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By Christiano Gianesi Bastos Andrade

Clays with high content of smectite are denominated bentonites, and are widely used in industry as, for example, agents for bleaching of vegetable oils, animals and minerals. For this use, the smectite clays are treated with inorganic acid of high concentration at temperatures under boiling point, which provide the bentonite´s bleaching power. In the present study, a sample of smectite from Cubati, Paraiba, Brazil, was submitted to treatment under moderate conditions (90°C, reaction times of 1, 6, 12, 18 and 24hours in close reactor, concentration of the aqueous solution of hydrochloric acid 1.5 M, acid solution/clay ratio of 1g/10mL), aiming to reduce impurities, responsible for the color of the clay, without causing significant changes in their structure. Thus, clay can be used in the cosmetics industry and other products with high added value. The treated clay was characterized by scanning electron microscopy (SEM), stereomicroscopy, energy dispersive X-ray detector (EDS) and X-ray diffraction (XRD). It was observed a bleaching in samples with time of 12h to 18h. With the DRX was possible to monitor the peak intensity of the clay structure and the sample with 12 hours of treatment was not significantly altered its crystalline structure, maintaining the peak clay at d001. The most pronounced changes in the bleaching occurred within the first 12 hours of acid treatment.

Aug 8, 2018

By Thales Botelho

Em função das condições desejadas no processamento do aço no Forno Elétrico a Arco (FEA), a escória final tem teor elevado de FeO, contém fósforo e pode ter, ainda, alto teor de alumina. Para controlar o consumo de desoxidantes, formar uma escória adequada no forno panela (FP) e evitar a reversão de fósforo, é importante minimizar a passagem da escória do FEA para a panela, no vazamento. Assim, é essencial conhecer a quantidade de escória passante para o controle e previsão adequados do processamento no FP. Neste trabalho é apresentada uma metodologia para, através de um balanço de massa levando em conta medidas de composição realizadas durante o processo, determinar a quantidade de escória passante e o volume de escória no final do processamento no FP. É empregado um método numérico simples e demonstra-se que os resultados obtidos são suficientemente adequados para melhor conhecimento e controle do processo por parte do engenheiro responsável, possibilitando gerar informações precisas para cálculos de correções (exemplo: formulação de uma nova escória sintética, correção de desgaste de refratários, ajuste de basicidade, etc.).

Aug 17, 2017

By André Oliveira

The present paper describes state-of-the-art Pulverized Coal Injection technology with focus to Dynamic Distribution guaranteeing highest accuracy on equal distribution and being thus one of the key factors enabling constantly highest injection rates. As an alternative to the construction of a new plant, existing plants may be modernized and upgraded to latest technology. Two recent examples are presented. As a conclusion, two case studies of return on investment are showing that the PCI technology, both for new facilities as well as for upgrades, is very profitable and mandatory for high blast furnace operation effectiveness.

Aug 17, 2017

By Osvaldo Guilherme Comineli

While the hot cracking of Cu-containing steels is a serious and widely known problem for the industry, the literature reports that copper only slightly impairs the hot-ductility measured in laboratory. A distinction is drawn between hot ductility and hot shortness and the respective cracking operating mechanism involved at the respective range of temperature. The representability of the laboratory assessment of hot cracking of Cu-containing steels by hot tensile tests compared with actual results in industrial practice is discussed. The effectiveness of the variable affecting in each cracking mechanism and respective temperature range, focused in improving the hot cracking assessment of Cu-steels and the relative importance of oxidation will also be discussed. It is concluded that the hot tensile test in argon might be a good simulation if properly interpreted and that the role of oxidation is secondary in causing hot shortness. A schematic diagram for the hot tensile test is proposed.

Oct 30, 2017

By Alexandre Silva Guimarães

A extração por solventes sinérgica dos metais cálcio, magnésio e níquel, presentes em soluções aquosas sulfúricas em níveis de concentração similares aos dos licores industriais HPAL (High Pressure Acid Leaching), foi avaliada neste trabalho empregando-se os extratantes comerciais Cyanex 272 e Cyanex 301. O uso de Cyanex 301 (10%v/v) sozinho não se mostrou eficiente, em decorrência do baixo percentual de extração e da baixa seletividade entre os metais. Quando misturado ao Cyanex 272, porém, observou-se a possibilidade de remoção seletiva de magnésio, deixando cálcio e níquel em solução. A melhor condição operacional foi obtida utilizando-se 5-10%v/v de Cyanex 301 e 20% de Cyanex 272, na faixa de pH entre 5,4-5,7, na qual se extraiu aproximadamente 70-80% de magnésio, 15-35% de cálcio e 10-15% de níquel.

Aug 16, 2017

By Michael Brandner

HSM can be divided into different groups such as Conventional HSM with Roughing stands and HSM without Roughing stands = Mills with just finishing stands. The roll requirements for different stands are quite different. In Roughing stands the temperature of the slab is very high. Therefore the resistance against thermal wear/fatigue is the most dominating factor. Today mostly Chrome Steel, Semi HSS and HSS rolls are applied. A comparison and evaluation of such rolls will be described. In the finishing mill the tendency/wish is to use HSS rolls in all the stands. The grade HSS is defined by at least a certain amount of carbide forming elements such as V, W, Mo, Nb etc. The matrix and other precipitations can be adjusted according to the need and situation in the mill. In the pre-finishing stands the HSS is already well introduced. In the last finishing stands the original HSS tended to stick and the cobble rate increased. New development decreased the problem and gave some very promising results. In the last finishing stands beside the high performance a higher resistance against incidents is needed. Solutions in this direction including e.g. residual stresses and special core material will be discussed. Proper testing and grinding procedures can avoid losses and reduce the TCO. Data sourcing and evaluation in regards of rolling and grinding is the key for the optimization of the TCO. Several examples and comparison between different applications will be given in detail and explained. Future possibilities will be discussed as well as results of latest trials in mills.

Aug 17, 2017

By Gerd Weyand

Gontermann-Peipers GmbH (GP) Germany developed a new, high alloyed steel grade for the manufacturing of back-up rolls. The advanced GP double pour casting processes provide highest flexibility in being quite open in rolls work layer chemistry and hence microstructure with no influence on core respectively neck properties. GP took the process advantage to provide a brand new back-up roll grade with remarkably reduced roll wear while operating with textured work rolls. In the meantime several successful trials have been made with this new roll grade on different Skin Pass Mills. As a result the performance of back-up roll and thus availability of mill will be improved while specific costs for mill will drop. This quite new back-up roll grade has recently been launched. As next step increasing the field of applications is under progress.

Aug 17, 2017

By Caio Luca Joppert

O objetivo do trabalho foi estudar a possibilidade de ajustar as características do biogás produzido a partir da fermentação de vinhaça de modo a torná-lo intercambiável com o Gás Natural (GN), ou um GN substituto (GNS) com características que permitam introduzi-lo na rede de distribuição. São considerados aspectos normativos e técnicos associados à composição química e comportamento durante processo de combustão visando o atendimento aos requisitos normativos estabelecidos para o GN. O trabalho considera a vinhaça, rejeito da produção de etanol a partir da cana-de-açúcar, como fonte para produção do biogás em razão da grande disponibilidade deste resíduo do setor sucroalcooleiro. O Estado de São Paulo (ESP) é tratado com destaque, uma vez que este concentra a maior parte da produção do setor sucroalcooleiro no Brasil. Cálculos de razões de mistura tratada com gases de ajuste foram realizados para verificação das proporções necessárias que viabilizam a utilização da mistura como GNS, tendo como referência especificações da ANP. Os resultados do estudo indicam que a alternativa de geração e beneficiamento de biogás da vinhaça é uma opção tecnicamente viável de conversão de fração considerável deste resíduo do setor sucroalcooleiro em gás com características similares ao GN. Ademais, a alternativa proporciona a valoração do conteúdo orgânico do resíduo, com redução da contaminação dos solos no processo de reaproveitamento dos nutrientes nos processos de fertirrigação.

Jul 31, 2018

By Liao Jianfeng

The Baosteel Zhanjiang 5,050m3 blast furnaces have been built with highly independent integration and innovation technologies and represented the state of the art of the world’s huge BFs. The proper of BF1 and BF2 is designed with long-campaign technology; both BFs share the same set of stockhouse, water and PCI systems; the BCQS serial-hopper no-bell top, TRT and blower are all local equipment as applied; four top-combustion stoves systems are matched; the BFG is cleaned by fully dry process; and the automation control system for the main process is self integrated. The BFs have been started up and performing with sound indicators. Their smooth proceedings symbolize China’s huge blast furnace ironmaking technology ascending a new high.

Oct 30, 2017

By Walter Hartig

Rogesa is operating two medium sized Blast Furnaces, No. 4 and No. 5 at Dillinger integrated steel works plant. The history of the results of the cooling concepts of the intersection between tuyère belt and bosh shows failures at both furnaces. At the 3rd reline of No. 5 Blast Furnace in 2010 changes were made to improve the cooling efficiency of the mentioned area. Two rows of copper cooling plates were installed. After commissioning and a short operating time hot spots occurred in the area of the cooling plates. The decision was taken to develop a new cooling concept together with Paul Wurth Umwelttechnik GmbH, Essen-Germany by replacing the cooling plates by one row of a short copper stave. The duration of the shutdown to perform the work was only 17 days including salamander casting. The operational results after the commissioning are very satisfying with outstanding performance of the new bosh cooling system.

Aug 1, 2018

By Ryoma Fujiyoshi

In this article, the technologies of highly durable MgO-C bricks for the scrap impact zone and bottom blowing tuyere of converters are demonstrated. On the bases of our recent investigations, wear of scrap impact zone and bottom tuyere are explainable in terms of crack initiation and propagation. Theoretically, crack propagation in brittle material is regarded as generation of new crack surface area. It occurs when the elastic strain energy stored in the material exceeds the energy required to generate a new crack surface area. Since the overall energy consumed for crack propagation until fracture is evaluated by fracture energy, materials exhibiting high fracture energy can be regarded as materials with high fracture resistance. Therefore, two fracture energy-improving technologies for MgO-C bricks were developed. One is matrix reinforcement and the other is carbon bond enhancement. These technologies were applied to bricks for the scrap impact zone and bottom tuyere. As a result of commercial applications, notable decreases in wear rates were recognized for high fracture energy materials for the scrap impact zone and bottom blowing tuyere of converters.

Oct 30, 2017

By Alexandre Rizek Schultz

Silat, Siderúrgica Latino-americana, selected Russula as the main engineering contractor for their 700,000 tpy Greenfield steel plant dedicated to long and flat steel production. The project is currently under construction in the district Guararu in Caucaia in the metropolitan region of Fortaleza. The project will be developed in two phases. First phase: 600,000 tons per year rebar mill and 60,000 tpy steel mesh line; Second phase: 700,000 tpy melt shop (90 ton/hr EAF and 4 strand continuous caster for billets up to 180 mm x 180 mm).

Aug 16, 2017

By Douglas Glenn Stalheim

Production of structural steel with a minimum yield strength of 700 Mpa produced as hot rolled coil has become increasingly popular due to cost considerations when compared to quench and temper equivalent product. This grade when produced as hot rolled coil requires the use of microalloy precipitation strengthening mechanisms. This is typically a combination of niobium and titanium microalloys. While the metallurgical concept of structural steel precipitation strengthening mechanisms has been well researched and published, actual implementation into the production process can be very challenging. In addition to achieving a minimum yield strength of 700 Mpa, in many applications additional mechanical property attributes of formability as measured by hole expansion testing along with low temperature toughness properties are now required. Achieving a balance of all the mechanical properties in a stable and repeatable performance in production using microalloy precipitation strengthening mechanisms further increases the challenges. This paper will discuss the metallurgical/process strategies required to successfully produce 700 Mpa minimum yield strength hot rolled structural steel coil. In addition, the role and goals of both niobium and titanium in this product design will be presented.

Oct 30, 2017

By Zhisong Chai, Wei Xu

Q&P steels undergo continuous multiple processes, including hot rolling, intermediate heat treatment, cold rolling and continuous annealing etc. The inheritant effect of initial microstructure could affect the final microstructure and mechanical properties of Q&P steels. In this work, effects of different hot rolled microstructure/texture on the final microstructure and properties subjected to Q&P process were investigated in Fe-0.38C-1.58Mn-1.6Si system. Different initial microstructures were generated combing different TMCP and cooling strategies. The microstructure and texture of hot rolled materials were characterized in detail. The hot rolled material was subsequently processed by intermediate annealing, cold rolling and continuous annealing. The comparison reveals great effects of the initial hot rolled microstructures, i.e. inheritance effect. The faster reverse transformation would lead to more sufficient austenitization and it would greatly weaken the inheritant effect of the initial microstructure. Although the difference of final phase fraction for different initial microstructures was not significant, the inheritance effect was mainly reflected in the effect on austenite morphology. For the mechanical properties, no obvious difference in strength was shown for the samples with different initial microstructures after Q&P heat treatment, but there was fluctuation in elongation.

Oct 1, 2019

By Luigi Giacomini, Bruce Kiefer

A new plant for special steel long products was commissioned in recent years at Dangjin, South Korea, for Hyundai Steel. Two multi-line rolling mills can produce yearly 1 million tons of billets, straight and coiled bars, with dimensions from 5.5 to 350 millimeters. The products are used for manufacturing engine and transmission components used by Hyundai Kia Automotive Group. The processed grades include carbon, special alloy, spring, bearing and free-cutting steel. The first mill rolls blooms into finished large round and square products, as well as into intermediate billets. A 2-high reversing breakdown stand is followed by a finishing and sizing train with CGA stands equipped with an under-load roll parting system for automatic gap control. The second mill combines lines of small bars, rods and bars-in-coil. Billets are rolled in a continuous rolling mill with original RedRing Series 5 stands. The rod outlet features Morgan No-Twist and Rod Reducing/Sizing mills, Morgan High-Speed Laying Head and Stelmor conveyor. Advanced sensors and electronics integrate with mechatronic packages, thus equipping the mill for Industry 4.0 applications. Hyundai can meet the demanding requirements posed by the automotive industry and benefit from optimized conversion costs, the flexibility to meet market changes, achieve high product quality, and reduce floor personnel.

Oct 1, 2019

By Pedro Jorge Walburga Keglevich de Buzin

A presença de elementos residuais nas sucatas ferrosas pode influenciar a qualidade do aço produzido na aciaria elétrica. Além disto, o cloro existente nos materiais orgânicos que acompanham as sucatas leva a problemas de ordem ambiental. Por este motivo, o acompanhamento destes contaminantes através de métodos de amostragem de sucata se torna uma tarefa importante na aciaria elétrica. Neste trabalho são apresentados alguns procedimentos de amostragem de sucata, bem como uma análise comparativa de sucatas processadas por moinhos do tipo shredder e sucatas sem processamento. Os resultados mostraram um aumento da densidade e a redução do teor de contaminantes (matéria orgânica, alumínio e aço inox) para a sucata processada por shredder em comparação com a sucata sem processamento. Complementando, é apresentado um perfil da concentração de cloro em diversos materiais orgânicos comumentemente encontrados nas sucatas.

Oct 30, 2017

By Daniel Carvalho, Marcos Viana, Leonardo Demuner, Herbert Castro

Intensive process and technology improvements related to the BOF converter — the key process to increase steel plant productivity and stability — have been performed at Ternium Brazil. This paper details the road map for process developments and investments in equipment technology, as well as the results achieved. The main topics of this development are the process control and optimization systems, slag forming model, oxygen blowing pattern, end-of-blow point control and slag carryover control. The outcomes of this development are improvements in the reblow rate, end-of-blow oxidation, direct tapping, slag carryover, slopping ratio, metallic yield and lining life.

Oct 1, 2019

By Eddy Dierckx

Modernization of flat rolling plants is essential to sustainably fulfill increasing market demands and to improve competitiveness. Intelligent modernizations ensure getting maximum prime yield of existing mills, even if they have gone through half a century of operation. Existing mills were designed based on former production, consumption and quality targets. Ever increasing requirements such as increase of productivity, change of product mix (e.g. new steel grades), reduction of energy consumption and improvement of product quality lead to the necessity to adapt the existing equipment to the new target. SMS group provides, besides the reliable equipment and automation solutions to successful upgrades of existing mills, also a systematic approach to develop technical and economical solutions together with our customers (conceptual engineering). This paper describes the SMS group approach to modernizations / upgrades, introduces powerful performance modules and provides a number of successful examples that have been implemented recently.

Aug 17, 2017

By Andrea Zanon

Slitting processes have been used for many years to increase the productivity of smaller diameter deformed bars, without making major investments in the rolling mill. This technology is used mainly for the production of reinforcing bars (7-20 mm diameter), but successful applications exist also for round bar production. The multi-slitting process enables to produce up to 5 bars starting from one billet, thus increasing the productivity of the smaller products. Danieli Morgårdshammar, world leader in the supply of rolling mills for long products, has been a front-runner in slitting technology since its first applications and has recently developed, first in the world, the technology to produce 5X8mm rebar. This process has been recently applied in BRSM steel, a company based in Bangladesh which is a worldwide benchmark for slitting technology performances. This paper presents the necessary modifications which need to be considered when developing a 5-strand slitting project (and multi-strand slitting projects in general), as well as the results obtained at BSRM Steel when the process was implemented in 2016, the first rolling mill in the world rolling 5X8 mm slit rebars.

Oct 30, 2017

By Henrique Silva Furtado

Light meter is an ArcelorMittal innovation that uses off-gas light intensity to predict bath carbon, which is akin to the visual cues that the operators employ to finish a blow. Light meter enables the prediction of end point that is independent of any operator’s judgment. The results have been in general consistent with the actual carbon content at BOF end point at Tubarão. Besides some outliers that occurred due to strange intensity curves, the system implemented in Tubarão BOF 3 reported a carbon prediction error statistic that is very similar to dissolved oxygen–carbon end point statistics. Preliminary trials using light meter without any filter improved carbon hit ratio significantly.

Jul 30, 2018