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By G. Derge

The chemical and physical propertties of slag systems are of special interest to metallurgists, for nearly all metals are in contact with molten slags during the primary reduction from their ores and then during the subsequent refining and alloying processes that determine their ultimate use. These processes are carried out at high temperatures and involve such complex chemical systems that funda-mental scientific knowledge of the Properties and behavior of these slags is inadequate. Various hypotheses have been Proposed to explain known slag characteristics. The commonest of these regard the molten slag as constituted of compounds that are dissociated in varying degrees into their constituent oxides, as illustrated by Schenckl and the recent Papers of Chipman and co-authors. Another proposal is that these compounds dissociate by com-plete6 or partial ionization, the evidence for which has been reviewed by Martin and Derge.? whatever hypothesis is favored, the exact formulation of these compounds is incomplete. It is based on three principal types of information: 1. Studies of solidified 51% samples by X ray diffraction, petrography, and similar methods that can be used at room temperature. The correlation of this information with the high-temperature properties of the molten slag is uncertain. 2. Studies of slag-metal equilibria, which have the advantage of providing observations on the molten slag at high temperature. However, even these data present problems of interpretation because they require a complete knowledge of the metal phase. 3. Direct measurements of properties of molten slag at the temperature of greatest metallurgical interest. Viscosity, electrical conductivity, specific heats, and similar properties have been measured, but the data of this type are widely scattered and frequently difficult to interpret. Additional direct measurements of properties of molten slag that can be interpreted in terms of chemical behavior are required, and this paper shows that the standard physical-chemical measurement of reversible electrode potentials, which measure the activity of specific constituents, is a fruitful source of such information. The purpose of this investigation, therefore, was to find an electrode combination that would yield reversible electromotive force measurements when dipped into the molten slag to be studied. Slags of the systems cao-sio2 and cao-120,-SiO2 were chosen for study because graphite containers could be used and the data could be correlated with those for viscosity, conductivity, and other proper-

Jan 1, 1948

By Y. Lin

It is difficult to remove arsenic and bismuth from antimony in the process of crude electro refining. The electro refining of antimony has been studied using ammonium fluoride-antimony sulphate electrolyte system. The Influence of temperature, current density and additives on arsenic and bismuth removal from crude antimony has been investigated in this paper. Optimum process parameters, namely, temperature of 25?, current density of 400A/m2, distance between anode and cathode of 50mm, electrolytic period of 24 hours, oxalic acid dosage of 10g/L and complexon III dosage of 0.2 g/L have been ascertained.

Jan 1, 2014

By P. Pal Roy, R. B. Singh

"This paper focuses on a number of interesting results to establish the theory and principle of air-deck blasting. It also gives the mechanism of breakage that takes place in air-deck blasting under varying charge load conditions. With these aspects in mind, the mine management can implement this up-coming technology to enhance safety and higher productivity. IntroductionThe method of air-decking has become an increasingly popular technique in production and presplit blasting. In the blasthole, an explosive column is combined with an airchamber. The main aim of the technique is to control breakage through effective distribution of explosive energy and thereby enhance uniform rock fragmentation. An air column lowers the initial pressure of the explosive products and simultaneously increases the time of interaction for the detonation front with the surrounding rock, which enhances rock breakage.To study air-deck blasting, CMRI initially conducted experiments using indigenously developed, low-cost wooden spacers of different sizes and strengths. Air-deck blasting was first tried using these spacers in 1993 at Jambad OCP, ECL and Chasnalla OCP, IISCO. The experiments were extended in 1994 at Bermo Mine, DVC. The results were subsequently published by Pal Roy et al., in 1995. It is worth mentioning that the performance of air-deck blasting during this period was only compared with conventional blasting practices without going into detail of the theory behind the process."

Jan 1, 2001

By A. J. Farstad

The use of radio signals for underground communications was considered as early as the mid-1920's [1] - [4] . However, early experiments did not produce promising results with the type of equipment that was available then [5] . With advancements in solid state technology many of the schemes considered impractical in the early days suddenly became practical. The properties of electromagnetic wave behavior in conducting media have been intensively studied by Wait [ 6] and others and can be utilized not only in communication with trapped miners, but also as a means of locating their position. This report deals with the development of portable electromagnetic equipment, powered by the miner's conventional lamp battery, which can be used to alert surface rescue personnel of the trapped miner Is location. The Westinghouse Georesearch Laboratory (WGL) under BUMINES sponsors hip initially approached the trapped miner location problem using seismic techniques. It was learned from this effort that two serious shortcomings of seismic techniques are (1) the extremely weak signals available on the surface from miner generated hammer blows, requiring long processing times at the surface receiver, and (2) the relatively slow procedure of deploying geophone arrays to sense the seismic uplink signals. By contrast, the electromagnetic techniques have proven much more practical from a deployment time standpoint and in most cases have also proven to be more accurate in determining location. Furthermore, these techniques have been successfully tested using a receiver in a heli- copter for reconnaissance purposes. However, before any electromagnetic location technique can become fully operational, the miners themselves must be equipped with emergency transmitters to be carried with them on each work shift. Consequently, much emphasis has been placed on the development of extremely lightweight transmitting equipment. The performance of some of the electromagnetic location equipment developed by Westinghouse will be described in the following sections. 2.0 Basic Concepts Theoretical concepts for locating magnetic dipoles in the earth have been treated by Wait [ 7] and Olsen [ 8] . A generalized curve for the attenuation of magnetic fields in a conducting half-space is derived from

Jan 1, 1973

By James G. Schotsch

Unmapped abandoned mines are hazards for under¬ground mines, surface mines and surface structures. The Radio Imaging Method (RIM) provides a cross borehole technique to remotely detect abandoned mine works. RIM was used at the Buck Creek Mine, an underground coal mine, to determine the extent of unmapped mine works. The information provided by the RIM survey assisted the mine planners in developing their mine.

Jan 1, 1990

By R. E. Hoffman, R. A. Ward

The self-diffusion coefficient in high purity nickel has been measured over the temperature range 870' to 1248°C. The results are described by the relation D = 1.27 exp[—-66,800/RT 1cm2ec-1. The measured activation energy correlates satisfactorily with absolute melting point, heat of fusion, and heat of sublimation. KNOWING the rates of self-diffusion is important in the understanding of many metallurgical reactions. However, in spite of the rather widespread interest in nickel, both commercially and in fundamental investigations, no measurement of the self-diffusion in solid nickel has previously been re- ported." In connection with a program of measuring rates of diffusion in some nickel alloys, self-diffusion in pure nickel has been investigated over a rather wide temperature range by combining a sectioning technique and a surface counting technique.

Jan 1, 1957

By Antônio Carlos Aguiar Gagno Junior

O Sistema de Controle de Equipamentos de Radiofrequência (SCER) nasceu a partir de uma demanda da área de Telecomunicações com o objetivo de minimizar as interferências dos diversos equipamentos emissores e receptores de ondas de rádio existentes em todo o perímetro da Usina ArcelorMittal Tubarão. Anterior ao sistema, todo o cadastro, controle e alocação destes equipamentos era feito em planilha Excel, mantida pela área de telecomunicações. Todas as verificações para liberação da instalação/configuração do equipamento a ser instalado eram feitas manualmente, com auxílio de equipamento analisador de espectro de frequência. Com a implantação do SCER, as fragilidades do controle manual foram supridas, trazendo o diferencial de cálculos automáticos de interferências feitos pelo sistema em função dos parâmetros de ajuste de cada equipamento, da sua abrangência e localização geográfica. Através de uma interface Web, os usuários podem não só controlar os equipamentos, fabricantes, modelos e aplicações, como também visualizar em mapas, com georreferenciamento, as áreas da Usina em que estes equipamentos atuam, bem como alterar os polígonos e perímetros de alcance e abrangência das áreas.

Aug 16, 2017

By Norman G. Foster

The mass spectra of four tertiary butyl substituted thiophenes are reported. A comparison and contrast with earlier structure correlations made by API-RP48 mass spectroscopists is presented. The fragmentation routes of these types of molecules are discussed and explained in terms of existing theories in mass spectrometry. Low ionization voltage data are presented to support the mechanistic picture developed. Structures are inferred about some of the ions, and these are correlated with existing theories. Metastable peaks in the spectra are used to support the fragmentation paths. The presence of doubly charged ions in the spectra is noted and the possible implications toward mechanisms discussed. The general picture of simple, small fragments leaving the ion moiety upon further fragmentation is developed in detail. Some suggestions are presented for further work utilizing isotopically labeled molecules to establish firmly the general picture of fragmentations of the alkylthiophenes.

Jan 1, 1966

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By Carol A. Hill

Native sulfur occurs with barite, celestite, and bioepigenetic calcite in the Culberson, Pokorny , and Leonard Minerals deposits, Delaware basin. The sulfur in these deposits, in "castile" masses, and in deposits of the Fort S tockton district have 6 34s values between +9 and -15. Native sulfur in the caves of the Guadalupe Mountains is somewhat lighter [(634s = -15 to -25)]. Barite in the Culberson, Leonard Minerals, and Comanche Creek sulfur deposits have 63% values of +35 to +73; celestite in the Culberson and Leonard Minerals occurrences have values of +38 and +36, respectively, and 87Sr/86Sr values of 0.707808 and 0.708138, respectively. Barite associated with sulfide, deposits, Guadalupe Mountains, have [634s] values of +41 to +62. Barite at Seven aeart Gap, Apache Mountains, is somewhat less enriched in heavy sulfur [(634s = +14 to +37)].

Jan 1, 1992

By T Tan, C P. Holmes, C E. Hartford

Transportation of iron ore from the mine to the plant is critical to business success. Ore from the mine may have to be transported across states, countries and even continents to get to the processing plant or export facilities, and ultimately to the client. Numerous transportation steps may result in potential logistical difficulties. Companies are continually seeking ways to increase production rates, decrease delivery times and reduce operating costs. Transportation cost is a major component of the total cost of mining iron ore and therefore requires effective use of transport systems.Bottlenecks in iron ore transport systems, due to material handling issues, can result in loss in profit in the order of millions of dollars per hour. Bottlenecks can be seen anywhere in the transport system where the desired flow rate cannot be achieved. These bottlenecks occur for various reasons such as increasing throughput in a transport system originally designed for a lower throughput resulting in plugged transfer chutes, changing material characteristics (eg finer material, increased moisture content), changing to a new type of material or blend that again alters handleability, or changes in operational philosophy due to equipment availability or process utilisation.Stockpiles may have limited live capacity such that an adequate amount of ore may not be readily reclaimed when required (eg to fill a complete train’s railcars). In bins and hoppers, material may discharge through a central flow channel resulting in the formation of a stable rathole, which can then collapse causing material to flood the downstream system and cause significant downtime for clean-up (eg railcars beneath train load outs). In transfer chutes, bottlenecks can be caused by pluggages or downtime required for the change-out of liners due to excessive wear. In ship loading, long settling or de-aeration time, or material exceeding its transportable moisture limit (TML) may result in further bottlenecks. These bottlenecks all have associated costs because of the need to address their causes and because of the lost opportunities for throughput.This paper will discuss how bulk material technology and proper understanding of material flow characteristics can be applied to mitigate bottlenecks. It will discuss how to predict potential bottleneck locations through a scientific method of analysis and evaluation to determine if an increase in throughput of an existing transport system is possible, as well as whether or not a new material will flow reliably through an existing system.CITATION:Hartford, C E, Holmes, C P and Tan, T, 2015. De-bottlenecking iron ore transportation from mine to plant, in Proceedings Iron Ore 2015, pp 393–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By R. M. Wilson

Concentrating plants, in common with other types of industrial plants, cannot operate without lectric power. The elctric distribution system and utilization equipment; therefore, must be carefully considered in all phases of plant design. Two important aspects of proper distribution and usage of electric power are the selection of voltage levels and the methods of system grounding. These are not necessarily the most important design considerations, but are perhaps more controversial than other major points, Modern plants demand increasing amounts of power which, since electric power is the product of voltage and current means higher voltages or currents. Higher voltages require more insulation, higher currents more conductor. The equipment designer?s problem is to obtain in his transformer, cable, switchgear, controller, motor, etc a balance of insulation and conductor to obtain a satisfactory design at lowest cost. To provide the most economical system, both in initial and operating costs requires the system designer to select the proper voltage level. Adequate voltage also permits expansion to meet future requirements, and results in better operation of utilization equipment, Relatively little advancement has been made in recent years in improving conductors; however, great progress has been made in improving insulation. Thus modern plants, in general, now find it more economical to use higher voltages than they did previously. For example plants which only a few years ago would have used 2400 volts as a system voltage often find nowdays that 4160 volts is their proper choice. If the plant requires 10,000 kva br more, then an even higher voltage, such as 13,800 volts, will prove economical. However, for the average concentration plant, with less than 10,000 kva demand, the choice of distribution voltages is between 2400 and 4160 volts, and 480 volts will be used for the low voltage utilization system.

Jan 1, 1958

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this study is to assess the impact of different reagents, such as limestone, lime, magnesium oxide, and sodium hydroxide, in experiments carried out in the single purification step and in two consecutive purification steps by raising the pH of a rare earth sulfuric liquor with the aim to remove or reduce the impurity concentrations in the rare earth sulfuric liquor. The choice for the best purification condition was made based on the minimum loss of rare earth elements (REEs), reagent consumption, and residue generation. The exploratory experiments show that it takes place in the two consecutive purification steps, the first one consists in dosing the limestone pulp until it reaches a pH of 3.5 followed by an addition of a lime pulp reaching a pH of 5.0. Under this condition, the results were a total removal of Fe3+, PO4 3− , and Th4+ ions and a reduction of 99%, 87%, and 37% w/w in the Al3+, UO2 2+, and SO4 2− concentrations, respectively, in the purified rare earth liquor. Furthermore, the lowest REE losses (8.3% w/w) and reagent consumption (4.3 kg/m3 ) and also a low residue generation (7.5 kg/m3 ) were observed in this condition. Despite reaching similar results regarding impurity removal, the experiments done with the addition of limestone, lime, magnesium oxide pulps, and sodium hydroxide solution in the single purification step, where the pH was raised to 5.0, presented higher REE losses (64.9%, 42.5%, 44.8%, and 60.9% w/w, respectively) and a higher residue generation (43.2, 25.1, 11.1, and 13.6 kg/m3 , respectively). This occurred due to the co-precipitation of salts containing rare earth elements in their composition. The experiments conducted with limestone, lime, and MgO resulted in a higher consumption of reagents, while the same result was observed when NaOH was used (4.3 kg/m3 ). In the experiments carried out with the addition of magnesium oxide and sodium hydroxide, the respective purified rare earth liquors presented a high concentration of magnesium, sulfate, or sodium, which could impact the quality of the marketable rare earth salts, whereas the salts obtained under the best condition observed in this study seem to be amenable for use as raw material in an attempt to obtain rare earth products with an acceptable chemical quality.

By Albert E. Schreck

[THE COMPOUNDS of strontium were confused with those of barium until 1790, when A. Crawford discovered that the mineral strontianite, long believed to be a barium mineral, was a compound of a new element. This discovery was confirmed 2 years later by I. C. Hope. The mineral was named strontianite because it was found near the town of Strontian in Argyllshire, Scotland. In 1808 Sir Humphrey Davy isolated strontium metal by the electrolysis of fused chlorides. Celestite (strontium sulfate) and strontianite (strontium carbonate) are the principal strontium minerals. Because of its more widespread occurrence, celestite is more important commercially.]

Jan 1, 1959

By J. A. Eisele

The Bureau of Mines conducted bench-scale cyclic tests to determine the composition of recycled leach liquor in the Bureau?s proposed clay/HCl leach/ HCl sparge process for producing Al203 from clay. The data developed from these tests make it possible to synthesize leach liquors for predetermined steady-state operating conditions when conducting large-scale crystallization tests. The results of two sparge tests were compared. One was a 20-cycle test with a 36-pct-HCl concentration in the mother liquor; the other was a 10-cycle test with a 26-pct-HCl concentration in the mother liquor. The effect of impurity concentrations in the leach liquor on the purity of aluminum chloride (AlCl30?6H20) crystals was determined, but there was poor correlation between this data and results that have been obtained from miniplant-scale work.

Jan 1, 1980

By Barry L. Warner

This program involves testing to determine whether a fire hazard exists when the exposed wood surface area of timber in a mine passageway equals 40 percent of the surrounding strata surface, excluding the sill. Twelve full scale fire tests were conducted in a simulated mine passageways, using kerosene pan fires as the ignition source. The tests included three timber sizes, plus one test with roof lagging, two wood types, plus one test with treated timbers, and two ventilation air velocities. The results show air velocity to be an important factor in the occurrence of flame propagation, and that the 40 percent surface area ratio of wood to surrounding strata appears to b0. a valid criteria for fire safety at 150 fpm, but not at 350 fpm.

Jan 1, 1975

By L. C. Brown, E. B. Hawbolt

The formation of grain boundary precipitates has been studied in Ag-5.64 wt pcl Al alloys at 688°C. Large-grain specinzerzs were used and the boundary misorientation measured by X-ray diffraction. At low-angle grain boundrrries Primary sideplates form. u)hile abore a 17-deg misorientation lenticular precipitates predominate. Growth of the lenticular precipitates was studied on individual grain boundaries using a statistical technique. The thickening and lengthening rates appeared to be independent of &apos;pain boundary misorientation, indicating that grain boundary diffusion was not significant in this system. The precipitates grew urith constant shape, with both the length and thickness increasing parabolically with time. The parabolic lengthening rates were unexpected since previous theory and experimerztal results had indicated linear growth. By approximating the shape of the precipitate to that of an oblate spheroid grouling with constant shape an equivalent diffusion coefficienl was calculated. The zlalue obtained was in good agreement with nleasurements obtained fron, diffusiorz couples. IF a single-phase alloy is heated or cooled to a temperature such that the phase becomes supersaturated, there is a tendency for a second phase to precipitate from it in order to remove the supersaturation. Precipitation takes place initially on grain boundaries due to preferred heterogeneous nucleation, but subsequently Widmans kitten plates may form in the grain interiors if the grain size and supersaturation are sufficient. The type of grain boundary precipitate formed depends on the nature of the boundary. Aaronson1 and clark2 have shown that grain boundary misorientation can be characterized by the simple parameter R, where and X, Y, and Z represent the minimum rotations about three orthogonal axes required to bring the two lattices forming the grain boundary into coincidence. The maximum value for R is 60 deg. In using this parameter the orientation of the grain boundary itself is, of course, neglected. However it was found in both Fe-si3 and A1-Ag2 that the precipitate shape depended only on the parameter R. Clark found that the vast majority of precipitates formed were allo-triomorphs— lens-shaped precipitates that grew along the grain boundaries. At low-angle boundaries, however, (R < 15 deg) Widmanstatten sideplates nucleated at the grain boundaries and grew into the adjacent grains. It has been reported that the rate of growth of grain boundary precipitates is controlled by diffusion within the supersaturated phase.&apos; The theories which have been developed for growth rates have assumed the diffusion coefficient constant over the composition range of the supersaturated phase. This is a fairly good approximation if the composition range involved is not large. Thickening rates have been calculated using the theory developed by Zener4 and by Frank5 for the growth of planar precipitates. A parabolic growth law

Jan 1, 1968

By Sufi Md Gulzar, L B. Roy

Rock engineering tasks like tunnelling, dam and building construction, and rock slope stability rely heavily on properly estimating the rock’s uniaxial compressive strength (UCS), a crucial rock geomechanical characteristic. As high-quality specimen are not always possible, scientists often estimate UCS indirectly. The primary objective of this paper is to assess the efficacy of long short-term memory (LSTM), K-nearest neighbour (KNN), a combination of particle swarm optimisation (PSO) with an artificial neural network (ANN), and adaptive neuro-fuzzy inference system (ANFIS) to estimate the UCS of sandstones from Jharia, Dhanbad, India. Point load index (PLI), porosity (n), P-wave velocity (Vp), density (ρ), and moisture content (%) are the parameters used for the present study. Finally, a comparison was made between the various prediction algorithms outputs. The findings of the study validated the effectiveness of computational intelligence methods in forecasting UCS compared to other models used in this paper. The KNN achieves overall the best results, with an R2 of 0.95 for training, 0.94 for testing, and an RMSE of 0.03 for training and 0.05 for testing.

Nov 23, 2023

By Anton Gronningsater

MR. J. R. GORDON: The authors are to be congratulated for their excellent papers on Copper-Nickel Matte Converting. Mr. Drummond&apos;s paper contains the results of a thorough and exhaustive study of a series of converter charges. Mr. Gronningsater has presented convincing arguments in favour of his claim that the converter has been neglected as a smelting machine for ore. Some of us may not be inclined to agree with his conclusions. Converting, like most metallurgical operations, is a compromise between an ideal and a practical operation. If it were possible for one to neglect entirely the matter of converter linings, I believe we would all agree that the proper flux for matte in a converter would be pure quartz. Under such ideal conditions, one would, if proper temperature were maintained, make the smallest quantity of slag containing a minimum of magnetite. Converter slags are notorious for their high metal content and must always be subjected to a further cleaning treatment before being discarded. For that reason, the tonnage of converter slag produced should be minimized. If norite is used as a converter flux, then the tonnage of converter slag would be greatly increased if the silica content is maintained at 27 per cent or higher. I cannot agree with Mr. Gronningsater&apos;s suggestion that, in con¬sidering a converter flux, the sum of the silica, alumina, alkaline-earths, and alkalis should be considered as being of value. The alkalis and alkaline-earth contents of the flux will replace iron in the silicates formed and tend to increase the viscosity of the slags. However, if the converter is to be used as a smelting machine, it will be necessary to drop the silica content of the converter slag in order to avoid production of excessive slag tonnages.

Jan 1, 1942

By M. J. GAVEN

COMING over from the plant on the Denver and Rio Grande yesterday afternoon I was an interested listener to a smoking-room conversation that had to do with the experimental plant near Rifle. The people who were talking didn&apos;t know me and I didn&apos;t know them, but I learned quite a little. I understood that the plant would never operate; that it was not intended to operate; that the "oil trust" would keep it from operating; that our tramway had eaten up all our money and still was not working and would not work; that the plant was run by a bunch of kids, and that the superintendent was probably the biggest kid of the bunch. I plead guilty to the latter. But the people who were talking were misinformed. The plant is producing oil. The first sample of oil that came from our unit at the Bureau of Mines experimental plant at Rifle, Colo., was produced on Sept. 18, the first that came out of the condenser, and it is still coming. This sample of oil may mean to the United States what the first oil produced from the first well meant.

Jan 1, 1926