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By M. W. Wadsley

"Physical and chemical property models are widely used in process engineering. There exist, in the published literature, completely empirical models of ''thermodynamic properties"", that is, property models that are not consistent with the laws of thermodynamics. There also exist property models that purport to be thermodynamically consistent but are flawed in their implementation. There are also published property models that are consistent with the laws of thermodynamics but that do not reproduce property values with an acceptable accuracy. A practicing engineer might be asked to assess very different property models for which there are a variety of claims. This paper discusses features of thermodynamic and empirical property models that may assist in their practical evaluation and implementation."

Jan 1, 2005

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By G. A. Young

THE Geological Survey was created in 1842 to aid the development of Canada's mineral resources. Although the institution has been in existence for nearly 100 years and has accomplished an immense amount of work, the need for its services remains as great as ever and, indeed, it is difficult to imagine a time when the country will no longer require a Geological Survey. This is so because of the tremendous effort required to make an adequate geological examination of so large an area as is embraced by Canada and partly because what today may seem an adequate geological examination proves, later on, to be inadequate. The ultimate objective of the Geological Survey is to complete the study of all phases of the geology of Canada, that is, to determine how and when the physical features originated, how and when the soils and other unconsolidated deposits were formed, and how and when the solid rocks and associated deposits were produced and assumed their present conditions. When the study has been completed, any only then, will it be possible to make a reliable estimate of the country's mineral resources. This appraisal embraces more than determining the value of already discovered deposits: it also involves attempting to establish what kinds of undiscovered deposits may be present and where they may occur. The estimating of the potential mineral wealth can be clone only after the geology of the country is known. Not until then will it be possible to forecast what types of valued deposits may occur in a district and what types will almost certainly be lacking. A thorough knowledge of the geology of the country is desirable not only to permit estimating the potential mineral resources but also as an aid in locating and developing mineral deposits whether these are of the nature of a bed of limestone, a seam of coal, a reservoir of petroleum, a vein, an irregular body of sulphides, or any other type of deposit.

Jan 1, 1940

By Bradley Stoughton

It is very easy to reduce iron ore at a temperature well below its melting point and produce a more-or-less-pure metal which can be used directly for implements, tools, or machines. This simplicity has been the cause of much money loss by persons who were so satisfied with the successful operation of a process that they paid all too little attention to the commercial aspects of it. How easy a direct process is may be gleaned from the fact that it was practised with some -success by primitive man, and has been in almost continuous operation in one form or another for a period of probably 4,000 years. The production of steel in ton lots, beginning about 1860, brought a new phase into the economic situation, which, however, had been already greatly modified in 1784 by Henry Cort's invention of purifying pig iron. Direct processes survived both of these revolutions, under special geographical conditions, even up to the last few years of the nineteenth century, but ceased to have any general use as the basis of supply for structural, machine, or tool industries even in countries which could have manufactured iron by a direct process, but, instead, imported the product of established iron and steel processes. And this is still the situation today, notwithstanding the invention of an incredible number of 'new' processes since 1900, most of which are abandoned, and only survived as along as their financial backers were willing and able to Jose money. Probably none of these processes failed to work pretty well, and all seemed to show a handsome profit on paper.

Jan 1, 1930

By F. A. McLean

Given a promising claim and the required financial backing to develop it, the first problem that confronts the mine operator is usually the selection of the necessary compressed air plant. The size and type of drive are questions that naturally follow, the former being determined largely by the amount of money available and the speed with which it is desired to carry on the programme of development. The type of drive, such as electric motor, steam or oil-engine, depends on local conditions and has an important bearing on the cost of operations. ns. Few prospective mine operators are fortunate enough to locate claims within the service radius of electric power-lines, although this is more likely to happen nowadays than formerly. In the majority of cases, however, some other form of prime mover is necessary. When wood or coal are available at moderate cost, a small steam-driven plant is usually chosen. Such plants are often arranged so that they can be converted to electric-drive should future developments at any time make this desirable. Many plants of this type are installed in northern Ontario mines. When wood or coal are costly or difficult to transport, oil-engine driven mining plants have many advantages in their favor, and are now quite commonly used. Oil in some locali-ties is considerably cheaper than wood or coal, and is much easier to transport over bad roads.

Jan 1, 1924

By E. C. Keeley

THE property of Buffalo Ankerite Gold Mines, Limited, is in Delora township, Porcupine area, Ontario. The southwestern part of the property is ground formerly owned by Marbuan Gold Mines, Limited, which was acquired by Buffalo Ankerite in January, 1936. Until 1938, the Ankerite (or North) mine and the Marbuan (or South) mine continued as separate operations, each developed through a surface shaft and winze to the 1050 level and each having its own mill. This meant high hoisting costs, which, in 1936 and 1937, amounted to 36 cents per ton. In 1938, the underground workings of the two mines were connected on the 1050 level, and ore from both mines was hoisted at the main, or No. 2, shaft of the North mine, location of which is shown in Figure l. This shaft was discontinued at a depth of 1150 feet because, owing to the soft nature of the talc (serpentine) rock in which it was sunk, it had to be concreted throughout, and also because of its great distance--1,100 feet and 1,400 feet, respectively-from the North and South orebodies.

Jan 1, 1945

By A. B. Baldwin

"Uranium and thorium mineralization occurs at several localities in eastern Quebec along the north shore of the Gulf of St. Lawrence. The main occurrences are near Sept-Iles, Baie Johan Beetz, Romaine and St-Augustin river. Mineralization occurs mainly as disseminated uraninite, uranothorite, uranothorianite, monazite and minor zircon and allanite. Yellow to orange oxidation products are observed along fracture planes of the uranium-bearing deposits to a depth of a few feet. Magnetite, biotite and smoky quartz have a distinct tendency to accompany the radioactive minerals. The host rocks include white to pink pegmatite, pink granite and also, in the case of the Romaine and St-Augustin River occurrences, cream to grey plagioclase-rich, well foliated paragneiss and migmatite. Radioactivity near secondary structures, such as fractures and joint planes, indicates some reconstitution of radioactive minerals.The North Shore of Quebec is the northeast extension of the Grenville sub-province. It is also a uranium-thorium metallogenic province."

Jan 1, 1970

By C-D. Johansson, B. Ögren, B. M. Ludvigsson, K-Å. Johansson, R. Lindh, G. Berg, M. Maliarik

This paper presents the High Current Density (HCD) Silver Electrorefining Process. A 25-year history of development of the silver electrorefining process as well as associated equipment is given. The process is simple and robust, but at the same time highly automated. With low operating costs and man power requirement it allows consistent production of 99.99 % quality cathode silver. The process ensures that no toxic gases are formed in the working environment. Silver Electrorefining is a heart of a Silver Refinery plant covering the complete range of processes from casting of silver Doré anodes to casting of the bars of refined silver or/and silver granulation. The process has been successfully applied at 11 installations world-wide with plant capacities ranging from 30 to 1500 tpa.

Jan 1, 2014

By George B. Saunders

It is the purpose of this paper to point out conditions as they exist in the merchandizing of coal, to compare these conditions with methods in use by competitive producers of coal substitutes, and to present briefly some suggestions which may help the individual operator to market more coal in the immediate future, while we are waiting for the scientist and research worker, who are now busy on coal betterment , to produce in a practical way the results which they now write about in such glowing terms. While it may be unnecessary to call the attention of coal operators to the present deplorable condition of the industry, it might be well to impress upon our members in other branches of mining, as well as upon the public at large, the seriousness of the situation. Emerging from the war and the period of reconstruction that followed, the coal industry found itself with too many mines and too many men for normal conditions. To make matters worse, the interruptions in deliveries caused by strikes, the unfavourable publicity caused by socialistic propaganda, and the repeated governmental investigations, made the market a fertile field for coal substitutes which were not so handicapped. These substitutes were well advertised, and were marketed in an up-to-date manner, furnishing an example from which the coal operator could well profit. Now, whether or not there is agreement as to the cause or causes of this condition, there can be no doubt that we are today face to face with the fact that the sale of coal has not kept pace with the sale and use of other commodities. Had it done so, we would ere this have been able to take care of the surplus labour and work our mines at least approximately full time.

Jan 1, 1929

By J. Shibata, N. Murayama, H. Yamamoto

As one of effective usages of wastes discharged in the non-ferrous metal industry, the syntheses of AlPO4-5 and hydrotalcite were carried out using aluminium dross as a raw material. AlPO4-5 is an aluminium phosphate condensate with properties of zeolitic materials and large pore size. Hydrotalcite is an inorganic anion exchanger and has a layered structure of complex hydroxide. They were synthesized in an autoclave at high temperature and pressure. Various physical properties such as crystal structure, surface texture, and specific surface area were measured. AlPO4-5 can be synthesized from aluminium dross under hydrothermal conditions at 180°C-200°C, and 3h. At the same time, AlPO4-34 and non-porous AlPO4 were also formed as by-products. The crystals of AlPO4-5 have a hexagonal structure. Lt is desirable to heat the reaction product at around 550 °C to remove tri-ethyl amine. The specific surface areas of the reaction product before and after heat treatment at 550°C were 17.9m2/g and 358m2/g, respectively. Hydrotalcite can be obtained by a co-precipitation method from the aluminium dross and waste MgCl2 solution discharged in the aluminium regeneration process. Small amounts of SiO2, Al2O3, and Fe2O3 remain in the reaction product as an impurity component. The interlayer distance of the obtained reaction product is about 0.3 nm. Hydrotalcite changes to Mg-Al oxide during calcination at 500 °C for 3h, and then hydrotalcite is formed again by a rehydration operation. The physical properties of the reaction products obtained from the wastes were very similar to those from fresh reagents.

Jan 1, 2004

By E. L. Warburton

Before entering into a discussion of wet washing, it will be advisable to consider the various phases and conditions sur- rounding the problem of cleaning coal from the Corbin mines. Corbin is located in the south-east part of British Columbia in the Crowsnest Pass district, about 35 miles north of the International boundary and about three miles west of the Flat-head Range of the Rocky Mountains. It is reached by a rail-way, about thirteen miles long, from McGillivray, B.C., a point on the Crowsnest branch of the Canadian Pacific rail-way, owned and operated by the Eastern British Columbia Railway Company, a subsidiary company of Corbin Coals, Limited. The coal is assumed to occur here, as principally elsewhere in the Rockies, in the Kootenai series of the Lower Cretaceous, but owing to the disturbed condition of the surrounding country and, therefore, the magnitude of the geological study involved, this has never been definitely worked out. The coal is of the usual Crowsnest high-grade steam-coal, containing from 9 to 12 per cent. of ash, but appears to have 4 to 5 per cent. less volatile combustible matter than other coals being mined in this district, a representative analysis being about as follows:

Jan 1, 1924

By Y. M. Shneerson, V. M/ Shpaer, E. E. Zhmarin, A. Y. Lapin, E. M. Vigdorchik

This paper describes studies of zinc concentrate oxidizing pressure leaching using the method of mathematical modeling. The concept of a kinetic function was taken as a basis for mathematical modeling of the leaching process. The kinetic function describes dependence of the unreacted component share OJ on the relative time x (the relative time is the ratio of the test duration and the time of complete dissolution). This kinetic function is determined in accordance with the results of batch laboratory tests. The laboratory tests have been carried out on zinc concentrate produced from Kazakhstan zinc-copper ores. Zinc concentrate consisted mainly of three types of minerals: sphalerite (70%), pyrite (13%) and chalcopyrite (10%). Oxidation reactions of sphalerite, pyrite and chalcopyrite have been considered as principal ones. The kinetic characteristics of the process (kinetic function, reaction order, activation energy, duration of complete dissolution of the concentrate components) have been calculated in the course of laboratory tests. The mathematical model was used for estimation of the main technological leaching process parameters (such as process rate, degree of metals extraction, autoclave capacity, heat balance, etc.). Mathematical modeling based on the kinetic function concept allows safe designing of metallurgical equipment and scaling the technology to industrial capacity.

Jan 1, 2004

By A. V. Corlett

MR. C. S. Gibson: Mr. Chairman, I listened with much interest to Mr. Corlett's paper. Those of us who are directly engaged in mine ventilation and dust control are impressed by the improved atmospheric conditions to be derived from the use of methods of mining such as those in operation at Aldermac, which Mr. Corlett has just described, and those employed at Noranda. It is a well known fact that drilling-dust is one of the most potent factors in the production of silicosis in mines handling ores containing quartz, so that from that angle the use of diamond drills, instead of percussion drills, to drill ore for blasts in stopes is an important development. A second point which I think merits mention is blasting. Blasting, we all know, creates the most dust in a mine and the fact that you can drill ore for a large blast with diamond drills and fire it, say, on Saturday night, and then have all the next day to ventilate the workings, is a great advance in dust control. 1 have wondered if Mr. Corlett, or possibly those at Noranda, can en-vision the use of the diamond drill as a means of advancing cross-cuts and drifts, preparing stopes, etc. I believe it is a matter which is receiving considerable attention at the moment in some parts of the world and J thought it would be interesting to have Mr. Corlett's reaction on that point. MR. A. V. CORLETT: I am not quite so hopeful of using diamond drills as a means of drilling holes in the ordinary drift. Maybe some of the diamond drill men can give us some further information on that point. MR. R. D. LoNGYEAR: The diamond drill manufacturers are working on that problem, but until further work is done we have nothing definite to offer. Drilling holes with a diamond drill to compete with rock drills for advancing drifts and cross-cuts is a desirable objective, because of the elimination of drilling dust and the ability to cut a smooth bore of uniform diameter. To reach this objective, higher rates of penetration are required, which can only be achieved by discovering the optimum bit rotating speed, by reducing vibration, and by further improving the bits and machines. We are optimistic, but the problem is still largely in the research stage.

Jan 1, 1940

By Matej Petružálek, Václav Vavrycuk, Tomáš Svitek, Tomáš Lokajícek

The most common type of waves used for probing anisotropy of rocks in laboratory is the direct P wave. Information potential of the measured P-wave velocity, however, is limited. In rocks displaying weak triclinic anisotropy, the P-wave velocity depends just on 15 linear combinations of 21 elastic parameters, called the weak-anisotropy parameters. In strong triclinic anisotropy, the P-wave velocity depends on the whole set of 21 elastic parameters, but inversion for 6 of them is ill-conditioned and these parameters are retrieved with a low accuracy. Therefore, in order to retrieve the complete elastic tensor accurately, velocities of S waves must also be measured and inverted. For this purpose, we developed a lab facility which allows the P- and S-wave ultrasonic sounding of spherical rock samples in 132 directions distributes regularly over the sphere. The velocities are measured using a pair of P-wave sensors with the transmitter and receiver polarized along the radial direction and using two pairs of S-wave sensors with the transmitter and receiver polarized tangentially to the spherical sample in mutually perpendicular directions. We present an inversion method for elastic parameters describing general triclinic anisotropy. We demonstrate on synthetic tests that the inversion becomes more robust and stable if the S-wave velocities are included. This applies even to the case when the velocity of the S waves is measured in a limited number of directions and with a significantly lower accuracy than that of the P wave. Finally, we analyze velocities measured on a rock sample from the Outokumpu deep drill hole, Finland, including the error analysis for several levels of confining pressure.

Jan 1, 2015

By D. Berkley

Off-gas systems often become the limiting factor in production increase and environmental projects. Any upgrade or new off-gas project needs to address control instability issues, instabilities that can result in safety hazards, significant loss of system capacity and/or emissions to the environment [1]. In addition, the design engineer must optimize system configuration and equipment size for the new operating conditions, to have a technically feasible and economically viable project. Dynamic simulations can be used for addressing both the control stability and the design optimization issues. This paper illustrates how the dynamic simulation of transient processes and of their control system can be used in "real life" situations for these purposes, presenting the example of an electric furnace off-gas system design.

Jan 1, 2005

By Muhammad Tawalbeh

The calculated temperature history of a single particle of MgCl2 hydrates when it came in contact with fused salt electrolyte at 650 °C was determined using the measured heat transfer coefficient for the molten salt bath at 650 °C. The calculations revealed that the entire interior of the particle reached the temperature required for the formation of MgOHCI from hydrated MgCl2 in less than 2 seconds. This was much less than the time required for dissolution of the prills as observed in experiments. It is very likely that the formation of MgOHCI during prill dehydration and dissolution is a result of hydrolysis in the interior of the prills.

Jan 1, 2004

By R. B. STEWART

A few days ago, while reading a report of the late Dr. Robert Bell in preparation for this afternoon's meeting, I found some impressive figures concerning the magnitude of the Hudson Bay basin. From the waters of the Bay itself, this great territory extends eastward 500 miles, westward l,300 miles to the Rocky mountains, and southward to the source of the Red river. It has a width of 2,100 miles from east to west, and a length of l,500 miles from north to south. Its area is almost three million square miles. It is not, of course, my intention to review the natural resources of this vast territory, but to confine my remarks to that portion of it adjacent to the waters of Hudson bay. A number of erroneous ideas exist in the minds of many concerning this northern country, especially as regards its latitude and climate. Burwell, at the entrance of Hudson strait, is in the latitude of 60 degrees or roughly that of the north of Scotland. The southern end of James bay has about the same latitude as the northern end of Vancouver .island.

Jan 1, 1928

By O. Lundhede

Today, systems and machinery usually are designed to meet only one specific customer?s requirements. One reason for this is that underground automation and smart functions are often developed tightly together with a customer. This is natural, since risk and cost can be shared between the customer and the supplier. Nevertheless, when the automation product develops and the market increase this will cause problems: The highly specialized products will not fulfill the next customer?s demands. In order to cope with this problem, Atlas Copco works towards a common platform. Instead of designing solutions for specific customers, we will lift the abstraction and focus on standardized modules. These modules, or function blocks, can then be combined in a large variety of configurations. The benefits of combining modules into products are, for example: increased flexibility when options are available for many machines; easier commissioning and maintenance since less different spare parts and tools are needed; and easier operation since the user interfaces have a similar look and feel. This paper will present the ongoing work towards standardized modules. We will discuss how our Rig Control System (RCS) allows for modular design at Atlas Copco. RCS has number of standardized modules that are used in different surface and underground mining and tunneling equipment. These modules are also used for optional products such as, drilling, radio-remote control, and telematics systems.

Aug 1, 2013

By Forrest A. Kerr

Northern British Columbia is a term which probably conveys to various individuals quite different meanings. To the average person it signifies an area of indefinite size and indefinite position which may start at Prince Rupert, Stewart, or somewhere else, and end at Alaska or .the Yukon. Many people, in their conception, fail to encompass in their mind's eye that vast tract of land lying ~o the east of the panhandle of Alaska. Few realize that the area north of an east-west line through Stewart represents more than one-third of the Province and is, of course, the part most appropriately designated as northern British Columbia. This section, more especially the northernmost 100,000 square miles, from political, geographic, and economic viewpoints stands isolated perhaps more than any other part of British Columbia. Unlike the rest of the Province, it has no coast line, being cut off from the Pacific ocean by a narrow strip of Alaska. It is bounded on the north by the Yukon, and on the east by Alberta. In the south this northernmost 100,000 square miles is limited by a divide of rugged mountainous country separating the drainage basins of the Stikine and Liard rivers from those to the south.

Jan 1, 1929

By Ralph L. Rutherford

Geologists or mining engineers familiar with geology are frequently requested by mine operators to give correlation in-formation regarding some mining property with respect to an adjacent area on one at some greater distance. It is the object of this article to mention a few of the difficulties involved in securing this information and to point out some of the salient factors upon which correlation is dependent. In view of the nature of the following discussion, a brief statement of the general character of coal formations .. seems appropriate. Coal formations, by reason of their environment of deposition which is in fresh or brackish water, exhibit the features common to continental deposits, in contrast to those of marine deposits. Such deposits are characterized by rapid variation in thickness and in lithological character both later-ally and vertically. (Plate 1 A). They consist essentially of sandstones and clay shales with all gradations between them, and also a few beds of coal and frequently some conglomerates.

Jan 1, 1924