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By Doug Russell

Natsource: At a Glance l 160 employees l Global reach ? New York, Washington, Calgary, Ottawa, Toronto, London, Tokyo l Major Environmental Commodity Broker ? Rated as Top GHG Broker (Environmental Finance Magazine Survey, Dec. 2000 & 2001) ? Leading RECs Broker ? Large Broker of SO2, NOx l Large Energy Broker ? One of Highest Volume Gas Brokers ? Major Electricity Broker Overview l International Market l Implementing the Rate-Based Proposal l Assessment and Management of Risk from GHG Emissions Limitations

Nov 1, 2002

By T. K. Akopyan, E. A. Naumova, V. V. Doroshenko, N. A. Belov

"A qualitative and quantitative analysis of the new Al-Ca-Mn-Fe phase diagram in the region of the aluminium corner is carried out using both thermodynamic calculations and experimental methods. Using the obtained data, the principal possibility of creating both cast and wrought sparingly alloyed aluminium alloys with calcium, manganese, scandium and zirconium at allowable iron contents of up to 0.4% that do not require solution treatment and quenching is justified. At the selected concentrations, the entire amount of manganese (1%) is practically included in the aluminium matrix, while calcium (~2%) and iron are in the multiphase eutectic, which has a fine structure. The joint introduction of 0.25% Zr and 0.1% Sc into the alloy leads to precipitation hardening due to the formation of the L12-Al3(Zr,Sc) phase during annealing. Based on the experimental data for the model multicomponent Al2CaMnFeZrSc alloy, it is shown that such alloys can combine high mechanical properties and good manufacturability during both casting and metal forming. This is due to the combination of a narrow temperature range of solidification with a fine eutectic structure.INTRODUCTION Hardening in branded aluminium alloys (both cast and wrought) is generally achieved by heat treatment of the T6 type, including quenching and artificial aging (Zolotorevskiy, 2007; Kaufman, 2004; Mondolfo, 1976). Heat treatment significantly increases the cost of the final products. Therefore, industrial companies are interested in developing alloys that can be hardened to the desired level without quenching. To solve this problem, alloys with scandium are the most suitable (Toropova, 1998; RØyset, 2005). This element (usually in an amount of ~0.3%) is one of the most effective hardeners in aluminium alloys, due to the formation of Al3Sc (L12) phase secondary precipitates, the size of which is less than 10 nm (Knipling, 2010; Fuller, 2005). These nanoparticles are formed during the annealing via decomposition of the supersaturated aluminium solid solution (hereinafter referred to as (Al)). This feature allows us to significantly increase the strength of aluminium alloys by simple annealing (at ~300°C), i.e., without heat treatment, including quenching. However, scandium is a very expensive metal, so its use as an additive is severely limited. The most effective method is the introduction of scandium together with zirconium (Lefebvre, 2009; Booth-Morrison, 2012). The optimal combination is the introduction of ~0.1% Sc together with 0.20–0.25% Zr, which, according to (Belov, 2006), gives approximately the same strengthening effect as the introduction of 0.3% Sc."

Jan 1, 2018

By C. O. Aksoy, P. M. Ozfirat, M. K. Ozfirat, C. Tatar, C. Pamukcu

"Temporal and other factors contributing to the occurrence of occupational accidents at an underground coal mine in Turkey between 1992 and 2000 have been analyzed. The time period of the study spanned the transition from hand-worked mining methods (1992 to 1996) to hand-worked mining methods and mechanized mining methods (1997 to 2000).The mine selected for the study employed an average of 5,835 men per year on three separate eight-hour production shifts for 302 d/y (Sundays are not worked, and there are 11 holiday days per year). Production on an annual basis averaged 190,000 tons per year between 1992 and 1996, and 300,000 tons per year between 1997 and 2000.The purpose of the study was to determine which, if any, of the factors studied contributed to the occurrence of accidents so that the mine could take the necessary steps to reduce the risk to the workforce. Regression analysis was used to determine the strength of the relationship between each factor studied and the number of occupational accidents.The strongest relationships observed were between the age of the employee, the day of the week, and the total yearly labour."

Jan 1, 2006

By F. J. Alcock

IN the summer of 1934, gold was discovered on Lodge bay, on the north shore of lake Athabaska in northern Saskatchewan, about fifty miles east of the Alberta boundary line. The first claims were taken up by the Consolidated Mining and Smelting Company of Canada, Limited, and there was a 'rush' to locate similar showings. Staking continued through the summer and succeeding winter, and in the spring of 1935 the provincial government established a recording office at a convenient point which is central to the more important holdings and where 'planes can land in any weather. During the past summer, the name of this townsite was changed from Beaverlodge to Goldfields, and a post office was established here. The season was one of great activity; a great deal of assessment and development work was carried out and a large amount of further prospecting done. In addition to the work by private companies, geological investigation was carried out in the region by a Federal Geological Survey party under the charge of the writer and a reconnaissance examination was made of an area of some 7,000 square miles surrounding the region of particular interest. Though this was the first discovery of gold in the region it was not the first occasion that prospecting had been carried out along the north side of lake Athabaska. Over twenty years ago, a number of prospectors were at work in the area and a large number of claims were staked, many of which were never recorded. One man by the name of Piché, in the years 1910, 1912, and 1913, took up a considerable number of claims north of Pine Channel narrows, east of Fond du Lac. His discoveries, which consisted of small showings of sulphides in sedimentary gneiss, proved to be of no economic importance. In 1915, a sudden widespread interest was aroused by the report that a sample of ore collected near Fond du Lac had yielded a very high assay in silver. In March and April of that year, prospectors began to rush into the field by dog teams to take up claims, and, as soon as the Athabaska river was free of ice, others started by boat from Athabaska Landing. Some hundreds of claims were staked and recorded in the Dominion Land Office at Edmonton or at Fort Smith. By July, most of the prospectors had? left the region, having failed to find any silver ore. In 1921, considerable prominence was given to the area a few miles east of Goldfields by reports that very large masses of iron ore were available there. Claims were taken up, but the material is much too low grade to be considered commercial ore.

Jan 1, 1936

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By Yongfeng Jia, Shaofeng Wang, Danni Zhang

Arsenic in mineral processing solutions and effluents is commonly removed and immobilized via iron(III)-arsenatecoprecipitation. The effect of re-crystallization of 2-line ferrihydrite on the long-term stability of iron(III)-arsenate coprecipitate is still not fully understood. This work investigated the redistribution of arsenic and iron during 2-line ferrihydrite transformation at different pHs and temperatures over time. X-ray diffraction (XRD), transmission electron microscopy (TEM) and chemical extraction were employed to characterize the crystallinity of the iron oxyhydroxides. Results showed that the amount of arsenic released into solution during aging increased significantly with increasing media pH.

Jan 1, 2014

A mini- or micro-machine is a small electro- mechanical device. There are several existing applications of micro-sensors such as the accelerometers used in automobile airbags or the force sensors and grippers used at the ends of micro-surgery tools. Potential applications of existing mini- and micro-technologies are possible and could be used to improve the control and efficiency of fragmentation, heap leaching and other mining and mineral processing operations. A more radical proposition is to devise mass-produced, possibly disposable, minimachines that would operate in large groups. These would be the basis of highly selective, efficient, flexible, and clean mining and mineral processing methods. The paper is intended to promote discussion of how innovative applications of mini-technologies can be used to improve and radically change current mining and mineral processing methods.

Jan 1, 2002

By R. I. Iacobescu, Y. W. Chiang, A. Van Audenaerde, R. M. Santos, T. Van Gerven, P. Knops

In this work, we explore a novel mineral processing approach using carbon dioxide to promote mineral alterations that lead to improved extractability of nickel from olivine ((Mg,Fe)2SiO4). The precept is that by altering the morphology and the mineralogy of the ore via mineral carbonation, the comminution requirements and the acid consumption during hydrometallurgical processing can be reduced. Furthermore, carbonation pre-treatment can lead to mineral liberation and concentration of metals in physically separable phases. In a first processing step, olivine is fully carbonated at high CO2 partial pressures (35 bar) and optimal temperature (200 °C) with the addition of pH buffering agents. This leads to a powdery product containing high carbonate content. The main products of the carbonation reaction include amorphous colloidal silica, chromium-rich metallic particles, and iron-substituted magnesite ((Mg1- x,Fex)CO3). Carbonated olivine was subsequently leached using an array of inorganic and organic acids to test their leaching efficiency. Compared to leaching from untreated olivine, the percentage of nickel extracted from carbonated olivine by acid leaching was significantly increased. It is anticipated that the mineral carbonation pre-treatment approach may also be applicable to other ultrabasic and lateritic ores.

Jan 1, 2014

By T. Gammatikopoulos, C. Gibson, M. Aghamirian

Lithium is an alkali metal found in brine deposits in the United States, Chile and Argentina, as well as in hard rock deposits in Australia and North America. In hard rock deposits, spodumene (LiAl(Si2O6)) is the major economic lithium bearing mineral. Spodumene is typically upgraded through a combination of dense media separation, flotation and magnetic separation. One of the major spodumene concentrate quality specifications is the iron oxide content because it will help determine if the concentrate is considered ceramic grade for use in ceramics and glass or chemical grade for use in lithium ion batteries. The rejection of iron bearing silicate minerals from artificial ore composites (high amphibole and low amphibole, high quartz/feldspar) from a hard-rock spodumene deposit was investigated using magnetic separation and flotation. The efficacy of Wet High Intensity Magnetic Separation (WHIMS) in iron rejection was found to be dependent on the mineralogy of the iron-bearing silicate minerals including modal distribution, liberation and association. When magnetic separation was conducted prior to flotation, the Fe2O3 grade in the final flotation spodumene concentrate was reduced from ~3% to ~1% Fe2O3 , and improved lithium recovery in flotation was observed. It was determined that it was most effective to conduct WHIMS on the flotation feed after scrubbing and de-sliming because this reduced the required magnetic field to recover iron-bearing minerals, likely because slime coating was greatly reduced. Flotation collector screening of four different collectors with varying rosin acid content demonstrated a potential increase in selective flotation of spodumene over some iron silicate minerals with decreasing rosin acid content in the fatty acid collector. However, due to marginal difference in flotation results with the various collectors tested, further testing is required to confirm the observations made and establish a hypothesis regarding the effect of rosin acid content.

Jan 1, 2017

By Jack Zhang, Yunguo Tang, Baodong Zhao

"Rare earth elements (REEs) have numerous key applications in both traditional and advanced technologies. A shortage of some critical REEs is expected due to the discrepancy between the REE abundance in REE deposits and the REE demand from the market. For example, Neodymium, Europium, Terbium, Dysprosium, Erbium and Yttrium are expected to be in short supply. REE recovery and separation from secondary resources such as uranium wastes, heavy mineral sands, and recycled materials can balance the shortfall in a cost effective way.The Saskatchewan Research Council (SRC) is engaged in the development and commercialization of complete REE recovery and separation technologies in Canada. One of SRC’s newest developments is the design and commissioning of a heavy rare earth (HREE) separation pilot plant. The pilot plant uses hundreds of stages of solvent extraction (SX) to produce high purity individual HREEs from both primary and secondary resources.This paper presents the design of an HREE recovery process for the particular case of uranium processing wastes. The separation results of a group separation are reported and discussed, as well as the issues and the challenges of the development, commissioning and operation of the continuous SX pilot plant.IntroductionSignificant amounts of strategic specialty heavy rare earth elements (HREEs) are found in uranium wastes in Saskatchewan. It estimated that about 47 tonne/a of heavy rare earth element oxides (HREO) including 27 tonne/a of Y2O3, plus 6 tonne/a of Sc2O3 are in the raffinate of every uranium mill for potential recovery. Since the HREEs are already in the raffinate, cost effective HREE production is promising in Saskatchewan.Selective precipitation including nutraulization, oxalate and double-salts precipitation, as well as sulfide precipitation, ion exchange (IX) and SX are commonly used technologies for the recovery and purification of REE solution. REE oxalate precipitation is an effective technology to remove Fe, Al, Ca, Si and other impurities by taking the advantages of the solubility difference between oxalates of REEs and impurities in acidic solution (Xu, 2005)."

Jan 1, 2017

By Mary Ann Bennett, Val Nichols, Colleen Proctor

"In 1997 when Royal Oak Mines Inc. went into receivership, the mineral processing technicians (mill operators) who had been working at Giant Mine in Yellowknife, Northwest Territories for most of their career walked out with no credentials to serve as testimony of their knowledge and skills.As a result of new diamond mining activity and the establishment of socio-economic agreements, mining industry representatives approached the Department of Education, Culture and Employment (ECE), Government of the Northwest Territories, in 1999. They requested support and direction to promote training and recognition for mineral processing technicians at BHP’s (BHP Diamonds Inc.) Ekati mine. ECE recommended the development of occupational standards and certification.This paper describes the development process and end products that resulted from this collaborative project between industry, government and education. In addition, industry representatives involved in the project share their views on the development process and the benefits of standards and certification.The conclusion invites industry members to support national occupational standards and certification with their associated benefits: standardized training in the workplace and institutions, proof of competence for hiring, recognition of prior learning, and a nationally and internationally recognized credential.INTRODUCTIONSwiftly changing labour market demands are nothing new in the North. The fur trade and mineral discoveries have brought employment to workers in a feast and famine cycle for decades. In the late 1990s, the Giant, Con, Lupin, Polaris and Nanasivik mines were nearing the end of productive runs. Many experienced workers found that without credentials, they had no proof of their abilities to offer prospective employers."

Jan 1, 2005

By Caroline B. Chapleau, Mélanie Proulx, Claude Bazin, Gaétan Lavoie

"Quebec Cartier Mining operates a pelletizing plant in Port-Cartier, QC. Grinding, agglomeration and pellets induration are the three main steps in the preparation of iron oxide pellets. In 1998, following different recommendations, the company increased the speed of one of its ball mill in order to increase the grinding efficiency of the machine. As expected, the increased speed lead to an increase of the power draught, which did not produce the expected increase of fineness of grind, neither its allows to increase the mill throughput. The change of behaviour of the mill could hardly be understood by comparison of discharge size distribution at initial and modified mill rotation speed. On the other hand, the use of the selection function from a population balance model provides an insight of the changes that occurred in the mill. This paper reviews the various steps required for the estimation of a grinding mill selection function. Results of the calibration to Quebec Cartier grinding mills show that the increase in the mill speed leads to higher rate of breakage of coarse particles, at the expenses of less efficient breakage of medium and fine size particles. In the case of the studied mill, breakage of coarse particles was probably not the critical step of the mill operation. INTRODUCTIONOre size reduction is the major energy consumption step in any mineral processing operations (Austin et al., 1984). Size reduction is required to either liberate valuable minerals from the gangue minerals in which they are imbedded, or to increase the specific surface of the ground material. Plant engineers continuously face the challenge to find grinding machines, operating conditions or grinding circuit flowsheet configurations that could improve the size reduction process at lower energy or m6dia consumption."

Jan 1, 2000

By Xiang Yu

Hong Kong has a dense distribution of utility services laid under its road network. Utility undertakers frequently demand road openings to install new services and/or maintain existing ones. Road openings can cause troubles to the road network and negatively impact the public interest. Highways Department is responsible for managing road openings in Hong Kong under the Land (Miscellaneous Provisions) Ordinance. Highways Department has spent a lot of efforts to computerize excavation permit processing and utility management. The computerized system has gone through several generations and the current one is called the excavation permit management system (XPMS). On the one hand, the XPMS handles various excavation permit processing functions including permit application/approval/refusal/issuance/extension/termination, fees/costs, permit conditions, and permit period assessment; on the other hand, the XPMS accounts for some important utility management issues such as spatial check, coordination of multiple openings, traffic management, audit inspection, and defect liability. This paper discusses how the application, coordination, and other administrations of an excavation permit are eased by using the XPMS in Hong Kong. Background information such as the governing legal and regulatory framework, and Highways Department?s administrative structure is introduced. The system architecture and advantages of the XPMS are presented. The work procedures and various functions of the XPMS are studied in detail.

Aug 1, 2013

By Erin Legault Seguin, Mike Rylatt, Curtis Mohns

"With energy costs increasing and ore grades diminishing, the role of pre-concentration in hard rock mining operations has been gaining greater interest. To maximize energy conservation, the pre-concentration process should be conducted at as coarse a crush size as possible while minimizing losses of pay metals. Dense medium separation (DMS) is a robust process that can be conducted at particle sizes as coarse as 300 mm and as fine as 500 µm with high separation efficiency, depending on liberation characteristics of the value minerals. The DMS process involves three steps: feed preparation, dense medium separation, and ferrous-based media recovery. This paper discusses each of these processing steps, but focus will be given to the dense medium separation stage. Various types of DMS equipment are reviewed. Pilot plant campaign case studies conducted at the SGS Lakefield site are presented, which have included a variety of mineral systems such as spodumene, sulphide-bearing gold ores, and complex sulphide ores. These case studies demonstrate that for amenable ores, mass rejection of 20-60% is possible while maintaining recoveries of greater than 90% in most cases.IntroductionPre-concentration is a process of rejecting mass of gangue while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Pre-concentration has been practiced in industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, typically requiring finer grind sizes and higher energy costs."

Jan 1, 2016

By D. C. R. Espinosa, P. Aliprandini, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel and cobalt are the main value metals in nickel laterite ore. Cyanex 272 is an extractant used to separate nickel from cobalt present in leach solutions. Previous studies demonstrated the extraction of cobalt, magnesium and manganese at pH 5 using Cyanex 272 as extractant, while nickel remained in aqueous solution. However, it is difficult to separate cobalt from a solution containing magnesium and manganese. One possibility to change the metals’ behavior during the solvent extraction process is to change the mixture of extractants used. In order to study the solvent extraction of cobalt from a solution containing manganese, magnesium and nickel, a mixture of two extractants was investigated. Cyanex 272 (CY) and Versatic 10 (VC) were selected as extractants in the organic phase. The extractant concentrations used were: 20% CY; 15% CY, 5% VC; 10% CY, 10% VC; 5% CY, 15% VC; and 20% VC. In all cases, kerosene was used as a diluent, at 80 vol%. The synthetic leach solution used in this study was prepared according to the composition of a typical nickel laterite leach solution. The pH value of the solution used was 5, and the aqueous/organic ratio used in solvent extraction testwork was 1/1. The study has shown that the composition of the organic extractant mixture did not increase cobalt separation.INTRODUCTION Sulfide and laterite deposits are the main sources of nickel. However, production from nickel sulfide ores has been decreasing over the years, relatively speaking, increasing the focus on the exploitation of laterite nickel ores (McDonald & Whittington, 2008). Laterite ore deposits are found in tropical and subtropical regions. A characteristic of laterite ores is the presence of a complex and heterogeneous mixture of metals (Crundwell, Moats, Ramachandran, Robinson, & Davenport, 2011; Georgiou & Papangelakis, 1998; Gupta, 2003; Kesler & Simon, 2015; Moskalyk & Alfantazi, 2002; Oliveira, 1990). Nickel concentrations in laterite ores are typically 1–2% (Dalvi, Bacon, & Osborne, 2004)."

Jan 1, 2017

By D. Imeson, T. Grammatikopoulos, G. Pearse, M. Aghamirian, C. Mohns

"Spodumene mineral is a source of lithium for lithium ion batteries. Thus, the production of a spodumene concentrate with an approximate grade of 6% Li2O is targeted. Traditionally, spodumene is concentrated by froth flotation using fatty acid as the collector. Amine collector can also be used to float mica ahead of spodumene as required or feldspar from the spodumene tailings. Slimes have a negative effect on spodumene flotation and they are commonly separated by scrubbing and de-sliming prior to spodumene flotation. The main losses in spodumene flotation typically occur in cyclone overflow, scrubbing slimes, spodumene flotation tailings and mica concentrate. In recent years, dense media separation (DMS) is the main concentrating process in Australian spodumene operations. In these operations, DMS is efficient at generating coarse grain concentrates and rejecting large portions of silicate gangue, thereby directly reducing the milling cost. The ore should be crushed to 3/8” or coarser while further crushing is possibly necessary on the middling particles to scalp further spodumene. The DMS feed should be classified to remove fines (typically -0.5 mm particles). The final middlings and undersize fractions could then be processed by flotation. The main requirement in DMS operations is to have good spodumene liberation at relatively large grain size. This paper reviews the most significant DMS and flotation parameters in spodumene beneficiation. The treatments of different minerals in the spodumene ore are also addressed.INTRODUCTION A number of laboratory/pilot plant programs have been recently conducted at the SGS Lakefield site, sponsored by different clients. The main objective has been to develop a process flowsheet to generate a spodumene concentrate containing 6.0% or higher Li2O (~75% spodumene) suitable for producing lithium carbonate by a hydrometallurgical process. Depending on spodumene liberation size, dense media separation (DMS) can be an attractive option to produce a final high grade concentrate and to reduce the mass to be treated in the flotation circuit. In such a case, crushing would typically be performed in stages, with DMS separation to recover a spodumene concentrate and reject gangue minerals following each stage. DMS middlings and -0.5 mm fines can be processed by flotation to further recover spodumene. In the flotation process, coarse stage grinding minimizes the grinding cost and formation of slimes. In the majority of cases, a grind size (K80) of approximately 200 microns is sufficient for flotation. After primary grinding, mica, if present in an appreciable amount, should be floated to minimize interference with spodumene flotation. Desliming after scrubbing and high density conditioning are the key process operations prior to spodumene flotation. Spodumene can then be floated from silicate gangue minerals with a fatty acid or a mixture of fatty acid and petroleum sulfonate at slightly alkaline pH. Subsequently, feldspars can then be floated from the spodumene tailings."

Jan 1, 2012

By S. Nakamura, M. Takaoka, Y. Mizuno, T. Kusakabe

"Mercury is produced as a byproduct from gold mines and, historically, has been transferred to recyclers and used for various industrial processes and products. However, under the Minamata Convention on Mercury, adopted in 2013,the intentional use of mercury in processes or products will be minimized in the world. Surplus elemental mercury should be treated as a hazardous waste and consequently, should be converted to a more stable chemical form for long-term storage or permanent disposal. A stabilization method has been developed to react mercury and sulfur using a planetary ball mill. The planetary ball mill can produce high-energy conditions and enable samples to react within a short period of time. A series of tests has been conducted to confirm that mercury sulfide can be produced using a bench scale machine with 2400 mL pot. Under a suitable experimental condition with 25 mm ball diameter, 30%of ball filling rate and 1.05 of molar ratio of S/Hg, a powdered mercury sulfide product was successfully obtained in 60 minutes. The leach ability and atmospheric emission from the product was extremely low. This stabilization method would contribute to an environmentally sound mercury management strategy for the gold industry.INTRODUCTIONDue to its unique physical and chemical properties, mercury has numerous applications, including in industry and medicine. However, mercury and its compounds are highly toxic. For example, in Japan, methyl mercury in waste water caused Minamata disease in the 1950s, which affected large numbers of people (Minamata Disease Municipal Museum, 2001). In recent years, environmental pollution caused by emissions and releases of mercury into the atmosphere, waterbody and land by various emission sources such as coal fire plants, artisanal and small-scale gold mining (ASGM), non-ferrous metal industries, waste incinerations etc. has also become a significant problem. To protect human health and the environment from anthropogenic emissions and releases of mercury and its compounds, the Minamata Convention on Mercury was adopted in 2013(UNEP, 2013)Because ground gold ore typically contains mercury at 0 to 100 ppm, mercury is often produced as a byproduct from gold mines (UNEP, 2016). In gold mining operations, mercury can be released from the ore by roasting or by leaching in cyanide solutions and recovery onto activated carbon. According to Yanget al. (2016), 85.1%of mercury in a concentrate was vaporized during a roasting process. Both processes finally discharge elemental mercury as a byproduct. In the USA, more than 100 ton of mercury was discharged from large-scale and industrial gold mining (Miller, 2004)."

Jan 1, 2017

By Andréa Lagacé

"The milling of sulphide ores inherently generates “thiosalts”, a series of partially oxidized sulphur oxyanions (S2O3 2-, S3O6 2-, S4O6 2- etc.), which make control of effluent treatment systems difficult because their natural oxidation produces acid with the potential to lower the pH within the treatment system and/or receiving environment.At the Xstrata Copper Kidd Metallurgical Site, thiosalt oxidation in the Tailings Management Area continues after buffer storage Ponds A and C where lime is added to precipitate metals and elevate the pH to within the required range for discharge. If the additional acidity generated during the continued process of thiosalt oxidation is not neutralized there is a risk that the final effluent will be non-compliant with regulated standards.To mitigate this risk, in 2007 a full scale pilot trial was conducted with hydrogen peroxide in order to force the complete oxidation of thiosalts prior to the lime treatment stations. This method of chemical oxidation had been shown to be effective at Xstrata Zinc’s Brunswick Mine. The pilot results indicated that a maximum of 50% of the stoichiometric quantity of hydrogen peroxide is required to reduce the thiosalt concentration in the No. 2 thickener overflow stream (feed to buffer storage Ponds A and C) to less than detection (10 mg/L); however, treatment was only effective in the presence of a 20 mg/L iron (Fe) catalyst. Since the hydrogen peroxide addition point at the No. 2 tailings thickener overflow typically contains <1 mg/L total Fe, a second reagent, ferric sulphate, was used to increase the total Fe concentration to the required level. This paper describes the set-up and results of the pilot trial which were used in the design of the full-scale plant.INTRODUCTIONTailings Management Area OverviewXstrata Copper’s Kidd Metallurgical Site, located in Timmins, Ontario, is an integrated metal refining facility producing copper, zinc, cadmium, indium, liquid sulfur dioxide, and sulfuric acid from third party custom feeds, and mineral concentrates recovered from its 7,800 tonne per day mill."

Jan 1, 2010

By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014

By R. Lasmanis

"Washington State&apos;s diverse geological setting is reflected by its several types of porphyry Cu-Mo deposits. All are associated with calc-alkaline intrusions, and they range in age from Jurassic to Miocene.The largest is the Mount Tolman Mo-Cu deposit located in the Omineca Belt. It contains 2.18 billion tonnes of material averaging 0.093% MoS2 and 0.09% Cu. There are intermediate-size Mesozoic deposits in the Intermontane Belt. The Cascade volcanic arc hosts small- to medium-Tertiary deposits. Among these, of particular interest is the Sunrise breccia pipe, which has been explored over a vertical distance of 1000 m. It contains reserves of 64.6 million tonnes averaging 0.319% Cu and 0.071% MoS2 with significant tungsten values. The Glacier Peak deposits have potential resources of 1.7 billion tonnes averaging 0.334% Cu and more than 0.015% MoS2 and also contain tungsten. The Margaret deposit can be classified as a porphyry Cu-Au type; it has reserves of 200 million tonnes averaging 0.434% Cu, 0.0175% MoS2> 0.27 g!t Au and 1.92 g!t Ag. Drill intercepts of the North Fork deposit also show significant gold values.Mineralization and hydrothermal alteration of these deposits are typical of porphyry deposits, although some differences can be noted. The Mount Tolman molybdenum deposit contains topaz alteration zones and is transitional between a plutonic type and a Climax-type molybdenum system. Other deposits, such as the Kelsey, Mazama, North Fork, and Margaret, are low-sulphide systems that contain significant amounts of magnetite."

Jan 1, 1995