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By S. K. Kawatra, H. J. Haselhuhn

"Fine-grained hematite ore can be concentrated by the process of selective flocculation and dispersion, which relies on proper reagent selection and control of water chemistry. While many previous studies have been performed analyzing the effects of different reagents on this process in a laboratory environment, this paper focuses on investigating the water chemistry within the process in a pilot-scale continuous deslime thickener.The pH, sodium concentration, calcium concentration and magnesium concentration were varied to determine their effects on the iron concentrate grade and recovery, and the phosphorus concentrate grade and rejection in the pilotscale selective deslime thickener. The ideal pH for the iron grade and recovery of the process using a starch selective flocculant was found to be 10.5. Phosphorus rejection, however, was increased at lower pH values. Minimization of sodium concentration was shown to improve iron grade, iron recovery and phosphorus rejection. Calcium acted as a nonselective flocculant showing higher iron recovery, lower iron grade and lower phosphorus rejection with increasing concentration. Conclusions could not be drawn from the experiments that varied magnesium concentration.The zeta potential of the solid-liquid interface of particles in each sample taken was also analyzed to show relationships between zeta potential and process performance. In all cases, a maximization of the magnitude of zeta potential correlated with increased iron grade and recovery. This supports the hypothesis that a higher level of dispersion enhances the selective flocculation and separation process.IntroductionThe United States produced 53.2 million metric tons out of the 3,000 million metric tons of concentrated iron ore produced worldwide in 2012 (Tuck, 2013). With this in mind, there has been a large increase in iron ore processing research (Bolen, 2014; Carlson and Kawatra, 2008, 2013; Halt and Kawatra, 2014; Halt et al., 2014; Haselhuhn et al., 2012a,b, 2013a,b; Liu et al., 2014; Manouchehri, 2014; Sandvik and Larsen, 2014; Semberg et al., 2014). Of the 53.2 million metric tons produced, roughly 8 million metric tons of hematite (Fe2O3) concentrate were produced using a process known as selective flocculation and dispersion (Cliffs Natural Resources, 2011). This process is the only economically viable method for concentrating low grade (< 40% Fe) fine grain (< 25µm liberation size) hematite ores. It is scarcely used due to difficulty in controlling the surface chemistry of the ore and high reagent costs (Department of Energy, 2001; Haselhuhn et al., 2013a). The process is highly dependent upon both reagent selection and precise control of the water chemistry during separation. This study shows the dependence of the process performance of a pilot-scale deslime thickener on the water chemistry in the feed slurry."

Jan 1, 2015

By S. S. Peng

This paper presents a computer program package for predicting surface movement and deformation caused by under-ground coal extractions. It is capable of: predicting final surface movement and deformation over underground openings; predicting dynamic surface movement and deformation process associated with underground lingual mining operations; processing and bookkeeping subsidence survey data; recommending subsidence parameters for those new coal mines where no subsidence data are available; and deducting subsidence parameters from collected subsidence data.

Jan 1, 1986

By Simon B. Blancher, Malo Rousseau, Renato Contessotto, Thomas Wallmach

The Manganese division of the ERAMET group extracts manganese ore in Gabon and produces manganese alloys for the steel industry. ERAMET has an economic interest to maximize the ore throughput without reducing the lifetime of its manganese mines. This can be achieved by means of research and development leading to innovative ore beneficiation processes. For this purpose, the ERAMET research center has designed and constructed a new pilot plant for ore beneficiation by physical separation processes. This pilot facility was erected within an infrastructural and synergetic framework, including competencies in hydrometallurgy, pyrometallurgy, numerical modelling, analyses and mineral characterization that provide ideal research conditions. After laboratory scale tests, a pilot operation of beneficiation of low grade Mn ore (around 35% Mn) was carried out by jigging of the 1-10 mm fraction. This gravity separation process exploits density differences between the various Mn-bearing minerals such as pyrolusite and lithiophorite as well as gangue minerals such as silicates and iron-hydroxides. Enrichment leads to the production of a marketable product associated with a high mass recovery (53% for the jigging step). However, 20% of pyrolusite and 30% of lithiophorite are lost in the waste. Mineral characterization has shown microtextural complexities, but grinding the ore to approach the liberation mesh was not an option due to commercially defined constraints given by the ferro-alloy industry. Recovery of the Mn-bearing minerals or adjustments of the feed grain size (6.3-10 mm) are two potential areas of process improvements identified by means of Qemscan® mineral characterization. This paper details the process tested on a pilot scale (0.5 t/h), which has led to a significant increase in the beneficiation of a low grade Mn ore.

Jan 1, 2016

By Sai Phaninder Reddy Chaganti, Corrina D. Beaven

This study investigates the effect of reagent type, dosage, and pH on flotation kinetics and copper recovery for secondary sulfide ore with elevated clay content. The primary objective was to determine whether Xanthate performs comparably to or better than the currently used primary collector, Thiophosphate. Approximately 80 kg of ore was collected from three blast holes and systematically prepared through drying, crushing, grinding, and flotation testing. Grinding tests were conducted to establish optimal grinding time and lime consumption for pH control, achieving a target particle size distribution in 13 minutes and 30 seconds. Elemental and mineralogical analyses using X-ray Fluorescence (XRF) and X-ray Diffraction (XRD) identified a copper content of 0.36% and significant clay presence, affecting flotation performance. Fifteen flotation tests were performed under controlled conditions, with variations in reagent dosages. Control tests confirmed reproducibility, with recoveries around 80–82%. Increasing the pH did not improve kinetics or recovery, making higher pH adjustments economically unjustifiable. Adjusting the Thiophosphate dosage yielded the best recovery of 83%. Xanthate collectors, tested both as tertiary additives and as replacements for Thiophosphate, delivered comparable or superior recoveries—up to 91.5% in plant tests—and demonstrated faster flotation kinetics, even under high-clay conditions. These findings highlight Xanthate’s reduced sensitivity to clay, potential for lower dosage requirements, and operational benefits such as improved selectivity and circuit efficiency, validating its role as a cost-effective and alternative for processing complex sulfide ores.

Feb 22, 2026

By J. Spotts McDowell

Ackowledgments........................... 5 Introduction............................. 5 The Silica Minerals. Stability Relations......................... 6 Optical Properties........................ 9 Density.............................. 10 Melting Points....;..................... 10 Thermal Expansion..................,..... 10 Solubilities............................ 12 Identification of Cristobalite and Tridymite.............. 12. The Silica Refractories. Raw Materia1........................... 13 American Deposits....................... 13 Properties Determining Usability................ 15 Expansion on Heating..................... 16 Texture........................... 17 Silica Brick............................ 17 Manufacture........................... 18 Properties of Silica Brick .................... 19 Analysis ......................... 19 Density......................... 19 Porosity......................... 20 Strength....................... 21 Melting Point....................... 22 Specific Heat....................... 22 Thermal Conductivity................... 23 Expansion........................ 24 Effect of Rapid Temperature Change.........:... 26 Constitution......................... 26

Jan 1, 1918

By W. K. A. Congreve

Introduction Less than a hundred years ago the engineer was able to do his job without concern for the science that underlay his practices or for the men who operated his machines. But toward the end of the last century science began to be applied to industry, and its success was such that the plant which clung to empiricism was unable to compete with the plant that followed science. Even more recently, the engineer has been forced to consider the men who operate his machines, for modern large-scale industry has given these men education, social security, and power. Hence the engineer can get good, steady labour to operate his machines only if he can offer inducements. Wages are in general outside the control of the engineer, but he is able to control working conditions. This essay is concerned with one factor of good working conditions: safety. The writer became interested in this problem during three months&apos; summer employment as a student at the Sullivan concentrator of the Consolidated Mining and Smelting Company and was surprised at the distance his investigations led him from the field of pure engineering into the fields of psychology, education, and publicity. Nevertheless, because safety has to do with machines and with men who operate machines, and because it profoundly affects plant efficiency, it is the job of an engineer, not of a psychologist or teacher, nor of the salesman publicity expert who is often so unfortunately employed in personnel relations. The size and complexity of the subject has limited the scope of this essay to the consideration of only a few aspects of industrial safety. Considerable attention has been given to the underlying principles, but the mechanical side of accident prevention, the design of equipment, erection of guards, etc., and the very important problems of organization and administration, have not been given attention proportionate to their importance.

Jan 1, 1948

By Robert B. Parsons

"Starting January 1, 1987 employers, employees, and other taxpayers are confronted with a new set of rules dealing with the taxation of travel and housing benefits relating to isolated posts in Canada, and tax deductions relating thereto. The new rules may not be the simplest in the world, but they are reasonably fair and at least offer a hitherto unknown degree of certainty as to how such allowances are to be treated. IntroductionThe first shoe fell on February 26, 1986 when Finance Minister Michael Wilson&apos; s first budget presented the framework for the future tax treatment of travel and housing benefits (so-called ""northern allowances"") provided to residents in remote regions of Canada. The second shoe fell some ten months later on December 22, 1986 when the Minister of Finance filled in the earlier announced framework with detailed rules. We now have a complete picture of the tax treatment of northern allowances. Here is what the picture looks like with effect from January 1, 1987.According to Revenue Canada, the net housing benefit to employees will be equal to the value of the accommodation provided, less any rent they have paid. In major centres such as Yellowknife and Whitehorse, having a developed rental housing market, the benefit amount will be based on the fair market value of the rental accommodation in that location. In other areas, employers will be required to value the housing benefits and, to assist employers, Revenue Canada has provided the following guidelines: Common shelter- $100 per month including the value of subsidized utilities Apartment! duplex-$270 per month excluding the value of subsidized utilities, or $400 per month including the value of subsidized utilities House-$450 per month excluding the value of subsidized utilities, or $650 per month in- c1uding the value of subsidized utilities.The amounts established as the values of accommodation will be adjusted annually after 1987 based on the housing component of the Consumer Price Index."

Jan 1, 1987

By Chenxi Ding, Chenglong Xiao, Guoli Shi, Zhiwei Zhao

This study investigates the directional blasting of a 90° slit charge structure using laboratory experiments and field tests. A 90° slit charge suitable for the corner of roadway is proposed. After the slit charge blasting, two long main cracks along the slit, and several short secondary cracks in other directions. The slit charge not only significantly reduces damage to the surrounding rock, but also improves the quality of the roadway contour. In addition, a comprehensive damage evaluation system of the roadway contour and the surrounding rock is constructed using digital image analysis, borehole televiewer, and CT scanning.

May 23, 2024

By David Newman

"Horizontal stress can have a profound effect on the stability of an underground limestone mine. The presence of horizontal stress is usually determined once the mine has been developed and the orientation of headers and crosscuts are well established. Multiple attempts are typically made to control roof falls without re-orienting the mine. Once the decision has been made to change the orientation, pillar centers, mine opening widths, and the question of how to determine the correct orientation must be answered.A case history is presented to illustrate how geologic structure, ground conditions and roof falls in adjacent mines, the World Stress Map (Heidbach et al., 2016), in-mine measurement of “cutter” roof orientation, the orientation of strata offset (cats eyes) within borescope holes, and the diametral deviation method of determining horizontal strain from drill core were used to establish the most likely range of horizontal stress.The main headers were re-orientated in a direction parallel to the median of the range of horizontal stress. The crosscuts were angled 60° to the headers to avoid being perpendicular to the horizontal stress direction. Pillar centers and opening widths were increased in the favorable stress direction of the mains and decreased in the less favorable crosscut orientation. The major principal horizontal stress magnitude was estimated using the strain measurements from the diametral deviation method and elastic modulus obtained through testing.INTRODUCTIONOver the past decade, there has been a significant increase in the number of underground stone mining operations in the United States. As stripping ratios at surface quarries become uneconomical and reach the extent of the mineral boundary, coupled with the encroachment of urban development on previously rural mining operations, the remaining mine reserves are best accessed through underground development.Although the majority of underground limestone mines in the Midwest are in relatively flat lying deposits with minimal geologic structure, many Appalachian mines are in folded and faulted environments. Tectonic horizontal stresses associated with multiple orogenic episodes are locked in the formation and are released as the underground mine is developed.A common misconception is that horizontal stress impacts are more prevalent at shallow depths where the ratio of horizontal to vertical stress may be high. However, field observations and academic research indicates that horizontal stress conditions may be encountered at any depth due to the tectonic compression of the limestone formation (Esterhuizen et al., 2007; Dolinar and Esterhuizen, 2007; Iannacchione et al., 2003; Slaker, Murphy, and Miller, 2017; Kuhnhein and Ramer, 2004). This paper outlines mine design and layout guidelines for the mitigation of horizontal stress impacts on underground stone mining operations through a case history example. This approach to mine planning and the ability to anticipate horizontal stress can significantly improve future production of multiple levels (Newman and Newman, 2019). As underground stone production continues at deeper depths and in more geologically and geometrically complex mining conditions, an emphasis on ground control and the anticipation of horizontal stress can provide safer and more productive single and multiple level mining operations."

Jan 1, 2019

By W. P. Sykes

IN CONNECTION with a study of tungsten steels, Honda and Murakami1 reported an investigation of the system iron-tungsten. This report included a tentative equilibrium diagram, photomicrographs of various alloys in the series, and qualitative measurements of hardness and magnetic properties. The present investigation originally had as its object the study of the hardness and tensile properties of a series of carbon-free iron-tungsten alloys. But, as the work progressed it became evident that the system possessed other features of interest, so the scope of the investigation was enlarged. MATERIALS The iron powder used in preparing the alloys was obtained as follows: Iron oxalate was precipitated from a ferrous-sulfate solution by the addition of a solution of oxalic acid. This oxalate, after thorough washing, was ignited to iron oxide, which after reduction in hydrogen at about 1000° C. yielded iron powder containing but about 0.2 per cent. iron oxide and about 0.005 percent. carbon. Tungsten metal in the form of powder, such as is used in the manufacture of filaments for incandescent lamps, was the other constituent. This material analyzed 99.8 per cent. tungsten and contained no carbon, The metal powders, in the desired proportions, were mixed by tumbling and formed, under pressure of 20 tons per sq. in., into rods 3/8 by 3/8 by 10 in. To form the alloys without contamination, sections of the pressed rods were placed on alundum slabs and heated in an alundum tube wound with a tungsten resistor and packed in heat-insulating material. While the resistor was heated, a stream of hydrogen was continually passed through both the tube and the case containing it. The tungsten winding on the tube, as well as the material heated within the tube, was thus protected from oxidation. Such a furnace will operate constantly

Jan 2, 1926

By AIME AIME

CHARLES A. CHASE, manager of the Shenandoah-Dives Syndicate, operating the Shenandoah Mines in southwestern Colorado, reviewed the current work at that property at a recent meeting of the Colorado Section, in Denver. This operation is a new one, having been in effect only two years, but the properties that were consolidated by Mr. Chase had had certain production in earlier years, since when they had: been inactive. These properties are located. in the high mountains of the San Juan section in Colorado, and although they had had a substantial production of ores of good grade in the upper levels, the project as a whole involved the bold undertaking of driving through the mountain, starting on the Mayflower claim on the Arrastre Gulch side and passing through the Mayflower, Slide, Terrible, North Star, Dives and Shenandoah No. 3 claims. This is a distance of over 8,000 ft. which is known to be mineralized, and the main operating tunnel was started at an elevation of approximately 11,000 ft. The main exploration work has already extended in nearly 4,200 ft. and the present mining production of nearly 550 tons daily is being secured while the main exploration work is being continued. The main heading is now within the North Star claim and the plan of operations involves continuing ahead for a few hundred feet and then starting an upraise which will he 2,200 ft. high and which will connect with the old workings of the North Star mine. The plan of ruining then will he to drive levels along the vein in both, directions to daylight and retreat downward, taking out all the ore and abandoning, the workings after the ore is removed. In this way one level after another progressing downward will be abandoned. The raise will be of two compartments, one of which will carry the 8-ton skip and the other the counterweight and manway. So far the ore has been broken over an average width of more than 11 ft., with an output of 39 tons per machine shift.

Jan 1, 1932

By Yuanhong Qi, Xun Fu Wang, Tao Fu, Kunkun Cui, Yingyi Zhang, Jie Wang, Junmao Qie

With the sharp decrease of sulfide nickel resources, the nickel laterite is becoming more attractive as nickel oxide, nickel matte, and nickel-iron. This study investigated the mineral phase structure, chemical analysis, thermal properties, and element distribution characteristics of the rotten rock layer deposited in the Southeast Sulawesi Ophiolite Belt. The results show that the nickel laterite deposited in Southeast Sulawesi Island, Indonesia, belongs to the typical high-nickel and low-iron garnierite-type laterite. The concentrations of nickel and iron of the nickel laterite are 1.99 wt% and 17.55 wt%, respectively. The serpentine, olivine, clay, chlorite, hematite, and magnetite are the major minerals, and the pyroxene, actinolite, limonite, and chromite are the minor minerals in the nickel laterite in Southeast Sulawesi, Indonesia. Serpentine and olivine are the main nickel minerals with an average nickel concentration of 3.65 wt% and 1.73 wt%, respectively. The Fe and Ni have homogeneity and symbiosis in the serpentine and olivine, and their concentrations are often positively correlated.

By K. H. Luo, J. Y. Liu

An experimental study on interparticle breakage of three iron ores was carried out by compressive stressing of particle-bed in a piston-die device. The feeds to the particle-bed stressing were five narrow size fractions in the size range of 0.2~3.2 mm respectively and a wide size fraction of 0/4.0 mm. The pressures applied were in the range between 30 and 360 MPa. The results show that the energy absorption of the particle bed increases linearly with the pressure; the increase of the product fineness with the pressure declines as the pressure goes up; and the product size distributions resulting from interparticle breakage of different narrow size fractions have no self-similarity. Using data obtained from the piston-die compressive stressing test, the suitability of a previously-developed material-characterization model for interparticle breakage was verified for these ores. It is shown that the particle-bed compression test conducted with piston-die device in lab-scale may provide a cost-effective way of studying and modelling size-reduction of ore materials by interparticle breakage.

Jan 1, 2014

By F. E. Gregory

MINING methods and customs in many districts of England are to this day strangely bound about by the records and traditions of the past. In some mining fields this is more apparent than in others, yet it is everywhere in evidence, for Cornwall with her mines under the sea, Wales with her famous quartzites, and Derbyshire with her remarkable cavern deposits, are all tinctured with quaint customs that have come out of the almost forgotten past. Here, modernism has never replaced tradition, and many of the laws are woven of the woof and warp of ancient custom. Indeed, these things exist because they have come to be part and parcel of the civil laws. And these laws are observed with meticulous care and accorded all the reverence due their venerable age. All activities pertaining to the mining of metals are hedged around by curious and ofttimes clumsy laws, each minute and trivial detail being covered by the civil code, and each petty law enforced by an ofttimes pompous official.

Jan 1, 1933

By Eduardo Lozano, Vilem Petr

The use of explosives bring countless benefits to our everyday lives in areas such as mining, oil and gas exploration, demolition or avalanche control. However, because of the potential destructive power of explosives, strict safety procedures must be an integral part of any explosives operation. The goal of this paper is to provide a solution against the hazards which unfortunately accompany the use of explosives. For this reason, a blast shield is specifically designed and tested for protecting personnel against these unpredictable effects. This document will develop a complete analysis answering the following questions: what are the potential hazards from an air blast; what are their effects; and how can we be protected against them. In order to answer these questions, theoretical, analytical, and numerical calculations are performed. Finally, a full blast shield prototype is tested under blasting conditions proving its effectiveness as a safety device while explosives are used.

Jan 1, 2015

By S. Luidold, A. Poscher, H. Antrekowitsch

"The rare earth elements (REE) are nowadays mainly used for permanent magnets, catalysts, hydrogen storage alloys in rechargeable batteries, for glasses, ceramics, and polishing agents. Other important areas of application are phosphors in different types of lamps (fluorescent tubes, energy-saving lamps, etc.). These lamps are often collected and treated at their end of life by disintegration and sorting. However, the obtained fine fractions comprise not only REE-containing phosphors but also small amounts of mercury and are therefore disposed till today in special landfills. Due to the enormous price increase of the rare earths during the last two years, a lot of activities started for extracting these elements from secondary resources such as for example phosphors. All recycling concepts for this task mainly work with hydrometallurgical methods. The large number of different compounds in phosphors with sometimes very different behaviors with respect to their solubility in aqueous phases forms a major challenge to achieve good yields as well as acceptable purities of the produced rare earth concentrates by a process with a reasonable number of operation steps. Therefore, this paper gives at first a brief overview about the compounds, used as phosphors and about existing concepts or investigations. It further describes our own process design and the results, obtained on laboratory scale. INTRODUCTIONThe rare earth elements (REE) have a central position in the industrialised world despite their marginal production volume in comparison to common metals such as aluminium, copper, zinc etc., because they are essential for many applications. They often cannot be substituted without a considerable loss on functionality and quality. This group of metals comprise the lanthanoids (f–block elements, lanthanum–lutetium) as well as scandium and yttrium.The estimated world mine production of REE amounted to 133,000 t rare earth oxide equivalent in 2010, whereat China accounted for 130,000 t or 98 % (Cordier, 2012). The European Union (EU-27) imported 23,013 t in 2008 to cover its demand. The figure 1 shows the fraction of the European member states in terms of the total imports of rare earth compounds from outside the EU-27 (Schüler, Buchert, Liu, Dittrich, & Merz, 2011)."

Jan 1, 2012

By G. Melcher

"A través de la introducción del proceso de flotación, el horno de cuba perdió su importancia como unidad de fusión en la metalurgia del cobre. El producto obtenido mediante este proceso de tratamiento de minerales constituye un concentrado de flotación de granulometría extremadamente fina. En ese sentido, el presente texto señala un proceso de fusión en el cual el combustible natural del concentrado: el azufre, se utiliza para el trabajo de fusión. Asimismo, la tostación y la fusión se realizan en una sola unidad de horno y la gran superficie natural del concentrado de flotación, se aprovecha para la fusión, de modo que el concentrado sea tostado en suspensión y al mismo tiempo, fundido. Finalmente, la cantidad de los gases que reaccionan con los sólidos, puede aumentar considerablemente y, por lo tanto, igualmente la velocidad de reacción. "

May 1, 1979

By D. G. F. Hedley, D. F. Coates, K. Barron

INTRODUCTION Preceding papers presented in this symposium have considered the influence of various parameters, such as geologic structure, groundwater, etc., on the stability of rock slopes and have given some analyses and guide lines for slope design. To carry out such analyses it is necessary to put numbers to these parameters; where possible, this is best done on the basis of in- situ observation and measurement. Since none of the design analyses can be considered exact and since conditions vary during excavation, it is also desirable to monitor the behaviour of the slopes as the excavation proceeds. In this manner a feedback of information on the actual excavation conditions can allow a continuous reassessment of the design parameters to be made and can give early warning of incipient failures. The purpose of instrumenting rock slopes is thus to provide information which fits into one of two categories: (a) To give basic data to assist on-site assessment and design of the rock excavation. (b) To provide data for the control and assessment of safety during excavation. The purpose of this paper is to review briefly some of the instruments and measuring techniques available for gathering this data and to indicate where such data may prove useful. This is not a comprehensive review of all available instrumentation but, rather, is a survey of some of the instruments and techniques with which the authors have had some experience and which have proven useful. STRUCTURAL ASSESSMENT Whilst most structural assessment of a site is done on the basis of geologic mapping and core examination, there exists some instrumentation which can, in particular circumstances, assist in this assessment. Seismic instruments can be used to determine the geometry of formations and to give an indication of the relative competency of rocks. These instruments operate using seismic reflection or refraction techniques and, although mainly confined to shallow sub-surface exploration, can be useful in distinguishing between soil/ bedrock contacts and, in some cases, the extent of weathered surface rock.

Jan 1, 1971

By A Suokas

Boliden Tara Mines Ltd, located in County Meath Ireland, produce in excess of 2.5 million tonnes per annum of ore from the underground resource located 40 miles north west of Dublin. The zinc-lead ore is mined using long hole open stoping techniques, with ore treated on site. The operation is continually searching for new ways to improve productivities at the mine, and have employed a detailed data acquisition and reporting system on site to provide feedback around performance. One area where both Boliden Tara Mines Ltd and Orica Mining Services believed improvements could be made was in the application of bulk emulsion technology through an Orica supplied but Tara operated Maxipump Delivery System for all production and development blasting at the mine. Both parties committed to the evaluation of this technology at the mine, however the capital cost and technical and economic changes meant the project needed to be diligently investigated and any improvements documented. The first stage of this project was for Orica Mining Services personnel to visit the operation, and conduct a detailed analysis of the operationÆs performance over the past 12 months. The next step in moving forward was then to commission and utilise the customer operated emulsion system at the mine. This was then followed with the collation and analysis of data from the demonstration period to examine and document the benefits of the system. This paper is a summary of the observations made during the site inspection and the data analysed to date, and has been used in determining operational and financial improvements in the comparison between a Maxipump Emulsion Service and the current ANFO loading systems.

Jan 1, 2005

By Charles L. Richman

The effect of the addition of Silver Sulfide on the rate of Chalcopyrite (CP) of Sulfuric acid (H2SD4 leaching is discussed, Although Ag2S in an expensive addition, a theoretical explanation of it&apos;s use will aid in the development of a economic substitution. We have used cyclic voltammography to show the presence reaction species at different potentials. Cyclic Voltammography maps the surface reaction current peaks on CP, to regions on the CP Phorbaix diagram. AC Electro-lmpedance spectroscopy (EIS) models the surface impedance properties, which control the rate of electron and ion transfer, and the surface kinetic reactions, with and with out light. EIS and other measurements show that AgCuS u Photo-reactive material- The EIS results are compared with the SEM and EDXA results to show the presence of diffusion pores, and diffusion controlled reactions during CP leaching without the addition of silver sulfate. We hypothesize that AgCuS is an ionic conductor like Ag2S. EIS shows an imposed negative leaching rate greatly. Our theory shows how the formation of Silver Copper (1) sulfide layer at open circuit potential gives an effect similar to negative potential, that is enhanced with illumination. We verify that AgCuAS is an N-type semiconductor that forms a diode type junction with the electrolyte with the Mott-Schoottly relation.

Jan 1, 2001