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According to our experimental results, the following oxygen probe recommended, that is, the magnesia stabilized zirconia was employed as a solid electrolyte and Fe.FexO solid elect- rode was used as a reference electrode. Using such an oxygen probe, we tried to measure the oxygen potentials in molten metals, mattes and gases in the following fields of non-ferrous metal industry, molten copper in the side launder before casting, molten crude lead in the forehearth of ISP blast furnace, molten copper mattes in the forehearth of blast furnace and in the settler of flash smelting furnace, gas in the settler of copper flash smelting furnace and flue gas in the electric furnace for ferro-silicon. In the past ten years or so, many experi- mental results in the field of fundamental studies have confirmed that the equilibrium oxygen potential could be measured conveniently and accurately by an electrochemical method using a zirconia solid electrolyte. Recently, such an electrochemical technique has been also applied to a device for physicochemical invest- igation or process control in the non-ferrous metal industry. Such a device consists of an oxygen con- centration cell with stabilized zirconia, and it is commonly called an "oxygen probe" or "oxygen sensor".

Jan 1, 1980

By Jena, Anand S, Das R. P

Leaching studies were carried out on Indian Ocean manganese nodules using sulphuric acid as the lixiviant. By leaching the nodules with 8 per cent sulphuric acid for 12h at 100°C, copper and nickel could be completely extracted along with 50 per cent cobalt and 6.2 per cent manganese.94.2 per cent of the iron was also dissolved. To increase manganese and cobalt extraction, charcoal was used as a reductant. The role of charcoal was to reduce the manganese dioxide and render it soluble as manganese sulphate as well as to facilitate solution of the cobalt minerals associated with the manganese dioxide. Various leaching parameters were studied including acid concentration, amount of reductant, leach time, pulp density and leach temperature. It was found that by leaching the nodules with 10 per cent sulphuric acid at 100°C for 4h using 5 wt/wt per cent charcoal (0.05g of charcoal per g of nodule) almost complete extraction of copper, nickel, cobalt and manganese could be achieved. However, under these conditions all the iron present in the nodules was also leached.

Jan 1, 1989

The mineralogy of regolith material for which whole rock geochemistry has already been done can be used to better understand/rank the significance of geochemical anomalies. Case studies show that the secondary minerals of the regolith environment have quite different capacities to incorporate pathfinder and target elements, eg hematite appears to be a better host to Pb than goethite and Pb rich alunite-jarosite minerals are a better Ag host than mimetite. Thus correlations between elements in regolith material may be strongly affected by mineralogy. Understanding of the significance of a geochemical anomaly is frequently enhanced by knowledge of the weathering susceptibility of different minerals. For example, when a mineralogical sequence which does not correspond to the expected order is found (eg feldspar overlying weathered material without feldspars) it is possible that transported material is present in the profile. Such mineralogical information is particularly relevant as exploration continues into areas of thick regolith.

Jan 1, 1997

By Watsford R. M S, Hutton R

Following the delineation of significant extra ore reserves during 1990, the decision was made to expand production from 350,000 tonnes of run of mine ore per year to initially 600,000 tonnes increasing to 750,000 tonnes per year. The existing plant consists of a conventional three stage crushing plant followed by a heavy medium separation plant that produces a product prior to grinding. Grinding is conducted in three stages of ball mill in series. Alternatives examined for expanding production included: aò SAG mill - ball mill circuit replacing the secondary and tertiary stages of crushing, the heavy medium plant and the existing ball mills; and, upgrading of the existing circuit configuration.

Jan 1, 1991

By Baafi EY, Appiah HK

The Prestea Goldfields Ltd of Ghana, West Africa has produced over 170 t of gold with average grade of 11 g/t since 1912. The deposits occur in a wide shear zone which closely follow the Birimian-Tarkwaian contact. Both the Birimian and Tarkwaian systems are of Precambrian age. Underground exploration is carried out to delineate ore bodies by means of AX size diamond drilling at 50 m sampling intervals. After the orebody has been delineated, development work is carried out by exposing the gold reef. Channel sampling is then carried out at about 3 m intervals in both the stope and stope drives. A channel sample length is commonly 0.6 in, but may vary depending on physical characteristics of the reef. The values of channel samples are linearly combined to obtain the average reef or slope values and/or widths of the exposed sections. The sampling practice and methods of improving the efficacy of sampling at the mine are described.

Jan 1, 1976

By Biswas AK, Hayes P

During the reduction of iron oxide pellets in the blast furnace it has been found that catastrophic swelling (up to 300% volume increase) can occur. Although the burden preparation conditions can be designed to avoid this phenomenon the exact reason and mechanism of the swelling has yet to be clearly identified. Swelling of the burden is undesirable since it reduces the interparticulate voidage in the blast furnace thus reducing gas flow through the stack resulting in low production rates of iron. The present study differs significantly from previous experiments in that reduction is carried out on single crystals of wustite thus the problems of control of gas composition and specimen preparation are minimised. The microstructures formed on reduction have been examined by optical and scanning microscopy. Pure wustite and wustite doped with various levels of CaO have been examined after reduction in controlled CO-CO 2 gas mixtures at 968¦C. The catastrophic swelling on reduction coincides with the formation of an unusually open iron structure in which the iron appears as whiskers or needles as previously reported. The spacing and thickness of the needles are shown to vary with impurity content and gas composition. Metallographic examination has shown in addition, however, that the whiskers do not necessarily constitute the only product form of the iron produced and in CaO containing wustites with less than - 2% CaO there is a transition from needle growth to porous growth of iron. Thus the % swelling of the oxide particles is dependent on the initial size of the oxide grains. Samples of FeO - 10% CaO exhibited a previously unreported product inorphology associated with the nucleation of 2CaO.Fe203.

Jan 1, 1980

This paper introduces a classification of gold orebodies, and comments on the importance of cutting high grade values, the choice of an appropriate ore reserve method and the necessity for producing recoverable ore reserves by considering the mining policy. The author stresses the importance of obtaining the appropriate information from the data relevant to a particular deposit as opposed to transfering parameters from one deposit to another.

Jan 1, 1987

Most coal mines in Chongqing Area are highly gassy mines and liable to outburst of coal cnd methane. In order to harness mine environment and raise the Prodction capacity, methane predrainage is generally taken as a main preventive measure against outburst by all mines. In the recent ten years, the drainage volume per year has increased from 38.25 million m3 to mote than 100 million m3 with a volume over 12 m3 per tome of coal. In some mines, the draining rate is approaching to 50 percent, the rate in mining districts is up to 60 to 70 percent. The predrainage volume accounts for one fourth of total drainage volume. All these have effectively prevented the occurrence of coal and methane outbursts.This is the current situation of methane predrainage in coal mines in Chongqing area, the methods of predrainage to prevent outbursts and related parametres comprise:1. methods, technologies, supervision and effect of predrainage in different geological and mining conditions,2. the change of methane parametres pre-and post-drainage and the analysis of the effect of methane predrainage to prevent outbursts, and3. ways to improve the effect of methane predrainage.Thus the safety, reliability and production of Changqing Coal Mines will be enhanced.

Jan 1, 1991

By Gordon N

The in situ behaviour of claystone floors associated with the Wallarah, Great Northern and Fassifem Seams has been studied using a comprehensive suite of stress and displacement monitors. The instrumentation was supplemented by in situ and laboratory testing of the claystone materials. The instrumentation demonstrated that the presence of claystone floors is associated with floor heave, extra rib spall, and settlement of the pillar into the floor. Horizontal floor extensometers showed that the depth of extrusion of clay was limited to 1-2 in. A pore pressure transducer installed in a claystone floor demonstrated the possible existence of short-term undrained behaviour of the claystone. Long term swelling of destressed claystone was also documented. Settlement of pillars into claystone floors can be analysed using simple elastic theory. The assumption of plane strain is valid for most claystone thickness/pillar width aspect ratios. Floor heave can be analysed using bearing capacity concepts. However, it is considered that heave is the result of local bearing capacity failure in the rib spall zone. The advantage of this model is that the bearing capacity equation can be applied without resort to unrealistically high factors of safety.

Jan 1, 1992

By Veloso L, Alvarez O, David D

Cerro Colorado operations The Cerro Colorado Mine is located 150 km east of Iquique in the Atacama desert of northern Chile. The mine is wholly owned by Rio Algom Limited of Canada and produces copper metal using a bio leaching process. Tw

Jan 1, 1998

By Javad Koleini S M

The sources of arsenic compounds vary from As(lll) oxide produced from roasters to wastes containing arsenic from chemical or mineral processing plants. The removal of arsenic via co-precipitation with iron is currently proposed as an acce

Jan 1, 1994

By D L. Richardson, B Tiedt, C D. Morgan

Following residentsÆ concerns that the ongoing operations of Collinsville Coal (CCP) mine may be resulting in the release of contaminants, including products of acid mine drainage (AMD), into downstream environments, the Queensland Environmental Protection Agency (QEPA) issued CCP with a Notice to Conduct or Commission an Environmental Evaluation at Three Mile Creek. A key objective of the Environmental Evaluation was to assess the extent and magnitude of impacts to aquatic communities and their habitats. A multidisciplinary investigation examined a suite of physical, chemical and biological indicators to meet this objective. The study also aimed to identify contaminants of concern and the location of potential pollutant sources. Potential indicators of AMD, including elevated dissolved solids concentrations and low pH, were evident within the mine lease. However, significant differences in concentration of these indicators upstream and downstream of the confluence with Three Mile Creek were not observed. Although only proxy indicators of AMD contamination, these results suggest that the extent of impacts downstream is minimal. For the purpose of this study, physio-chemical indicators were selected on the basis of those best likely to provide an understanding of the likelihood of contamination, within the constraints of readily available long-term monitoring data. Ecosystem health indicators were adopted to supplement the existing data set and provide a more æroundedÆ perspective of water quality attributes within the system, generally unattainable by standard physio-chemical assessments. In contrast to AMD products, sediments were considered more likely to have a widespread impact on aquatic ecosystems. Waterways throughout the study region, including those unaffected by mining, have been affected by broad-scale sedimentation and were typically highly turbid. Due to the many diffuse sources of sediment potentially liberated within the catchment, the contribution of the mine compared to other land uses on total sediment loads entering streams is difficult to determine. This is clearly a major management issue for mines throughout the Bowen Basin. Streams of the central Queensland region display enormous variability in water flows and physio-chemical characteristics over a range of spatial and temporal scales. This variability presents major difficulties in distinguishing anthropogenic impacts from natural variability (noise). Despite this variability, impact monitoring by mines in the central Queensland district has tended to focus almost entirely upon physio-chemical indicators. The results of the present study indicate that a multiple indicator approach to environmental assessment is more useful for separating mine related impacts from natural ænoiseÆ and impacts from other land uses. In the absence of such information, by adopting the precautionary principle of Ecologically Sustainable Development (ESD), there is potential for an environmental impact to be incorrectly attributed to mining when other activities in the catchment may be contributing to changes in stream æhealthÆ.

Jan 1, 2003

Spatial continuity as described by a variogram is a reflection of the underlying mineralisation/geology. Modelling of the spatial continuity (variogram) must account for both the quantitative data (ie sample grades), on which the variogram calculations are based, and the qualitative information as provided by the geological interpretation. An understanding of the geology and the variogram interpretation tie together the sample values and allow us to go beyond the actual data (Journel, 1995). Variography makes geology transportable and allows the geological interpolations to be channelled downstream into mine planning, ultimately affecting the economic decisions surrounding a deposit. As such the process of variography and resource modelling is critical. Thus consistent expert decisions need to be made which force geologists to have a closer look at the available information and the geological interpretations. The aim of this paper is to provide an overview of the latest developments in visualising variography and to demonstrate their usefulness in decisions regarding the spatial continuity of mineralisation. New ideas concerning potential future developments in visualising and modelling spatial continuity through variography are introduced.

Jan 1, 1996

Powercoal Pty Ltd operates eight underground coal mines in New South Wales and produces coal for both domestic power stations and the export market. Approximately 40% of total production is from continuous miners. Over the past five years, place change mining methods have been introduced to improve productivity from continuous miners. This has involved utilising the existing coal clearance system from the continuous miner to the ratio feeder using trailing cable shuttle cars.By late 1996 average productivity at Cooranbong Colliery using this system had plateaued at 800 tonnes per eight hour shift. A number of factors were identified to increase average productivity to 1500 tonnes per eight hour shift. An improved coal clearance system was one of the factors identified.

Jan 1, 1998

The middle-Devonian Dulladerry Volcanics is a complex of A-type, predominantly rhyolitic ignimbrites, lavas and breccias. They form a NNW trending belt some 90 km long and 10-20 km wide, east of Parkes, NSW. The volcanics are dominated by widespread ignimbrite units with minor basalts, sediments and rarer andesites. The volcanics were deposited in a sub-aerial, possibly continental rift setting and are similar in chemistry and age to the Eden - Comerong - Yalwal Volcanic Zone (EVZ) on the NSW south coast. The volcanics exhibit an unusual Atype chemistry (high Zr, Y, Nb, REE, Ga). This distinctive composition illustrates that the volcanics are not comagmatic with the adjacent Yeoval Granite Complex or Eugowra Granite, which show typical I-type fractionation trends. Epithermal gold veins occur in basalt and andesite in the Dulladerry Volcanics at Mt Aubrey (Hopf, 1992), near Baldry. Alteration also occurs in the Glen Isla and Red Hill areas, with epithermal sinter recognised at Glen Isla. Copper and minor gold mineralisation occurs at the contact of rhyolite and andesite at Reedy Creek, but is not of epithermal origin. The analogous EVZ also contains several epithermal gold fields and it is this style of mineralisation which provides the most prospective targets in the Dulladerry Volcanics. Although the Dulladerry Volcanics also contain high background levels of REE and metals such as Zn and Pb, the general lack of fractionation and water-undersaturated character of A-type magmas does not lend itself to the development of significant concentrations of these elements into a fluid phase and mineralisation. The prospectivity of A-type volcanics in general could not be regarded as high. However, an indicator of some fractionation in the Dulladerry Volcanics is provided by the fairly low abundance (average 230 ppm) and wide range (

Jan 1, 1995

The link between exploration success and new ideas from research and development (R&D), although often assumed, is rarely well explained or well illustrated. One issue is understanding the role of innovative ideas in the exploration process, and another is determining the relative contributing factors to an exploration success. A useful measure of gold exploration success over an extended time period and geographic area is discovery rate (θ): Discovery rate θ = gold discovered/exploration expenditure (usefully expressed as tonnes of gold per $1 million). The total gold discovered is strongly leveraged to discovery rate, as any increase in θ typically has a positive effect on exploration expenditure. Hence, improving the discovery rate is a key driver for a sustainable mineral industry, especially for gold. There are very few ways to influence θ beyond innovative R&D ideas and breakthroughs, and well-motivated and trained staff. The Australian gold industry has experienced exceptional exploration success with 9956 tonnes of gold discovered from 1979 to 2003, inclusive. This equates to: Discovery rate θ = 0.9 t/A$1 M Two-thirds of this gold has been found in the Yilgarn craton of Western Australia (6265 tonnes Au). Without this exploration success, there would have been no platform on which to build the current gold industry and to take advantage of elevated gold prices and advances in mining and processing. Several causes of the Western Australian gold success have been proposed, and more than one may be correct. Gold price, and mining and processing advances have all had influence; but exploration success and discovery of gold were essential to add to the miniscule resource base of 1979. A comparison of the exploration methods used to search for gold in the Yilgarn craton in 1979, and 1990, highlights a small number of breakthrough ideas introduced to the industry during the 1980s, and in most cases emanating directly from local R&D. By the 1990s, these ideas were being used in most gold exploration programs in the Yilgarn craton, and are still used today. These six breakthroughs are: epigenetic timing of gold deposit formation (ie after formation of rock sequence), chemical and mechanical role of host rocks, relevance of carbonate alteration haloes, gold dispersion in the regolith, optimal sampling media, and appreciation of landforms in exploration program design. Interestingly, gold exploration science in Western Australia entered the 1980s period without rigid paradigms in place regarding gold deposit formation; there was a balance between descriptive and genetic models, there was scope to research gold deposits from microscopic to global scales and there were highly effective industry research uptake processes in place: it is suggested here that these favourable conditions contributed to the exploration success and industry growth.

Jan 1, 2007

By Valenta R. K

A technique is presented for the integrated forward modelling of the three-dimensional structure and the geophysical response of multiply deformed terrains. This technique allows information collected by field geologists and geophysicist to be reconciled by the development of a simplified kinematic structural history of the area. The structural modelling simulates the deformation history of the area in terms of a succession of structural events, such as folds, shear zones and intrusions. The interaction of these events with a starting stratigraphy results in the prediction of the geometry of the structures. By specifying geophysical rock properties for the units in the initial stratigraphy predictions are possible for the potential field anomalies for gravity and magnetics. This approach is suited to a range of applications, and its uses in the modelling of regional structures, testing of geophysical data processing, volume balancing, multiply constrained inversion and training are discussed.

Jan 1, 1995

By Luke K. A

Pressure on production at New Zealand China Clays has led to the development of a dewatering control loop for fine halloysite china clay. The development was based on the analysis of data from the automation of plate and frame filter presses. The analysis of the data has led to process changes, and the ability to quickly solve dewatering problems. As a result of control in the dewatering circuit press times have reduced on average 117% and output has increased proportionally.

Jan 1, 1989

By Tarvainen M, Mattila O

Outokumpu Oy has systematically developed the automation of mineral flotation covering the technology of both new devices and control methods, and as a practical result of this effort currently produces two on-stream X-ray analyzers. The Courier 300 system basing on conven- tional X-ray technology is applied to complex or large processes. The newer Minexan 202 dis- tributed probe system based on radioisotope technology is developed mainly for simple or small scale applications. In this paper aspects and experiences of these analyzer systems and their applications for flotation control are discussed with particular reference to the role of the computer

Jan 1, 1977

An on-stream iron ore analyser has been developed in collaboration with Hamersley Iron Pty. Limited for determining the iron content of both lump (- 30 + 6 mm particle size) and fines (- 6 mm particle size) on conveyor belts. The analyser, which is called IRONSCAN, is based on pair production, and is now commercially available from Mineral Con- trol Instrumentation Limited (MCI) in Adelaide. It can be mounted under existing conveyor belts with minimal modifications to the conveyor struc- ture, and the presence of steel cables in the belt does not interfere once the analyser has been correctly calibrated. The analyser has been exten- sively tested on both lump and fines on the shiploading conveyor at Damp- ier, and typically the root mean square (r.m.s.) deviation between single IRONSCAN measurements and conventional chemical analyses is better than 0.5% Fe. It is currently being evaluated on - 150 mm ore from the primary crusher at Mount Tom Price, and initial results are encourag- ing. The principal advantage of IRONSCAN is that it provides rapid infor- mation on ore grades. But perhaps its greatest potential is at the primary crusher where conventional sampling and analysis is very expensive to Implement. at the University of Melbourne, and those of us who were his students had learnt of the application of physical chemistry to pyrometallurgical processing, pioneered by Chipman in the USA, Wagner in Germany, and Richardson in the UK. It was possible, by applying this theoretical insight to the equilibria between metal, speiss or Legierung, matte and slag phases, to find a practical and effective way to recover metal values in some residues which had been accumulating for many years at the NA, but which had defied all attempts to treat them to that date. There was also an opportunity to study the batch lead refining methods still in use at all lead refineries apart from Port Pirie, and to devise optimis- ing techniques which greatly improved the operations and effected considerable savings. Next the writer spent some six years alternating between the BHAS, Port Pirie, and Imperial Smelting at Avonmouth in the UK, concerned with lead or lead-zinc smelting, and the develop- ment of several further continuous lead refining processes, before returning to Australia as Section Leader, Process Development in the CSIRO Division of Chemical Engineering, Fisherman's Bend, Victoria. Metallurgical opportunities which arose during this last period included the problem of tin smelting which had developed over about a decade: the world's tin smelters had been accustomed to treating fairly high grade tin concentrates, con- sisting of almost pure cassiterite, with very little impurity-mostly quartz, limestone, iron oxides, and sundry other silicates. Most such concentrates had been produced from alluvial deposits, where nature had already done some of difficult part of the mineral processor's work-at who knows what recovery-so that he could now produce high grade concentrates at high recovery. The smelters were not really set up for the treatment of lower grade concentrates, such as could be made with reasonably high recoveries from rock mining. Thus they imposed such penalties on impurities and lower than desired tin grades, that whenever a mineral processor improved tin recovery at the expense of lower- ing grade, such an improvement entailed a lower financial return to the miner. There was clearly a need for improved understand- ing of tin smelting, (at that time shrouded in secrecy) and develop- ment of techniques better suited to the treatment of lower grade concentrates. As well as the practical development, a start was made with the computer modelling of the smelting process, with the obiect of optimising the process parameters.

Jan 1, 1988