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By J. M. Uys, T. B. King

WalSH, Chipman, King, and rant' have measured the water content (as hydrogen) of actual steel-making slags. An average water content of 290 ppm was found for basic open-hearth tapping slags and 114 ppm for acid open-hearth slags. Upon equilibration of these slags at 1550°C with a 25 pct H20-75 pct Nz atmosphere, the water content increased to about 410 and 300 ppm for the basic and acid slags, respectively. Walsh et al. concluded that an acid slag was thus relatively far removed from equilibrium, and that basic slags showed a closer approach to equilibrium, with the water vapor in the furnace atmosphere. Herasymenko2 contended that these conclusions were unjustified, as the oxygen pressure used in the equilibration experiments, ;bout 5 x X atm, was quite different from that found in the furnace. Consequently, during the experiments the slag composition would have changed due to oxidation of ferrous iron. As an extension of Walsh's work and to attempt to clarify this matter, the solubility of water in a basic open-hearth slag was measured as a function of oxygen pressure. Similar measurements were also made on synthetic silicates in the "Fe0"-Fe203-SiO, system. The experimental technique has been described previously by Walsh et a1.l and Uys and King.3 Samples of the basic open-hearth finishing slag, contained in 10-cc platinum crucibles, were equilibrated at 1550°C with atmospheres of different oxygen pressure but constant water-vapor pressure, Ph~o = 0.192 atm. Calculations, as well as measurements, indicate that this figure approximates the water pressure of the combustion gases in a steam-atomized, oil-fired open hearth. Oxygen pressures in the open hearth can vary from 10"2 atm in the combustion gases to between l0-' and 10" atm in the steel bath. The former figure depends on the combustion practice and the latter on the carbon content and temperature of the bath. The oxygen pressure of the slag should lie somewhere between these extremes and is expected to be closer to that of the steel bath than that of the combustion gases. Oxygen pressures were therefore varied between 10" and 6 x l0 atm. At the lowest pressure the slag "puffed up" when quenched (indicating possible loss of water) so experiments were not conducted at lower oxygen pressures. The results are shown in Fig. 1, which includes the water content of the slag "as sampled". The results show that the water content of the slag increased appreciably on equilibration with water vapor at 0.192 atm pressure and that the water solubility apparently decreases with increased oxygen pressure. The solubilities found are comparable to those of the Li20-Ca0-Si02 system.3 Work with synthetic slags in the "Fe0"-Fe203-SiOz system was performed at 1500" C, with Ph20 = 0.192 atrn and for oxygen pressures varying between 10"2 and 10-lo atm. Samples for chemical analysis were prepared as described by Larson.4 The results are shown in Fig. 2. Some low-silica melts tested at low oxygen pressures "puffed up" when quenched and analyzed less than 100 ppm water; these results are not included in Fig. 2. The melts containing 40 mol pct silica also showed a tendency to "puff up" during the quench, when they were tested at the lowest oxygen pressure. These results indicate that, at constant silica content, the solubility of water decreases somewhat with increased oxygen pressure. The effect is, however, small considering the wide range of oxygen pressures studied. Also, at constant oxygen pressure (above about lom5 atm) the solubility increases

Jan 1, 1963

During development mining, ventilation capacity may decrease and the ventilation requirements may depart from initially planned values depending on the mining rate, increases in the methane emission rate, and changes in ventilation airway leakages. Insufficient ventilation air quantities and the occurrences of high methane liberation rates can overwhelm the existing quantity of ventilation air and result in elevated levels of methane gas during development mining. This condition can both limit the development of that section and increase the risk for an ignition that may lead to an explosion. Thus, the prediction of ventilation air requirements prior to mining can enhance worker safety by reducing the likelihood that explosive methane-air mixtures form. This study presents an approach for prediction of methane inflow rates using coalbed methane reservoir modeling. For this purpose, a two-phase coalbed reservoir model of a three-entry type roadway is developed. In the model, grids are dynamically controlled to simulate development of entries. Examples are given for methane inflow and ventilation air requirements as a function of mining rate, development section length, mining height, and the existence of degasification boreholes. This technology can be used to limit the methane concentrations occurring as a result of the influences of various coalbed and operational parameters.

Jan 1, 2008

By M. M. Botz

There are currently more that 460 mines worldwide that utilize cyanide for gold and silver extraction. Despite this large number of cyanide-related mining operations, there have been no published accounts during the previous 25 years of the death of humans due to cyanide as a direct consequence of major mining-related environmental incidents. All published accounts of human deaths due to mining-related environmental incidents have been the result of physical inundation with tailings or waste rock materials. It appears that major mining-related environmental incidents have not been concentrated in any geographic location, are likely to occur regardless of the size of the mining company and do not occur more frequently with a specific type of mining activity. Several cyanide treatment and recovery technologies have been widely demonstrated to reliably control cyanide levels in mining solutions. With proper use of these technologies, tailings cyanide concentrations can be maintained at levels protective of wildlife while reducing the potential for adverse environmental incidents. The development of an international cyanide code of practice or management plan is recommended and should take into consideration the adoption of a weak-acid-dissociable (WAD) cyanide standard that maintains the levels entering a tailings impoundment below 50 mg/L.

Jan 1, 2001

By Thomas P. Mucho, David C. Oyler, Jim Pablic, Dennis R. Dolinar

A room and pillar coal operation in central Pennsylvania was experiencing roof cutters and long running roof falls caused by high horizontal stresses. The roof conditions created hazards for the miners, and caused several production panels to be abandoned prematurely. The mine requested assistance from the National Institute for Occupational Safety and Health (NIOSH) in applying the "advance and relieve" mining to reduce the affects of the horizontal stress during panel development. The "advance and relieve" plan that was developed called for removing a pillar on one side of the panel as it was being advanced, thus creating a cave. The caving then relieved a portion of the horizontal stress across the panel. Because the horizontal stress direction is key to the success of this method, stress mapping as well as mining experience was used to establish the direction of the horizontal stress. Subsequent field measurements provided an estimate of the stress magnitude. Three panels were mined using this technique, and good roof conditions were achieved in all these panels. Instrumentation was used to monitor the stress changes in the roof created by the cave. Stress relief of over 1,000 psi was measured 120 ft from the cave and to depths of 20 ft into the roof. The lateral extent of the stress relief zone across the panels appears to be about 400 to 500 ft. This case history has provided much insight into the practical application of the "advance and relieve" method discussed in this paper.

By G. I. Mathieu, R. W. Bruce

Flotation schemes for the separation of molybdenite from other minerals are based on utilizing the Inherent hydrophobicity of molygdenite (Fuerstenau1). This natural floatability was attributed to the crystalline structure of molybdenite by Gaudin et al.2 who suggested that any surface formed by the rupture of van der Wall's bonds should be hydrophobic and, therefore, naturally floatable. Other authors argued that "natural floatability" is dependent of adsorption of hydrocarbon ions and/or molecu1es on the surface of the minerals. This theory, albeit-c questioned 1,2 has long been recognized in actual practice of molybdenite flotation as the latter in carried out with hydrocarbons, such as fuel oil, kerosene and stove oil. Although conferring ready floatability to molybdenite, these presents generally have little effect on other sulphides and silicates. However, talc is a noteworthy exception because of its innate floatability4. Not withstanding the reason for this behavior which has also been attributed to crystal structure2 its end results as in the case of molybdenite is an immediate flotation response to frothing oils arid kerosene, as was observed by Baranovski5, Sutherland and Wark6.

Jan 1, 1974

A computerised cataloguing system for geological specimens is described. The catalogue is designed for use with a compactus-type storage system. The information stored in the catalogue for each specimen includes the type of specimen, locality information in terms of standard ~ap sheets and descriptive location, geological age, stratIgraphy, and specimen descriptions. The catalogue can be interrogated at any level of detail on the basis of any combination of these specimen parameters.Other information stored for each specimen 'is the compactus address, collection date, reference information and the type of analyses performed on that specimen:Any mterrogatlon produces a listing of those specimens which satisfy the search criteria.

Jan 1, 1974

By Bjørn Nilsen, Werner Stefanussen

The construction of the Guaigui Multipurpose Project includes a 74 metre high concrete face rock fill dam, a 350 metre long diversion tunnel and a 350 metre long spillway tunnel. The topography in the project area is very steep, and the rock masses are characterized as soft rocks. The stability of the 80 to 100 metre high dam abutments and the excavation of the tunnels in soft rock conditions have caused various challenges and problems to be solved. Limited pre-investigations have called to a great extent for estimation of parameters for the stability calculations based on experience. The preliminary calculation of the stability of the planned rock slope above the spillway intake platform has been carried out by conventional partial factor methods and by use of a computed based Slide Program. The two methods of calculation give different results , and that rock support is necessary to obtain an acceptable factor of safety for a slope inclination of 52o. The input parameters for the rock mass characteristics need to be verified for the permanent calculations.

Jan 1, 2006

Investigation on Comprehensive Utilisation of Nickel Slag from JNMC

Sep 13, 2010

By A McDowell

Pound Road Quarry is an alluvial gravel quarry owned and operated by Fulton Hogan Ltd. for the supply of aggregate in Canterbury, and is the largest quarry in the South Island in terms of production. It has evolved from three separate quarries, as a result of which extraction has occurred sporadically in a number of areas. Due to this factor, and the need to manage environmental impacts, a detailed quarry management plan was completed in 1995 which formed the basis for implementation of a certified environmental management system.   In December 1997, the quarry was the first in New Zealand to achieve ISO 14001 (TELARC) accreditation for implementation of an environmental management system. The main potential environmental impacts arising from the quarry operation include dust, noise and groundwater contamination, and visual landscape effects associated with gravel extraction, the mitigation of which is achieved by means of æbest practiceÆ methods. All quarry operations are controlled in terms of the environmental management system by means of regular (monthly and yearly) environmental reviews, appropriate auditing of environmental documents, and monitoring of environmental targets in accordance with consent and statutory requirements.

Jan 1, 1998

By Sergio Sanchez-Segado, Yuan Zhang, Animesh Jha, Ahmad Fahmi Ruzaidi

Niobium and tantalum are considered critical materials because the increasing demand in the energy sector which is reliant on limited abundance of these two metals in minerals. Traditionally, niobium and tantalum mineralsare digested using hydrofluoric acid at moderate temperatures, producing oxy-fluorides which are separated by solvent extraction, involving the use ofhazardous chemicals. The increasing environmental pressures are forcing the industry to search for alternative low carbon processing methods. In this paper alkali roasting based separation and beneficiation, which is not well understood in the literature, is proposed, for which the kinetics and thermodynamic equilibria for the formation of sodium tantalate and niobate with sodium hydroxide are analyzedat the temperature range of 400ºC to 700ºC. The apparent activation energy of formation,changes from 31.0±0.8 to 22.3±1.2 kJ mol-1 and from 23.8±1.2 to110.2±12.8 kJ mol-1, for tantalate and niobate, respectively. The reaction mechanism is examined on the basis of the analysis of reaction products using X-ray powder diffraction (XRPD) and X-ray fluorescence (XRF).

Jan 1, 2015

By Luisa Pérez, Carlos Perea

En el caso de la minería de zinc es común emplear el método de explotación por subniveles, el cual exige rellenar los caserones vacíos, por ejemplo, con una mezcla del relave producto de la planta concentradora de mineral con un 3.5% de cemento, lo que actúa como pilar de sostenimiento de la mina (0.8 MPa). Debido a que al momento de avanzar en los tajos aledaños se producía una dilución con el mineral a explotar y, también, a que era necesario automatizar las operaciones; se decidió evaluar el relleno detrítico cementado, mediante análisis de resistencia, estudios de factibilidad, rendimiento en costos, aumento de productividad y seguridad en la operación. Como resultado, se obtuvieron valores máximos de resistencia de los pilares de 1.6 MPa, lo que evitó la dilución y mejoró el porcentaje de recuperación de mineral.

Jun 30, 2020

In choosing such a threadbare subject for a paper I fear that I may in some measure be taxing your patience, yet as upon the accuracy with which the work is done depends the result of conclusions drawn as to whether a property will be profitable to work or otherwise. The subject cannot be too well threshed out, and I trust that upon certain points that have come within my own experience I may be able to give 'hints that will prevent others from making mistakes. First as to alluvial. Gold is often found from the grass roots down, often ill particular horizontal bands in the wash, but more generally concentrated either on a true or false bottom. When sampling dry ground for proposed hydraulicing I have obtained accurate results only by taking the whole of the dirt from measured shafts, stacking it as it was lifted on a tarpaulin, and putting the whole quantity through a carefully constructed box. In wet ground careful borings will in most cases give fairly correct results, but where it is possible to sink shafts, that should be done, as a guide is then also obtained as to the nature of the wash, whether it is bouldery, cemented, or free. Sampling in a face is a more difficult work in many respects than in new ground, as so many elements enter into action to spoil accurate sampling. Of course the great thing to avoid is sampling in any place where either natural or artificial concentration has taken place, and very much has to be left to circumstance and the sampler's own judgment. In passing I may mention that I have on several occasions seen diggers deceive themselves in wet ground where they were sinking and coping as best they might with water. They would take a dish of dirt from the bottom of their hole, pan it off, and take the result as a fair yield, and on the strength of it perhaps spend a lot of time and money in tail races and whereas in their sample there had been a process of concentration carried on, the movement and working in the water had caused the gold to work down, and anything like accurate estimations by the method pursued were out of the question.

By John Wilson

This report describes the performance of Phase I of a project to design, analyze, and demonstrate a multilift longwall mining method applicable to mining coal seams twelve (12) feet or more in thickness. A non-simultaneous multilift operation is the most viable thick seam mining technique for introduction to the United States coal industry. In the case of the proposed site at Emery, Utah it will result in an increase in coal extraction from 30% with present methods to at least 50% and possibly more. The major technological advance involved in this project is mining a lower lift under a previously mined upper lift. To accomplish this, entries must be developed and maintained beneath the upper lift gob. This will necessitate the use of steel supports at frequent intervals throughout the lower lift' entry system. This has not been done in the U.S. to date. An economic analysis of the project indicates that, while this method will result in a higher than average cost per ton for coal mined, the coal would be competitive with current-operation in the area.

Jan 1, 1976

By Arthur Matzick

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Jan 1, 1966

By William H. Schiffbauer

One of the safety and health research programs of the former U.S. Bureau of Mines Pittsburgh Research Center was the evaluation of technology that will provide remote-controlled operation of mechanized equipment in underground room-and-pillar mining. The purpose of this effort was to enable workers to be located away from the hazardous and unhealthful coal extraction area (the face). As part of this program, advanced machine navigation and control technologies were developed for underground room-and-pillar and highwall coal mining that can be applied to commercially available mining equipment. These technologies use off-the-shelf components and a flexible control software architecture to minimize the effort required to adapt them to mining equipment. An accurate, reliable navigation system that can provide the mining machine's heading and location is a critical requirement for a remote-controlled mining system. After investigating several different types of navigation sensors, researchers selected the Honeywell Ring Laser Gyro Inertial Navigation System (INS) as showing the most promise. It was installed on a continuous mining machine at our Mining Equipment Test Facility. Extensive testing at an open pit (OP) site was also performed. This report describes the INS as it was employed on the mining machine in the laboratory, in the field, and OP tests, and provides the accuracy and performance results of the OP and highwalltests.

Jan 11, 1997

By Andrea Koschinsky, Akira Usui, Michael Bau, Katja Schmidt, James Hein, Thomas Kuhn

Marine ferro-manganese (Fe-Mn) crusts and nodules are metal-rich chemical sediments that are archives of paleoceanographic proxies and potential metal resources and targets of deep-sea mining. Traditionally, crusts and nodules are subdivided into hydrogenetic, diagenetic, and hydrothermal types. While hydrogenetic Fe-Mn crusts are a potential resource for Co, Te, Pt, and REY, nodules are enriched in Cu, Ni, Mo, and Li, and hydrothermal deposits may be enriched in individual metals such as Mo, Ba, and Li, depending on the temperature and composition of the hydrothermal fluid. The different types of marine oxidic Fe-Mn precipitates, therefore, have different economic potential. Hence, a robust classification is not only helpful in the general geochemical characterization of such precipitates (and as such is a useful teaching tool, for example), but may also simplify the evaluation of their importance as a potential metal resource, which helps to prioritize exploration targets for deep-sea mining.

Sep 1, 2014

By F. D. Ford, Z. Dai

"Vale’s Ontario Operations re-introduced Cu/Ni separation at Clarabelle Mill in 2006. The mill processes ores from a number of mines in the Sudbury basin. A saleable Cu concentrate is produced at 30-60% Cu recovery from mill feed, which has to meet the quality specification. In particular, Ni content in Cu concentrate must be less than 0.6%, otherwise, penalties will apply and diminish the value of Cu concentrate, in addition to the lost Ni value. Generally, a Ni grade of less than 0.4% is obtained in Cu concentrate. More recently, while processing Cu-rich ore, Cu concentrate contained more than 0.6% Ni which is abnormally high. Detailed mineralogical investigation shows that Cu-rich ore contains more millerite in comparison to typical Sudbury Ni sulphide ore. Millerite is found to be more floatable than pentlandite and is much more difficult to depress using high-lime aeration conditioning, which is the standard practice in Cu/Ni separation to float chalcopyrite while depressing pentlandite. The current operation uses sodium cyanide at 20 g/t to depress pentlandite and pyrrhotite. However, it is found that a high dosage is required to depress millerite. It is also shown that starch and dextrin are promising in millerite depression.INTRODUCTIONPrior to bulk smelting in 1991, Cu/Ni separation was carried out at Vale’s Copper Cliff Mill, Ontario Operation. The typical Cu concentrate grade was around 30% Cu and 1% Ni. This is very high in comparison to today’s value of 0.4% Ni and would not be acceptable for external processing. However, the Cu concentrate was processed internally at the Copper Cliff smelter/refinery, so the Ni contained in Cu concentrate was not lost and no actual penalties applied. During the SO2 abatement initiative, bulk smelting was chosen because of the perceived simplicity and consequently, Cu/Ni separation was eliminated (Agar, 1991) and the Copper Cliff mill was subsequently demolished. In 2005 and after more than one decade of bulk smelting, business changes required the removal of some Cu concentrate from Clarabelle Mill bulk concentrate to provide smelter capacity for Voisey’s Bay concentrate in the Copper Cliff smelter. In essence, this strategy calls for Cu removal at Clarabelle Mill (Lawson, 2006). In this case, Cu concentrate is sold externally and it must meet the quality requirement of less than 0.6% Ni."

Jan 1, 2011

By T. Lilley

The use of membranes in wastewater systems has increased rapidly in recent years. Microporous or semi-permeable barriers augment conventional chemical or biological processes to meet stringent treatment targets. These developments enable elegant solutions to wastewater discharge challenges and extend the scope of water recycle redressing the overall water balance and operational economics Wastewater treatment processes are discussed by reference to the spectrum of waterborne contaminants and the respective membrane separation capabilities. The role chemical pre-treatment to enable physical separation of metals with micro-filtration (MF) is described and how integration of MF with reverse osmosis (RO) is used to control a broader range of dissolved contaminants Membrane configurations are considered apropos function, operational economics and sustainability. These features are exemplified with case studies. Firstly, MF alone following chemical precipitation for the removal of heavy metals, then MF onto two stages RO of different configurations for TDS reduction and waste volume minimisation and finally an open channel RO alone for the reduction of inorganic COD from a leach stream.

Feb 27, 2013

Tyre costs constitute 20-40 per cent of the operating cost of large haulage trucks, and tyre pressure maintenance is an important factor in minimizing costs.In the past, control over the hot (built-up) pressures of earthmover tyres has been inaccurate and inconsistent because it has not been possible, in a practical way, to measure the tyre's contained air temperature.A method for measuring this contained air temperature has now been devised using a bi-metallic probe thermometer inserted through the valve stem. Using these measurements in conjunction with a pressuretemperaturechart drawn up using the general gas equation, very accurate control over hot tyre pressures is now possible.

Jan 1, 1979

By Heikki Jalkanen

The mineralogical composition and morphology of solidified copper smelting and converting slags are of some interest from slag cleaning (by froth flotation), impurity elimination, and environmental points of view. Properties result from both the state of molten slag before solidification and processes taking place during solidification and cooling. In solidification and cooling, copper and sulfur dissolved in molten slag are .precipitating substantially from the silicate phase. Even in water quenching of slag, dissolved copper is pushed out of the solution in the form of finely divided precipitate. Elements present in the raw materials are distributed in a distinct manner between the solidified slag and non-silicate solidification products. Arsenic, antimony, and tin are strongly accumulated in copper precipitate, but not the other metallic constituents common in copper concentrates. Smelting and converting slags differ remarkably on their mineralogical composition and morphology although resulting principally of same chemical processes. Converter slags are more inhomogenous; they often contain solid particles and copper content is .as a rule higher than in matte smelting slags. The final copper content of converter slags was observed to be in a distinct manner dependent on iron oxide - silica ratio. Slag forming, solidification, and precipitation phenomena are discussed on the basis of mineralogical and morphology analysis of smelter slags and laboratory scale experiments.

Jan 1, 2002