Search Documents

By Alex I. Kociubczyk, Wilky Desrosin, Lucía Mabel Boycho, Alicia E. Ares, Carlos E. Schvezov

In the present research, commercially pure Sn and Zn, and Sn-Zn alloys (Sn-1wt.%Zn, Sn- 2wt.%Zn, Sn-4wt.%Zn, Sn-8wt.%Zn and Sn-8.9wt.%Zn, weight percent) were obtained by a horizontal directional solidification process with two opposite senses and heat extraction. The solidification process was realized using a horizontal furnace with two heat extraction systems at both ends. The temperature was measured using eight K-type thermocouples and an electronic recorder of temperature data. The resulting structures were analyzed using optical microscopy. From the solidification process the thermal and metallographic parameters were determined in all samples. The presence of defects in the solidified pieces was observed. Internal defects pretended to be dependent not only on the composition of the alloys under consideration but also on the size of the structures formed, also, on the velocities and accelerations of interphases, and on the variation of thermal gradients. A model of the phenomenon from the first principles is presented.

Jan 1, 2015

By R. G. Reddy

Viscosities of alkaline metal oxide-silicate melts were estimated using our previously developed mathematical model. The structural based model considers depolymerization effects and related breakdown of the silicate network structure, on the addition of metal oxides to the melt. The developed expression: n =4.9x10 9 NO 0 T ½ exp(E/RT) poise was used to calculate the viscosities of various binary silicate systems such as, CaO-SiO,, MgO-SiO, and MnO-SiO,, as a function of temperature and composition. Excellent agreement was obtained between the calculated and experimentally determined viscosities.

Jan 1, 1991

By E. Kozeschnik

A new model is presented for the simulation of the evolution of precipitates in a multi-component multi-particle multi-phase environment The mathematical formulation as well as the physical background of the model are briefly introduced and its capabilities are discussed on the example of a precipitation sequence in a complex steel. Keywords: Modeling, precipitation kinetics, nucleation, growth, coarsening

Jan 1, 2003

By L. Lewczuk

A detailed mineralogical and liberation study was performed on the iron ore mill products from the Scully concentrator of Wabush Mines, Newfoundland. Automated image analysis techniques were applied to deter-mine grain size distribution and liberation of all mineral components of the ore. As a result of the study it was indicated that iron recovery can be improved and the Mn minerals reduced in the iron ore concentrate by (a) increasing spiral middlings, (b) regrinding the middlings, and (c) separating the Mn minerals from the iron minerals in the reground middlings.

Jan 1, 1988

By Yuanbo Zhang, Yongbin Yang, Guanghui Li, Zhengwei Yu, Yufeng Guo, Tao Jiang, Xiaohui Fan, Youming Hu

"Composite agglomeration process (CAP), as an innovative method for preparing blast furnace burden, was developed and has been put into operation in China. CAP is different from traditional agglomeration processes of iron-bearing materials involving sintering and pelletizing. Compared to the traditional agglomeration processes, CAP is characterized by several strengths such as permission of diverse iron-bearing materials in production, obvious improvement of permeability in the feed bed, decreasing the fuel consumption and remarkably increasing the productivity of sintering machine. Furthermore, the use of the composite agglomerates prepared with CAP is capable of obviating the negative effects caused by the differences in quality of sinter and pellets on the operation of blast furnaces. This paper mainly presents an overview of the principle and applications of CAP.Development Background and Principle of CAPhe traditional agglomeration processes including sintering and pelletizing have been the two predominant methods for preparing ironmaking burden from iron-bearing materials. Sintering is a way for agglomeration by heating the coarser fine ores (general granularity 0~10mm). The mechanical strength of irregular porous sinter is obtained by the solidification of molten phase at high temperature process. It has been shown that the production of high basicity sinter (R=1.8~2.2) is characterized by low energy consumption and high efficiency compared to low basicity sintering. Meantime, the finished high basicity sinter is characterized by good mechanical strength and metallurgical performance. Pelletizing is another way for agglomeration by firing wet green pellets, which are balled from the fine grained iron ores or concentrates. Based on the differences of chemical compositions, the finished pellets can be divided into acidic oxidized pellets, fluxed pellets, magnesium-bearing pellets, and so on. The acidic oxidized pellets are the dominant products of modern pelletizing."

Jan 1, 2012

By Donghai Li, Cheng Pan, Pan Chen, Xuewei Lv, Mei Liu

"Chromite concentrate after beneficiation can not be directly used in the electric furnace. Therefore sintering is one of the effective way to agglomeration, by which the chromite concentrate can be utilized and the power cost of ferrochrome smelting can be reduced. The properties of raw materials and the sintering process of chromite concentrate were studied in this work. The results showed that chromite concentrate used can hardly granulated alone, while chlorite addition can improve the effect of granulation. Moisture plays an important role in sintering process. The granulation effect is optimal when the amount of water addition is 12%. Strength and abrasion index are the evaluation indexes of sinter quality. It was found that the strength of sinter increased with coke dosage increasing to 12%, and then decreased when it continuously increased. Opposite regularities were found for the abrasion index of the sinter.1 IntroductionChromium is a very important metal element which is mostly used in the production of stainless steel. In the earth, it is always formed compound with iron as ferrochromium spinel (FeO.Cr203), and its mineralogical name is chromite.[1] Currently, the global production of chrome ore is about 20 million tonnage every year , in which fine ore (less than 8 mm) accounted for about 80% [2] Although the price of the fine ore is cheaper than the lump one, too much fines will lead to the poor permeability and causes increased electricity consumption while producing ferrochrome. Therefore, the agglomeration process of chrome ore is one of the effective measures to increase the usage ratio of fine ore."

Jan 1, 2013

By Graham Cooke, Abhishek Lahiri, Animesh Jha, E. Jeya Kumari

"CO2 reduction by alternative energy devices such as wind-power, electric vehicles utilize rare-earth elements (REE) in several forms; such as in piezo-electric devices, batteries and magnetic materials. In 2010, the 95% of Rare Earth supply is controlled by China, compared to USA being dominant supplier in the 1980s. The dependence upon a single source of lanthanides has prompted the utilization of lower grades of titaniferous mineral concentrates, which often have rich seams of REE. We propose a new methodology, which utilizes the low-grade minerals for the extraction of synthetic rutile and also significant quantities of REE. We demonstrate the alkali roasting of lower grades of mineral concentrates and subsequent leaching in an aqueous medium for preferential flocculation of REE during the extraction of synthetic rutile. Changes in mineral structure during alkali roasting and leaching determine flocculation of REE and permit their separation at the front end of unit process.The physical chemistry and crystal structure of minerals in equilibrium with alkali and aqueous medium play an important role, which we explain by demonstrating the changes in the crystal structure. The quantification of separation of RE oxide via chemical analysis suggests that it may be possible to separate rare-earth oxides between 50 and 80% of the initial concentration in the non-magnetic fractions of ilmenite, for example. The microstructural and X-ray diffraction analysis points out that the presence of alumina and roasting with potassium based alkali enhances the separation and flocculation of rare-earth elements at the front end of the process after roasting. The process allows the recovery of CO2 generated by recycling into the process for the regeneration of alkali."

Jan 1, 2011

By Vinicius Alves Gomes, Jean Igor Margem, Frederico Muylaert Margem, Sergio Neves Monteiro, Marina Rangel Margem

The interface between the matrix and the reinforcing fiber plays an important role in the efficiency by which an applied load is transmitted through the composite structure. The shear stress at the fiber/matrix interface can be associated with this load transference and, consequently, affects the composite strength. In the present work, pullout tests were used to evaluate the interfacial shear stress of malva fiber in epoxy matrix composites. A small critical length was found for the malva fiber embedded in epoxy, which corresponds to a relatively weak fiber/matrix bond and lower interfacial strength.

Jan 1, 2015

By Osamu Iida

Since 'start-up of the larger Mitsubishi Continuous Copper Smelting Process in 1991, furnace relining campaign was gradually prolonged to once every 2 years according to deregulation of governmental boiler inspection. On the other hand, in 1998 Naoshima smelter embarked on an intermediate strategic expansion plan to strengthell its international competitiveness. As part of this plan, modifications were implemented in the copper smelter designed to increase output of anodes from new charge source to 270,000 tpa. In May 1998, treatment of dried neutralized residue was started in C furnace, and during the shutdown for brick relining in April 1999, intensive modifications to the boilers as well as the installation of new spray coolers for furnace off gas treatment were implemented. Finally, the new larger oxygen plant was commenced its operation in May 2000 and the expansion was achieved around 30% increase of anode production from original design.

Jan 1, 2001

By Kazuyuki Kakegawa

The sintering characteristics and the change in the compositional distribution in the PbTiO3 PbZrO3-Pb(Mgl/3Nb2/3)O3 system during the sintering process by spark plasma sintering (SPS) method were examined. They were compared with those by a normal sintering method. The densification by the normal sintering was slow even at high temperatures, When SPS method was employed, much lower temperature and shorter period resulted in sintered bodies having almost the theoretical density. As expected in normal sintering, the compositional distribution decreased as the sintered density increased. On the contrary, the change in the compositional distribution by SPS was much smaller than that in the normal sintering. This sintering characteristic of SPS suggested a possibility of fabrication of sintered material having a desired compositional distribution.-

Jan 1, 2003

By Mikiya Tanaka

Keywords: Solvent extraction, nickel, electroless plating, accelerating effect With the increasing importance of electroless nickel plating technology in many fields such as the electronic and automobile industries, the treatment of spent baths is becoming a serious problem. Although the spent baths are currently treated by a conventional precipitation method, a method with no sludge generation is desired. Previously, we proposed the solvent extraction recovery of nickel from the spent baths by means of solvent extraction using LIX84I as the extractant. However, a problem of this method was that the extraction and stripping of nickel were not fast enough to achieve high efficiencies when the continuous extractor was used. We have overcome this difficulty by finding that the addition of an acidic organophosphorous reagent in small amount into the organic phase markedly promotes the extraction and stripping rates of the nickel. Shaking-out tests using a separatory funnel at 240 spm revealed that the time to reach the equilibria is more than 60 min with only 20 vol% LIX84I, but is reduced to 10 min and 2.5 min by adding 2 vol% DP8R, respectively, during the extraction and the stripping with sulfuric acid.

Jan 1, 2004

By Jiang Feng, Li Chuanhua, Zhang Libo, Peng Jinhui, Ju Shaohua

Solvent extraction of Cu2+ from the leaching liquor contain Cu and Fe use a microfluidic technology. Currently, the conventional copper extraction process has many problems such as long distance and small driving force of mass transfer. In order to solve the problems, studies are carried out on the extraction process of low grade copper leaching liquid using Lix984N as an extractant with a new microfluidic solvent extraction technology. The effects of flow rate on the separation and extraction efficiency between Cu and Fe are studied, and the results show that a steady liquid-liquid interface of laminar flow is form in the micro-extractor, and extraction efficiency is 78 % and 2.5 % for Cu and Fe at the contact times of 0.84s respectively. Besides, the separation coefficient between Cu and Fe is as high as 140.04. The studied microfluidic technology has the advantages like improving extraction efficiency and reducing reaction time and providing the potential application in the hydrometallurgy extraction of Cu.

Jan 1, 2015

By Seshadri Seetharuman

The present paper summarises a series of measurements of the interaction parameter of oxygen in liquid copper with respect to a third element, e(M)o, where M is Mn, Zn, As, Se or Te which are common impurities in the liquid metal. The technique employed was the solid electrolyte galvanic cell method. The cell used may be represented as Pt, W or cermet / Cu-O-M // ZrO2 - CaO // AO, A /PT where AO/A represents a suitable oxide/metal reference. The measurements indicate that Mn and Zn interact very strongly with oxygen in liquid copper while, in the case of arsenic the interaction parameter is nearly zero. The behaviour of the elements Se and Te is unique with respect to oxygen interactions in copper bath. At oxygen levels, xo= 10-4 ? 10-5, the apparent interaction parameters are negative, comparable to that for sulphur. On the other hand, at lower oxygen levels, the results indicate that the interaction parameter values are positive. The results are discussed in the light of some of the theoretical models for solute interactions in liquid metals.

Jan 1, 1993

By Bowen Li

Copper vermiculite is a special nanomaterial with excellent antibacterial and antifungal performance. By means of ion exchange, copper vermiculite containing up to 5.8wt% copper was prepared. The chemical and mineralogical characterization of the material was investigated in this study based on the XRD, AAS, TEM and EDS analysis, as well as the calculation of crystalline parameters and crystal chemical formula. Cu2+ and Mg2+ have similar atom radius and same electrovalence. Correspondingly, the structure character of copper vermiculite is very close to that of standard Mg-vermiculite. Most of the CU21 may have occupied the interlayer cationic positions in the form of hydrate in vermiculite. However, some may have entered into octahedral coordinate positions. The values of au and bo of the copper vermiculite crystal cell have no obvious change compared to that of original vermiculite micropowder, but the Co value decreased slightly, which is desirable for the stabilization of the Cu2+ in copper vermiculite.

Jan 1, 2003

By Nobuaki Sato

The electrical conductivity, k, of pure and sodium doped sulfur melts was measured with and without ultrasonic waves at temperatures ranging from 140 to 340° C by the two probe method using an ultra high resistance meter. The II: value of the pure sulfur melt with irradiation jumped at around 170°C by an order of 102 after which it monotonically increased from 10-5 to 10-4 (omega) 1cm-4 with an increase of the temperature. The addition of the sodium metal to the sulfur melt was found to cause a larger jumping in the II: value. The II: value increased with the increase of Na proportion in the melt. For a 10 mol% Na doped sulfur melt it was as high as max. ~30 (omega) 1cm-1 above 180°C under the irradiation of ultrasonics.

Jan 1, 2003

By Qin Hua, Xiangru Chen, Qijie Zhai, Yongsheng Yan, Liang Chang

"In this paper, pure bainite ductile iron and their alloying form of 0.2wt% niobium were prepared by a controlled cooling heat-treatment. The effect of niobium alloying on the microstructure, hardness and impact toughness of bainite ductile iron was studied. The results show that adding niobium effectively improves the hardness and toughness of bainite ductile iron. The hardness and the impact toughness of niobium-alloyed bainite ductile iron were investigated by varying the temperature at which samples were fed to the incubator.IntroductionThere are two essential methods to prepare the bainite ductile iron: isothermal quenching [I-31, and alloying [4• 51• Isothermal quenching process is very time and energy consumable, concerned as a high cost technique for mass production. Besides, there are certain limitations on the size and shape of castings in this process. In addition, it potentially harms the environment. As for the alloying, Ni, Mo, and Cu have to be utilized to obtain bainite. However, the large demand and high cost of Ni makes it not feasible in practice.It is well known that niobium can promote the formation of carbon compound, and improves the stability ofundercooled austenite, which is preferred to the increase of the hardenability. Previous studies showed that niobium could refine the grain and improve the mechanical properties of gray cast iron [6-81 • Therefore, in the present work, the effects of niobium and the temperature at which samples were fed to the incubator on the microstructures and properties of niobium alloyed bainite ductile iron were investigated."

Jan 1, 2014

By Yong .. Jun Wu

Laminated ceramics have received widely scientific and commercial attention because their properties, such as mechanical properties and electrical properties, can be tailored by adjusting the structure, thickness and composition of the different layers. For example, ferroelectric Bi4Ti3O12 (BIT) which has a positive temperature coefficient of dielectric constant (,E) can be used to modify the negative tE of typical microwave dielectric ceramic BaNd2Ti4O12(BNT), However, BaNd2Ti4O12/Bi4TiO12/Bi4Ti3O12/BaNd2Ti4O12 (BNT/BIT/BNT) laminated ceramics could not be prepared by the general method because the optimal sintering temperature of BaNd2Ti4O12 ceramic (around 1350°C) was much higher than that of Bi4Ti3O12 ceramic (around 1100°C). In this research, a new method of spark plasma sintering (SPS) combined with post-sintering was successfully proposed to prepare BNT/BIT/BNT laminated ceramics. It was divided into three steps. In first step, the BaNd2Ti4O12 ceramics were prepared by conventional sintering method. In second step, the calcined and pre-pressed Bi4Ti3O12 powders were sandwiched between BaNd2Ti4O12 ceramic pellets and spark plasma sintered at 900°C for 10min to synthesize BNT/BIT/BNT composite ceramics. In the last step, a post-sintering was employed to reoxidize the partially reduced BNT/BIT/BNT composite ceramics. The results of scanning electron microscopy (SEM) and electron probe microanalysis (EPMA) showed that BNT layer and BIT layer were well bonded and no significant interfacial infiltration between them was observed. The sandwiched BNT/BIT/BNT ceramic with 10.7% BIT in volume has a dielectric constant of 92.85, a low dielectric loss of 01068 and a small temperature coefficient of dielectric constant of 35 ppm/°C at MHz.

Jan 1, 2003

By G. C. Yao

Branch and needle-shaped intermctallic compounds of iron, silicon and aluminum normally exist in the molten aluminum. If a suitable amount of manganese metal is added into molten aluminum, the shape of the intermallie compound particlcs may become lumpish and spherical. According to the difference in electric and magnetic properties of these impurity particles and molten aluminum, these impurity intermctallie compound particles can be separated by applying an alternating magnetic field. In this experiment the alternating magnetic field was formed by a "C" type loop with AC (50Hz) current. The inner vacuum of the fireclay refractory separator is 25>< 15" 130mm3 with a lateral baffle inside. The separator was put into the interspace of the "C" type loop. It was found that the longer the separation time, the larger the amount transferred of impurities. The amount of transferred impurities increases with the increase of separation time and intensity of magnetic field. The addition of manganese metal enhanees signifieantly the efficiency of impurity separation.

Jan 1, 2003

By Brajendra Mishra, Mark L. Strauss, Gerard P. Martins

Europium is a critical material required for LED, florescent lamp, cell phone screen, and flat panel display production. This process recycling europium from waste lamp phosphors is an innovative method to supply europium. The selective reduction and precipitation method using sulfate precipitation is investigated to recover high-purity europium from yttrium-europium mixed solutions.

Mar 1, 2017

By Zhiqiang Han, Anil K. Sachdev, Baicheng Liu, Guomin Han, Alan A. Luo

The growth of precipitate phase ,B-Mg11Al12 in Mg-Al alloy is closely related to interface anisotropy and elastic interaction. The aim of this work is to investigate the effects of the interface anisotropy and elastic interaction on the morphology evolution and growth kinetics of the precipitate. In the work, the precipitation of ,B was studied using phase field modeling. In the model, the chemical free energy of the precipitate and the matrix were obtained via thermodynamic calculation. It is demonstrated that the interface anisotropy results in lath-shaped precipitate and the elastic interaction affects the shape of the end of the precipitate. The interface anisotropy causes uneven growth in different directions and the elastic interaction influences its preferential growth orientation. By combining the interface anisotropy and elastic interaction in the phase field modeling, the results showed that the precipitate phase has a lath-shape with lozenge ends, which is in agreement with experimental observations.

Jan 1, 2013