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By R. M. Brick

A PREVIOUS publication 1§ has described the effect of quenching stresses on the lattice parameter values of high-purity aluminum-copper alloys particularly with reference to the solution and precipitation of CuAl2. A similar study has been made of the aluminum-rich aluminum-mag-nesium alloys. Attention has been directed in the present investigation to the magnitude of the quenching stresses as affected by the specimen size and shape, the number of solute atoms and the quenching rate. The effect of cooling stresses in causing plastic deformation or cracking has been considered in relation to the physical properties of the alloy. On reheating alloys in the two-phase field, the time required for pre-cipitation to occur has been observed in connection with the degree of supersaturation, the rate of diffusion of the solute atoms as a function of the comparative atomic radii, degree of strain, temperature of reheating and grain size. A few qualitative comparisons on the relative effect of these factors have been drawn between the aluminum-copper alloys and the aluminum-magnesium alloys.

Jan 1, 1935

By J. W. Evans

ONE possible method for the separation of hafnium from zirconium is by the vapor phase oxidation of the purified mixed chlorides. An important factor for success depends on the difference in free energies of the following reactions: ZrCl(g) + O2 = ZrO2(s) + 2C12 [1] HfCl4(g) + O2 = HfO2(s) + 2C12. [2] Prakash and Sundaram1 have calculated these values from certain data and carried out experimental work with partial success. However, their free energy values for reaction 2 diverge rather widely from other data which are presented here. The possibility of successful separation is briefly considered in the light of these alternative values. Table I shows the free energy values (?F°) for reactions 1 and 2 derived from the recent compilation of data on oxides and chlorides by Glassner.2 The corresponding values of Prakash and Sundaram for the same temperatures are also shown. The alternative values to those of Prakash and Sundaram for reaction 2 are substantially confirmed by the data of Kubaschewski and Evans" and Cough-lin' on heats of formation, entropies, and heats of vaporization. In spite of the considerable uncertainty in the hafnium data it is reasonable to suppose that the oxide-chloride free energy difference for two such chemically similar elements would not be very far apart. These figures indicate clearly that the oxidation of hafnium chloride is appreciable at all temperatures. Nevertheless, there is a significant difference between the values for reactions 1 and 2

Jan 1, 1959

By Byron W. Cheever

While engaged in experimenting with the usual methods for estimating phosphorus in iron and steel, it occurred to me that potassium chlorate might be used to oxidize the carbon, and thus avoid the tedious and vexatious evaporations necessary for successfully carrying out the usual methods. After many trials, the following plan was adopted : Take, for analysis, of Bessemer or other low-carbon steels, from 3 to 5 grammes; of crucible steel, 10 grammes; of pig-iron, 1 to 5 grammes, according to the percentage of phosphorus supposed to be present. Of iron, high in phosphorus (1 per cent.), take 1 gramme. Place in a No. 4 evaporating dish the amount of iron or steel decided upon, cover with a funnel which will just fit inside the dish, and then add gradually HNO3, (1.20 specific gravity), using 12 C.C. of acid for each gramme of steel or iron taken. (A larger quantity of acid will be required for small samples.) When the full amount of acid has been added, and the violent action has ceased, place the evaporating dish on a sand-bath, add 10 C.C. HNO3, (1.40 specific gravity), and boil till the bulk of the solution is reduced about onehalf. Then add 10 C.C. HNO3, (1.40 specific gravity), continue the boiling, and add from time to time, during the next 15 minutes, small portions of pulverized KCIO3, till about 2 grammes have been added. (If the solution shows signs of going dry, more strong acid must be added.) This will precipitate the manganese, with some iron. Sometimes it happens that the manganese does not come down readily, and more KCIO3, or further concentration, or both, will be required. The process is not complete till the manganese is precipitated, which may be known by the appearance of a dark, mirror-like deposit on the dish, at the edge of the solution. Boil the solution 5 minutes after the last addition of KCIO3, and then add cautiously (to prevent sudden explosions) 5 C.C. strong HCl. This will dissolve the precipitated manganese and iron. Continue the boiling till the chlorine is all expelled, adding from

Jan 1, 1885

By S. P. Barber, G. W. Cutting, V. Alesse, M. Ciriachi

Just what is happening in the preparation and mineral separation stages are questions frequently asked about most processing plants. It is unusual to find the answers readily available in the operating metallurgical data. Knowledge is nominally available from metallurgical balances about the head ore grade, grade and recovery of the concentrates, and the plant tailings. However, the mechanisms which control grade recovery and losses are seldom monitored in such a way as to permit specific analysis: Thus, when questions about the effectiveness of the process are asked, the answers are based frequently upon intuitive professional judgments and local expertise. Detailed investigations of process functions are extensive in terms of manpower, time, and interference with production. An investigation method in which process operating conditions could be provided in a cost effective manner would assist in local process assessment and control. Such a collection of process operating data is defined as a process audit and the development of the necessary techniques forms the subject of this paper. A typical application to a lead-zinc concentrator highlights both the manner of implementing a process and the plant data made available for local use.

Jan 1, 1980

By Arthur Coffinberry

EVE have studied the gold-aluminum system by X-ray diffraction and by the microscope over the entire range of composition for temperatures between 300° and 500° C. Results obtained are shown in Fig. 1, com-bined with the work of Heycock and Neville1 at higher temperatures. The diagram differs in important details from that given by Hansen2 in his critical compilation of the literature of binary alloy systems. This work was, undertaken both because of the intrinsic value of a knowledge of the phase diagram of this system and because of the need of theoretical metallurgy for precise and accurate data, particularly X-ray diffraction data. Systematic studies of equilibrium diagrams, particularly by Hume-Rothery,3 have shown regularities that yield a certain insight into the nature of alloying forces. It has been shown, for example, that solid solubility depends on the concentration of free electrons in the alloy, on the relative radii of solvent and solute atones, on the forces of attraction between atoms, and on the relative stability of intermediate phases. The well-known Hume-Rothery rule states that the crystal structures and compositions of many intermediate phases depend on the electron-to-atom ratio. This has been confirmed and extended by wave mechanical calculations.4 A knowledge of the forces between atoms in alloys, even an imperfectly developed empirical one, should be a valuable guide in the preparation of technological alloys of desirable properties. Furthermore, such informa-tion is basic in such problems as rate of diffusion, age-hardening, phase transformations, and others. The most valuable data for this purpose are furnished by X-ray diffraction studies. Unfortunately, work has been

Jan 1, 1938

By R. A. Foos

During the radium boom in the early part of the twentieth century, the basic chemistry of uranium was fairly well defined. Uranium production has progressed from the status of a radium by-product to a very important industry. With the ever increasing need for more efficient and cheaper methods of processing uranium ores, new techniques are being developed. Since uranium and vanadium often occur together in nature, the latter element will also be considered. As production rates, costs, and certain aspects of uranium chemistry are still classified by the Atomic Energy Commission, these will not be discussed. Domestic uranium deposits, in general, are composed of the minerals carnotite, which contains hexavalent uranium, and to a lesser extent, pitchblende and uraninite, which contain tetravalent uranium. Carnotite also usually contains vanadium. The uranium and vanadium contents of these ores vary considerably. The ores currently processed on the Colorado Plateau assay from 0.2 to 0.4 pct U and from trace amounts to 5.0 pct V. On the other hand, the phosphate rock deposits of the southeastern U. S., from which uranium is also recovered, contain only about 0.01 to 0.02 pct; processing of the

Sep 1, 1956

By J. B. Hiskey

The hydrometallurgical application of thiourea in processing precious metal ores and concentrates has reached the development stage. This paper reviews recent technical literature covering the process development of thiourea leaching. In addition, recent fundamental contributions are discussed. Most of the interest in thiourea leaching has involved treating high grade concentrates that have sufficient value to just the use of thiourea as a reagent. An important development in thiourea technology is the addition of SO2 to the leaching solution. This procedure effectively reduces the decomposition of thiourea and eliminates the problems of passive surface layers that limit the leaching efficiency. Results for the thiourea leaching of a bulk sulfide concentrate and a residue from the autoclave leaching of a smelter flue dust are also reported. As determined by a standard bottle roll cyanidation test, the bulk concentrate was extremely resistive to cyanide leaching yielding only 16% gold and 2% silver extraction in 24 hours. Leaching with a relatively concentrated thiourea solution (1MCS (NH2)2) resulted in 83% gold and 75% silver extraction in four hours. With the treated flue dust residue, gold extraction was about 60%. Gold and silver extraction with cyanide was sensitive to both cyanide concentration and oxidizing conditions. Cyanidation resulted in 59% gold extraction and 77% silver extraction in 24 hours.

Jan 1, 1985

By G. W. Poling

Chemical and physical properties of thiol collectors are re-examined to compare the prospects,of heavy metal-thiolate or disulphide surface reaction products acting as actual collector species. Recent evidences for the existence and importance of each of these types of adsorbed species on sulphide minerals are also discussed. A conclusion is reached that partial coverage by chemisorbed heavy metal thiolate is often sufficient to confer practical levels of hydrophobicity and floatability. Only on a few highly conducting and "noble" sulphides does adsorbed disulphide-type collector oxidation product appear to be significant.

Jan 1, 1976

By Charles Legrand

The power plant of the Burro Mountain Copper Co. is located near Tyrone, N. M., at 5,950 ft. elevation. It is interesting because it uses the largest stationary Diesel engines in the United States. The general layout of the plant is shown in Figs. 1 and 2. The building is of steel-frame construction with hollow-tile walls and corrugated-iron roof; the floor is concrete and all windows have steel frames, making a fireproof building. The building is made to accommodate one more electric generator unit which is being installed; also two 4,000-cu. ft. air compressors direct-connected to three-cylinder engines with the same size cylinders as the electric units. The power plant consists of two 815-kva., 60-cycle, three-phase, 6,600-volt, 180-r.p.m. generators, direct-connected to five-cylinder, two-cycle Diesel engines; the necessary circulating pumps for cooling water, cooling towers and oil storage tanks. A portion of the power is used in the same building as the generating units to run one of two 200-kw. rotary converters delivering 260-volt direct current, and a 2,500-cu. ft. air compressor, delivering air at 95 lb. pressure, direct-connected to a 400-hp., 6,600-volt, three-phase synchronous motor. The remainder of the power is used to run a 1,500-ton concentrating mill 3 ½ miles from the power house, various hoists, pumps and motors about the mines and the lighting and water-works of the town of Tyrone. The direct current is used for electric traction in the mine, also to run hoists and motors that were installed before the new power plant was built. Due to the large hoists that take starting peaks of 250 kw. and the 10-ton electric locomotive that takes at times 150 kw., the load is extremely variable, as shown in. Fig. 3.

Jan 9, 1916

By Richard W. Markley

A centralized online data acquisition system has been developed by the U.S. Bureau of Mines Pittsburgh Mining and Safety Research Center for rapidly digitizing, storing, and processing experimental signals originating up to 1100 feet away from a central computer. This system, which services seven laboratories, is currently based on a CDC System 17 1/- computer with 56K of semiconductor memory, four disk drives (one shared online with a CDC 1700), two magnetic tape drives, high-speed A/D hardware, and other input/output peripherals. The laboratories are linked to the central computer by 15-pair cables and signal conditioners and to the computer's communications controller by modems and current loops. The A/D throughput rate is approximately 30,000 samples per second (9 bit plus sign resolution) and permits scanning about 30 instruments once every millisecond for up to 100 seconds, being limited only by disk capacity. The laboratories serviced by this facility conduct explosions research and include such facilities as an Experimental Coal Mine Explosion Facility (45 channels), a Constant Volume Combustion Laboratory (4 channels), and a Simulated Coal Mine Laboratory (15 channels). Personnel support includes one systems analyst, two applications analysts, one operator, and a hardware technician. The system has performed adequately for burst-type data acquisition, but due to a lack of long-term reliability (24 hours) of the real-time multiprogramming operating system and unpredictable power failures, slow phenomena signals are generally digitized and stored offline. This latter data is input to the computer through peripherals such as a high-speed paper tape reader, or high-speed asynchronous communications ports. Processing of data is done either in real-time (as soon as data is collected) or in batch mode. Smaller batch jobs are run on this computer, and all others are transmitted by means of the system's high-speed UT 200 terminal simulator to a CDC-6000 series computer.

Jan 1, 1977

By E. A. Beck

For a number of years many attempts have been made to use thermit in order to do away with piping in ingots. Some of these attempts were successful, while others did not give the expected results. Nearly every plant had its own method of using the thermit, and no special care was taken to study the results or to find the causes for lack of success. Formerly the principle of the process was to decrease the piping by introducing a can filled with thermit, attached to an iron rod, into the head of the ingot directly after it had been poured. In this case the thermit reaction took place in the upper part of the ingot, and it was thought that through the heat produced the head would keep liquid longer and piping thus be reduced. In other words, the aim was to keep the head of the ingot open by making use of the heat of the thermit reaction, which would thereby give the gases in the steel sufficient time to escape. This result can be attained by the application of a large enough quantity of thermit, but it would not be economical in general practice, and could only he used for high-grade material. Many steel-makers abroad and in this country have had this experience. The Th. Goldschmidt A. G., Germany, has, therefore, made a special study of this question with the cooperation of a well-known steel company, and has worked out a new method for the application of thermit for this purpose. The results obtained have been most satisfactory and reliable, and this process is now used in Germany on a large scale in many prominent steel-works. The thermit is applied in cans, as in former years, but the principle of the process is entirely different. The object of using the thermit is not to heat the steel and keep it liquid,

Jan 1, 1914

By Jackson M. Langton

Substantial evidence supports the theory that high-angle faults and overthrusts in the Morenci-Metcalf region were initially caused by a Late Precambrian-Early Paleozoic stress field. These faults were reactivated in Late Paleozoic-Early Mesozoic time which completed the structural framework prior to the Laramide Orogeny. Excluding an interruption by diabase dikes and sills, Paleocene-Eocene magmas invaded the pre-existing structures and became progressively more sialic in composition and nearer to the surface with each subsequent injection. The last sialic intrusion was highly explosive, rendering the country rocks more permeable for hypogene and supergene activity. Widespread dilation, instigated by uplift and subsequent magma intrusion, caused extension to the northwest and southeast. A major locus of hypo gene alteration and mineralization appears to be centered around the south and southeast periphery of the youngest granite porphyry stock. A potassic, sulfide-deficient core is telescoped by a pyritic, phyllic zone which in turn is enveloped by widespread propylitic alteration.

Jan 1, 1974

By T. Guilford Smith

In presenting the subject of " Armored Turrets for Coast Defense " to this Institute, I am indebted to the Gruson Ironworks, a company incorporated under the laws of the State of New York, for valuable information, model and plans, by which I hope to make clear the construction and peculiar merits of this class of gun-protection. I wish it understood, however, that this is not an undeveloped and untried inventor's ideal, but an advanced and fully perfected system, which has long since passed the experimental stage and has been adopted by most of the foreign governments, after years of extensive experimenting and the expenditure of millions of dollars. The present seems an appropriate time to present the matter to the scientific public, since, for the first time, it is possible to produce these turrets in this country, of American material, and made by American workmen, owing to an agreement entered into between the Gruson Iron-works and the Fried. Krupp Grusonwerk, of Magdeburg-Buckau, Germany, where they have hitherto alone been manufactured. Although its full development and present perfection have been attained at the German works, it may be of historic interest to state that the first idea of using a rotating protected platform for large guns originated with Mr. Theo. Ruggles Timby, a native of the State of New York, who filed a caveat in 1843 for a " metallic revolving fort, to be used on land or water, and to be revolved by propelling engines located within the same and acting upon suitable mechanism." This was followed in 1862 by the issuance to Mr. Timby of two patents (No. 35,846 and No. 36,593) covering the ideas described in his caveat of 1843. The first practical application of this system was made on the " Monitor," of Civil War fame, Mr. Timby receiving $10,000 for two

Jan 1, 1901

By R. S. Burns, J. G. Erskine

The performance of the nine 5.5 m diameter x 6.4 m mills (18 x 21 ft) initially installed at Bougainville Copper Ltd. did not meet the laboratory and pilot plant derived design expectations as measured by Bond Work Index. During the post-commissioning period, inefficient grinding of coarse material resulted in a build-up of large circulating loads and led to reduced throughputs because of pump and cyclone overloading. Installation of larger pumps and cyclones and development of an improved circuit control philosophy alleviated materials handling problems and permitted higher tonnages to be attained. Since 1977, plant throughput has been increased by installation of three additional mills. These are 0.9 m (2.9 ft) longer than the other nine and have a higher capacity. Developments in classification and mill speed-up, together with a finer ball mill feed size and substantial improvements to mill availability (99% in 1982) have further increased plant capacity. There is a continuing emphasis on improving grinding circuit efficiency in terms of throughput/grind. Current development work includes trials of graded ball charges, different liner profiles, and assessment of scalping/regrind proposals.

Jan 1, 1985

By R. W. H. Atcherson

BLAST-FURNACE flue dust is one of the most troublesome operating factors in the iron and steel industry. It is usually involved in all the unpleasant phases of blast-furnace operations. It adds to our aggravations until we are willing to spend large sums of money to keep it out of our stoves and boilers acid more money to handle it again and again on one scheme or another to induce the furnaces to retain it without bad after effects. Several successful operators claim that it is useless to recharge raw flue dust because the furnace would never have blown it out if it had been suitable material for blast-furnace consumption. Most of us who have made persistent efforts to return raw flue dust to the furnaces have decided that it is very often false economy to do so. Yet some remarkable results have been attained at the Ohio Works of the Carnegie Steel Co. through recharging raw dust. The plant comprises six modern blast furnaces. Up to 1909, about 300,000 tons of flue dust had accumulated in stock piles. During the last 10 years, there have been recharged into these furnaces all of the flue dust recovered from the furnace operations, the entire stock pile of flue dust, and nearly 80,000 tons of dust shipped from other furnaces of the Carnegie Steel Co. The results obtained are shown in Table 1.

Jan 2, 1920

By H. E. Rowen

As high grade iron ore deposits dwindle and costs rise, sintering becomes more and more important. The steel industry is now faced with beneficiation problems once peculiar to nonferrous work. Succeeding articles describe recent advances in this field. Here is presented the first chapter of a history still being written. SINTERING, for the purpose of this discussion, is defined as the art of burning a solid fuel with 90 to 95 pct ash content. Considering problems of combustion involved in keeping a home furnace burning properly with 12 to 20 pct ash in the fuel, it is evident that combustion represented by the definition has to be right or nothing is going to happen. Our forefathers discovered that many ores containing metals essential to the steadily rising standards of living were associated with elements such as sulfur and arsenic, which had to be removed before refining. This they did by utilizing the solid fuels they had available-the sulfur or other readily combustible components-to create roasting heat. One of the early methods is demonstrated in an old woodcut of the roast heap, Fig. 2. Ore was broken into chunks, piled on an ignition layer of solid fuel-logs in this case-and then. ignited. The sulfide ores roasted as the sulfur burned out. As shown in the background, the countryside was rapidly denuded of all vegetation by the great quantities of SO2 and other liberated gases.

Jan 1, 1961

By J. H. Clemes

The process of leaching silver ores with sodium hyposulphite is comparatively new, and published accounts of the details and losses of the process are as yet very few. The following account of a careful series of experiments to determine the actual loss in this process may therefore be acceptable to members of the Institute. The ore treated was highly calcareous, and the principal sulphide present was iron pyrites. Following is an analysis by Professor Price, of San Francisco, of the ore treated : Per cent. Silica,..........15.13 Sulphur,.........13.31 Arsenic,.......... 9.82 Iron............ 17.33 Alumina,..........1.35 Zinc,...........4.92 Lead,..........1.78 Carbonate of lime,..33.78 Magnesia,.......... 2.58 100.00 Ten tons were crushed dry with a 30 X 30 screen = 900 holes per square inch. In order to feel our way with this ore, two experimental or "pilot" charges were roasted. Pilot Charge No. 1. Treated 1000 pounds in a four-hearth reverberatory. 8.30 p.m.—Entered fourth hearth, remaining there one and onehalf hours; sulphur began to burn. 10 p.m.—Changed to third hearth; ore became red-hot half an hour after entering; the fireplace was kept almost destitute of fuel. 2.30 A.M.—Changed to second hearth. Charge continued, giving off a large quantity of sulphurous fume; the fireplace was kept dark.

Jan 1, 1884

By W. A. Krivsky, R. Schuhmann

PREVIOUS papers in this series on the thermo-•t dynamics of copper-smelting systems have presented a survey of the field and an outline of the overall program: thermodynamic studies of iron silicate slags, 2-4 and thermodynamic data for simple mattes in the Cu-S system.5 Since this program was started, an excellent summary of the whole field of physical chemistry of copper smelting was published by Ruddle. The present paper represents a further step in the study of liquid mattes, and deals specifically with the Cu-Fe-S system. The importance of the Cu-Fe-S system to copper smelting is evident from the fact that these three elements constitute 90 to 99 pct of the totalweight of most commercial mattes. In copper mattes oxygen is an important fourth component. Oxygen was rigorously excluded in the work to be described in this paper. However, the behavior of oxygen in mattes was the subject of a companion research by Lander' which will be described in a subsequent publication. Several studies have been made previously of phase equilibria in the Cu-Fe-S system,8-10 so that the ternary phase diagram is fairly well established in most regions. Also, separate studies have been made of the phase diagrams and thermodynamic properties for the three binary systems: CU-S,5,12-15 CU-Fe,11,14,17 and FeS.11,14,16,17 However, no work has

Jan 1, 1958

By Robert C. Berggan

The hot-milling process for reconditioning rock-drill bits is not new. It has been employed by a few mines for years and in the past decade it has been widely adopted, as its advantages have become better known. Because of the extensive commercial development in England and Canada of machines to operate on this principle, general acceptance has been largely in the British possessions and until recently has been chiefly in the field of conventional steel. In the past two years there has been a definite trend toward hot-milling of detachable bits in Canada, but only in the past year has any considerable attempt been made to build special machines for this type of work. Generally a machine designed for conventional steel has been used and special holders employed to manipulate the bit. As early as 1934 at least one operator in the United States had adapted hot-milling to conventional steel with a substantial saving in resharpening costs.1 Several other operators have taken it up but there has been no widespread adoption of the method in this country by users of conventional steel. This may be partly explained by the fact that until recently no American manufacturer produced this equipment and operators have been obliged to build their own hot-millers or import them. Several years ago a few machines were built in Seattle, Washington, and operated in some mines in the northwest, but, for reasons not generally known, the effort was abandoned. The Process Hot-milling performs the function of re-dressing the bit at a forging temperature of about 1650°F., by the removal of metal from the flutes with a milling cutter, followed by a similar cut from the bit gauge. Conventional bits are thus treated following the usual forging operation in a sharpener, and usually in the same heat.

Jan 1, 1940

By Raymond B. Ladoo, C. A. Stokes

T is unfortunate that the word "economics" has -¦¦ come to mean, in the minds of many people, a sort of half-baked mixture of New Deal philosophy and bookkeeping. It may mean anything from mine cost keeping to the theory of gold as a monetary standard. As applied to the industrial mineral industries as a whole it means to us an integrated study of all of the technical, geographical, market, financial, and other factors which determine whether or not a given enterprise has a sound chance of making a business success. Of course it is impossible to generalize too freely in this large group of industries which go to make up the nonmetallic minerals. This group includes such dissimilar products as crushed stone and ca- pacitor mica, phosphate rock and spinning fiber asbestos, roofing granules and potash salts, borate minerals and monumental granite. Yet in many respects their economic problems are similar and, at the same time, far different from those of the metals and of petroleum and coal. These basic differences are almost never recognized by people outside the industries and are rarely appreciated even by metal mining engineers. But in many instances these economic factors are fully as important as, if not more important than, technologic problems. It has been a long fight to get an intelligent and wide-spread appreciation of sound technology in the nonmetallic mineral industries. The importance of the economic side of the problem has yet to be widely understood and appreciated. The problem was outlined in considerable detail by one of the authors some 18 years ago in a long series of articles* and he has since prepared numerous talks

Jan 1, 1951