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By Hirokazu Narita

Keywords: solvent extraction, precious metals, thiodiglycolamide, rapid separation, hydrochloric acid The solvent extraction of some precious metals (Pd(II), Pt(IV), Rh(III) and Au(III)) and base metals (Fe(III), Cu(II) and Zn(II)) in a hydrochloric acid solution was carried out using N,N'-dimethyl-N,N'-dioctyl-thiodiglycolamide (MOTDA) dissolved in the mixed solution of 80 vol-% dodecane and 20 vol-% 2-ethylhexanol. The extraction percentages of Pd(II) and Au(III) in the 0.01 M MOTDA-1.0 M HCl solution system are 99.6% and 71.8%, respectively. In contrast, the other metal ions are hardly extracted under the studied conditions. The Au(III) and Pd(II) extracted in the organic phase are easily back-extracted with a 1.0 M thiourea/1.0 M HCl solution. A comparison with the conventional extractant for the Pd(II) separation, di-n-hexyl sulfide (DHS), revealed that the extraction rate of Pd(II) with MOTDA is much greater than that with DHS. The extraction percentage reached over 99% in less than a 2 min contact time. However, in the DHS-Pd(II) system, it takes about 240 min to achieve the extraction equilibrium. Furthermore, MOTDA can quantitatively extract Pd(II) up to half the molar amount of MOTDA. Therefore, MOTDA is a promising extractant for Pd(II) from the HCl solution after the removal of Au(III).

Jan 1, 2005

The United States Bureau of Mines frequently receives requests for information regarding the details of its organization and the nature of its activities. In response to such an inquiry a series of articles outlining the work of the bureau as a whole and of its different divisions was prepared and published in the United States Daily, Washington, D. C., during November, 1929. These articles are reprinted here in the hone that they may assist in giving the public a more complete understanding of the aims and purposes of the bureau and the methods by which it is laboring for the attainment of safer conditions and more efficient methods in American mineral industries. An index of these articles, with the dates of 'their publication in the United States Daily, is given below.

Jan 1, 1930

By DR. SAMUEL B. CHRISTY

? THE man is always greater than his work.? The training of the men who are to develop the mineral resources of the world is the most important problem connected with mining engineering. It becomes ever more important to civilization as the mineral wealth of the earth approaches exhaustion. I have therefore decided to consider a few of the more important problems arising in the training of the mining engineer, and especially those arising in America. THE PECULIAR NATURE OF MINERAL WEALTH. Mining and Agriculture are the two fundamental arts. Without the latter our existence would be precarious; without the former, our civilization impossible. Agriculture furnishes that regular supply of food and raiment which leads to the growth of large communities in which cultivated leisure first becomes possible; while raining furnishes the metallic thread from which is woven that complex fabric we call civilization. But in these two arts the conditions for success are widely different. Most of the crops that the farmer reaps may be harvested year after year, and the proper fertilizers being added, he may continue the annual harvest indefinitely, while, as a result of cultivation, his farm becomes yearly more valuable. But the crop the miner reaps can be harvested but once in the history of the race. Our mineral wealth has taken unknown ages to mature in the bosom of the earth. The ripened fruit can be plucked but once. There are no fertilizers for worked out mines. It never pays to work over a mine that has been

Sep 1, 1905

By Shirley F. Colby

The past 40 years have seen the sand and gravel industry grow from small roadside pits and holes in farmers' back yards to giant corporations selling millions of tons of sand and gravel each year and owning plants representing huge capital investments in land and equipment. The days hen a man could "work out" his taxes by providing the materials for nearby roads are gone forever. In addition to the hundreds of privately owned and operated plants, Government agencies operate sand and gravel pits and plants to supply aggregates for the tremendous road-building and public-works programs in progress during the past few years. EXPANDING PRODUCTION In 1940 the send and gravel industry produced almost a quarter of a billion short tons valued at more than 110 million dollars. This compares with less than 2 million short tons worth 1 1/2 million dollars produced in 1902. The practice of screening sand and throwing away the gravel in the early days of the industry's growth has stopped, and in 1940 gravel constituted two-thirds of the total production. In 1906, the first year in which sand and gravel were reported separately gravel accounted for only one-

Jan 1, 1942

By H. Seguin, J. A. Le Gac, S. Bernhard, P. R. ZETTWOOG

The "Service de Protection Technique"of the "Institut de Protection et de Sûreté Nucléaire" was asked by the Commission of European Communities to conduct measurement campaigns which would make it possible to evaluate, on an experimental basis, the collective risk to miners exposed to radon in underground, non-uranium mines located in countries within the European Community. 1. METHODOLOGY USED TO CONDUCT THE CAMPAIGNS This campaign is original in that direct measurements of the individual monthly exposure to potential [a]-energy from short-lived radon daughters are made using personal [a]-dosimeters described previously (1). We call this type of dosimetry "personal dosimetry". The workers who wear the personal [a]-dosimeters were selected taking into account the various categories of workers and their work assignments in the various areas of the mine. Another way of finding out the occupational exposure of these miners consists in making numerous measurements of the radon concentration at the various work places, taking into account the time spent at each place by each worker. This procedure is too complex for an evaluation of the collective risk as requested by the Commission of European Communities and was therefore rejected. Additional data was gathered during these measurements campaigns using the following techniques (table 1). [ ] (1) Current [a]-dosimetry as practiced in France - SPT international report N° 234 - February, 1981 - P. ZETTWOOG The mines were chosen to include a larger variety of types of ore, of geological situations, and of mining methods. 2. RESULTS OF THE RADON DATA-GATHERING CAMPAIGNS 2.1 – [Uranium content of the surrounding rocks and ore] The samples taken during the campaigns make it possible to establish the U content in the rocks of the mines selected. These values, from 2 to 15 ppm, are slightly higher than those usually found (2 to 5 ppm) (table 2). [ ]

Jan 1, 1981

By Joseph A. Holmes

The investigations carried on at the fuel-testing plant of the United States Geological Survey at St. Louis in 1904-1907 included tests of the steaming and gas-producing qualities of many coals and of the possibilif3 of their improvement by briquetting, together with washing and coking tests and tests of some of the resulting coke in the cupola. These tests were part of a general inquiry into the manner of utilizing most efficiently each of the coals under investigation. The equipment used in the cupola tests of coke, the manner of conducting the tests, and the essential results have been described in publications of the Geological Survey," and only the more important conclusions to be drawn from the tests are mentioned in the following pages. The tests were made to show the fitness of the cokes for foundry purposes, but an incidentlll result was to show foundry men and the coke producers the advisability of studying the conditions of foundry practice. The present bulletin, published by the Bureau of Mines because the analyzing and testing of fuels have been transferred from the Gilological Survey to the Bureau of Mines, briefly reviews the status of the coke industry, some features of practice in the use of coke in the foundry, the probable happenings of a cupola heat, and the reasons for modifying charging practice so that a particular coke can be used to best advantage.

Jan 1, 1910

By M. Mirnezami, D. Lascelles, J. A. Finch, E. El-Ammouri

"Aggregation, i.e., the tendency of particles to cluster, can be expected to influence flotation selectivity. In this paper, a method of measuring aggregation is introduced and used to conduct plant surveys.Aggregation is measured using settling rate and turbidity converted to an aggregation index (AI) where 0 corresponds to most dispersed and 1 to most aggregated over the range of conditions tested, normally pH. Surveys of Cu and Zn flotation stages at four concentrators showed the AI increased significantly above pH 9. The metal ions identified in the process waters, principally Ca and Mg, were tested to determine which might be responsible. The presence of Mg was found to be the most important. In doping tests, Mg was shown to cause significant variation in AI over the pH range of 9 to 12.The impact of Mg was restricted to pH > 9. Over this pH range, Mg forms a range of hydroxy species, including Mg(OH)2 precipitates. An aggregation mechanism associated with these precipitates, electrostatic bridging, is suggested. Possible problems and opportunities in flotation practice arising from the findings are discussed."

Jan 1, 2002

By Richard Addison

Introduction A staccato beat rings out across the Australian bush. The stamps are at work, slowly pulverizing gold-bearing ore for a patient, grizzled prospector. This is the State Battery near Marvel Loch, a tiny 22.6-t/d (25-stpd) capacity gold plant operated by the Western Australia government. It is one of many such plants located in remote corners of Western Australia and the Northern Territory. They are miniature custom mills operated for the benefit of prospectors and small mine operators. These state batteries are so called because they are operated by state governments and because the principal item of machinery in the plants are stamp batteries. They are fascinating anachronisms - throwbacks to times past, a century ago, to the hard and heady existence of gold rush days. Marvel Loch plant Typical of these operations, and perhaps a trifle more sophisticated than most, is the plant near Marvel Loch, a small center for mining and farming about 400 km (250 miles) due east of Perth. Marvel Loch. The name evokes visions of a pristine lake set in a cool, green, misty glen of the Scottish highlands. Actually, it is probably a hot, dry salt pan somewhere nearby. Just where the "loch" is difficult to discern. There is no sign of it on the map.

Jan 7, 1986

By J. Fletcher Smoak

The value of abrasive materials consumed in the United States increased 37% in value over that of 1983 to $439 million; of which, 58% was manufactured abrasives, 36% was industrial diamond (natural and synthetic), and 6% was natural abrasives. Production value of natural abrasives, which consist of crude tripoli, special silica stone, garnet, and emery, increased 4% Production of crude tripoli, a finely disintegrated chert, increased 12% in quantity and 8% in value. Shipments of processed tripoli increased only 3% in quantity but increased 16% in value, with large increases occurring in both major end-use categories. Production of garnet, an abundant iron-aluminum silicate, decreased slightly in quantity and value after posting continued increases in quantity and value since 1980. There was a significant decrease in the quantity and [ ]

Jan 1, 1985

Mineral sand beneficiation plants comprise a complex combination of electrostatic, magnetic and gravity based separation techniques. These are combined and replicated in ways that provide the most efficient and cost effective separation of the valuable components. On line instrumentation has been developed at the JKMRC (eg. conductor/non-conductor(CNC) ) to measure the properties of the dry plant process streams. This paper provides results from the recent development of a novel low cost mass flow meter and discusses their combined use with the CNC instrumentation for the control of dry separation circuits.

Jan 1, 2003

By V. R. Voller

"The World Wide Web (the web) provides a very useful resource for the enhancement of teaching and research dissemination. This paper advocates that researchers take control of this resource and become actively involved in creating web content. Two examples of the use of the web in a materials setting is provided. The first illustrates how a concept quiz for teaching can be developed. The second shows how a materials processing model can be run in real time over the web. The paper closes with a summary of some resources that can be used to create web materials.IntroductionA recent copy of a newspaper advertisement read""Share what you know, learn what you don't""This neat phrase sums up a powerful teaching and research philosophy. In an educational setting a prime motivation for research is to uncover the unknown and venture in directions previously uncharted. The balance to this search for knowledge should be a desire to share that knowledge with others; whether it be with students in the classroom or research colleagues in a wider setting.The .World Wide Web and its associated multi-media software offer a perfect platform for researchers to share their knowledge with an extremely wide sector of the research community. To enable the use of this resource researchers must take the power that the web offers them into their own hands and create products that take maximum advantage of the medium. It is key that researches at the forefront become directly involved, otherwise a potential powerful medium will not realize it's true potential, and colorful products with no core content will proliferate. The object of this paper is to outline two ways in which the web can be used to enhance teaching and research objectives."

Jan 1, 2000

By F. Mwaura

"The aim of the audit was to determine whether the mining project environmental impact assessments (EIAs) in Kenya are undertaken according to international best practice. A sample of 50 EIA reports for the 2007–2016 period was evaluated using 18 criteria in the Environmental Law Alliance Worldwide (ELAW) guidelines. The findings showed that only two criteria were considered ‘excellent’ according to the ELAW guidelines, namely baseline environmental assessment and prediction of physical impacts. Six criteria were found to be ‘satisfactory’, including prediction of social impacts, analysis of alternative options, and impact mitigation. The reports were quite weak in terms of: consideration of all phases in the mining cycle, environmental regulatory framework, prediction of biological impacts, stakeholder consultation and engagement, integration of human right issues, and integration of climate change and cost-benefit analysis. It is therefore recommended that the Kenyan National Environment Management Authority (NEMA) should consider tightening the EIA terms and conditions in the approval of statutory terms of reference (ToR) for full-scale mining EIAs to ensure improved performance of EIA as a tool for environmental protection. IntroductionThe nexus between society and the environment has continued to generate interest because the environment is the source of goods and services that sustain the various needs of human beings as outlined in the UN sustainable development goals (SDGs) (Armstrong and Peart, 2000; Sutton 2004; Chakrabarti 2007; Strange and Bayley 2008). All the five generic categories of societal needs, namely physiological needs (food, water, clothing, medicines, etc.), residential and occupational needs (shelter, transport, energy, etc.), economic needs (tradeable goods and services), leisure and recreational needs (tourism), and cultural and spiritual needs (e.g. sacred resources and ecosystems) (Mwaura et al. 2016) are addressed by the environment. Consequently, a wide range of development sectors have been established around the world in order to address the above needs (Lederer, Galtung, and Antal, 1980; Rammelsberg et al., 2006; Noonan, 2014). All these development sectors rely entirely on the environment for their proper functioning, as shown in Table I."

May 1, 2019

By D Kentwell

A resource model serves two main purposes depending on the stage of a project. The first is to provide an early indication of likely tonnages and grades at certain cut-offs so that decisions can be made on whether continued spending on the project is justified. The second is to provide a basis for mine planning, feasibility studies and reserves. Resource models are not designed for selection of actual blocks in the ground for processing. This is the purpose of a grade control model, which is created at a stage beyond both resources and reserves.Inferred, Indicated and Measured Resources contain different levels of uncertainty with respect to the accuracy of the resulting grade and tonnage curves. These uncertainties arise from three broad areas: quality of information, geological assumptions and estimation technique. This paper focuses on known problems with the ordinary kriging (OK) estimation technique. Resource estimates often produce smoothed block grade distributions with much lower block grade variability than true selective mining unit (SMU) block grade distributions. There are two main factors that are involved in this smoothing. Firstly, where the block size used for estimation is larger than the SMU block size, this will smooth the block grade distribution and move the grade and tonnage curves away from the true SMU block grade and tonnage curves. Secondly, and less well recognised, is that smoothing is inherent in the OK estimator. This also moves the grade and tonnage curves away from the true SMU grade and tonnage curves, even when the estimate is done at the SMU block size. There are a number of techniques, such as simulation, uniform conditioning and degraded search neighbourhoods that can provide a better approximation of the true SMU block grade and tonnage curves at the expense of individual block accuracy.This paper aims to explore the extent to which OK resource estimates designed to maximise individual block accuracy can differ from (an estimate of) the true resource at SMU block size in terms of grade and tonnage curves. The differences at economic cut-offs and above are examined. In some cases these differences are significant. Both the OK estimation technique and block size play a part in the differences observed. To do this we will examine a number of commodities and deposit types using real project data.The conclusion is that the current industry standard default practice of targeting maximum individual block accuracy (conditional unbiasedness) using OK at resource stage, without consideration or evaluation of the extent of associated smoothing at SMU scale, can lead to significant errors in fundamental mine planning decisions. This then has implications for resource classification if the classifications are based heavily on the OK quality without consideration of the true SMU distribution.CITATION:Kentwell, D, 2014. Aligning resource estimates with mine planning, in Proceedings Orebody Modelling and Strategic Mine Planning Symposium 2014 , pp 185–192 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 24, 2014

By R. Adsero

"In view of the decade long decline in worldwide mine equipment productivity and with heavy economic pressures and survival at risk, improvements for those remaining in the game are essential. The latest Multifactor Productivity data for the US mining industry indicates a continuing descent with Australia on a similar course. The world’s mining industry has a fleet of over 400 large draglines moving billions of tons of material annually. The most efficient use of this equipment resource will provide a competitive advantage to those companies who are committed to improving performance. A dragline monitoring system is a requirement for optimum operations. The monitor reports the facts. Focused actions can change the facts and create improved performance. Analyzing monitor data to build knowledge and create understanding is a beginning. Understanding the key productivity indicators for dragline operations and an effective benchmarking process are the basis for improvement. There is overwhelming evidence that adopting new technologies and concepts including AC drive technology can and will bring about a step change in dragline operating cost with improved production performance.STATE OF THE MINING INDUSTRY A high altitude review of the state of the mining industry provided by a study of multifactor productivity shows a continuation of lower and lower output year on year for the capital and labor inputs applied. The story is sadly similar for both U.S. mining and the Australian mining sector. In fact, according to PwC analysts the worlds mining equipment productivity has declined 20% over the past seven years. (Lumley, 2014) Although the reasons for the continuing decline in mining productivity are varied, the need for improvement is clear. The world’s mining industry fleet of well over 400 large draglines moves billions of tons of overburden and ore (phosphate, limestone, etc.) annually.This discussion will review a few of the tools available for improved productivity in dragline operations."

Jan 1, 2016

By A. L. Worthen

This is one of a series of pacers being published by the United States Bureau of Mines, describing mining and milling methods at crushed-stone plants throughout the United States. These pacers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total production costs. Although the publication of total production cost might not be advisable in some instances, yet a knowledge of operating costs is essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called o this differentiation in order that there will be no misunderstanding of the scope of the cost tabulations. This paper deals with the quarrying and crushing methods used at the Plainville plant of the New Haven Trap Rock Co., which produces annually between 275,000 and 300,000 tons of trap rock, Although pct the largest quarry operated by the company, it typifies the standard methods used by all the quarries in producing crushed stone and has one or two rather unique operating features. The cost of production at this plant is close to the average cost at all quarries of the company.

Jan 1, 1936

By Graham W. Marks

Recently it was shown the total energy method of spectrochemical analysis is suitable for the quantitative estimation of many of the elements of which ores are composed. It was shown how this method can be applied to the determination of germanium, tin, and lead. Continuing, this work, the present report deals with analyses for beryllium, zinc, cadmium; and indium. There are three basic problems in these investigations. The first is to study the influence of those elements that make up the greater part of an ore sample on the spectral-line intensities of the elements for which analyses are being made, the latter generally being the minor constituents. The second is to develop proper methods for the preparation of standard spectrographic curves. Finally, we are concerned with improvement in equipment and procedure, so that greater accuracy can be achieved. As discussed previously, it is better to study as groups those elements that belong to the same group in the periodic table because their spectra are similar. Beryllium, zinc, and cadmium are thus related. Indium was included in this work because it is, associated with zinc and cadmium in zinc ores.

Jan 1, 1948

Jan 1, 1903

By J. B. Cheung

The results of a program to demonstrate the technical feasibility of hydraulic borehole coal mining are presented in this report. The hydraulic borehole method of coal mining involves inserting a hydraulic mining device into a borehole that has been drilled from the surface into the underground coal bed. The borehole mining device issues a jet of water under high pressure, which breaks the coal. These pieces of coal, along with the water, form a slurry, which flows to the base of the borehole where it is pumped to the -surface. Phase I of the program encompassed the design, fabrication and factory-testing of a hydraulic borehole mining device. The program was successfully completed with the field tests being conducted at the Wilkeson-Carbonado Coal Field near Wilkeson, Washington. The technical feasibility of hydraulic borehole coal mining was demonstrated by mining 32 tons of coal at a depth of about 75 ft over a period of 4 hours.

Jan 1, 1976

By Yehia M. Eyssa

A "straight wire" flow through magnetic ore separator has been designed, built and successfully used to separate magnetite from typical slurries. The purpose of these experiments was to simulate the high field profile of a "straight wire" superconducting magnetic separator which would be capable of separating weakly magnetic hematite ore from typical slurries. Magnetite was used as the test mineral because it experinces the same magnetic forces at low field as does hematite at high field. The present separator concept is based on the fact that there is a particle concentration profile due to the gravity field for low velocity turbulent flow. When a magnetic field force of -g is applied the concentration profile of the magnetic particles will be reversed leaving the nonmagnetic particles flowing alone at the bottom of the channel. By means of a divider at the end of the channel the concentrate is separated from the tailings. It is shown that the time needed to deflect hematite particles in a narrow cylindrical channel concentric with the superconducting wire is small enough so that high throughputs in the turbulent flow region are possible. In the case of a high field superconducting separator the centrifugal force could replace gravity by rotating the flow around the straight wire conductor.

Jan 1, 1974

By S. E. Vanderslice, J. A. Hummer

"The results of laboratory evaluations were used to compare the potential of two alternative, biomass-derived fuels as a control strategy to reduce the exposure of underground miners to aerosols and gases emitted by diesel-powered equipment. The effects of fatty acid methyl ester (FAME) biodiesel and hydrotreated vegetable oil renewable diesel (HVORD) on criteria aerosol and gaseous emissions from an older-technology, naturally aspirated, mechanically controlled engine equipped with a diesel oxidation catalytic converter were compared with those of widely used petroleum-derived, ultralow-sulfur diesels (ULSDs). The emissions were characterized for four selected steady-state conditions. When fueled with FAME biodiesel and HVORD, the engine emitted less aerosols by total particulate mass, total carbon mass, elemental carbon mass and total number than when it was fueled with ULSDs. Compared with ULSDs, FAME biodiesel and HVORD produced aerosols that were characterized by single modal distributions, smaller count median diameters, and lower total and peak concentrations. For the majority of test cases, FAME biodiesel and HVORD favorably affected nitric oxide (NO) and adversely affected nitrogen dioxide (NO2) generation. Therefore, the use of these alternative fuels appears to be a viable tool for the underground mining industry to address the issues related to emissions from diesel engines, and to transition toward more universal solutions provided by advanced engines with integrated exhaust aftertreatment technologies. IntroductionDiesel engines have been the workhorses of modern society for industrial and transportation enterprises. Diesel engines of all generations are extensively used in a variety of light-, medium- and heavy-duty applications in underground mining operations around the world. Fuels obtained from various sources and with wide-ranging chemistries have been combusted in diesel engines. However, the bulk of the currently used fuel can still be traced to nonrenewable petroleum sources. The petroleum-derived diesel fuels are primarily made up of saturated acyclic hydrocarbons (parafins or alkanes), aromatic hydrocarbons (arenes or aryl hydrocarbon), and unsaturated hydrocarbons with double bonds (olefins and alkenes). Improvements in the quality of petroleum-based diesel fuels was identified in federal regulations as an important piece in resolving the puzzle of diesel engine emissions (Environmental Protection Agency, 2001, 2004). The reduction of U.S. diesel fuel sulfur content below 15 ppm had the effect of lowering sulfate emissions and enabling the development and implementation of catalyzed emissions control technology across a wide spectrum of applications."

Jan 12, 2017