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By Peter Claus

In the last years, supported gold catalysts with particle sizes smaller than 10 nm have attracted a lot of attention. While gold bulk metal is rather inert in chemical reactions and, thus, is of low interest for catalysis, highly dispersed gold particles supported on oxides as TiO2 or ZrO2 show surprisingly high activities in some reactions important for the chemical industry. The oxidation of carbon monoxide at low temperatures is mainly used as model reaction to study the unusual properties of gold catalysts [1]. On the other hand, to evaluate the catalytic potential of gold, other chemical reactions which allow to control also the selectivity have to be considered. The selective hydrogenation of ???-unsaturated aldehydes to allylic alcohols is of both commercial relevance (e.g. in fine chemical and pharmaceutical intermediate production) and specific scientific interest [2]. Note that thermodynamics favors hydrogenation of the C=C over the C=O group (stronger negative free reaction enthalpy of 35 kJ/mol), and for kinetic reasons the C=C bond is more reactive than the C=O group. Thus, in the presence of most of the conventional hydrogenation catalysts, based on Pt, Rh or Pd, -unsaturated aldehydes such as acrolein and crotonaldehyde are hydrogenated predominantly to the saturated aldehydes and only to a minor extent to unsaturated alcohols. Therefore, it is desirable to find catalysts which are able to control the intramolecular selectivity by hydrogenation preferentially the C=O group while keeping the olefinic double bond intact (Fig. 1).

Oct 1, 2003

By F. Sorenson, P. A. Castellarini, F. Garbarino, M. N. Garcia

"Recently, significant efforts to improve productivity from the tight intervals of the Mulichinco Formation within the Sierra Chata Field in the Neuquén Basin have been ongoing. Because conventional high quality reservoirs were being developed in this field, a proper reservoir understanding and completion approach was applied. After developing these high permeability reservoirs, the operator began evaluating the tight intervals and new areas within the field, but a completely different approach was necessary to achieve motivating production improvement.An extensive study to help enhance reservoir understanding and identify key factors controlling productivity of these tight intervals (which tend to be in the range of 5 µD) has been ongoing. Some of the issues discussed in this study are 1) petrophysical review, 2) rock properties calibration, 3) geomechanics understanding, 4) faulting and micro faulting/lineaments description, 5) stimulation and completions review and, 6) understanding key production drivers.As in many other tight reservoir projects, a considerable area of the reservoir must be effectively stimulated during the hydraulic fracturing process to achieve economic productivity. Two critical issues hinder these objectives. First, the low permeability in addition to a pore pressure close to or even lower than hydrostatic are critical characteristics when attempting to flow back the well and clean up fractures. Second, very high horizontal stress anisotropy resulting from a strike slip stress regime promotes the generation of simple planar bi-wing fractures. It is well-known that this fracture geometry will contact much less reservoir area compared to more complex fractures, as the operator would normally intend to create at very low permeability reservoirs.This paper discusses these issues and how they were addressed. A pilot drilling and completion program was initiated during 2012 to validate this study. Key factors include well location relative to formation unconformities, their orientation relative to the far field principal stresses, hydraulic fractures generated, and overall completion design."

Jan 1, 2015

"Some of the tools developed for the processing of nickel laterite ore by resin-in-pulp (RIP) may be applicable to the remediation of metalliferous mine drainage (MMD). In both cases, recovery of metal value and production of a stable waste stream appropriate for long term storage is desired. MMD typically has the additional challenge of management of toxic low-value metals. Seen in this light, innovations in RIP reactor configuration, selective elution strategies and novel synthetic ion exchange resins become useful tools for taking on the MMD challenge in a way that maximizes both environmental and economic benefit. INTRODUCTIONAcid mine drainage (AMD) is a common problem in any country with significant past mining activity. When sulphide containing minerals, tailings or slag are exposed to water, oxygen and sulphur oxidizing bacteria, AMD will result. Abundant and reactive iron sulphide minerals leach first, providing acidity and the ferrous/ferric couple that can enhance the oxidation kinetics of other minerals. If this runoff contacts encounters acid consuming carbonates or silicates, the acidity may be neutralized, but certain heavy metals remain in solution and can continue to be an environmental hazard (Gray, 1997). For this reason, the remainder of this paper will refer to the broader term metalliferous mine drainage (MMD) rather than acid mine drainage. In either case, such drainage, containing high heavy metal concentrations and often significant acidity, is toxic to aquatic life and can lead to significant damage to ecosystems and to public watercourses. MMD is a problem most commonly associated with now defunct sulphide mineral mines, but similarly toxic streams can result from many types of waste, such as poorly stabilized leach tailings, slag heaps, and coal flotation tailings (Johnson and Hallberg, 2005; Lee et al., 2002; Sainz et al., 2002; Schüring et al., 1997). In any case, the management and remediation of MMD is an important ongoing problem for the resource industry, particularly for the many mines in Canada closed before the advent of more stringent environmental standards. MMD remediation represents a significant long term expense for the resource industry. Multi-disciplinary efforts to understand and mitigate this problem range from creation of artificial wetlands (Poulin and Lawrence, 1996; Sheoran and Sheoran, 2006) to sophisticated biochemical reactors and precipitation processes (Hatami, 2010). Certain remediation technologies such as ion exchange offer methods to make a saleable product by recovering valuable dissolved metals. This paper will show how these technologies can help defray the cost of remediation, and offer potential to turn a dangerous waste stream into a useful product."

Jan 1, 2012

By John Convey

This paper, a follow-up to an earlier study, gives the history of Canadian developments in mineral processing from 1921 to the fall of 1964. It deals extensively with comminution and flotation, and then goes on to cover the fields of gravity concentration, magnetic concentration, cyanidation, the processing of uranium ores, and instrumentation. Several outstanding examples of installations are given. The paper concludes with a discussion of present-day trends in mineral processing. Introduction T HE history of the developments in mineral processing in Canada from its earliest times to 1920 has already been published by one of the authors (1). The present paper is thus a logical follow-up to bring this history to date. From 1834 to 1920, mineral processing in Canada, as elsewhere in the world, was in its formative stage. This, however, prepared the ground for developments that have resulted in a mining empire from the Atlantic to the Pacific, a mining empire which could be said to be almost on par with that in the United States.

Jan 1, 1965

By P. Trudel, M. A. . Cloutier

This lithogeochemical study demonstrates that the Gilman and Blondeau Formations in the Chibougamau area belong to a subalkaline suite of tholeiitic affinity poor in potassium. The Gilman Formation is composed mostly of basalts, with subordinate andesites and rare dacites, while the Blondeau Formation comprises all lithologies of the basalt-andesite-dacite-rhyodacite-rhyolite ensemble. Both AFM and Harker variation diagrams show that all these rocks originated by differentiation from the same magma reservoir, and are related to one volcanic episode, This study did not, however, identify hydrothermal alteration zones useful for regional geochemical prospect ion.

Jan 1, 1984

By J. Muralha, L. Lamas

"Given the results of triaixial tests, regressions are commonly used to evaluate the parameters of failure criteria that model intact rock strength and to perform statistical inferences used to evaluate characteristic values defined in EC7. Statistical robustness of these inferences is affected if the basic hypothesis underlying regression are not met, namely homoscedasticity (constant variance of the errors). This paper presents analyses of 23 sets of triaxial tests, starting by the evaluation of the regression parameters of the Mohr-Coulomb linear criterion and of the Hoek-Brown non-linear criterion, followed by carrying several statistical tests to check the homoscedasticity null hypothesis of independence between the variance of intact rock strength and the confining stress.INTRODUCTIONThough rock engineering design is clearly included in the scope of Eurocode 7(EN1997-1), its implementation raised a wide discussion regarding the applicability of structural safety concepts to geotechnical design of construction works in or on rock masses. The basis of the limit state design philosophy adopted in EC7 is that, for each particular design situation, all the possible limit states for a structure, or part of it, shall be considered and that it shall be demonstrated that the likelihood of any limit state being exceeded is sufficiently small. Though EC7 allows the limit states to be verified by one or a combination of methods, use of calculations is by far the most used, and it is often confused with the EC7 itself. It involves using characteristic values of actions, ground properties and geometrical data, as well as obtaining their design values by the partial factor method.Characteristic value of a given material property is defined in Eurocode (EN 1990) as: “value of a material or product property having a prescribed probability of not being attained in a hypothetical unlimited test series. This value generally corresponds to a specified fractile of the assumed statistical distribution of the particular property of the material or product”. As regards the design value of a material or product property, according to the Eurocode it is a “value obtained by dividing the characteristic value by a partial factor”."

Jan 1, 2015

By J Zhou

Based on the mineralogical characteristics and mineral processing techniques required, gold ores can be classified into 12 types, including gold placers, quartz vein-lode ores, oxidized ores, silver-rich ores, iron oxide copper gold ores, porphyry copper gold ores, iron sulphide ores, arsenic sulphide ores, antimony sulphide ores, bismuth sulphide ores, telluride ores and carbonaceous sulphide ores. The bulk mineralogy and gold deportment of each ore type is different and may have a significant impact on ore processing and metal extraction. This paper summarizes the bulk mineralogy and gold deportment in some major types of gold ores and discusses the potential impact of gold deportment on gold metallurgy.

Jan 1, 2011

By J. Aiello

"Introduction Byron Creek Collieries Limited Corbin mine is located in southeastern British Columbia approximately 180 air kilometres southwest of Calgary (Fig. I), twenty four kilometres south of Highway No. 3 via a newly constructed provincial road (Fig. 2). The development of the area began July 30, 1905, when D.C. Corbin, a prominent businessman from the northwestern U.S., and his associate E.J. Roberts first visited the site of Coal Mountain on horseback. Coal was in great demand by railways and other industrial users, so the Corbin Coal and Coke Co., after acquiring 6,000 hectares of land in the area, began to develop a mine. Mr. Roberts was responsible for the construction of the 22-kilometre rail spur, the Eastern British Columbia Railway, which joined the mine to the CPR main line at the McGillivray Loop. Rail access to the mine and its developing community, Corbin, B.C., was completed in September 1908, the same year that the first underground mine began production. The Corbin Coal and Coke Co. operated six mines on Coal Mountain (Fig. 3) and production from 1908 to 1930 inclusive totalled 2,120,800 tonnes. This production was allocated to the mines as follows:"

Jan 1, 1985

By Grant J. Goddard

"The Iron Ore Company of Canada (IOC) has been in operation for over 30 years. Today, and in the future, technology and its application will play an ever more critical role in the company’s business success.The Carol Mining and Concentrating (CMC) division of IOC is energetically applying technology today to enhance performance and results, and is aggressively exploring opportunities to apply technology to support improved business results in the future.A critical area of focus is the application of technology to maintenance management performance. CMC has taken a “back to basics” approach to the fundamentals of maintenance management in 1995 and 1996. In parallel, the mine is aggressively implementing its Vision 2000 maintenance integration plan. This plan is targeted at levering the energies applied to sound maintenance management fundamentals as the company moves to a fully condition based maintenance approach.This paper discusses some of the strategies, key technologies and objectives of theVision 2000 maintenance integration plan at the mining operations of IOC."

Jan 1, 1996

By C. I. Garcia, G. Zhou, W. Gao, A. J. DeArdo

The development of X-100 and X-120 linepipe steels was investigated using a series of low-carbon Mo-Nb-B steels. The laboratory steels were vacuum melted and processed using advanced thermomechanical processing (TMP) philosophies. Prior to the laboratory hot-rolling experiments, the grain coarsening temperature, the conventional T95 and T5 start-stop recrystallization temperatures and the transformation behavior of y were studied using a computer-controlled high temperature deformation MTS-458 and a Theta-IV High Speed dilatometer systems. The results from these experiments provided the guidelines for the design of the laboratory hot-rolling TMP processing experiments. The mechanical properties of the experimental steels showed yield strengths in the range 700-850 MPa and CVN impact properties of over 80 J at -20°C. The best balance of mechanical properties was obtained by using CCR+DQ+Tempering treatments. The major microstructural features responsible for the observed mechanical properties in order of importance were: a) substructural refinement associated with lower bainite, b) dislocation strengthening, c) fine recrystallized ferrite, and d) small amounts of retained austenite. Fine Nb(C,N) precipitates formed in ferrite were observed, however their contribution to the strength was minimum. Most of the Nb(C,N) precipitation took place in austenite. This precipitation was used to exert microstructural control of austenite during hot rolling. The physical metallurgy and optimum TMP to achieve the mechanical properties are detailed in this paper.

Jan 1, 2005

By Peter K. Kaiser

Planning and design of deep underground mines involves a process of complex three-dimensional data integration utilizing information from exploration (geology, rock mass characteristics), engineering (mining method, excavation geometry, stress) and operations (time, in the form of sequencing). As new logging and monitoring technologies are being developed, the amount and data complexity becomes overwhelming and decisions are often made based on only a small part of the available data. Recently, Laurentian University opened a state-of-the-art Virtual Reality Laboratory (VRL), a Mining Exploratorium that is unique in the world of mining and offers an exceptional data interpretation environment for mine planning and design. The Mining Exploratorium combines a large format spherical stereoscopic projection system, equipped with high definition projection providing the highest resolution of active stereo in the world today, with advanced features of earth modeling software. Combined, this creates the first virtual reality facility geared specifically to the interpretation of mine geometry, geology, geochemistry, microseismicity, geomechanics and mining data sets. This paper demonstrates how value can be added to the mine planning and design process by utilizing this unique tool in the mining decision-making process via better comprehension of spatial relationships of data and by interpreting the data in a collaborative immersive virtual reality environment.

May 1, 2002

By Lawrence Devon Smith

"The concept of risk is well established in the mining industry. It is acknowledged when estimates of reserves are expressed as proven or probable, when mining and metallurgical recoveries are applied to the ore, and when contingencies are added to costs. However, it is difficult to provide a quantitative assessment of risk. The significant sources of risk in a mineral project and how these are addressed in project evaluations are discussed. The discount rate is examined as a fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk.IntroductionThis paper examines the components of the discounted cash flow discount rate and proposes a method of estimating project-specific discount rates. The motivation for this work comes from experience of project evaluations in which owners and purchasers had agreed on virtually every aspect of the evaluation except how much the project was worth. Agreement was reached on reserves, grad~, recovery, capital costs, operating costs, taxes, and, by combining these components, even on the fmal cash flow values. The only difference in opinion concerned the discount rate to be used in the calculation of the net present value. Depending on the life of the project, such differences of opinion can cause a variation of more than 50% in the value placed on a project! This is illustrated in Figure 1."

Jan 1, 2003

"The McArthur River uranium deposit is the single richest uranium ore body developed in the world to date. The ore body’s average grade is 15% U3O8. Proven reserves are in excess of 450 million pounds. The grinding circuit is located underground. The ground ore is pumped to a surface facility where the slurry is thickened and loaded into containers for shipping to the Key Lake mill 78 kilometers to the south.The paper will briefly describe the mining method employed. The underground ore handling and grinding circuit, and surface facilities including slurry load out, wastewater treatment and the freeze plant will be described in detail. The paper will emphasize radiation and safety procedures that are followed to minimize operator exposure to radiation risks.LOCATIONThe McArthur River mine is located 78 kilometres north of the Key Lake mill. It is located at latitude 57’ N in northern Saskatchewan, within the southern boundary of the Athabasca formation. The nearest town is Pinehouse, located 320 kilometres to the south. Access to the mine is by an all weather road and by a private airstrip.HISTORYThe McArthur River Operation is jointly owned by Cameco Corporation (69.805%) and Cogema Resources Inc. (30.195%). Exploration for uranium in the McArthur River area started in 1980 by the Saskatchewan Mining Development Corporation, a predecessor company of Cameco.In 1984, a 12-kilometre long basement conductor was identified at a depth exceeding 500 metres. Systematic exploration drilling of this conductor resulted in the discovery of the P2 North deposit. Subsequent surface drilling programs from 1989 to 1992 delineated a narrow ore zone over a strike length of 1700 meters at a depth of 500 to 600 metres. At this time, geological reserves for the deposit were estimated to be 2.4 million tonnes at a grade of 5.0% U3O8 for a uranium content of 260 million pounds U308"

Jan 1, 2001

By M. Lahtinen, P. Latostenmaa, I. Kojo, E. Peuraniemi, M. Lindgren, S. Jyrkönen, M. Jåfs

The year 2019 marks the 70th anniversary of Flash Smelting. The technology was operated on industrial scale for the first time at the Outokumpu Harjavalta copper smelter in Finland in 1949. Since then Flash Smelting technology, now owned and developed by Outotec Oyj and the first plant, now owned by Boliden Harjavalta Oy, have been evolving throughout history by optimizing the process for various feeds and raw-materials, as well as through developing the equipment and operating practices. Even though sustainability was not a popular theme during the first days of Flash Smelting, it has still been the key principle in guiding the development. This is well proven by the wide adoption of Flash Smelting for the processing of copper and nickel concentrates, mostly due to its ability to fulfil the economic and resource efficiency criteria demanded by its operators. This paper describes the history and improvements of the Outotec® Flash Smelting process by looking into the early days of operation and how the development of the process and equipment has taken place over time as a joint effort between the technology provider and the users of the technology. INTRODUCTION In the 1940s, Outokumpu Oy refined the concentrate produced in the Outokumpu mine into metallic copper initially in Imatra, and later from 1945 to 1949 in Harjavalta, based on the most modern electrical melting process of the world at that time. After the war, Finland lost a significant part of its hydropower production, and due to the increasing use of electricity, the availability of electricity weakened, and the price rose. To maintain Outokumpu's profitability, it was forced to look for a melting solution that was not based on electricity.

Jan 1, 2019

By Jim Wickens, Vince Lofftus, Mark Kravetz

"This paper discusses how Bald Mountain Gold Mine (Ely, NV) dramatically reduced mercury production by treating process solutions with a liquid reagent based on organic sulfide chemistry. Cherokee Chemical Co. Inc. (Vernon, CA) markets this reagent as UNR 81 1A.A summary of the bench tests comparing various reagents is given. The ensuing plant trial is discussed and successful mercury removal results are presented. Data is presented to show that early removal of mercury in the process reduces the amount of mercury collected at retort. Data is also presented to show that use of this reagent does not reduce gold recovery. Plant trial treatment costs are discussed. Finally, the potential of this technology to substantially reduce closure costs as compared to traditional mercury removal options is discussed.INTRODUCTIONBald Mountain Mine produces gold. Mercury is a costly by-product of gold production because no revenue is generated from mercury. Traditionally, mercury leaches out with gold and follows the gold throughout the processing circuit until it is eventually condensed and collected at Retort. Minimizing or eliminating mercury production minimizes worker health and safety risks, minimizes environmental liability, and reduces costs. In the long term, minimizing mercury production will make mine closure easier and less costly.Bald Mountain Mine dramatically reduced mercury production by treating process solutions with liquid reagents called UNR 811 and UNR 811A. Several reagents were bench tested before proceeding with a plant trial. The reagent complexes the mercury to form an insoluble organic sulfide precipitate. In independent tests, the precipitate passed acid mobilization tests and is considered stable."

Jan 1, 2001

By Michael Hood

An overview is given of some of the major mining research activities in Australia. Automation of mining equipment is not an objective in its own right. The objective is to improve the safety and the economic performance of mining operations. Automation can be a useful method for achieving this objective. There is a strong focus on mining equipment automation and related issues and specific examples of ongoing and recently completed automation projects are described.

May 1, 2002

By Marcel Vallee, D. C. Gagnon, C. CARBONNEAU, P. ST-JULIEN

The Magdalen Islands archipelago, a cluster of fifteen islands, is located near the centre of the Gulf of St. Lawrence on the thickest portion of the Carboniferous Fundy Basin of the Maritime Pro vinces. The bedrock of the Magdalen Platform includes a thick succession of evaporites of Visean Age, occurring as a series of thickenings, ridges, domes and diapirs reaching a probable vertical thickness of close to 6000 m. The emplacement of 1hese salt structures by flowage has much dislurbed 1he SlrOligraphic sequence of the rocks of the Windsor Group, particularly 1he Havre-aux-Maisons Formation. Subsequent tectonic movemenl has broken the overlying Cap-auxMeules Forma1ion info an assemblage of panels and blocks now slightly tilted. Following detailed gravimetric surveys and more than 30,000 m of diamond drilling, SOQUEM has discovered, at various dep1hs, seven salt domes on four of 1he main islands of the archipelago. These evaporite bodies generally are localized near the cemre of complex anticlinal struclUres where diapiric movements and faulting have disturbed the original stratigraphic succession. At Rocher du Dauphin near Grosse 1/e, in 1he northern part of the archipelago, Seleine a SOQUEM subsidiary is developing a mining complex with an annual capaci1y of 1,250,000 1onnes of deicing salt for 1he Canadian and Eas1ern United Swtes marke1s. The stan of operations is scheduled for April 1982.

Jan 1, 1984

By C. J. A. Davie

"SUMMARY A practical application of nitric acid oxidation of sulphides, based on the principles of the Arseno process, has been developed for the Cinola ore. Development of the process has been based on testwork conducted by Bacon Donaldson of Vancouver and Hazen Research of Denver, and on conceptual engineering performed by Minproc Engineers of Denver.A comprehensive Stage II report for the project has been submitted to the B.C. permitting agencies, containing provisions for a zero discharge tailings impoundment system and prevention of acid mine drainage. Approval in principle is expected in early 1989.A feasibility study recently completed by Minproc Engineers and Davy McKee Corporation demonstrates that this project can be brought to production for a capital expenditure of C$120 million for a mill throughput of 6,000 tonnes/day and operated at a total direct operating cost of less than $20/tonne.INTRODUCTION The Cinola orebody was discovered in 1970. It is situated approximately in the centre of Graham Island, the largest of the Queen Charlotte Islands. It represents the mid to upper levels of a hydrothermal precious metals system, characterized by intense brecciation and silicification. Gold is associated with finely disseminated sulphides in a breccia matrix and in free form in numerous quartz veins.Ownership of the property has changed hands a number of times, and previous attempts to bring the property to production have failed. Two critical factors have frequently been blamed for difficulty in creating a successful project: namely, process and environment factors, hence the title of this paper.City Resources (Canada) Limited (""City"") acquired the property in 1986, and commenced an aggressive campaign to verify ore reserves, to carry out metallurgical research and to address environmental issues.PROJECT OVERVIEW When the Cinola orebody was discovered, the significance of hydrothermal mineraliza¬tion associated with crustal plate boundaries was not recognized, and for several years, the orebody was considered an uneconomic curiosity. If the type and location of orebody sought by many companies engaged in gold exploration were to be specified, it would probably be a description of the Cinola orebody - it is a large (greater than 1.5 million ounce), low grade (2.45 gm/tonne), refractory ore reserve associated with the Pacific rim crustal plate boundary. The industry appears to have recognized in the past few years that its future lies in the exploitation of such orebodies, and is prepared to come to grips with the technical problems associated with such ores. In this sense, the Cinola orebody might be considered to have come of age."

Jan 1, 1989

By Philippe Henry

HYDROMETAL is using suitable technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy while keeping the environment cleaner. Hydrometal is treating on average 60000 t per year of complex materials through a unique hydrometallurgical recycling concept. Zn, Cu, Sn, and Pb are the most important in volume, but in the last 15 years, Hydrometal has also developed a few specific recycling treatments for the minor metals including Ge, In, Co, etc. In 2010, Hydrometal commenced the recycling of RE (Rare Earths) from wastes generated by the RE refining industry in Europe and has decided to initiate new recycling projects for the RE recovery from the magnet or glass industries. Two case studies of recycling of materials in our integrated hydrometallurgical facility (Hydrométal) in Belgium are discussed: recycling of cerium from polishing sludges; and recycling of Ni- Co from cement produced in the zinc industry.

Jan 1, 2014

By C L. Briend, O&apos

This paper presents the main features of coal mining in Japan, as determined by the author while attending the International Coal Conference in October of 1963. The general economy of the country is considered, and the requirements for coking coal are outlined. Statistics and comments on production and consumption are then given, with accompanying cost figures, and the characteristics of Japanese coal mining are compared with those of Canada. Mining methods and underground transportation are covered, with emphasis on undersea mining. Finally, a description is given of a visit to the Miike colliery, the largest in Japan. I T was my privilege to attend the International Coal Conference held in Tokyo in October, 1963, to meet many prominent members of the Japan Coal Association and to visit one of the major coal fields. This is probably the reason why I was asked to present this review of the coal situation in Japan. In doing so, it must be pointed out that I am not an expert in coal mining, that my

Jan 1, 1965