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By Jianbo Lan, Desheng Huang, Xiaoying Qiu, Zhaohua Ke, Liusheng Ge, Xinjin Xiao, An Guo, Qiaofa Lan

Magnesium salt rare earth enrichment (MREE) is a crucial intermediate raw material in the deep processing of rare earth elements and material preparation, serving as a front-end raw material for the synthesis of rare earth oxides. With the current disposal process for MREE, neutralization slag with high rare earth residue is generated during further extraction of rare earth from the MREE and accumulates in huge piles. Therefore, the combined disposal process of MREE and neutralization slag was put forward. MREE was solubilized using 4 mol/L sulfuric acid to achieve an endpoint pH of 0.75, dissolving the rare earth and obtaining an acid solution. The MREE and neutralization slag were added in a mass ratio of 1:2 to the acid solution sequentially. The pH of the endpoint was controlled to 4.8~5.0 for neutralization and decontamination. This resulted in the production of rare earth sulfate liquid of similar quality to the original MREE disposal process, meeting subsequent extraction requirements. The neutralization slag underwent a water washing process, with two washes (first with 0.2 mol/L acidity water at a solid-liquid ratio of 1:2 and second with deionized water at a ratio of 1:4), resulting in water-washing slag with a rare earth content of 0.24% and a rare earth yield of 97.08%. Notably, zero wastewater discharge was realized. This innovative process effectively addressed the challenges of high rare earth residue in neutralization slag and stockpile accumulation, offering valuable theoretical and practical insights for MREE disposal.

May 31, 2024

The Ngakuru zeolites are located about 20 km south of Rotorua and comprise a number of deposits dispersed along several fault lines. Relatively recent volcanic activity (250,000 years ago) resulted in ash depositions that vary in depth and mineralogy. Subsequent variable thermal alteration intensities generated predominantly clinoptilolite and mordenite zeolites with a range of physical characteristics. Typically the zeolites have low density (650 kg/m3), have high liquid (60% of dry weight) and odour absorption characteristics, and a high affinity for soluble cations (CEC =: 100 meq/100 g). Traditional kitty litter and oil absorbency markets are being expanded. New opportunities in waste and potable water treatment, organic and synthetic slow release fertilisers, use as a light weight aggregate for speciality concretes, and pozzalome activity are currently being researched.

Jan 1, 2000

By P. L. M. Wong, N. W. Johnson

Surface analysis by X-Ray Photoelectron Spectroscopy (XPS) of samples taken from the galena flotation section of the Hilton Concentrator of Mount Isa Mines Limited are presented. Flotation rate and pulp chemical data taken during the sampling period are also presented and discussed. Surface analysis suggested that, under normal operating conditions, an overlayer of precipitated calcium sulfate existed at the surface of the sulfide minerals. In particular, there was a decrease in the surface concentration of calcium sulfate for the concentrate samples relative to that occurring on the tailing samples. This suggests that the flotation process was selective against minerals which have calcium sulfate predominating at the surface. Heterocoagulation of hydrophilic calcium sulfate on to the galena surface considerably reduced galena flotation rate. Methods to control calcium sulfate precipitation, which include sodium carbonate treatment of the pulp, are also discussed. Sur- face analysis results of samples taken from the Hilton Concentrator during sodium carbonate addition to the grinding circuit are also presented. This shows clear evidence for the removal of calcium sulfate from the mineral surfaces without concomitant surface precipitation of calcium carbonate. Reasons for the apparent dispersion of precipitated calcium carbonate are discussed. Galena flotation rate was increased by the addition of sodium carbonate apparently due to the removal of interfering calcium sulfate.

Jan 1, 1995

By I. Yildirim

Free energy of interaction between particles in water can be calculated if one knows the values of appropriate interfacial tensions, which in turn can be determined from the surface free energies of the particles involved. The latter can be determined using the Van Oss-Chaudhury-Good (OCG) equation. This method requires the measurement of contact angles of well-defined liquids on the surfaces of the particles of interest. In the present work, the contact angles were determined using heat of wetting, capillary rise, and thin-layer wicking methods. The results are compared, and the utility of the surface free energy data obtained from the contact angles are discussed.

Jan 1, 2002

By T. McKeon

Gravity separators are commonly used in multistage cleaning and scavenging circuits to improve the quality and/or recovery of the final concentrate. Unfortunately, studies suggest that many industrial plants are poorly designed in terms of equipment layout. This shortcoming can often be attributed to a failure by engineers to make use of fundamental process engineering tools for circuit design. One of the most important of these is linear circuit analysis. This powerful tool makes it possible to mathematically compare the relative efficiencies of circuit configurations in advance of experimental testing. This article provides a basic review of the linear circuit analysis concept and discusses some of the key insights it provides for the layout of multistage circuits. An industrial case study is provided to show the tremendous impact that this process engineering tool can have on the design of multistage spiral circuits in a heavy mineral wet plant.

Jan 1, 2005

By R. L. Brown

This report, summarizing the Bureau of Mines research and technologic work on coal and coal products for the period July 1, 1950, to July 1, 1951, is based largely on publications issued during the year. The sixteenth in an annual series, it gives footnote references to publications giving further details of the research and technologic work described, except in a few cases where research data presented herein has not been published previously. During the year, the national fuels situation was generally one of plentiful supply.3/ Mineral-fuel resources appeared adequate for several hundred years at reasonably increasing rates of supply. Coal-production capacity was in excess of demand; petroleum supplies were adequate; and natural gas use was limited only by pipeline capacity. However, it was pointed out that a world war would drastically change this situation of relative plenty, particularly with regard to supplies of petroleum and its products. Conversion to the use of coal on a large scale would be required, and improved methods of mining and of processing and using coal in solid or fluidized form or converted to liquid fuels could materially contribute to our national safety.

Jan 1, 1952

By Steve Klein

The Transbay Downtown Extension (DTX) in San Francisco involves the construction of a large-span tunnel with a width ranging from 43 to over 60 feet. The tunnel will be excavated using the New Austrian Tunneling Method (NATM), also known as the Sequential Excavation Method (SEM), in highly fractured and sheared rock. This paper discusses the FLAC (Fast Lagrangian Analysis of Continua) analyses that were completed for conceptual design of the tunnel support system and to develop surface settlement estimates for the evaluation of measures to protect existing buildings located above the tunnel from damage.

Jan 1, 2008

By Guillermo Silva, P. Katsabanis

The conventional approach to design wall control blasts relies on the borehole pressure as the most important explosive parameter. Borehole pressure is intimately linked to explosion pressure, which in turn is related to the detonation pressure of the explosive. For fully coupled charges, the borehole pressure is equated to the explosion pressure, while for decoupled and decked charges its value is typically calculated under the assumption that the explosion products behave like an ideal gas when they expand into the volume of the hole.

Jan 1, 2003

By Morgan Sears

The LaModel program (Heasley, 1998) is a displacement discontinuity, boundary element model (BEM) for analyzing stresses and displacements in single and multiple-seam coal mines. After the Crandall Canyon mine collapse, the need for better design guidelines for LaModel was observed and a new calibration method for deep cover pillar retreat was developed (Heasley et al., 2010). However, the scope of this initial calibration was limited to single-seam mines deeper than 750 ft. This limited application of the initial calibration method lead directly to the research presented in this paper, which attempts to define appropriate LaModel calibration guidelines for pillar design where shallow cover and/ or multiple-seam mining scenarios are encountered. As part of this research, a database of shallow cover case histories has been developed, and this database is used to help validate the shallow cover calibration method. By adding the shallow cover database to the previous deep cover database, the LaModel calibration method has now been extended to the complete range of mining depths, as well as to multiple-seam cases. With this shallow cover calibration, the utility of the LaModel program continues to increase.

Jan 1, 2013

This study was conducted to determine the effects of a machine-mounted scrubber and water sprays on face methane levels. Testing was conducted in the NIOSH ventilation test gallery which was designed to simulate a full-scale mine entry. In the test entry, a model mining machine, equipped with water sprays and a simulated dust scrubber, was located at the face of a 20-ft box cut. Blowing ventilation was provided using a curtain with a 40-ft setback distance. Methane released from a pipe manifold located inby the mining machine was monitored at six locations that were 1 ft outby the pipe manifold. Tests were first conducted to evaluate the effects of using sprays and scrubber separately on face methane levels. Additional tests were conducted to determine how a scrubber used with various water spray systems would affect face methane levels. The use of either sprays or scrubber reduced face methane levels significantly. The combined use of sprays with the scrubber further reduced face methane levels a small amount. Primarily the sprays affected methane levels by changing airflow distribution close to the face.

Jan 1, 2001

By G. Velarde

This paper presents the metallurgical results of column and stockpile leach tests with forced aeration to determine the usefulness of this process in the operational leaching at Sociedad Minera Cerro Verde S.A.A. The evolution of the aeration system is presented and also an innovative solution developed to overcome forced aeration’s main problem, which is the early obstruction of the aeration pipes located at the base of the stockpile, causing a decrease in air and oxygen levels and therefore a reduction in the metallurgical benefits.

Jan 1, 2006

By H. A. Dakin

"An introduction to the metallurgical requirements of the Flin Flon concentrator reveals the magnitude of ore blending which is required in its operation of three flotation circuits. The resulting variability in flotation heads which has in-creased the separations complexity justified the development of an on-line analysis system.This paper provides a summary of the development and operation of that system. Particular attention is devoted to the problems encountered and where possible their solutions; as the requirements of accurate information and minimum downtime of the sampling system and x-ray analyzer are considered essential. The addition of a recess central computer has provided information in a more easily understood form and as well has allowed the start of automatic reagent control.An indication of the on-line analysis system's value to the concentrators' operation is provided by an examination of the plant in metallurgical data and reagent costs in previous years.The metallurgical plants of Hudson Bay Mining and Smelting lie adjacent to the city of Flin Flon on the Manitoba-Saskatchewan boundary. Plant operations commenced in 1930 treating copper-zinc ore from the local mine. In recent years ore bodies near Flin Flon and in the Snow Lake area, about seventy-five miles east, have been brought into production.By the beginning of 1973 the number of producing mines had increased to nine; with all the ore being handled by the Flin Flon concentrator. Figure l, showing mine ore assays during 1973 indicates the variation in metal content possible."

Jan 1, 1974

By S. Sun

Recent studies on the physico-chemical properties of molten slags and oxide solid solutions of interest is reviewed. The review covers redox and phase equilibria in slags, viscosity, diffusivity, electrical conductivity, kinetics of interfacial reactions between slags and CO-CO2, interfacial properties and phenomena. Some highlights from ongoing work on modelling phase diagrams, component activity, viscosity and electrical conductivity of multi-component slags will be presented and results compared with published experimental data on slags with or without suspended solid phases.

Jan 1, 2004

By Robert T. MacMillan

A process has been developed in the laboratory and expanded to semi-pilot-plant scale for recovering titania, iron, and byproducts from two types of titaniferous iron ores. A reducing roast with coke and soda ash followed by grinding and magnetic separation produced powdered iron and slag from which titania and byproducts were recovered by H2SO4 decomposition. Based on the steps tested on a. semi-pilot-plant scale supplemented by the results of the laboratory investigations, enough data are available to make a balanced flow sheet. Combined data from the laboratory and semi-pilot plant indicated that 85 to 9O percent of the titania content of the ore was recoverable and that approximately 90 percent of the iron could be recovered as a metallic-iron powder. Tahawus magnetite from the Maclntyre mine at Tahawus, N. Y., was successfully treated as follows: (1) The ore was roasted at 1,050° to 1,080° C. with carbon and soda ash, thereby reducing the iron to metal sponge and retaining the titania in the slag. (2) The metallic iron was separated, after wet grinding, by magnetic or gravity means. (3) The slag fraction was air-roasted at 850° C. and leached with NaOH to recover Na3VO4. (4) The leached solids received a dilute-H2SO4 leach to remove interfering impurities, chiefly Na2O and SiO2. (5) Titania was dissolved from the leached solids of step (4) by a H2SO4-bake followed by a water leach. (6) Titania was precipitated by seeding and boiling the resulting solution. The spent liquor was used for the dilute-H2SO4 leach in step (4). The following scheme was found to be technically feasible for recovering other byproducts of the process. (1) The gelled filtrate from the dilute-acid leach step was washed and dehydrated to produce a commercially acceptable silica gel. (2) The wash liquor containing sulfates of Na2O, Al2O3, Fe2O3, and TiO2 was combined with the highly alkaline filtrate from the wet-grind and metallic iron-separation steps, precipitating iron and titanium hydroxides, which were separated for special treatment. (3) Anhydrous Na2SO4 and Al2O3?3H2O were recoverable from the alkaline filtrate from step (2) by evaporation and carbonation, respectively, and the barren liquor was recycled to the magnetic-separation step.

Jan 1, 1952

By Vinay Kumar

The present investigation describes R & D studies carried out for recovery of copper from the sulfate solution expected from the leaching of e-wastes in presence of minor constituents such as cadmium, zinc and nickel using solvent extraction process. In order to extract copper in continuous mode in mixer settler unit (MSU), basic studies have been made to optimize the experimental condition using 5%LIX84 in kerosene. Subsequently, the solvent extraction of copper was made in MSU maintaining leach solution flow rate 4.0 L/h and A/O ratio 1. The results showed complete extraction (~97%) of copper in three stages at A/O ratio 1 from the aqueous solution containing 1.98g/L Cu at pH 1.91 in presence of impurities. Loaded metal was completely stripped after scrubbing with 10% sulfuric acid in two stages. The stripped solution could be used for metal/ salt recovery by electrolysis/ crystallization.

Jan 1, 2010

By A. Nieto

A dump edge and vehicle proximity warning system is being developed at the Colorado School of Mines using GPS and wireless local area networks to improve the safety of off-highway trucks in open pit mines. After two years of research, software development, and testing in the laboratory, field tests are currently being carried out at operating limestone quarries and open pit mining operations to evaluate the effectiveness of the system under rugged operating conditions. This paper describes the progress made on this NIOSH-funded project and discuss, tests carried out recently, at the Morenci open pit copper mine in Arizona.

Jan 1, 2002

By Stephen L. Chryssoulis, Daniela Venter, Stamen Dimov

"Comparative surface analysis of floated and rejected free gold grains from a number of full scale benefication plants and from pilot plant testwork, has shown silver (the most common impurity in gold) and sulphur invariably in greater concentration on floated gold grains, implying that they assisted gold flotation (gold activators). Collector loading measurements on individual gold grains from concentrates of staged rougher flotation tests on a cyclone U/F product of a pyritic gold ore, revealed first progressively lower concentrations of the collector monomer on gold from each follow-up concentrate and secondly a direct proportionality between the surface concentration of silver and the collector monomer. These two observations leave no doubt that silver activates gold and that collector monomers play a significant, previously not fully recognized role in gold flotation.INTRODUCTIONGold to some degree is naturally floatable in industrial systems, which means that it can be recovered without collector addition (Marsden and House, 1992). This is due to the adsorption of hydrocarbons and deposition of sulphur, which are dependent on the metallic properties of gold, particularly its high electrical conductivity, which allows surface electrochemical reactions to occur catalytically and selectively. Cyclic voltammetry has shown that gold can be rendered hydrophobic by deposition of a surface layer of sulphur (Sº) from S2- and HS- solutions (Walker et al., 1984). Twenty monolayers of sulphur were required to produce a hydrophobic gold surface.However, no sulphide flotation plant relies solely on the natural floatability of gold for its recovery. Gold hydrophobicity is enhanced by the addition of flotation collectors such as xanthates (X), dithiophosphates (DTP), dithiophosphinates (DTPI), mercaptobenzothiolates (MBC) etc., as used in sulphide mineral flotation (Dekok, 1973: Adams et al., 1986). The mechanism invoked in enhancing the hydrophobicity of pure gold with the aforementioned four groups of collectors is similar to that of pyrite, whereby collector anions are oxidized at the gold surface to form dimers (Groot, 1987; Marsden and House, 1992; Basilio et al., 1992) As an example, xanthate ions are oxidized at the gold surface to form the neutral dimer dixanthogen (X2):"

Jan 1, 2003

By José Arango

La Planta Hidrometalúrgica de Cerro Verde tiene como objetivo alcanzar la máxima calidad en cada uno de sus procesos operativos. Para ello, desarrolla un diseño que permita la transformación del control remoto a una operación automática, generando decisiones lógicas. En ese sentido, el presente texto señala la importancia de los Sistemas de información de operaciones en el sistema de automatización de Cerro Verde - en tanto es soporte de la implementación de un completo sistema de instrumentación y de la instalación de una red de PLC’s que colectan la información y en base a esta, desarrollan una lógica de operación manteniendo interconectados todos los circuitos operativos. Posteriormente, con el uso de software se crea una interfase de conexión entre la red industrial y la red Administrativa, permitiendo adjuntar la información en una base de datos que junto a la otra base administrativa, constituyen un ERP que da vitalidad a nuestra operación. De forma que los sistemas de informacion instalados en Cerro Verde consideran a los sistemas de instrumentación como los ojos del operador de planta.

Jul 17, 2000

By Alex Naudts

Pre-excavation grouting is a predictable and reliable technique performed to prevent or minimize settlement in advance of, or during the tunneling operation. It safeguards the infrastructure above the tunnel alignment. Cement based suspension grouts and sodium silicate based grouts are frequently injected to consolidate and strengthen the formation and create a reinforced canopy above the tunnel trajectory. Grouting is typically performed through permeation and permeation in conjunction with hydrofracturing. Multiple injection passes through steel sleeve pipes are ideal, since they create an effective forespiling system to facilitate tunneling without causing unacceptable settlement, even with minimal overburden thickness. Ten pre-excavation grouting projects performed in the North America are discussed in this paper.

Jan 1, 2008

By M. Royker

Gold has been demonstrated as a possible catalyst for oxidation reactions. Some evidence for a possible promotion effect of platinum has also been recorded. The influence of platinum as promoter for Au/?-Al2O3 prepared via anionic ion-exchange for the oxidation of glycerol was investigated in a batch reactor at 60°C. It is inferred that the addition of platinum reduces the catalytic activity and therate of deactivation, resulting in an overall higher final conversion of glycerol with increasing platinum loading. The addition of platinum to the catalyst favours the formation of the desired product, glyceric acid.

Jan 1, 2012