegmatite overlapped very well with surficial gahnite of Group 1. Gahnite from volcanogenic massive sulfide mineralization and Sedex-type mineralization overlapped well with surficial gahnite of Group 2. These results suggest that determination of gahnite composition in indicator mineral surveys may be useful in exploration programs when assessing the mineral potential of a region.

Jan 1, 1997

By H. J. McQueen

Aluminum was hot worked at 400 - 500°C and strain rates (e ) of 0.004 -0.1s-1, under reversing strains (c) of 0.5 to 0.2 or 0.5 to 0 and also advancing from 0.5 to 1 or 0.5 to 5. Under similar test conditions for different parts of the strain paths, the average measured flow stresses are found to agree with each other. In the forward and backward strain path tests, the almost identical steady state plateaus affirm the occurrence of dynamic recovery (DRV). On reversal of strain direction at constant e , there was generally negligible Bauschinger effect. In specimens annealed at 400°C, static recrystallisation (SRX) was followed microstructurally. mainly by disappearance of elongated grains with serrated boundaries because the new grains were only little a finer than the old due to low strain energy. The only influence of reversing strain path observed was the effect of change of grain boundary area as grains elongated or returned towards equiaxed. In optical microscopy, elongated grains with serrations and deformation bands confirmed DRV in forward path specimens. In reverse path specimens, equiaxed grains were gradually restored with retention of serrations and bands. In low magnification polarized optical microscopy, grain alignment increased with strain for forward path specimens; whereas it decreased in reverse path ones, supporting DRV. Orientation imaging microscopy (OIM/SEM) revealed that elongated grains are broken up as deformation bands rotate during the forward path and that grains return to equiaxed appearance on backward straining. Comparative studies using optical microscopy in polarized light (POM), OIM/SEM and transmission electron microscopy (TEM) revealed that while subgrains remain equiaxed and constant in size and character during the forward and backward paths, the fraction of low angle facets decreased while that of high angle grain facets increased with increasing strain; these are coupled with a fairly low fraction of medium angle boundaries. The results contribute to the understanding that dynamic recovery in aluminum maintains sub-boundaries with low misorientation but as grains elongate and more subgrain become adjacent to grain boundaries the fraction of high angle boundaries rises (with backward straining it was vice versa).

Jan 1, 2007

By A. Mcdonald, F. W. Breaks, T. F. Morris, S. A. Averill, D. C. Crabtree

Gahnite, a zinc-bearing spinel, is a resistate mineral that may be used as an indicator mineral of polymetallic deposits in high-grade metamorphic terrain. The Ontario Geological Survey recently completed sur?cial mapping and sampling programs in the Separation Lake area of north-western Ontario and Kinniwabi Lake area of northeastern Ontario in which gahnite was recovered from samples of sur?cial sediments. Ternary plots of the composition (ZnO, MgO, FeO[t]) of gahnite recovered from these sur?cial studies reveal three distinct groups: Group 1 is characterized by low (< 1 wt%) MgO values; Group 2 by higher (>1 wt%) MgO values; and Group 3 by higher FeO(t)values than Groups 1 and 2. The composition of in situ gahnite recovered from volcanogenic massive sul?de mineralization, Zn-rich Sedex-type mineralization and peraluminous rare-element mineralized granite and pegmatite also was determined. The composition of the gahnite obtained from sur?cial samples was compared with that of in situ material. Gahnite from the peraluminous rare-element granite and pegmatite overlapped very well with sur?cial gahnite of Group 1. Gahnite from volcanogenic massive sul?de mineralization and Sedex-type mineralization overlapped well with sur?cial gahnite of Group 2. These results suggest that determination of gahnite composition in indi-cator mineral surveys may be useful in exploration programs when assessing the mineral potential of a region.

Jan 1, 1997

By H. Watari

In 1998, a voluntary agreement was reached between the European Commission and the European Car Manufacturers Association (ACEA) to reduce average carbon dioxide emissions of new cars to 25% below 1995 levels by 2008, Agreements have also been reached between the European Commission and the Japanese Automobile Manufacturers Association (JAMA) and the Korean Automobile Manufacturers Association (KAMA), However, the target average of carbon dioxide emissions of less than 140g/km in 2008 is a very challenging goal, Therefore, total product weight reduction is an objective for many manufacturers, This can be achieved utilizing materials possessing high strength and low weight, One material that has recently attracted interest is magnesium alloys, The magnesium alloys are expected to play an important role as next-generation materials, which have possibilities of contributing to lighten the total product weight when magnesium products can be used to replace aluminum and mild steel products.

Jan 1, 2005

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By Y. Huang

Corrosion of GaAs in aqueous electrolytes is a major limitation in implementing GaAs-based photoelectrochemical solar energy conversion systems, In this work, the corrosion behavior was investigated by electrochemical methods and surface analysis approaches, in both H2SO4 and NH3?H2O solutions, Open-circuit measurements showed that the cleaned GaAs surface was very sensitive to water/air, Impedance measurements for n-GaAs showed that an inductive loop only appeared at a high corrosion rate because a reaction intermediate is the oxidant for a further decomposition step in combination with chemical reaction with water, The results suggest that the same corrosion/decomposition mechanism occurred on n-GaAs in the two solutions, When the surface-hole concentration was low, the hole injection or generation process was the rate-determining step, At large reverse bias on n-GaAs, with high-hole concentration, the corrosion rate was limited by a Faradaic adsorption process, involving an adsorbed intermediate, The different surface compositions after corrosion in the two solutions can be explained by the dissolution of As(0), Further oxidation of As(0) to As(III) in NH3?H2O solution is still slow, as suggested from X-ray photoelectron spectroscopy (XPS) analysis,

Jan 1, 2005