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By J. Baumbach, H. Bombach, M. Stelter

"Today technical electro-refining processes for copper exclusively use sulfuric acid, for silver refining nitric acid electrolytes are used. Sulfuric acid is characterized by very good chemical and electrochemical stability, good conductivity and low cost. The disadvantages of sulfuric acid are the precipitation of fine-grained cathodes with smooth surfaces only by using additives like glue, thiourea and chloride. In case of silver the electrolyte is electrochemical unstable and bears the risk of the formation of toxic NOx when pH is too low. A second disadvantage is the form of electrodeposition of silver as dendrites with their removal from the bottom of the Möbius cells.This paper reports the results concerning the application of an alternative electrolyte in copper and silver electro-refining. At first the electrolyte was characterized by the determination of current density potential curves. Electrolysis experiments were performed in laboratory scale using technical anodes for copper and synthetic anodes for silver. During the copper tests the solubility of contaminations from the anodes and the amount and chemical composition of the anode slimes were determined. Moreover the influence of current density, electrolyte temperature and the effect of several additives on the precipitation and chemical purity of the cathodes were investigated. In all experiments cell voltage as well as anodic and cathodic polarization was measured and current efficiency and specific energy consumption were calculated. A comparison with the results with those of tests using conventional sulfuric acid electrolyte shows the advantages and disadvantages of both systems, additionally the technical application chances and limitations for the new electrolyte. This electrolyte enables the precipitation of smooth copper cathodes with low silver and sulfur concentrations even at lower temperatures without any additive. For silver refining the electrodeposition of compact silver sheets is possible, that can be stripped comparable to those in copper electro-refining."

Jan 1, 2016

By Art Hamilton

Abstract -The Zn-Pb-Cu-Ag ore deposits of the Boundary and N-5 zones near Bathurst, New Brunswick, occur in a polydeformed volcano-sedimentary sequence that is part of the Ordovician Tetagouche Group. Massive and disseminated sulfides are hosted by an argillaceous to cherty sedimentary sequence that is stratigraphically underlain by a siliceous fragmental unit and is overlain by a feldspar-rich crystal tuff and related tuffaceous rocks. The deposits have a low iron sulfide con­ tent relative to that of most stratabound sulfide deposits of the Bathurst-Newcastle mining district. The ore is commonly associated with chlorite- and talc-rich sediments. The N-5 deposit is considered to be the fault-displaced extension of the Boundary deposit. The Boundary deposit is estimated to contain 891 000 t grading 3.310Jo Pb, 7.96% Zn, 0.32% Cu and 44 g/t Ag; the estimate for the N-5 zone is 330 000 t grading 3.24% Pb, 7.15% Zn, 0.33% Cu, and 37 g/t Ag. The ore is processed at 1000 tpd at the Heath Steele mill.

Jan 1, 1992

By X. S. Yuan

With the production increase of Oil Sand in Fort McMurray Alberta, more efficient tailings disposal has become a priority for Syncrude Canada Ltd. A lot of work on tailings research and development has been compiled to determine the most effective deposition to increase reclamation options, water re-use and thermal energy recovery. Efficient flocculation of fine oil sand tailings is the key technology for thickening. It was identified that flocculation of fine transition/marine ore tailings using a single flocculant was not effective. The thickener overflow contains 1-4% solids content compared with the target solids content of <0.5% obtained with Estuarine ore. As a result, novel processes for treatment of fine transition/marine ore tailings have been developed at Syncrude Bitumen Production Development since June 2004. While the conventional processes using a single flocculant, a single coagulation, or a coagulant-flocculant combination was ineffective for transition and marine ore tailings, the new processes including Coagulation-Flocculation-Coagulation (CFC), Flocculation-Coagulation (FC) and Flocculation-Coagulation-Flocculation (FCF) were acceptable options. The key components of these technologies consist of the recipe of chemicals and their adding sequence. With these technologies, almost all sub-micron clay minerals are aggregated together and settle as a whole, resulting in a clear supernatant of less than 0.1% solids.

Jan 1, 2006

By R. G. McDonald

"High iron solution concentrations often result in the formation of basic ferric sulfate during the high temperature oxidation of sulfidic materials such as base metal and refractory gold concentrates. Consequently, the “Hot Cure Process” followed by limestone neutralization is required to facilitate subsequent processing and/or disposal of the leach residue. The present paper discusses strategies that can be employed to influence the composition and nature of the high-iron content leach residues produced during pressure leaching.INTRODUCTION Control of iron deportment in hydrometallurgical processing remains a key challenge for a range of reasons. Strategies generally relate to the control of conditions under which iron is optimally rejected (Demopoulos, 2009). Supersaturation provides the driving force for crystallization and this can be controlled by a number of factors that include (1) pH and/or Eh control, (2) the presence of matrix anions and impurities, (3) dilution, (4) complexation and dissociation and (5) manipulation of the rate at which the metal to be precipitated is released to solution. Each of these factors is impacted by temperature. Good control of crystallization is essential to the control of precipitate properties such as the degree of crystallinity, stability, particle size and quality which covers both the extent of impurity uptake and suitability of the precipitate for waste disposal. The quality and properties of iron precipitates in turn can impact downstream processing. It is the aim of this paper to discuss the generation of iron-containing residues produced during the pressure oxidation of sulfidic ores and concentrates and how the nature of these can be controlled to potentially facilitate further processing. A brief overview of several related topics will now be given and include, where relevant, discussion of work undertaken in our laboratories. In addition, brief discussions of selected process options that enable good control of iron rejection will be provided."

Jan 1, 2016

By Bing Li, Kai Liu, Yongcheng. Zhao

With the ongoing development of copper smelting technology, the improvement of environmental emission control and achieving an automated continuous copper pyrometallurgical process have become the key development goals for copper smelting. The double bottom blowing continuous copper smelting process combine bottom blowing smelting (SKS) and bottom blowing converting (BCC) process and fire refining as “three-connected furnaces” arrangement is a pyrometallurgical process independently developed by China’s ENFI which can continuously produce copper from raw material through to anodes. This technology can improve energy efficiency and reduce environmental emissions for the overall copper smelting and converting process. This paper discusses the engineering characteristics and production practice of the SDIC Jincheng Metallurgical Project, which operates SKS smelting and BCC converting process with “three-connected furnace” arrangement for the first time in the world. Advanced engineering concepts and tools were used to optimize the configuration during the project engineering stage. The operation shows that the process has good environmental performance, reduced energy consumption and high level of automation, which is a new choice for copper continuous smelting process. INTRODUCTION One of the most important developing trends for the overall copper smelting process is to develop a continuous operation. Continuous copper smelting can maximise energy efficiency in copper concentrate and make full use of the rich heat treatment system. Cold charge and a part of low-heat-generating materials, which are processing with additional equipment in traditional copper smelting process, can be processed with rich reaction heat in continuous copper smelting and converting process to achieve good economic benefits. Yuan and Wang (2017) noted that SKS+BCC copper smelting process can reduce the secondary SO2 emissions compared with discontinuous copper smelting process, which required transportation of melted matte by matte ladle and may cause secondary pollution. The continuous copper smelting process can also reduce the generation of intermediate cold materials.

Jan 1, 2019

By Therese Schneck

The presence of xenon isotopes from in-situ spontaneous fission of short-lived Pu244 has been confirmed in Hadean detrital zircons from Western Australia. Hadean and meteoritic zircons can retain secondary overgrowths developed after primary cristalization at 3.97-3.94 Gyr. On the moon, the metal grain in sample 66095,78 is mantled by troilite, schreibersite and cohenite. High chlorine content FeCl2 is deposited around metallic FeNi. The magnitude of Pollonium-210 to Radon-222 on the Aristarchus plateau spectrum indicates a past greater activity. The Earth Moon system from Nb/Ta systematics is consistent with a Moon iron core delayed to 3,9 Gyr.

Aug 1, 2010

By R. F. Favreau

"After a blast, the volume of the blasted rock normally occupies more space that it did before the explosion. The degree of such swell significantly affects the efficiency of digging the muck with a shovel or dragline. This paper explains why swell occurs, and describes the new subroutine SWELL of the blast simulator BLASP A which can simulate blast-induced swell. Results are also presented which display the effect of various blasting parameters on the degree and distribution of the swell within the muck pile of a bench blast. IntroductionIt is a common opinion that fragmentation is the most important of the various aspects which affect the efficiency of excavating rock with explosives. This paper proposes that, in fact, displacement and swell of the blasted rock are as important as fragmentation if the excavation process is to be rapid and efficient. It must ""a priori"" be recognized that a minimum degree of fragmentation is indeed necessary. For a given shovel or dragline, this minimum degree of fragmentation may be defined as follows: even the largest fragment of rock must be easily contained within the bucket. Once this criterion is met, however, there are good reasons to believe that displacement and swell take over as the key criteria which influence the rate of mucking, in cubic metres/hour. If the muck pile is not well displaced and swelled, the teeth of the bucket have difficulty penetrating between the rock fragments even if fragmentation is good and, as a result, the mucking is slow and inefficient. The purpose of this paper is to use computer simulations on the model BLASP A to demonstrate the effect of the blast design parameters on the displacement and swell of the blasted rock."

Jan 1, 1993

By Kenneth L. Graham

Horizontal directional drilling from existing underground workings will greatly reduce, if not replace, surface exploration drilling. Diminishing ore reserves along with increasing difficulty in acquiring access and permitting of drilling surface holes requires a change in procedure. The length and direction of the required long holes is site specific, but once determined could be quickly mobilized. Data would be available for a much more timely evaluation without any surface disturbance and required reclamation issues. Preplanned directional drilling from underground will also provide an evaluation of already inconsistent uranium deposits located under surface terrain that is inaccessible to surface drilling.

Aug 1, 2010

By C. Andrews

Fuel cell testing requires fully automated operation, on-site configuration of tests, and real-time monitoring for performance and failures. Balancing the flexibility and programmability of a test station with reliability, cost, and user interface can be a daunting challenge to the test equipment engineer. Endurance testing of fuel cells requires the highest level of reliability for test stand hardware and software without compromising automation capabilities or users interface. Techniques for implementing an ultra-reliable test platform addressing hardware limitations, sophisticated watchdog monitoring to prevent inadvertent shutdowns, and software limitations (e.g., balancing a highly-functional graphical users interface with reliability) are presented.

Jan 1, 2005

By C. Cekerevac

The paper addresses some geotechnical issues related to the construction of the Deriner dam and HEPP. Design considerations and rock stabilization measures are presented for the excavations which took place in a highly fractured and weathered rock mass prevailing on site. Particularly, the shallow excavations for the overflow spillways tunnels are discussed. These present huge openings that are 12 m wide and 18 m high in portal areas, with an overburden of approximately 20 m, for which numerical finite element analysis and structural discontinuity analysis have been performed to ensure safe excavation process and future operation.

May 1, 2009

By Murray W. Grabinsky

This paper considers thickening mine tailings to dense non-segregating slurry or paste for surface disposal. The driving motivation for this initiative is the elimination of ponds, reduction in containment dams and significant decrease in water being sent to the tailings basin. This inherently reduces risks of environmental and structural failure. Some of the engineering challenges in creating a stable stack of thickened or paste tailings are identified, and possible field and laboratory testing techniques in support of design are discussed. Finally, the integration of monitoring activities into the ongoing management of the surface disposal site is considered.

Nov 1, 2002

By A. Fortin, C. Fréchette, M. Kreuh

Éléonore project is a gold ore processing plant at a mine site located near James Bay, Quebec, Canada. SNC-Lavalin was mandated by Goldcorp to perform EPCM services on the ore processing plant and permanent infrastructures of the project following an internal pre-feasibility study. The project incurred considerable challenges due to fast-tracking from a pre-feasibility to detailed engineering and construction. The paper reviews how the EPCM was carried out. Some of the challenges resulting from skipping the feasibility study stage are discussed. The paper also presents how multiple offices across Canada were used for the engineering design.

Jan 1, 2015

By W. L. Stuewe

The Dominion Steel and Coal Corporation requires enormous quantities of bricks each year for its Sydney steel plant operations. Clay brick of all types are purchased, while silica brick is made in the Company&apos;s plant at Sydney. A description of this plant was given in a paper presented by H. B. Gillis and F. C. Morrison at the 1938 Annual General Meeting of the Institute. The rock used to make silica brick was for years obtained from a quarry at Leitches Creek, about eighteen miles from Sydney. Due to the gradual deterioration of this deposit, the Corporation was forced to look for other sources of supply. In 1945, the problem was presented to the Nova Scotia Department of Mines and, through the efforts of Dr. A. E. Cameron and Mr. J. P. Messervey, an examination was made of a silica-rock deposit some six miles northwest of Yarmouth, N.S. Preliminary samples proved satisfactory, and arrangements were made with the Department of Mines to ship to the steel plant at Sydney a fifty-ton car load for the purpose of further testing. Brick made from this sample shipment stood up very well in the furnaces. At the same time, two hundred and fifty tons of silica rock from a deposit at Lac Bouchette, Que., were purchased from the Industrial Silica Corporation, and brick made from this rock also was found suitable for our requirements. Comparative transportation costs, however, led to a decision to open the Yarmouth deposit. The silica rock, or quartzite, of this deposit outcrops at Chegoggin point along what is known as the &apos;Pembroke shore&apos;, a northerly trending section of the coast-line at the extreme southwest of the Province, in Yarmouth county. The country here is fairly flat, with elevation averaging about twenty feet above high tide, and is for the most part mantled by a growth of brush and some scrub trees, chiefly small fir. Bed-rock is generally concealed beneath three to four feet of clayey soil, but scattered outcrops of the quartzite indicated that a band of this rock, some 260 feet wide, extended inland in a northeasterly direction from Chegoggin point at least to Utleys lake, a distance of about three miles.

Jan 1, 1947

By S. F. LEAMING

Jade occurs with alpine-1ype serpe111iniIes in a be// of middle Paleozoic to Triassic rocks extending from southern British Columbia in10 Yukon Territory. Most known deposiIs are in BriIish Columbia and are associa1ed wi1h the Cache Creek Group. Jade deposits are generally small len1icular masses 1ha1 lie along con1acIs beIween serpenIinites and various countIy rocks; some are 1ec1onic inclusions wi1hin se1pen1ini1es. Qualify and quan1i1y of 1he jade varies widely. Deposi1s occasionally, but rarely, reach 3,000 /Onnes. The ma1erial may be rendered non-commercial by .frac1ures, impuriIies, inferior colour and poor IexIure. Because unit value of jade can approach $80.00 per kg, greaI incen1ive exisIs 10 exploi1 1his resource. Successful commercial operations, however, depend on large- *A more detailed version of 1hi paper occur in Leaming (1978). PHOTO I . Sawn blocks of nephrite ready for shipping. 270 volume sales, for which $6.00 to $15.00 per kg is more realistic. Many undiscovered jade deposits undoubtedly remain in the Canadian Cordillera.

Jan 1, 1984

By M. J. Young, C. A. Aird

"The Gem molybdenum prospect is situated at the head-waters of Clear creek, between the Fraser river and Harrison lake, about 30 miles north of• Harrison Hot Springs, B.C. Clear creek follows a deeply eroded fault zone southwesterly through the center of the claim group. Elevations range from 2,000 feet in the creek bed up the steep slopes flanking the creek to a height of 5,500 feet. The property lies within an area underlain by schists and gneisses which strike from north to west in a broad fold plunging steeply to the northeast. This metamorphic complex has been invaded by numerous bodies of grano-diorite, much of which is gneissic. A granite plug, roughly 2,400 by 4,000 feet in size, has intruded this broad fold just west of Clear creek and encloses a circular breccia pipe 1,500 feet in diameter. In the breccia pipe, fragments of metamorphic rocks, granite and quartz monzonite porphyry are firmly cemented in a matrix of quartz monzonite porphyry. All the above rocks are cut by numerous fractures filled by vuggy quartz veins, many of which contain molybdenite. Attentien was first drawn to the area by a quartz vein, 18 inches in width, known as the Gem vein, which consists of several laminated bands of quartz and molybdenite. Since 1964, exploration efforts have been directed toward attempting to outline a large, low-grade type of molybdenum deposit."

Jan 1, 1969

By M. Mezbahul-Islam

Thermodynamic modeling of the Mg-Cu-Ni system is carried out as a part of multi component thermodynamic database for Mg alloys. This system is being modeled for the first time using the modified quasichemical model, which considers the presence of short range ordering in the liquid. The thermodynamic descriptions of the binaries Mg-Cu, Cu-Ni and Mg-Ni have been extrapolated to the ternary Mg-Cu-Ni system using Toop geometric model. The constructed database has been used to calculate and predict thermodynamic properties, isothermal sections and liquidus projections of the Mg¬Cu-Ni system, which showed very good consistency with the experimental data.

Jan 1, 2011

By L. Henry Smith, David C. Arthur

"The Williams Mine is Canada’s largest gold producer, with annual production of 450 000ounces from 2 300 000 tonnes of ore. Highly mechanized and automated underground mining practices are employed in order to achieve and maintain high levels of productivity and minimize costs.The mine ventilation system is modified to include a new vent raise and variable pitchvane-axial fan. This addition allows several fan installations underground to be decommissioned. A substantial net savings in installed horse power is achieved.Heating costs associated with under-ground ventilation air are a significant portion of mine operating costs. Air heating costs are substantially reduced by recovering heat from upcast exhaust air, minewater and compressor cooling circuits. This waste heat is used to supplement propane fired air heating systems for underground ventilation air. An additional benefit is the availability of a heat sink for summer cooling of the compressors.System design, energy savings data and payback calculations are presented."

Jan 1, 1996

By A. Gakwaya, K. Ba, M. Guillot, J. Levesque

"In the aerospace industry, parts requiring tight dimensional tolerances and high mechanical properties are often produced by forging. This forming process allows for an optimal use of the material and can produce high quality parts at a reasonable cost. Thanks to CAD techniques, it is now easier to predict flow profiles and in-process defects occurrence as well as wear of the forging dies. However, in order to determine the properties of the forged part with computer simulation methods, a good material constitutive law is a prerequisite. This paper presents a virtual manufacturing process modeling for the closed die forging of a workpiece performed with Abaqus. The hot closed die forging is a regular process applied to manufacture metallic components used in aerospace industry. In this forming process, the material flow and final properties depend on the microstructure evolution during the process that is why it is important to include the microstructure effects in the material model. Based on the stress-strain data measured experimentally, the material parameters of the standard (classical) Johnson-Cook constitutive model and of a modified Johnson-Cook constitutive law including the microstructure effects have been determined. The obtained simulation results are compared with the experimental results for validation.INTRODUCTIONDue to their good physical and mechanical properties such as ductility, fatigue strength, corrosion resistance and rupture, aluminium alloys are often used in the aeronautic and the automobile industries. In this work, we present the forging of an Al-Zn-Mg-Cu alloy, a high strength aerospace alloy recognized for his good combination of physical and mechanical properties. The forging process is simulated in Abaqus Explicit using both the standard Johnson-Cook law (Johnson & Cook, 1983; Hor, 2011; Lin et al., 2012), and its modified version as proposed by Andrade et al., (1994). The Johnson-Cook law offers the advantage of considering the coupled effect of the plastic strain, the plastic strain rate, the temperature of forging and the hardening effect. However, it is a phenomenological model which does not account for the effect of the microstructure evolution. In this work, a modified Johnson-Cook model implemented in a user subroutine is used. It includes the effect of the dynamic recrystallization phenomenon during the hot deformation. The dynamic recrystallization has a noticeable influence on the microstructure and on the properties of the material. The term dynamic means that the process starts and acts during the deformation and this is different from the static mechanism of recrystallization which occurs during an annealing and after cold or hot deformation. Since properties of the alloy used in this work are not readily available in the literature then characterization tests have been done at various temperatures and strain rates, in order to determine the thermomechanical properties and the material behavior during the process of hot forming, more precisely during the hot forging process."

Jan 1, 2016

By G. Yan

The gas diffusion layer (GDL) is one of the most critical components of the proton exchange membrane fuel cell (PEMFC) in achieving good performance. The GDL serves as a current collector, transport media for fuel and oxidant to the catalyst layers, a support for the catalyst layer and a medium for water management. In this paper, we will discuss the modeling and experimental measurement of the reactant distribution in the GDL and to the catalyst layer. This will be done for some new and advanced engineered GDLs. Novel optical technique which correlates measured data with reactant distribution are used. This technique combined with modeling allows optimal design of engineered GDLs.

Jan 1, 2005

By R. D. Lindsay

Originally the focus of Deak Resources Corporation Business Plan was to establish a method for treating small gold and possibly base metal mineral deposits located in the Kirkland Lake - Noranda area of Northeastern Ontario, Northwestern Quebec at a central treatment facility. Since the establishment of this original business plan in 1988 other processing options have availed themselves for handling the base metal ores off site at a central facility which may preclude their processing at Deak.The site selected for the Deak processing plant was Kerr Addison's Virginiatown operation. At the time this property was acquired from the Receiver following Golden Shield Resources' Bankruptcy in 1989 the mill had been processing in the order of 1, 100 SDT per calendar day through one processing module; a module originally designed to process 1,500 SDT/day of a free milling gold ore. This tonnage level however had not been achieved since 1966 when an average throughput of 1481 SDT per calendar day was recorded.In order to realize Deak's overall Business Plan it would be necessary to expand the mills processing capabilities to provide:(1) A 2200 SOT per day circuit capable of processing a free milling, medium work index gold ore;(2) a 1 ,000 SDT per day flotation and/or cyanidation circuit capable of processing refractory gold bearing materials containing refractory minerals (i.e. copper) that should be removed prior to cyanidation; and possibly(3) a 1200 to 1500 SDT/day base metal circuit capable of processing the broad range of Deaks' Base Metal Property ores. If this circuit were introduced it would be completed in two tonnage phases.Further, it was recognized when operations resumed under Deak in 1990 that the existing tailings dam was suitable for, and had sufficient capacity for additional gold tailings with necessary physical modifications and changes in disposal techniques (including the construction of containment storage cells) that would allow storage for an additional 3.4 million tons of gold ore tailings approximately 1.0 million of which has been deposited since 1990. The focus of Deak's long term tailings disposal strategy is to acquire the Barber Lake Basin which is currently adjoined to our main tailings system which will provide an additional 10 million tons of storage capacity.

Jan 1, 1993