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By Stephen J. Roberts

Gold catalysts were prepared on co-precipitated, calcined copper oxide - zinc oxide support by an inverse deposition-precipitation method. These catalysts were characterised by X-ray diffraction (XRD) and temperature-programmed reduction (TPR) and studied for CO oxidation activity at various catalyst calcination temperatures. TPR studies of the support material exhibited a double peak and shift to lower temperatures for the reduction of Cux+ to metallic copper, as opposed to the single reduction peak for pure CuO. This phenomenon is possibly caused by an interaction with the zinc oxide. The addition of gold to the support CuOZnO led to a further shift in copper reducibility to lower temperatures. Gold present in the initial uncalcined catalyst as Au3+ was auto-reduced to Au0 under various calcination temperatures. The Au3+ reduction peak was observed to shift to lower temperatures with increasing calcination temperature. The catalytic activity was found to pass through a minimum value with respect to calcination temperature. Catalysts with both gold in entirely the 3+ or metallic oxidation state were found to exhibit high activity. Furthermore, the catalysts were found to decrease in activity with decreasing Au3+ content up to an intermediate calcination temperature, afterwhich the activity increased sharply. Possibly at higher temperatures, a stronger Au-support interaction is formed, leading to a new active site.

Oct 1, 2003

By M. Kerr, Petra Lampinen, Jinming Zhang, Petra Brodin, C. Hull, Nils-Johan Bolin, R. Asmatulu

"According to Darcy’s equation, the rate of dewatering varies as inverse square of the surface area of the particles to be dewatered and is proportional to the pressure drop across a filter cake. Thus, the difficulty in dewatering fine mineral concentrates can be overcome by using high-pressure filters. When treating ultrafine particles, however, it is often necessary to further dewater the filter cake using a thermal dryer. In the present work, novel dewatering aids that can reduce the pressure requirement have been developed. The reagents are designed to reduce surface tension, increase particle hydrophobicity and increase capillary radius, all at the same time. They were tested for dewatering mineral and coal concentrates in both laboratory and pilot-scale tests. The results show that the use of the novel dewatering aids can substantially reduce cake moistures and, at the same time, increase throughput. In this communication, the case history of using the reagents commercially at the Garpenberg concentrator is given. The use of the novel dewatering aids allowed the operators to use a vacuum filter to obtain desired cake moistures and obviate the need to use a thermal dryer.INTRODUCTIONDewatering is an integral part of mineral and coal processing operations, as it is necessary to remove water from concentrates (or clean coal) to minimize shipping costs, meet contract specifications, and recycle the process water. In general, the cost of dewatering increases with decreasing particle size, which can be attributed to the difficulty in removing the water trapped in the pores (or capillaries) formed between the particles constituting a filter cake.The various parameters affecting the process of dewatering, including the effect of particle size, can be understood in view of Darcy’s equation (Darcy, 1856):"

Jan 1, 2005

By P. Marcotte, G. LeBlanc, S. Ouellette, J. Boutin

"To characterize noise and vibration sources of different types of mining equipment used in underground mining, the authors performed a study in eight Quebec mines on 28 pieces of equipment. This paper presents the procedure followed to select the equipment to be evaluated, and the low-cost acquisition system developed to perform multichannel time-domain data acquisition in harsh environments. It also presents the results obtained for the noise level produced by the equipment and for handarm and whole-body vibration exposures.RÉSUMÉ Dans le but de caractériser les sources de bruits et de vibrations de divers équipements miniers utilisés sous terre, les auteurs ont étudié 28 équipements dans huit mines du Québec. L’article présente la procédure suivie pour choisir les équipements à évaluer ainsi qu’un système multicanal à faible coût développé pour acquérir des données dans des environnements difficiles. Il présente aussi les résultats obtenus pour les niveaux de bruit produit par les équipements et pour les expositions main-bras et du corps entier aux vibrations."

Jan 1, 2015

By Stoyan N. Groudev, Ioannis Paspaliaris, Plamen S. Georgiev, Irena I. Spasova, Kostas Komnitsas

"The uranium deposit Curilo located in Western Bulgaria for a long period of time was a site of intensive mining activities including both the open-pit and underground mining techniques as well as in situ leaching of uranium. The ore was rich in pyrite and, apart from uranium, contained some non-ferrous metals. The mining operations in the deposit were ended in 1990 but since that time the deposit is a permanent source of acid drainage waters. The generation of these waters is connected mainly with the oxidation of pyrite and other sulphide minerals by the indigenous acidophilic chemolithotrophic bacteria.Laboratory and pilot-scale studies revealed that an efficient clean-up of the above-mentioned waters was achieved by means of passive systems of the wetland type. In 2001 a wetland was constructed in the deposit to treat a portion of the acid drainage waters which were discharged to a small ravine. This ravine reaches into the Teina, a small river that is a tributary of the upper reaches of the Iskar river.The wetland was constructed in the ravine and its bottom was located on intrusive rocks with a very low permeability. The rocks were covered by a 30 – 50 cm layer consisting of a mixture of soil, plant compost and crushed limestone. The wetland was characterized by an abundant water and emergent vegetation and a diverse microflora. Typha latifolia, Typha angustifolia and Phragmites australis were the prevalent plant species in the wetland but species of the genera Juncus, Eleocharis, Carex and Poa as well as different algae were also well present.The acid drainage waters treated by the wetland had a pH in the range of about 2.5 – 4.1 and contained uranium, radium, some heavy metals (iron, manganese, copper, zinc, cadmium, lead), arsenic and sulphates in concentrations much higher than the relevant permissible levels for waters intended for use in the agriculture and/or industry. The watercourse through the wetland covered a distance of about 0.2 – 1.0 l/s."

Jan 1, 2003

By D Cork, R Peet

"Methane is a signifi cant greenhouse gas. Methane is released from coal seams during the mining process, both in surface and underground operations. This uncontrolled release is termed æfugitive emissionsÆ and in underground mines is transferred to the atmosphere in ventilation air, known as ventilation air methane (VAM). The global VAM emissions are over 369 Mt of CO2-e/a (Butler, 2011; US EPA, 2010). Coal mines may abate this VAM or consider abatement should there be a price on carbon. These fugitive emissions are heading towards ten per cent of AustraliaÆs emissions by 2020 (Department of Climate Change, 2011).There are safety issues involved in VAM destruction. Due to the nature of coal, and coalextraction, unpredicted methane spikes above the lower-explosive-limit (LEL) can occur in theventilation air; for example outburst events or ventilation failure. This could lead to a mine fi re ifthe mine ventilation air was connected to a VAM abatement plant and the risks are left unmitigated.CorkyÆs is working with the mining industry to directly address these safety issues. CorkyÆs calltheir technology VAM RAB, which stands for ventilation air methane regenerative afterburner(VAM RAB). VAM RAB utilises the principles of a thermal oxidiser.This paper discusses fi ve independent layers of protection (ILPs) to fi rst stop methane reachingthe thermal oxidiser and secondly prevent the fl ame front from burning away from the VAMRAB. The test work completed or contemplated includes safety integrity level (SIL) assignmentto various vents, barriers and door systems to prevent a fl ammable mixture reaching the VAMRAB, proven rapid response methane monitoring sourced from the petrochemical industry, anddefl agration experiments to test the eff ectiveness of the passive geometry and active engineeringcontrols. These experiments and SIL assessments indicate that it is possible to safely connect theVAM RAB to a working coal mine.Further work is required to upscale the pilot safety work. Refi nement to the design is possible;for example improvement to safety duct controls once trialled at demonstration scale plus thermalenergy capture for power generation or other applications to provide heat. Nevertheless, thispaper shows how safety issues can be managed by a multilayer of protection approach usingvents, barriers and doors, and appropriate thermal oxidiser geometry."

Jun 1, 2012

By I T. Ross

In the last 50 years there have been tremendous improvements in equipment used in development on underground mines. Compressed air powered jacklegs have been replaced by high powered electro-hydraulic drifters on sophisticated drill jumbos and load haul dump units have taken over from small shovels and rail cars.Despite the increase in power applied in key parts of the development cycle, average advance rates have fallen and costs have increased. The factor that is most often regarded as the main contributor to slowing advance rates is increased support requirements. Whilst there is no denying that the drive to improve safety has resulted in the requirement for more bolting and the installation of a skin support (mesh or shotcrete), this is not the only factor.Within the industry as a whole, many of the basic principles of development appear to have been lost over time. This paper looks at a historical case study and discusses some of the features of old development cycles that are no longer in use. This highlights some of the basics that appear to have been forgotten. These may be indicators to what may provide improvements in the conventional drill and blast development cycle.CITATION:Ross, I T, 2014. Development – back to basics, in Proceedings 12th AusIMM Underground Operators’ Conference 2014 , pp 67–74 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 24, 2014

By Thomas S. Jones

This Bureau of Mines publication reviews characteristics, manufacture, and uses of natural and synthetic iron oxide pigments. Supply and demand trends within the domestic industry and in foreign trade are presented for 1955 through 1976. Iron oxides are expected to continue in demand for traditional uses, and if anything, to be favorably affected by technological developments. Imports have been significant in relation to domestic production, most notably for synthetic oxides from West Germany and Canada.

Jan 1, 1978

By Choi Sang-Ken, Chung Hun-Saeng, Kim Byoung-Gon, Lee Jae-Jang, Park Chong-Lyuck

"Graphite has unique properties such as high thermal resistance, low thermal expansion coefficient, and good thermal and electrical conductivity, and is often utilized as coating materials for electrical conductors, TV Brown tubes, electromagnetic shields, and so on. Additionally, its excellent lubrication property is widely used in oil and solid lubricants. Finely ground graphite particles in the sub-micron range are commonly used for these applications.Sub-micron fine graphite particles are typically prepared in liquids by vibration ball mills. However, it is known that the wet process takes long periods of grinding time like 24 hours or more and requires a series of subsequent highenergy operations such as de-watering, drying, regrinding and classification. On the other hand, there would be numerous advantages if fine grinding could be done effectively in dry atmosphere. However, since crystalline graphite has a layered structure giving a high lubrication property, its dry grinding, especially when obtaining sub-micron size particles, is extremely difficult. The shape of the graphite particles is also important for its utilization since particles with flaky shape can maintain relatively high electrical and thermal conductance as well as lubrication ability. Therefore, it would be necessary to reduce the size of graphite particles into fines with flaky shape while grinding proceeds. Dry grinding characteristics of natural graphite under various atmospheric conditions with gases using different mills were studied, and fine flaky particles by grinding the graphite intercalation compounds and the exfoliated graphite were produced. However, there were no sufficient investigations on the size reduction of natural graphite at low atmospheric pressures in attritional milling conditions. The main purpose of this paper is to provide sub-micron fine grinding characteristics of natural crystalline graphite at various degrees of low atmospheric pressure, and to discuss the size reducing models in an attrition mill"

Jan 1, 2003

By Wenbing Guo

The stability of strip pillar is the key to successful strip pillar mining. In analyzing the stability of the strip pillar, the width of yield zone must be determined. The determination of the width of yield zone has been an important subject for researchers. In this paper, the numerical method was used to study the relationship between the width of yield zone in strip pillar and coal recovery ratio. The results showed that as the recovery ratio increases, the width of yield zone increases exponentially. Accordingly, the formula for determining the width of yield zone was updated and the effect of changing coal recovery ratio on strip pillar deformation is presented.

Jan 1, 2006

By Kenneth Eltschlager

Business says that location is a primary component of being successful. So too is the importance of location in blasting. For blast seismograph data to be useful, the location of the blast and seismograph must be clearly documented. Another location of importance is that of a nearby structure. Establishing the spatial relationships between the blast, seismograph and nearby structures, allows the blaster to correctly interpret the data, evaluate the performance of the blast and gauge the validity of any complaints.

Jan 1, 2004

By N. A. Gjostein

From their study of the anisotropy of grain boundary mobility in aluminum, the authors conclude that tilt boundaries have a higher mobility than twist boundaries because the atomic misfit at the pure-twist boundary is relatively small compared to the misfit at a tilt boundary for a given amount of misorientation. If this is true, then one would expect a twist boundary to have a lower grain boundary energy than the corresponding tilt boundary. Fig. 6, taken from the work of Gjostein and Rhines,10 shows that this is indeed the case for [001]-cu tilt and twist boundaries in the high-angle region, thus lending support to the authors' conclusion.

Jan 1, 1968

By Hong Nguen Vu, Pavla Ovcarí, Peter Fecko, Barbara Tora

"The goal of the work was verification of bacterial leaching on the samples of black coal. From the results obtained it was clear that the coal is very well leached by Thiobacillus ferrooxidans and this technology can be used for coal desulphurization. A leaching time of one month is required, to remove 65% of total sulphur and 85% of pyritic sulphur.Microscopic evaluation of samples from Jaworzno showed, that it should be classed as a coal with low coalification, probably from black coal hemiphase. Macerals of the liptinite group were well distinguishable; they were of a dark brown colour. Evidence of coal mass oxidation was apparent on the fresh sample; in the test samples (during bacterial leaching) small grains were oxidised."

Jan 1, 2003

By G. Onal, E. Gock, H. Dincer

"During the conventional chromite dissolution process; chromite ore concentrates were ground to at least <90 µm using the ball mill and after adding Na2CO3 and leaning material (instead of CaCO3 also residues from the leaching process) at a ratio of e.g. 1:0.75:1.2, depending on the specific formulation, follows the digestion e.g. in a rotary kiln, heated in countercurrent. The reaction time is 3 to 8 h. The calcine is comminuted and leached with water or a thin chromate solution. Depending on the type of ore used, the yield is 75-85 %. The disadvantage of the above-described process is that it is impossible, using current technology, to achieve a complete digestion of the chromite ores and that the chromium-containing residues have to be disposed of as special waste, involving a large financial effort.The subject of this study was the investigation of the effect of vibratory milling on chromite dissolution. The impact stress in the vibratory mill causes the mechanical activation of chromite, which is characterised by lattice defects. The degree of mechanical activation can be quantified by measuring the relative X-ray diffraction intensities at the parent lattice planes of chromite. Each relative X-ray diffraction ratio correlates with a certain degree of digestion. As opposed to vibratory milling, a complete digestion of chromite using a ball mill is impossible, even at extremely long grinding times.In this investigation a chromite concentrate from Pulpinar/Kayseri with content of 44 % Cr2O3 and the Eccentric Vibratory Mill was used. In order to verify the effect of the vibrating grinding on chromite dissolution, reaction kinetic investigations on digestion and leaching were carried out."

Jan 1, 2003

By T. R. Ellis

Minerals Appraisers/Valuers often find great difficulty or failure in attempting to employ the Sales Comparison Approach to the Market Value Appraisal of development and operating stage mineral properties. An important factor generally overlooked is a comparison of net operating income (NOI) margins on a per-unit-of-production basis between mineral properties, whether these be demonstrated or forecast margins. NOI margins can vary greatly between mines or quarries that are producing similar products. Ultimately, the expected NOI margin determines what a buyer is willing to pay for an income producing property. Common criticisms of the sales comparison approach by minerals appraisers are introduced. These are counterbalanced by raising some issues in the way the inputs for the Income Approach are usually derived by minerals appraisers, and by review of some conspicuous examples of the much too common misuse or abuse of the income approach in market value minerals appraisals. Example transaction analyses and sales comparison analyses are used to demonstrate the author?s methodology for adjusting units of resource in his transaction adjustment tables (see APPENDIX). The examples are used as the basis for discussion of ways to employ adjustments for operating economics and many other factors, while cautioning about the potential for double counting. The conclusions include a recommendation that minerals appraisers attempt to apply at least two of the three valuation approaches when appraising the market or fair value of development and operating stage mineral properties, the two being the sales comparison and income approaches.

Jan 1, 2011

By Alok Garg, Rajeev Kumar Dayal

The Himalayan ranges have complex geological formation induced with locked up tectonic stresses and squeezing ground conditions. High overburden, steep slopes, perennial snow, and forest cover restricts accurate prediction of geological features, resulting in surprises during excavation. The tunnel planning under high altitude, extreme climatic, and unfavorable approachability conditions requires elaborate detailing. The construction technique and working faces for excavation are influenced by site accessibility/high overburden conditions, restricting the provision of access tunnel or shaft. The paper discusses site constraints influencing construction method and working faces for 8.9 km long highway tunnel at elevation 3,000 m under 1,900 mover burden through quartz-mica-schist formation.

Jan 1, 2001

By Gerhard Nel, Huziel Masiiwa, Marthie Kotze, René du Preez, Simon Donegan

Tati Nickel is currently operating a hydrometallurgical demonstration plant in Botswana, using the Activox® process developed by LionOre Technology, to produce nickel cathode and a cobalt salt from a sulphide concentrate. Cobalt is extracted using Cyanex 272. This reagent also extracts all the iron, aluminium, copper, zinc, and manganese from the nickel stream. Versatic 10 carboxylic acid is then used as extractant to recover nickel from the stream, separating it from calcium and magnesium, and upgrading it to provide a suitable advance electrolyte for nickel electrowinning. However, the selectivity of Versatic 10 for nickel over calcium is limited, and gypsum formation in the extraction circuit is a problem when it is attempted to maximise the recovery of nickel. Mintek has developed a synergistic system with Versatic 10 for improved separation of nickel from calcium and magnesium. Laboratory test work was conducted on the raffinate of the cobalt solvent extraction circuit to optimise the Versatic 10/Nicksyn? (Mintek synergist) system to be employed. Extraction and stripping parameters suitable for this stream were optimised in the laboratory and then applied on the demonstration plant. A commercial batch (0.5 tons) of Nicksyn? reagent was produced for the demonstration plant. The laboratory test work results and the demonstration plant performance are discussed in detail in this paper.

Jan 1, 2007

By Volker Vogt, Wolfgang Sand, Eberhard Gock

"For about 20 years, the use of bacteria to control the flotation process for the production of raw material concentrates has been the subject of worldwide scientific and engineering efforts. The objective is to reduce the consumption of biologically non-degradable toxic reagents. The principle idea is to use the activity of bacteria in natural leaching processes – known since the middle of the last century – for controlling flotation processes.It was discovered that the selective activity of bacteria during the extraction of raw material concentrates by means of flotation could also be achieved with extracellular polymeric substances (EPS), excreted by bacteria. EPS, which is extracted by means of centrifuging bacterial cultures, can help to significantly reduce the use of cyanides, approximately 200,000 t/a are used for ore dressing today.The bacterium used was Acidithiobacillus ferrooxidans. In order to identify the bandwidth of the oxidation activity, 21 bacterial strains of the strain collection of the University of Hamburg were attracted to iron(II) sulfate and pyrite under defined conditions. All strains oxidized iron(II) sulfate ten times faster than pyrite.EPS has so far been derived from four strains. In general, EPS extracts are divided into a hydrophilic and a hydrophobic fraction. The hydrophilic fraction is composed of e.g. fucose, rhamnose and glucose; fatty acids such as dodecanoic acid, hexadecanoic acid, octadecanoic acid and nonadecanoic acid were found in the hydrophobic fraction. Pure mineral phases and mineral mixtures were used for the flotation tests. The outcome was reproducible results with technical flotation machines. The research results known so far are mainly based on investigations with micro flotation devices, which are usually used for the characterization of reagents and which do not allow a direct translation to the technical scale."

Jan 1, 2003

By Jean-François Lapointe

Many advances have been made concerning the automation of heavy equipment teleoperators such as those found in mining. Complete automation, however, is not achieved yet and the operation of these vehicles still relies on the presence of a human operator. Fortunately, a lot of research has been done in order to improve the performance of these human-machine systems. This paper presents the characteristics of different control modes and input devices used for the control interface of those telemanipulators. We describe the benefits and drawbacks of each particular control interface on the overall system performance, based on a review of research in the field. We conclude with some recommendations and a discussion of future research needs, given the new potential advances offered by virtual environment technology and embedded computing.

May 1, 2001

By P Holt, M Allen

On the first of July, 2012, the Australian GovernmentÆs Clean Energy Act commenced. From this point, a price of $23/t of CO2-e will apply to facilities that trip the liability threshold. This first part of this paper concentrates on the mechanics of the Clean Energy Future legislation and how it will be applied to the mining and mineral processing industry.The second part of this paper contains analysis of the data presented for typical mine operations. Methodologies for constructing a carbon strategy are also presented. This will entail determining what the objectives of the carbon strategy are, and defining what the strategic priorities for a business should be. An action plan to address the risks identified from the Clean Energy Act is also developed as part of the strategy.Details such as the advantages and disadvantages of opting into the carbon price scheme for liquid fuels are shown. Other considerations such as the ability to acquire permits through the carbon farming initiative or through overseas clean development mechanism projects are explained.CITATION:Allen, M and Holt, P, 2012. Implications of the carbon price and developing a carbon strategy, in Proceedings International Mine Management 2012, pp 105-114 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 20, 2012

By C. J. H. Brest van Kempen

The objective of this contract was to provide thrust and torque control and visual output torque readout systems to an existing mine roof bolting machine and to test the consistency of torques obtained under actual field conditions. A Lee Norse TD1 roof bolter was modified by adding a simple torque sensing device to the drill rotation mechanism and a pneumatic logic control circuit that measures torque and controls the hydraulic circuit to the rotation motor. The modification controls and indicates the final installation torque of mine roof bolts. A total of over 5,000 mechanical roof bolts were installed in an operating coal mine. The installed torque of these bolts were within an error band (standard deviation) of 8%.

Jan 1, 1978