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By J Green, R Bartlett, A Goldstone, D Ferguson

Solid Energy New Zealand is developing an extension of its Rotowaro open cast coal mine near Huntly. This large 8 year, 11 million tonne opencast coal mine, referred to as the Awaroa Project, is fundamental to Solid Energy's medium term business strategy and meets its open pit coal resource needs while further resources are developed for the long term. Equally importantly the project is also fundamental to meeting New Zealand's energy requirements in the face of growing demands, a dwindling gas resource, and dry winters creating hydropower shortages. This project with its national significance in the current energy climate, its significance to Solid Energy as a business and its significant size has been consented against a backdrop of criticism of the Resource Management Act and the introduction of the 2003 amendment to the Act. As is common practice for this type of project Solid Energy conducted a significant technical programme in order to complete a comprehensive assessment of environmental effects. Solid Energy also has an active programme of community and interested party consultation and this programme formed the basis for project based consultation with local residents, regulatory bodies and iwi. As a result of the approach taken the environmental effects of the project were shown to be no more than minor and Environment Waikato considered that the project should be processed under the limited notification provisions of the RMA amendment. The project was processed under RMA quickly and efficiently and consents were granted within 6 months of lodgement. The RMA and its 2003 amendment provided a good framework for dealing with this project and did not impede the process of development of this important energy resource.

Jan 1, 2004

By M Foster

The new environmental legislation of 1986 was left incomplete and to date remains so. The 'missing' process by which environmental consideration should be applied was never embodied in law and has predisposition to a wide interpretation. The Resource Statutes which govern land use and development place demands on the environmental process without that definition. The Resource Statutes are themselves under review by Government. There is a new Government Department of Conservation. It is still in its early days and facing a challenge to compose its role as a steward over large tracts of land holding significant marketable resources, animal, vegetable, mineral, and abstract. It has also taken over numerous consent and advocacy roles in legislation beyond its own empowering Act. Enter the mining company, anxious if not able to get an easy passage for consents to prospect and mine, then at least to have a clear path to tread to get there, within a fixed time period. Whichever options appear available to process environmental approvals, public participation is that being favoured most by the regulatory bodies. Where a public notification of consent applications is mandatory, public participation should lead to the fastest track available.

Jan 1, 1988

By J Andrina, D Richards

The Grasberg is a large copper and gold open pit mine operated by PT Freeport Indonesia and located in the high equatorial mountains of Papua Province, Indonesia. The climate is alpine/sub-alpine with little seasonal variation in temperature and rainfall. The annual precipitation varies from about 3000 to 5000 mm over short distances around the Grasberg, but in general, an average daily precipitation of 10 mm per day applies and leaching of the overburden is continuous throughout the year. Mining commenced in 1988, and almost all of the overburden mined up to 2003 was potentially acid forming. The current acid drainage from this overburden is being collected and treated. From 2004 to the end of the Grasberg pit operation in 2014, approximately 70 per cent of the overburden will be potentially acid forming and 30 per cent limestone. A program of laboratory leach columns, field test pads and an instrumented full-scale dump was developed with the objective of defining scale up factors to quantify the acid and metal leaching rates and to evaluate the stockpile geochemistry and control options. The results of an ongoing seven year program have demonstrated feasible scale up between laboratory columns, field test pads and the trial dump in relation to material geochemistry and ARD evolution trends at Grasberg. The potentially acid forming waste types are highly reactive and maximum acid generation rate occurs within two to three years and that maximum copper release occurs within one to two years of exposure. The results also show that the net acid generation (NAG) test provides a good estimate for the potential acid load from overburden types. The chemistry, temperature and oxygen data from the trial dump suggest that oxidation and acid generation is occurring throughout the dump but at a decreasing mass rate with increasing distance from the toe of the dump. It is apparent that convection and/or advection are important mechanisms for the transport of oxygen into and within the dump. Key results and findings of the investigations carried out are presented and the implications of the findings for long-term ARD management at the Grasberg mine are outlined.

Jan 1, 2003

By M DellÆAmico, K Vining

The iron blast furnace is the most widely used and efficient producer of liquid iron; however, emissions from sintering and coking cause environmental pressure for the integrated steel works. The combustion of coke fines (breeze) during sintering contributes to greenhouse gases (GHG) (eg carbon dioxide) and is a source of SOx and NOx emissions. Coking capacity is also constrained by environmental concerns and economic factors, such as increased coke consumption, and short supply is leading to high prices. Improved coking practices, which result in reduced production of fines, are also contributing to the tight availability of breeze for sintering. This combination of factors presents an opportunity to consider alternatives to coke as a fuel for sintering. CSIRO Minerals has been investigating the use of wood biomass/char as a substitute for coke during sintering. Wood biomass, or char produced from it, is an attractive carbon source as carbon dioxide liberated during combustion can be sequestered back into growing biomass. It has great potential to reduce the emissions from integrated steelworks and improve their environmental acceptability. Harvested biomass/char is also a renewable and sustainable resource and can be integrated with good land management practices such as remediation of salinity affected land. Weeds, especially woody weeds, can also be used as a source of biomass for charcoal, and integrating char production with weed management can help address a pressing environmental issue in Australia. Previous reported preliminary testwork indicated that the use of Red Gum char as a replacement for coke resulted in a product sinter of comparable quality, improvements in productivity and significant reductions in SOx and NOx emissions. In the latest testwork, CSIRO has examined the properties of a range of potential charcoals, and has conducted a further series of granulation and small-scale sintering trials with them in simulated Japanese Steel Mill iron ore blends. Sinter fuels characterised and evaluated include industry sourced coke breeze, commercially available wood char and a charcoal from prickly acacia (acacia nilotica). Prickly acacia has been declared a noxious weed, is widespread in Australia, and is classified as a æWeed of National SignificanceÆ. The results presented in this paper support the notion that charcoal outperforms coke in many aspects of iron ore sintering and factoring in environmental considerations makes the switch to charcoal even more favourable.

Jan 1, 2005

By J E. Everett

An essential requirement of product quality control in the mining industry is to be able to reliably predict key quality properties of finished product from the data available before the extraction of the ore. From a production viewpoint, the unit of data collection is generally the input and output data set for each shift of crusher production, but could be any period where mine precrusher data can be reliably matched with product data.This paper demonstrates that linear regression models can be used to predict crush grades from blast grades, even where the crush material is blended from multiple sources or pits for each of which differing regression models might apply. The advantage of using increasingly complex regressions models to match the available data to give increasingly more powerful models is examined. The best model for any application will be a balance between required predictability, available data and the business’ tolerance for complex models.The regression modelling approach has several advantages over the more classic method of run-of-mine (ROM) crusher trials, which will be discussed.The models can use any predictor variable such as grade, geotype and in situ density provided the preextraction data set can be reliably matched with post-crusher data and is significant as a predictor. The models have been used extensively in the generation of the daily crusher plan with the aim of maintaining finished product grade. This approach has also been used associated with exploration drilling and long-term planning.It is acknowledged that there are inherent problems in fitting lump and fines grade to a linear model. However, these problems are minor when they are used for interpolation within the window spanned by the shift blend records used to produce the model. This paper discusses some of the issues limiting linear regression models in this application, and suggests methods enabling consistent models to be formulated

Sep 5, 2011

By S R. Grano, J Duan, T A, D Fornasiero

We have determined the experimental rate constants for chalcopyrite particles floated from a complex sulfide ore and compared them with those calculated using a recently developed flotation model. The model incorporates contributions from the efficiencies of collision, attachment and stability between particles and bubbles, as well as their frequency of collision. For these calculations, the contact angle of the chalcopyrite particles in the ore was obtained independently using a surface spectroscopic approach. The calculated flotation rate constants were in good agreement with the experimental data and able to reproduce the characteristic maximum in flotation rate constant for particles of intermediate size. The values of bubble velocity and turbulent dissipation energy derived from these calculations are relatively low and may well correspond to mean values of these parameters inside the flotation cell. We have extended this approach through the application of a property based model to an operating plant, with a satisfactory outcome.

Jan 1, 2005

By E Christodoulou, L Zoumpoulakis

The kinetics of the thermal decomposition of MgCO3 was investigated using isothermal experiments performed in a thermogravimetric analyzer under a nitrogen atmosphere at 380¦, 400¦, 450¦ and 480¦C. The weight loss data as a function of time were modified to give the fraction that reacted (ß) and the rate of reaction (dß/dt) vs. time (t). Kinetic analysis of the experimental results, using three different methods, showed that diffusion predominates the MgCO3 decomposition over the investigated temperature range, with the data being best fitted by JanderÆs equation ([1−(1−ß)1/3]2=kt). The activation energy was estimated by Arrhenius plots using both the initial reaction rates and rate constants from fitting the above equation. The values estimated were 27.1 and 171.4 kJ/mol respectively.

Jan 1, 2001

By J Rubio

This work presents design features of an innovative in-line mixing helical (coiled) reactor for flocculation and flotation as a solid-liquid separation process for suspended particles (including liquid droplets). The device has been named flocs generator reactor (FGR), a compact system whereby the flocculation of particles is assisted by the kinetic energy transfer from the hydraulic flow through the reactor and/or by the injection of microbubbles (30 - 70 ¦m). The flow mixing presented a plug flow regime with a low dispersion degree, promoting the required hydrodynamic conditions to disperse the polymer flocculant (cationic polyacrylamide) and to generate æstrongÆ flocs of Fe(OH)3 or clays (as colloidal model systems) with aggregation using an anionic polymer, Al2(SO4)3 and poly aluminium chloride (PAC), and oil emulsions destabilisation with a high molecular weight cationic polymer. The solid-liquid separation of the flocs was then achieved either by settling or by flotation with microbubbles. This paper discusses advances in this new in-line flocculation-rapid flotation device to remove æaerated aggregatesÆ, aggregates with entrained and entrapped bubbles. Studies were carried out with different models of FGRs (varying the length:volume ratio) and process efficiency (mainly kinetics) evaluated as a function of polymer concentration and some operating parameters, namely, feed flow-rate, air:solids ratio and residence time. Results showed that the aerated flocs are readily floated with rising rates in the order of 120 mh-1, values higher than those obtained for the settling of the non-aerated flocs (18 - 24 mh-1). The FGR requires short residence times and generates dense, well structured flocs (with a mass fractal dimension, dF of about three) which withstand high shear forces. Mechanisms involved appear to include small bubble formation and their rapid occlusion (entrapment) within flocs, nucleation of bubbles at floc/water interfaces, polymer coiling as a result of æsalting outÆ effects at the aqueous/air interface and plug flow type of mixing (flocculation). Successful examples of emulsified oil and solids removal from water are shown and because in all cases high efficiencies were obtained (>90 per cent removal). Due to the high process efficiency and high loading capacity shown, the FGR appears to have good potential as an in-line flotation-separator device in applications requiring high rate solid-liquid or liquid-liquid separations.

Jan 1, 2005

Design and construction techniques used to develop two highway tunnels in inaccessible mountainous terrain are described. Measures used to adapt the design to the unusual geology and topography are discussed, as well as measures to adapt the construction methods to available equipment, materials, and skills. Sharp local variations in geoloqic conditions resulted in field modifications to both design and construction techniques. The geology is a volcanic ash and breccia-agglomerate at one site, a jointed andesite at the other, which is also the site of a major landslide. Both rock reinforcement in the form of pretensioned and grouted rock bolts with a shotcrete lining,and rock support by struc- tural steel sets with a reinforced concrete lining were used. A canyonside location and high lateral in-situ stresses required modification of design procedures. Pilot tunnels at both sites resulted in adapting the designs to site conditions with large savings in lining costs, disclosing problem areas in advance of the main excavation, and cushioning of blasting pressure to minimize stability problems.

Jan 1, 1976

Current models for the origin of banded iron-formation (BIF) derived in situ iron ore deposits assume that the typical chert and iron oxide banded BIF is the primary rock from which enriched iron ore deposits arise by the selective leaching of quartz and the residual accumulation of the iron oxides. Weathering extends to the base of all the hematite deposits of the Hamersley Province, which lie within the saprolitic weathering zone, as shown by the preservation of the primary textures, and are overlain by a hydrated goethite zone representing the solum. Since groundwater typically contains dissolved silica, derived from the hydrolysis of silicate minerals, greatly in excess of the saturation solubility of quartz, it is incapable of removing quartz from below the watertable, and quartz is preserved in all saprolites derived from quartz bearing rocks. Quartz may be dissolved in the solum due to the influx of meteoric water having little or no dissolved silica, but soil-forming processes that dissolve quartz likewise alter the oxides by hydration and transposition with consequent destruction of primary textures, and there is no suggestion of soil-forming processes having produced the deposits, which typically extend to considerable depths below the water-table. A characteristic feature of the typical hematite orebodies is the unaltered nature of the iron oxides in the ore compared to those in the adjacent cherty BIF. Although the solubility of ferric iron at >10 ppb is much less than quartz, any process capable of dissolving the huge volume of quartz must also affect the iron oxides, but evidence of this is completely lacking in most ore deposits. Hydrothermal alteration at Koolyanobbing in the Southern Cross Province affects both cherty BIF and ore, and clearly shows equal mobilisation and recrystallisation of hematite within quartz/hematite veins and in the surrounding cherty BIF, which shows no evidence for the selective leaching of quartz. Similarly, any metamorphic process capable of removing all quartz from BIF would leave characteristic evidence in the remaining oxides. However, a hydrothermal process may account for at least portions of certain ore deposits, in which the chert bands have been replaced by carbonates at comparatively low temperatures, to produce a quartz-free magnetite/ carbonate rock that is readily upgraded to high-grade ore by supergene dissolution of the carbonates. This process is interpreted to have formed high grade ore at Mt Gibson, Koolyanobbing æAÆ Deposit and Mt Tom Price North Deposit. In addition to carbonate replaced cherty BIF at Mt Gibson in the Murchison Province, there are extensive sequences of magnetite BIF without chert bands, and this chert-free facies of BIF is interpreted as the precursor to the majority of in situ hematite ore deposits, through oxidation and weathering of magnetite and iron silicate and carbonate minerals. The world-class martite/microplaty-hematite deposits of the Hamersley Province are a special case of BIF-derived iron ore deposits that were initiated during the Proterozoic era. Evidence from overlying Wyloo Group conglomeratic horizons containing clasts of Hamersley Group BIF indicates that microplaty-hematite formed within the clasts before deposition, and that Proterozoic subaerial oxidation and weathering of uplifted Hamersley Group formations produced the microplaty-hematite in both chert-free and cherty BIF.

Jan 1, 2002

A new lead refinery with a. capacity of 230,000 tons per year com-menced operation at*Port'Plsie in October, 1959. This plant' superseded the refinery which had operated from 1933 with the advent of thecontinuous lead refining process. The incorporation of new equipment following local metallurgical developments, together with the overseas demand for lead of extremely low antimony content, created difficulties in operating the original plant. The new refinery project was under-taken to cover this disability and to gain the full advantage of the new processes.Desilverising and softening are carried out in units identical in size to those used previously. Metallic'zinc is now recovered from the entire output of desilverised bullion by vacuum distillation. Final refining is then carried out by batch'treatinent with caustic soda yield-ing lead of purity previously unattainable at Port Pirie.These two processes have replaced continuous dezincing by oxidation, a high temperature process which caused large quantities of lead and antimony to be recirculated. As the final stage is a .batch process the product composition can be.checked before casting. Individual batches can be adjusted to produce special alloys to,consumer's specification.Improved casting equipment has allowed the quantity production of pigs of good physical characteristics either as 56 lb bars or 2000 lb pigs. This, together with the high purity of the lead, has assured the B.H.A.S. position in world markets.Automatic control systems have been extensively employed particularly on the vacuum dezincing unit.The anticipated financial benefits have been achieved mainly by a reduction in the tonnage of recirculated materials, a smaller labour force, and reduced maintenance requirements.

Jan 1, 1963

By Morsky P, Kalapudas R, Natunen H, Virtanen M

The development of autogenous grinding modification in Outokumpu, known with the name 'Outogenius Comminution', was 'reversed'. At first the metallurgists studied and tested tens of years autogenous grinding in detail in full scale circuits at the concentrators of the company. After the final solution already had been found, also a pilot plant was built and now finally, research work is under way to develop a special laboratory method for testing the suitability of ores for 'Outogenius Comminution'.

Jan 1, 1993

The Golden Cross is the first large precious metals mine to be both commissioned and closed in the æmodernÆ era in New Zealand. This paper discusses the life cycle of the Golden Cross mine, with emphasis on the closure process and post closure management.   The closure process has generally been very well managed, and successful, but in spite of that some on-going issues remain unresolved. Nearly nine years after the end of mining the mine owners are still actively managing the site, with no immediate end to that in sight.   The site has been described as atypical, due to the identification of a deep seated landslide below the tailings and waste rock storage facilities. However that should not be given too much emphasis when addressing the overall closure and post-closure management issues, which could well apply to other existing and future mine sites in New Zealand.   The Golden Cross can provide valuable lessons for other miners, and the issues arising at this site should be watched closely by the industry as a whole.

Jan 1, 2006

By Bishop I, Toon S

To determine whether 130 felt earth tremors around Edwinstowe, Nottinghamshire U.M, which also experienced severe surface fissuring, were caused by coal extraction, a surface seismometer array was established around Thoresby Colliery. Over the next year, 785 microseismic events were detected. The spatio- temporal seismicity patterns are clearly associated with the commencement, continuing extraction and closure of faces. Of particular note are events which locate at the surface and appear to be related to the active fissuring. Events occur within days of commencement of production and cease when production finishes, with good correlation between face advance and hypocentral position. Naturally occurring microseismic events have also been detected up to 1 km ahead of active longwall faces in the Midlands using triaxial geophone packages grouted into the seam together with a surface seismometer in the top of the borehole. The quality of these data were very high and guided waves can clearly be seen with the dispersive characteristics associated with seam waves. In one experiment more than 2000 events were detected in only two days of monitoring even in a relatively noisy surface environment. This paper demonstrates how very accurate locations (5 10 metres) can be generated using three-component digital data from only one borehole. The surface seismometer and the borehole P-wave onset can give extra precision for the height of the event relative to the seam. The event distributions give a dynamic, three-dimensional image of the developing patterns of fracturing above, below and ahead of the longwall face with important implications for roof control, subsidence prediction and gas Migration.

Jan 1, 1992

By S W. Richards, J Buys

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Magmatic arcs are prime targets for porphyry- and epithermal-style mineral deposits, although settings within continental arcs and/or tectonically-thickened crust generally tend to be more prospective than intra-oceanic arcs in extensional settings. In this paper, we report new geochemical and geochronological data on igneous rocks of the Western Belt of the Vanuatu intra-oceanic arc. Dating of igneous hornblende (Ar-Ar) and zircon (U-Pb) from the igneous rocks place their formation in the late Eocene to Miocene. In most respects, these are typical arc igneous rocks. However, they contain inherited zircon grains with significant age populations at ca 2.8–2.5 Ga, 2.0–1.8 Ga, 1.75–1.5 Ga, 850–700 Ma, 530–430 Ma and 330–220 Ma. This inheritance signature is unlike anything recognised from the oceanic realm of the south-west Pacific, but, in general, does match the age of the major crustal blocks of the Australian continent. An exception is the significant proportion (~20 per cent) of zircons of Rodinia breakup age (~800 Ma), which previously has not been found in eastern Australia or the south-west Pacific.We propose that part of the Vanuatu arc basement comprises a ribbon of continental material rifted from northern Australia prior to, or during, the Cretaceous. The presence of ancient continental material within the Vanuatu island arc may help reconcile the relatively large thickness and low density of the crust of Vanuatu, and may enhance the prospects for significant porphyry and epithermal ore deposits in the region.CITATION:Spandler, C, Buys, J, Holm, R J and Richards, S W, 2015. Remnants of ancient Australia in Vanuatu – implications for south-west Pacific tectonics and mineralisation potential, in Proceedings PACRIM 2015 Congress, pp 183–188 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

FOR some years after the erection of the first chlorination plant at Mount Morgan the ore sent to the works for treatment was mined entirely from the oxidized zone; consequently, the bullion recovered at the refinery was of unusual purity, averaging about 972 in fineness, and, as no impurity in any way detrimental to the softness or toughness of the bullion was present, there was no necessity to subject it to any refining process.The charcoal from the filters was calcined to ash in small reverberatory furnaces of the usual type. The ash was mixed with suitable proportions of soda and borax to form a good liquid slag. This' mixture was then charged into salamander cruciblesand run to metal and slag in the ordinary wind furnaces-a slow and tedious proceeding in the Mount Morgan climate. The bullion, cleaned of slag, was re-melted under borax and poured into bars weighing from 350 to 400 oz.; these bars, after being dipped while hot into dilute sulphuric acid, were packed and sent to the mint. Of late years, however, the ore coming from the deeper ground of the oxidized zone became much lower in gold values, and contained variable but increasing quantities of sulphides, sulphates...

Jan 1, 1911

By Bin H

East Guangdong tin province overlaps the southmost part of the mesozoic magmatic arcof continental margin type in Southeast China and is dominated by mesozoic syntectic magmatism,which associated to tin mineralization. It is distinguished from Nanling tin province but quite close to NW Bolivian tin province in both tectonic and magmatic relations.Tin deposit's mostly of cassiterite-sulfide, cassiterite-silicate formations are localized along exsocontact zone of granitoid batholith or stock, boundary area of volcanic depression, or, within volcanic edifice. Petrochemistry studies show tin was concentrated as intermediate-acidic magma evolved by fractional crystallization. Xiling tin deposit of vein type related to extrusive... the lava dome was formed at T C 221-301 and at very shellow depth,seems to correspond to type A in classification for Bolivia tin deposits by J.N.Grant. Tashan tin deposit of dissemination type related to hypergene intrusive facies,with mineralization occured in endocontact zone of granite porphyry dykes is considered as porphyry type,which spported by H-0 isotope and gas-liquid inclusion evidences. It formed at T C 250-430, comparable to Bolivia porphyry tin deposits,but at a greater depth 1.3 3.0km.A model for known tin deposits in East Guangdong was worked out. A good prospecting perspective was revealed for the potential type of tin deposit in East Guangdong--subvolcanic porphyry tin deposit.

Jan 1, 1990

By Pinczewski WV, Nowak LP, Tanzil WBU, Jenkins DR, McCarthy MJ

An experimental and theoretical study has been made of the drainage behaviour of two-dimensional packed beds drained from an outlet in the sidewall of the bed in order to identify the fundamental me- chanisms involved. Under these conditions a grad- ient develops in the air-liquid interface in the direction of flow with the interface tilting towards the outlet. This results in a significant volume of liquid being retained in the packing on completion of draining when the interface first reaches the bed outlet. Residual liquid volume and the shape of the air-liquid interface as a function of time were det- ermined experimentally in a two-dimensional packed bed where the packing consisted of glass spheres ranging in size from 0.6 to 10 mm dia. and the bed was drained at superficial liquid velocities rang- ing from 0.007 to 0.32cm/s. The test liquids used were water, glycerine/water solutions and kerosene resulting in a viscosity range of 1 to 10 mPa.s and a surface tension range of 0.0243 to 0.072 N/m. Assuming laminar flow within the bed, a compu- tational model was developed to predict both the liquid residual ratio and the temporal evolution of the drainage profile within the bed. The computed results were in good agreement with the experimental data over the entire range of conditions invest- igated. the computational model was used to estimate the relative importance of the effects of changes in hearth conditions on residual slag volume for typ- ical blast furnace operating conditions. On the basis of the computed results it is concluded that coke quality is a major parameter affecting hearth drainage performance.

Jan 1, 1981

Mineral Processing Education in China

Sep 13, 2010

By A Gerson, S Miller, R Smart, J Thomas

Environmental Geochemistry International (EGi) and the Ian Wark Research Institute (IWRI) collaborated in a three-year Australian Minerals Industry Research Association (AMIRA) research project (Project Number P387A) focussed on the prediction and kinetic control of acid mine drainage. As part of this project, single addition, and sequential net acid generation (NAG) testing was carried out on sulfide mineral samples. The test samples comprised a range of synthetic waste materials prepared using a quartz bulk and controlled quantities of the commonly occurring sulfide minerals; pyrite (FeS2), pyrrhotite (Fe7S8), arsenopyrite (AsFeS), chalcopyrite (CuFeS2), chalcocite (Cu2S), covellite (CuS), bornite (Cu5FeS4), galena (PbS) and sphalerite (ZnS). NAG test results clearly show that there are significant differences between the acid forming potential of sulfide minerals. The NAG test results for each mineral were compared with theoretical acidity values (NAPP*). The NAPP* calculation was based on stoichiometric oxidation reactions assumed for each of the sulfide minerals. Sequential NAG values for pyrite corresponds closely to predicted NAPP* values, confirming the assumption that pyrite oxidation occurs according to the stoichiometry assumed. For the pyrite sample with 5 wt per cent S, two NAG stages were sufficient for all of the sulfur to be released to solution. Since sulfides in waste materials will generally be dominated by pyrite, results also confirm the validity of including NAG testing for ARD evaluation of most waste rock. NAG testing confirms that of the sulfide minerals examined, only pyrite, pyrrhotite, arsenopyrite and chalcopyrite are acid producing, ie able to produce leachate with a pH less than 4.5. In the case of sphalerite, galena, bornite, chalcocite and covellite the pH of the final NAG solution was greater than 4.5. The significant differences between the acid forming potential of different sulfide minerals could lead to overestimation of acid producing potentials based on NAPP values calculated from total per cent S alone, ie assuming all S is present as pyrite. The oxidation of galena during the NAG test resulted in the consumption of acid. The examination of the galena surface by X-ray photoelectron spectroscopy (XPS) after oxidation in peroxide solution indicated the presence of polysulfide. The reaction of sulfide to polysulfide is acid consuming, thus explaining the net acid consuming behaviour of galena in the NAG test. This reaction pathway may provide a possible explanation for the lower than expected acid production observed for some of the other sulfide minerals examined.

Jan 1, 2003