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By Robert Strachanm

The East Kootenay coal-field, situated close to the boundary between the provinces of Alberta and British Columbia, is composed of four small areas locally called the Crow's Nest Pass, the Upper Elk, the Flathead and Crown Mountain, and comprises an area of about 3 78 square miles. From eleven to twenty-five seams have been exposed of two feet and over in thickness, with a total thickness of about 200 feet of coal, and reckoning about one hundred feet to be workable, gives an estimate of coal available of about thirty-seven billion tons. The coal is a high-grade bituminous, occasionally tending towards anthracite, and the majority of the seams furnish a. very good quality of coking coal as well as an excellent steam coal. The coal-field is found in the mountain ranges in long narrow strips. The age of the fonnation and the thickness of the covering beds have had considerable influence on the character of the coal, and lateral pressure and disturbances in the process of mountain-building have wrought great changes. With such an abundance of coal, it has been a disappointment that the East Kootenay field has not figured larger industrially. So far only one portion of the coal-field has been utilized. This is the Crow's Nest, where, in 1898, the Crow's Nest Pass Coal Company commenced development. Access to the coal seams was easily obtained, the mountain creeks having eroded away the covering, and mines were driven into the coal seams. In that year about ten thousand tons of coal were produced from the mine at Coal Creek.

Jan 1, 1924

By J. McCreedy

"The addition of Portland cement to hydraulic sand fill has resulted in the production of stable and self-supporting cemented sand fill. The use of cemented fill in the mines of The International Nickel Company has resulted in substantial economies in timber requirements, de-creased dilution of ore and greater flexibility in mining methods.Coupled with special mining techniques, it has permit-ted mining by both cut-and-fill and shrinkage stoping methods to much greater depths than heretofore. The use of cemented sand fill has permitted revisions to undercut-and-fill mining which have significantly improved the efficiency of this method.Automated mixing systems have been developed for preparing cemented sand fill in surface sand plants on a continuous throughput basis. Control of cement-sand mixtures is obtained by the use of a mass flow measuring system and weighing cement feeders."

Jan 1, 1966

By M. Gimpel, R. Galler, T. Antretter, H. Kargl, R. Tichy, W. Ecker, M. J. Mikl-Resch, G. Pittino

"A computational method based on a continuum-mechanical approach to simulate rock cutting is developed and evaluated. The aim is to obtain the local loading acting at the cutting pick during operation. The explicit FEM is chosen to model the pick-rock interaction. The presented method takes advantage of (i) an advanced material model (ii) a robust contact algorithm and (iii) fast calculations due to parallelization. A damage-plasticity law is chosen and modified with user-subroutines. A user integrated element deletion routine evades critical mesh distortions. Infinite elements at the model boundaries avoid unrealistic deformation wave reflection.INTRODUCTIONExcavation in mining and tunneling is a costly and complex process. Special equipment such as the roadheader (Figure 1) is employed to cut the rock in the excavation process but high material strengths limit their usability (Tockner 1999). Nowadays a challenge is to extend their field of application to harder and more abrasive rock materials. The forces on the pick (Figure 2) are of great importance and determine wear and especially the efficiency of the machine. Figure 2 shows the principle of cutting and the predominant forces. The variation of pick geometry, cutting depth or attack angle will result in an alteration of these forces and determine the efficiency of the process (Tockner 1999). The mechanisms of rock cutting follow the principle of indentation (Kou et al. 1999). Directly under the indenter a hydrostatic stress state evolves causing the material to fail only due to crushing and fragmentation mechanisms. In the close surroundings large strains emerge and tensile cracks are formed but in a further distance the material behaves elastically."

Jan 1, 2015

By M. Gimpel, R. Galler, T. Antretter, H. Kargl, M. Mikl-Resch, R. Tichy, W. Ecker, G. Pittino

"A computational method based on a continuum-mechanical approach to simulate rock cutting is developed and evaluated. The aim is to obtain the local loading acting at the cutting pick during operation. The explicit FEM is chosen to model the pick-rock interaction. The presented method takes advantage of (i) an advanced material model (ii) a robust contact algorithm and (iii) fast calculations due to parallelization. A damage-plasticity law is chosen and modified with user-subroutines. A user integrated element deletion routine evades critical mesh distortions. Infinite elements at the model boundaries avoid unrealistic deformation wave reflection.INTRODUCTIONExcavation in mining and tunneling is a costly and complex process. Special equipment such as the roadheader (fig. 1) is employed to cut the rock in the excavation process but high material strengths limit their usability (Tockner 1999). Nowadays a challenge is to extend their field of application to harder and more abrasive rock materials. The forces on the pick (fig. 2) are of great importance and determine wear and especially the efficiency of the machine. Figure 2 shows the principle of cutting and the predominant forces. The variation of pick geometry, cutting depth or attack angle will result in an alteration of these forces and determine the efficiency of the process (Tockner 1999). The mechanisms of rock cutting follow the principle of indentation (Kou et al. 1999). Directly under the indenter a hydrostatic stress state evolves causing the material to fail only due to crushing and fragmentation mechanisms. In the close surroundings large strains emerge and tensile cracks are formed but in a further distance the material behaves elastically."

Jan 1, 2015

By J. Butra

The underground research presented in this paper was carried out in the two Polish copper mines: Rudna and Polkowice-Sieroszowice. The aim of the research was to determine stress field parameters. The measurement method and measuring positions are described as well as the measuring technique adapted to the geological and mining conditions of the Rudna mine and the Polkowice-Sieroszowice mine. The identified values and directions of principal stresses and horizontal stresses and their importance for optimization of mining operation and safety improvement are discussed.

Aug 1, 2013

By J. G. Pearson, F. H. MacDougall, A. G. Galley

The difference in age, host rock lithology, alteration and style of mineralization indicates a fundamental difference in the format ion of gold deposits in the Flin Flon and Amisk Lake areas. The Flin Flon area contains early quartz-sulfide-gold veins fo rmed within intermittently active fractures and later plutonic hosted deposits thought to be generated in a porphyry system. In the Amisk Lake area two types of gold occurrences are recognized: I) gold-quartzcarbonate- sulfide veins within or flanking fault zones and 2) structurally and stratigraphical ly controlled zones of dissem inated and vein type sulfide-gold mineralization within extrusive and intrusive rhyolite and dacite porphyries. Both types of deposits are set within supracrustal rocks. are accompanied by intense alteration haloes and were formed prior to the major deformation event suggesting an early, epigenetic hydrothermal origin.

Jan 1, 1986

By C. Hari Manoj Simha, J. Gholipour, M. J. Worswick

Due to the high pressures involved in the hydroforming process, friction and lubrication play an important role and can affect formability of the material. Tubes of A1Mg3.5Mn aluminum alloy, of 76.2 mm (3 inch) outside diameter and 2-mm thickness were considered in this study. Three kinds of lubricants, Al070, Hydrodraw711 and water, were applied to the tubes and tubes were hydroformed to burst in a square shape die cavity. The key process parameters were recorded during the tests. An in-house Gurson-Tvergaard-Needleman (GTN) damage-based material model, implemented in LS-DYNA, was used to model the process and predict the formability of this material. The applied axial loads and internal pressures recorded during the tests were used in the computations. The effect of different types of elements (solid and shell) with different constitutive models (von Mises and GTN models) in predicting the strain distribution is studied. The GTN damage-based material showed a good ability to capture necking and displacement histories in this process. Both predicted and measured results showed that the lubricant with lower coefficient of friction can effectively increase the comer expansion.

Jan 1, 2006

By Saravarim A.

"The aim in flotation systems is to control the grade and recovery of the product., numerical method or sampling and analysis is used to achieve this goal. Weakness of measuring instruments, lack of process knowledge, deficiencies in management and data processing in the control of flotation cells, has led the academic and industrial units to use numerical models. In this regard, using the results obtained from the experimental design carried out in the DTP line of Gol Gohar industrial and mining complex, a regression model was developed based on the analysis of variance. To present this model, after variance analysis of factors and interactions, all models were investigated and the final model was created based on 75% of the data. The model was tested with the remaining 25% of the data to confirm the goodness of the fit. The coefficient of determination for training and testing resulted 71% and 74%. Moreover, a feed forward back propagation neural network with different layers and neuron was used to model the results. The best network structure was 6-27-1 and the coefficient of determination for this network was 99% and 98% for training and test respectively. Given the complexity of neural network models and the relatively low accuracy of the regression model, neural network has a priority assuming we have access to a specialist. In addition, the results obtained from neural network can be used as expert systems to control and optimize the flotation cells.INTRODUCTIONThe primary objective of the flotation cell control is to maintain the product's (in this case tailing) recovery and grade, which represents the index for process efficiency and product quality. Continuous estimation of these indexes requires a significant amount of maintenance, and calibration of the continuous analyzers, in order to maintain an acceptable level of accuracy. Weakness of measurement equipment, lack of process knowledge and the general deficiency in management and processing of data in the flotation cell control, will lead industrial units to use smart methods such as mathematical models, regression and neural networks in near future (Panahi, Abdollahzadeh, & Sam, 2010). Artificial neural networks are inspired by the very complex structure of human brain in which millions of nerve cells solve problems or store information by communicating with each other. The duty of neural networks learning. It should be noted that learning in artificial neural networks is limited, and what is practically considered is the computing power of the network. A neural network consists of units called neurons, and has the capacity to handle a set of input data to produce a desired output data set. Each of these input and output data sets can be assumed as a vector (Soltanmohammadi & Noparast, 2006)."

Jan 1, 2016

By D. Atkinson

"Porphyry molybdenum-tungsten mineralization on the east flank of Hudson Bay Mountain crops out over 5 km2 and is intersected to depths of 2 km. Features such as a hornblende-biotite aureole, mineralogical zoning and dike, vein and fracture geometries within lithologies of the Middle to Lower Jurassic Hazelton Group and Cretaceous Skeena Group reflect an intrusive complex, the Upper Cretaceous to Early Tertiary Hudson Bay Mountain stock which has been intersected by drill holes. The stock is believed to be the mineralizing agent. A southeast-dipping granodiorite sill has been outlined by drilling within the Hazelton Group. Molybdenite and scheelite veins cut all rock types; however, the granodiorite sill hosts a higher density of fine-grained, banded, quartz-molybdenite and pegmatitic quartz-molybdenite veins reflecting a competency contrast between the intrusive sill and other country rock. Due to the relative abundance of these veins, grade is higher within areas of the sill. Above the 15000£ cross-cut 20.6 million tonnes grading 0.401% MoS2 and 0.041% W03 have been defined. During exploration of the deposit sampling procedures had to be adjusted because of the nugget effect attributed to drill intersections of banded and pegmatitic veins.IntroductionMolybdenite was discovered in outcrop at the foot of Kathlyn Glacier on Hudson Bay Mountain and first reported by the Geological Survey of Canada in 1944. The deposit has several names: Hudson Bay Mountain or Glacier Gulch, both after its location, and Yorke-Hardy after the original staker.The deposit is on the east flank of Hudson Bay Mountain, 9 km northwest of Smithers, west-central British Columbia, within NTS area 93L/14 (54° 49' North, 127° 18' West, Fig. 1). Hudson Bay Mountain, on the southern edge of the Bulkley Valley, is a dominant topographical feature reaching 2590 m elevation. Mineralization is partly overlain by the Kathyln Glacier which is visible from Highway 16. Access to the 3100 m of underground development is from a portal at 1066 m elevation on the east slope of Hudson Bay Mountain."

Jan 1, 1995

By A. J. Baer

"DEFINITION OF THE REGION AND ITS BOUNDARIESTHE EXPOSED PART OF THE GRENVILLE PROVINCE is the southeastern part of the Canadian Shield, characterized by crystalline rocks with K-Ar ages of about 1,000 million years. Its Canadian portion is bounded on the southwest by Georgian Bay •and by Paleozoic sediments south of a line passing through Orillia and Kingston, on the southeast by the St. Lawrence River valley and the north shore of the Gulf of the St. Lawrence, on the east by the coast of Labrador and on the northwest by the Grenville front, a linear tec-tonic feature that is a metamorphic transition zone and/or a fault. Rocks located to the southeast of the front have younger K-Ar radiom€tric ages than rocks located to the northwest of it.The region is formed of complexly deformed and highly metamorphosed crystalline rocks and in part differs from other areas of the Canadian Shield by the presence of large amounts of crystalline limestone and bodies of anorthosite."

Jan 1, 1970

By C. Van Den Heuvel, C. B. Van Buuren

BIOX® has been successfully demonstrated over the past 2 decades for the recovery of gold from refractory sulphide concentrates. To date 12 successful BIOX® plants have been installed in 8 countries spanning 4 continents with the 13th installation currently nearing completion in the Philippines. In 2010 BIOMIN introduced the ASTER™ process for improved water balances in commercial BIOX® applications by supporting tightening environmental legislation on water usage and availability in both arid and tropical regions. Previously, a common challenge for BIOX® plants was the inability to recycle thiocyanate containing water due to the low tolerance of the organisms. ASTER™, a biological thiocyanate and cyanide destruction process, renders a non-toxic solution for re-use in BIOX®. Two commercial ASTER™ plants are in operation with the 3rd ASTER™ plant under construction in the Philippines. A 3rd BIOMIN technology, specifically developed for double refractory ores is available for implementation. The HiTeCC process has shown considerable success on ores where competition from disseminated carbon has rendered ineffective gold recoveries. Through HiTeCC, gold is desorbed from the carbonaceous matter by manipulating the ionic strength and temperature of conventionally treated CIL product. One Australian commercial plant utilises HiTeCC while a 2nd installation is set for commissioning 4th Quarter 2014. BIOMIN’s premier solutions for refractory gold processing are described herein.

Jan 1, 2014

By J. R. Parga T., P. J. Valenzuela G., L. S. Quiroz C., P. Guerrero G., J. L. Valenzuela G.

"Pressure oxidation is a hydrometallurgical pre-treatment process used for refractory auriferous sulfide ores. In the work reported here, a refractory pyrite ore sample from the Mulatos mine, Sonora, Mexico was characterized. The sample was subjected to atmospheric cyanidation, and simultaneous pressure oxidation and cyanidation under different conditions of temperature and pressure. The mineral characterization showed that pyrite is the main species in the sample. The gold extraction tests were carried out in an 1-litre Parr pressure vessel at a temperature range of 90-120 °C, a pressure range of 87.5–150 psi (using oxygen), and a cyanide concentration range of 0.8-1.2 %wt. The gold extraction results showed that diffusion through product layer is the rate controlling step.INTRODUCTIONIn hydrometallurgical precious metals extraction, the most commonly used process is sodium cyanide leaching, as shown in the next reactions involving gold and silver (Fleming, 1992; Marsden & House, 2006):4Au(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Au(CN)2 -(aq) + 4OH- (aq) (1)4Ag(s) + 8CN- (aq) + 2H2O(l) + O2(g) ? 4Ag(CN)2 (aq) + 4OH- (aq) (2)“Refractory” auriferous ores or concentrates often contain gold and silver locked inside other sulfide phases such as pyrite. This renders cyanidation ineffective, so oxidative pre-treatments are used in order to convert the sulfide minerals into porous oxide minerals and make cyanidation work more efficiently. Reaction (3) shows the oxidation of pyrite in alkaline media and the formation of the porous oxide (Koslides & Ciminelli, 1992):2FeS2 (s) + 15/2 O2 (g) + 8H- (aq) ? Fe2O3 (s) + 4SO4 2- (aq) +4H2O(l) (3)A process of simultaneous chemical pressure oxidation and cyanide leaching for a flotation concentrate produced in the mine of Bacís, Durango, in Mexico, gave good results (Parga et al., 2007). In the study presented here, it was intended to use this treatment for a refractory pyrite mineral from the Mulatos mine in Sahuaripa, Sonora, Mexico, modifying variables such as pressure, temperature and cyanide concentration to find the best conditions for oxidation and leaching."

Jan 1, 2012

By M. Tanaka, H. Narita, K. Morisaku

"The selective separation of palladium (Pd), platinum (Pt), and rhodium (Rh) from a hydrochloric acid solution by solvent extraction was investigated using amide-type extractants, i.e., N,N,N’,N’-tetra-n-octyl-thiodiglycolamide (TDGA) and N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide) amine (BisAA). The separation experiments employed two separation schemes: (1) extraction of Pd with TDGA and that of Rh and Pt with BisAA; and (2) extraction of Rh, Pd, and Pt with BisAA. Separation scheme 1 achieved the highly selective separation of each metal. For separation scheme 2, Rh can be recovered prior to Pd and Pt, despite having a lower selectivity for Pd/Pt than separation scheme 1. INTRODUCTIONThe recent increase in the use of platinum group metals (PGMs) in industry (especially auto catalysts containing palladium (Pd), platinum (Pt), and rhodium (Rh)) has lead to their increasing waste; therefore, improvements in the recovery techniques for PGM have received significant attention. In metal refineries, PGMs are mainly separated and purified by solvent extraction (Cox, 2004). The extraction process used in INCO’s Acton precious metal refinery is one of the most famous commercial processes and is utilized worldwide. In this process, silver is first removed as a residue (AgCl), and then gold, Pd and Pt are extracted from hydrochloric acid (HCl) solutions using dibutylcarbitol (DBC), dialkylsulfide (DAS), and tri-n-butylphosphate (TBP), respectively. Finally, Rh remains in the raffinate (Barns & Edwards, 1982).The development of a successful solvent extraction process depends on the choice of the appropriate extractants. We have studied the extraction of PGM using N,N-disubstituted amide compounds (Narita, Tanaka, Morisaku, & Abe, 2004; Narita, Tanaka, Morisaku, & Tamura, 2006; Narita, Tanaka, & Morisaku, 2008a, 2008b). They are relatively stable against acids, and their metal extractability can be improved by changing the side chain length and/or introducing additional donor atoms like sulfur and nitrogen. We have recently found that thiodiglycolamide and an amide-containing tertiary amine have good extractabilities for Pd and Rh, respectively."

Jan 1, 2012

By D. Q. Li

"This paper briefly introduces problems that can occur in the design of rare earth separation processes and that require close attention during engineering design. Important factors must be considered include the following. 1) The separation process is primarily based on two points. One is the raw material composition and the other is the product purity requirements. 2) Optimization of the rare earth separation process requires optimization of the flowsheet configuration and each process parameter. 3) The separation of heavy rare earths is performed under non-equilibrium conditions. 4) The radioactive elements uranium and thorium must be removed from the feed to separation. 5) Process economy and environmental protection must be considered together in the evaluation of any separation technology options. INTRODUCTIONThe importance of rare earth (RE) is well recognized in high-tech applications and sophisticated national defense technologies. RE is the treasure house of the 21st Century new materials. The RE separation processes developed using HEHEHP (P507), P507-alcohol (ROH) and naphthenic acid (NA) have been widely applied in China. These processes have led to industrial production of all of the individual RE with up to 4N (99.99%) or higher purity (Li, Wan, Lin, Xie, Lin, & Wang, 1980; Li, Wang, & Xie, 1985; Li, 1995; Li, Wang, Meng, & Li, 2005). In order to achieve the best economic and environmental benefits, this paper discusses several problems to which attention must be paid in the design of rare earth separation process."

Jan 1, 2016

By Jan W. Merks

The objective of metrology in mineral exploration is to derive unbiased confidence limits for masses of metals contained in reserves and resources. Sets of test results for gold and silver determined in pairs of interleaved bulk samples give unbiased confidence limits for the central value of each metal. The same sets of test results show how to verify spatial dependence by applying Fisher?s F-test to the variance of a set and the first variance term of the ordered set. A significant degree of spatial dependence gives a higher degree of precision for the central values of gold and silver. Plotting variance terms of an ordered set against the variance of the set and its lower limits of asymmetric 99% and 95% confidence ranges gives a sampling variogram. Sampling variograms put in plain view where spatial dependence in sampling units or sample spaces dissipates into randomness. The application of statistical methods to test results for sets of ordered core samples within boreholes, and for sets of ordered ore volumes within profiles, plays an important role in defining reserves and resources.

Oct 1, 2009

By Greg Baiden

Telerobotics focused on mining is currently being introduced into production systems around the world. Mining companies in Canada, Sweden, South Africa and Australia have tended to lead the international charge to this form of technology for mining. While this introduction is taking place a few basic questions have yet to be answered. How many machines can a single operator run? How many types of machines can a single operator run? A new Canadian Research Chair in Robotics and Mine Automation has been established at Laurentian University. This chair will investigate these questions and many more through a series of experiments in a newly established telerobotics laboratory that connects Laurentian teleoperation workstations to model mining machines at Cambrian college?s eDome. The laboratory will support many experiments allowing researchers to physically run multiple robot scenarios differing the numbers and types of machines at one/quarter scale. Further experiments are being designed to investigate the potential for managing time delays in telerobotics. This paper describes the laboratory, experiments and some preliminary results.

May 1, 2003

By Z. Zhao, B. Li

"Fractures are the key channels for fluid flow and mass transport in fractured rocks of low/negligible matrix permeability. In single rock fractures, surface roughness causes fluid flow in tortuous paths, and reduces the overall fracture conductance. A number of empirical models have been proposed to relate the reduced hydraulic aperture to the mechanical aperture due to surface roughness, which were revisited and compared. Using two of those relationships between hydraulic apertures and mechanical apertures, we studied the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks. The results show that fracture roughness can affect the flow rates and residence time to varying extent, mainly depending on the empirical models between hydraulic apertures and mechanical apertures. However, fracture roughness has negligible influences on the general patterns of fluid flow (channeling) and solute migration (e.g., travel paths and shape of breakthrough curves). This is because the connectivity of a fracture network is mainly determined by other geometrical parameters (fracture positions, orientations, and lengths), rather than roughness or apertures. INTRODUCTIONIn fractured crystalline rocks of low or negligible matrix permeability, fluid flow and contaminant migration mainly occur within the connected fractures. An understanding of fluid flow and contaminant migration in fractured rocks is a crucial issue in many deep underground projects, e.g. underground repositories for radioactive waste, CO2 sequestration, enhanced geothermal systems, oil and gas production, etc. Rock fractures are typically rough-walled, and surface roughness appears to have first order control on the mechanical and hydraulic behavior of single rock fractures (Boutt et al., 2006).It is well known that the mechanical aperture of a rock fracture is usually larger than its hydraulic aperture, due to fracture surface roughness (Tsang and Witherspoon, 1983). However, for naturally fractured rocks including numerous discontinuities, the effects of this reduced hydraulic aperture in local fractures on macroscopic fluid flow and solute transport in complex fracture systems still remain unclear. Many previous studies assumed identical hydraulic and mechanical apertures in discrete fracture network models for simplicity (Min et al., 2004; Zhao et al., 2011). Therefore, the main objective of this study is to evaluate the influences of local surface roughness of fractures on fluid flow and solute transport processes at the macroscopic scales of fracture networks, by employing the empirical models that relate the hydraulic aperture to the mechanical aperture."

Jan 1, 2015

By Qin-yong Ma, Jing-shuang Zhang, Bo Han, Pu Yuan

In order to improve the utilization rate of blasthole and blasting effect in vertical shafts, 5 kinds of millisecond blasting model tests with three circle vertical blastholes have been conducted in various delay times with concrete as model material. The blasting effects of millisecond blasting model tests are investigated from cutting volume, cutting depth, and blasting fragmentation, then a reasonable delay time is obtained. In the middle of concrete model, there are 4 blastholes uniformly distributed in the first circle, 6 blastholes uniformly distributed in the second circle, and 10 blastholes uniformly distributed in the third circle. Each blasthole is charged with one millisecond delay electric detonator, and the rest is blocked with stemming. The depth of blastholes in the first and second circle is 180mm, which is 20mm deeper than those in the third circle. After initiation, the blasting cavity is cleaned up, then the cutting volume and cutting depth are measured. Meanwhile, the blasting fragments are gathered and have analysed by function Rosin-Rammler. The test results show that when the inner two circle blastholes initiated simultaneously and the third circle blastholes initiated with millisecond delay, the reasonable delay time is 50 ms. At this time, the cutting volume and cutting depth of blasting model are 3920 cm3 and 68 mm respectively. The fragmentation indexes of blasting fragments, X50 and X80, are 53.2 mm and 74.6 mm respectively. While when all three circle blastholes initiated with millisecond delay, the reasonable delay time is also 50 ms. At this time, the cutting volume and cutting depth of blasting model are 10705 cm3 and 118 mm respectively. The fragmentation indexes of blasting fragments, X50 and X80, are 51.0 mm and 81.7 mm respectively. The researches indicate that for millisecond blasting with multiturn blastholes, the reasonable blasting scheme is multiturn blastholes initiated in millisecond delay and the reasonable delay time is 50 ms.

Jan 1, 2015

By Takayuki Takasugi, Naoya Masahashi, Yasuyuki Kaneno, Satoshi Semboshi, Yusuke Kadoi

Cu–Ti alloy wires doped with and without a small amount of Ni were fabricated by over-aging and using intense drawing procedures. For both the Cu–Ti alloys with and without Ni doping, the over- aged microstructure was occupied fully with a coarse lamella of Cu solid solution and β-Cu4Ti plates precipitated discontinuously by grain boundary reactions. The full-lamellar microstructure was developed much more rapidly by aging in multi steps at 873 K to 723 K rather than by isothermal aging at 723 K. Ni doping in Cu-Ti alloy was also effective to accelerate the formation of the lamellar microstructure. When drawing the over-aged alloy with inferior hardness but superior electrical conductivity, the strength increased steadily and eventually exceeded that for the wires drawn from the peak-aged alloy. In addition, the electrical conductivity of the wires drawn from the over-aged alloy was always much greater than that from the peak-aged alloy. Eventually, the procedure of over-aging, followed by intense drawing, could enhance both the strength and electrical conductivity of Cu-Ti alloys, whichever they contain a small amount of Ni or not, rather than the conventional peak-aging and drawing process. INTRODUCTION Cu-based alloy wires, which have an excellent combination of strength and electrical conductivity, have attracted extensive attention for highly mechanically stressed electrical devices, such as conductive lead wires and wires in suspension springs. Cu-Be alloys are widely used for such electrical components owing to their combination of strength and electrical conductivity among industrial Cu-based alloys. However, since beryllium is potentially toxic and also a rare element, substitute materials for Cu-Be alloys have been searched for several decades. Age-hardenable Cu–Ti based alloys have been proposed as candidates because their mechanical and physical properties are comparable to those of Cu-Be alloys; however, their electrical conductivity is inferior (Datta & Soffa, 1976; Soffa & Laughlin, 2004). In order to satisfy the requirement of downsizing and streamlining electrical devices, further improvement of the mechanical and electrical properties of Cu–Ti alloy wires is needed. Age-hardenable Cu–Ti alloys, which contain approximately 3 to 6 at.% Ti, are typically prepared using a solid solution treatment above 1100 K and then aging at a moderate temperature of 700 K to 800 K. It has been revealed that the microstructural events during aging progress as follows (Soffa & Laughlin, 2004): (1) compositional modulation of the parent supersaturated Cu solid solution in an initial aging stage (Laughlin & Cahn, 1975), (2) continuous nucleation and growth of fine needle-shaped precipitates of metastable β’-Cu4Ti with a tetragonal structure in a peak-aged stage, and (3) discontinuous precipitation of cellular components laminating the plates of a terminal Cu solid solution and stable β-Cu4Ti with an orthorhombic structure at the grain boundaries in an over-aging stage. It has been also accepted that the highest number density of dispersed fine β’-Cu4Ti needles should contribute to maximal strengthening. On the other hand, decease of the strength in the over-aging stage occurs due to the replacement of the fine β’- Cu4Ti needles with cellular components containing coarse β-Cu4Ti plates, while the electrical conductivity is significantly enhanced due to the depletion of solute Ti in the Cu matrix. This suggests that a combination of strength and electrical conductivity for age-hardenable Cu-Ti alloys is in a trade-off relationship, and that innovative improvement of both properties might be limited to tuning the aging conditions.

Jan 1, 2019

"THE GOLD MINING REGION of Timmins - Val d'Or, astride the Ontario-Quebec border, has long suffered the effects of rising costs during the period when the U.S. price of gold was fixed at $35 per ounce. The federal government, through such assistance programs as that set up under the Emergency Gold Mining Assistance Act (E.G.M.A. ) in 1948, has subsidized the gold mining communities of Canada for a total of over $300 million to March 31, 1972. Of this, the Timmins - Val d'Or ""gold belt"" has received more than twothirds, almost $220 million. In spite of these continuous subsidies, only 12 gold mines are still producing in the Timmins - Val d'Or belt, whereas 71 mines have received subsidies for some period since 1948. The vital question is how the communities previously supported principally by the mining of gold will survive in the long run, as many of the older mines either are already depleted or are quickly becoming so. With the rising price of gold on the 'free market in recent months, prospects look a little brighter for the time being. Even with the increased official price of U.S. $38, which made the maximum government subsidized price about $48 per ounce, gold mines have not sold any gold to the government since January 1972 and some stopped doing so months before that. The populace of the region has not been enthusiastic about relocation nor about extensive retraining programs in the past and probably will not be in the future. So, when the remaining gold mines become depleted, the old problems of community depression will remain."

Jan 1, 1973