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By Karl S. Vorres

Coal my not seem like it, but it is a perishable commodity. The basic coal scientist cannot always replicate earlier experiments with a given sample because of changes that have taken place in the sample. This has led to a stated need for stable samples Coal looks like a uniform black solid to many people, but it does vary in its composition from state to state and mine to mine it also can be shown to vary significantly within a mine or seam. These variations have led to a stated need for consistent samples.

Jan 1, 1985

By X. Wang, Y. Luo

The propensity of coal spontaneous combustion can be evaluated using various laboratory testing methods, such as R70 adiabatic tests, thermal gravimetric analyzer (TGA) tests and critical self-heating temperature (CSHT) methods. Each of the methods has its unique characteristics and index for classifying the propensity of self-ignition of coals. Accountable relationships among the propensity indices of different methods should be established. Using the newly established R70 and TGA testing setups in our ventilation laboratory, samples from U.S. coal mines have been collected and tested. The TGA is a relatively new quantitative method. A test can be conducted in a relatively short time, within about one and a half hours, compared to the adiabatic tests. The temperature and weight of the sample can be measured with high precision and then used to determine the activation energy of the coal, which is a good indicator of the potential for self-heating. Under a specific experimental design, the TGA technique could perform the proximate analysis for determining coal quality parameters (e.g., moisture, volatile matter, fixed carbon and ash content). These parameters can be used in an empirical equation for assessing the potential for coal self-ignition. The trend of activation energies determined using TGA techniques is reasonably consistent with the trend of activation energies determined using adiabatic tests. As a case study, a comparative analysis of these two methods for determining activation energy was made on coal samples collected from Indiana. The kinetics of the spontaneous combustion mechanism has been explained. If the functional groups of a coal such as hydroxyl (-OH), carboxyl (-COOH), methyl (-CH3), etc., activate more easily with a small amount of activation energy at a relatively low temperature, the coal will have a higher potential for self-heating. With the kinetic and coal quality parameters determined by the TGA setup, it has been found that the coal with a low potential for self-ignition has low self-heating rate, a high activation energy and a high minimum self-heating temperature.

Jan 1, 2012

By Zohreh Kazemi Motlagh, Virginia T. McLemore

There are more than 15,000 abandoned mine features in New Mexico. A considerable number of these mines have not been cataloged or assessed for prioritized reclamation efforts. These mine wastes can be examined as a resource of critical minerals. Many of legacy mine waste deposits have undiscovered commodities and critical minerals, due to low recovery processes during past production. In this project, Black Hawk mine wastes in Grant County, New Mexico are examined by thorough mineralogical and geochemical characterization. This project seeks to characterize and estimate the critical minerals in mine wastes of Black Hawk mine, and determine the acid generating potential of mine waste. Identifying and producing critical minerals in New Mexico may directly benefit the U.S economy and national security.

Feb 1, 2024

By Christopher Mark

Sixty years ago, underground coal mining was the most hazardous job in the United States. Roof falls killed about 100 miners every year, more than all other causes put together. Fast forward half a century to 2016, and the first year ever with zero roof fall fatalities. Just three miners were killed by roof falls during the following six years. To understand how this historic goal was achieved, this study analyzed hundreds of roof fall fatality reports covering five decades. It found that the immediate effect of the Federal Coal Mine Health and Safety Act of 1969 (Coal Act) was to reduce the riskiest activities, like needlessly going under unsupported roof. Other hazards, like large roof falls, required technological developments before they were brought under control. Roof control plans, which the U.S. Bureau of Mines had been advocating since the 1920s, fostered the necessary improvements in both the safety culture and the mining technology.

Jun 1, 2024

By N. Myung, G. Hwang, H. Kim, Y. Han, S. Choi

"According to research presently being conducted on selective lithium recovery in seawater, inorganic adsorbents with high selectivity and capacity for capturing lithium ions from liquid lithium resources are called lithium ion-sieves (LISs). Their low toxicity, low cost and high chemical stability make LISs suitable for lithium recovery from seawater. In the present study, the ultrathin LMO nanofibers with controlled diameter were successfully fabricated by an electrospinning technique with a hypothesis that greater aspect ratio (i.e., smaller diameter) would lead to the enhanced recovery of lithium ion from seawater. Design of Experiment (DOE) and dimensionless analysis were performed to systematically optimize the diameter and morphology of nanofibers. Several complementary techniques including FE-SEM and XRD were used to evaluate the physical/physicochemical properties of the nanofibers. Lastly, the lithium ion recovery was tested for the nanofibers with different physical properties using lithium ion solution. INTRODUCTION Demand for lithium resources is increasing in many industries across the world.1-2 However, the conventional resources for lithium is very limited, and it even gets worse to secure the resources due to low grade and/or complexity of feed materials. Much effort has been, therefore, devoted to obtaining lithium from aqueous lithium resources. Several methods such as solar evaporation3-4, co-precipitation5, and solvent extraction6 have been proposed for recovering lithium from an aqueous lithium source, but there are limitations on its use; It takes a very long time or conditions such as temperature, pH and Mg/Li ratio are severe. Lithium ion-sieve (LIS) materials are considered as a good lithium adsorbent because of their unique chemical structure that can selectively separate lithium ion from brine and seawater.7- 10 Furthermore, their low toxicity, low cost, and high chemical stability make LIS suitable for lithium recovery from aqueous lithium resources. Spinel hydrous manganese oxide (HMn2O4) derived from spinel lithium manganese oxide (LiMn2O4) after topotactically extracting lithium from the spinel structure by acid treatment is most widely investigated LIS.10, LIS materials have been actively studied in various forms for easy handling and high efficiency (i.e. membrane11,12, foam13-14, granular15,16). Among them, the 1-D nanostructure LIS with high specific surface area is excellent in efficiency.9 In this study, we present the part of our recently submitted work17. Specifically, we fabricated systemically lithium manganese oxide nanofibers with different diameter as a lithium ion adsorbent using electrospinning technique through design of experiment (DOE). Enhanced lithium ion adsorption properties of the HMn2O4 nanofibers with different diameter were investigated in lithium liquid resources."

Jan 1, 2018

By Peter Werner

Technological advances in mine equipment and milling processes have enabled mining companies to exploit ever lower grades of ore. The result has been larger disturbances, greater volumes of waste, a complex web of infrastructure, and an overall trend towards mega-projects that can extend over several square kilometers. This explosive growth in a mining operation’s disturbance footprint provokes an obvious question: What’s it going to cost to reclaim all of this? At face value, this can be an enormous financial liability for a company, but since the timing of reclamation may be years in the future for many operations, these costs can be heavily discounted thereby limiting the burden on the corporate balance sheet. Nonetheless, mining companies are eager to remove these liabilities as quickly as possible, conversely, regulators want assurance reclamation will, in fact, occur. How might one bridge these competing interests? Navigating the practical and financial requirements of a post-closure landscape requires foresight, judgement and assumptions, however, companies who do not adequately plan for these future expenditures when there is no off-setting income stream will likely face some difficult decisions. Simple risk analysis tools and utilizing the time value of money can help bring some clarity to this end-of-mine life phase.

Feb 1, 2025

By M. F. Werneke

Flotation of the carbonate, oxide and silicate minerals of copper (malachite, azurite, chrysocolla) has been the subject of much research in recent years, but few effective solutions to this problem have been found. With decreasing reserves of sulfide minerals, the economic recovery of these "oxides" appears to be an important source of copper for the future. Xanthates have been known for many years to be malachite collectors (1), but only at very high dosages, or at lower dosages following activation of the mineral by sulfide ion. Dewitt and Batchelder (2, 3) found that chelating agents such as certain oximes were collectors for malachite and azurite, but also required high reagent dosages. Fuerstenau (4) has suggested, for example, that potassium octylhydroxamate may be an effective collector for malachite, On the other hand, Balberyszski (5) has found that oxide minerals may be completely sulfidized at high temperatures with gaseous sulfur or H2S, and then floated with conventional collectors. None of the above approaches appear to offer an economically effective method for the direct flotation of these oxide minerals.

Jan 1, 1977

By D. Scott Scovira, Karl Dufresne

Blasting in geothermally high temperature ground and/or extremely reactive ground is an increasing common challenge for surface and underground mines. Many current PETN based non-electric and electronic detonators have manufacturer published in-hole temperature limits ranging from 55°C to 65°C (131°F to 150°F). When confronting blasthole temperatures above the manufacturer published limits, operations may request site-specific guidance and qualification for use. The advised safe loading window for in-hole PETN based detonators is often too short to be practicable for production blasting. To overcome limitations of PETN based initiation systems, surface mines with high temperature ground and/or reactive ground are known to load blastholes with a qualified high temperature bulk emulsion that are top primed with a cartridge of temperature qualified detonator sensitive emulsion plus an RDX detonating cord downline. As there is no in-hole delay detonator in this system, blasthole timing is accomplished with surface delays. Although this system is safe, top priming and surface delaying does influence floor quality and top size fragmentation, and safe loading windows times reduce blast block size and increase blasting frequency. A mining company with a site characterized by geothermally high temperature ground plus highly reactive ground employed a blasting system like the one described above. The site desires to improve blasting performance by moving to an in-hole delay initiation system that can withstand the site ground conditions. At the request of the mining house, DynaEnergetics developed an electronic initiation system for application in geothermally high temperature ground and/or extremely reactive ground conditions. The DynaEnergetics IGNEO high temperature electronic initiation system is rated for in-hole use in ground up to 150°C (302°F) for 48 hours. The detonator consists of a high strength detonator with an HMX base charge and thermally resistant downline. To make up a primer, the detonator is inserted into a booster charge assembly that is fitted with a small HMX shape charge. This high energy primer is designed to be compatible and reliable for firing bulk emulsions, including those with high percentages of urea inhibition to combat reactive ground. Up to 1000 detonators may be programmed in 1 ms increments up to 1500 ms. The system is controlled by a digital firing panel that can be used with either a wired or wireless trigger. The system enables high temperature and/or reactive ground sites to utilize in-hole delay initiation and realize the associated performance benefits.

Feb 1, 2024

By S. F. Diehl

Suites of monomineralic sulfide and carbonate minerals, as well as mine-waste composite samples, were analyzed using chemical and microanalytical techniques to understand behavior and bioavailability of mine waste elements such as Cu, Fe, Pb, or Zn. Petrographic, scanning electron microscopy (SEM), and laser-ablation inductively-coupled mass spectrometry (LA-ICP-MS) studies of mineralogical residence sites of trace elements are important because trace elements affect the chemical and physical behavior of minerals. Leachate solutions show that chalcopyrite, bornite, azurite, malachite, and galena are host to the trace elements Ag, Al, As, Cd, Co, Cr, Mn, Ni, Pb, and Zn. SEM studies reveal whether these trace elements occur within mineral inclusions or are substituted within lattice structures. SEM analysis reveals mineral phases not identified by X-ray diffraction (XRD), such as inclusions of sphalerite and cobaltite(?) within chalcopyrite.

Jan 1, 2010

By D. A. Baker, W. J. Mullin, T. P. Philip, P. A. Korpi

Some of you will recall from the last Randol conference held in Cairns, Australia in April 1991 that I shot my mouth off when I declared that I believe that these conferences are covering only a small slice of the overall mining industry pie because the major emphasis is on ore processing. The attendees at these conferences to date have been composed principally of metallurgists, which naturally leads to a preponderance of papers on this important feature, but it is only one of the areas of the mining business.

Jan 1, 1992

By J. Dasher

Regarding the March 1991 ME technical paper by De Souza and Moore: For more than a decade since my February 1981 article on how to use modern metric, which SME-AIME had decided to do, I have monthly pointed out metric errors to the editors. In part, I do this because there has been no action to al low editors to fix figures and tables or to allow them to require authors to do so. The latest resulting atrocity provokes this discussion of vibrating drill handle units being stated in decibels.

Jan 1, 1991

By W. Bakiewicz

The Lower Indus Basin deposits form a substantial unconfined alluvial aquifer of excellent quality. This aquifer contains basically highly saline groundwater, overlain in places by considerable amounts of freshwater whose origin can be traced to the present and historical courses of the River Indus. In the past the main source of groundwater recharge has been direct river seepage and water tables were generally deep. Since the establishment of a perennial irrigation regime however, deep percolation from the increased irrigation supplies has predominated and the water-table has risen to within a few feet of the surface. The river system itself is being progressively developed for irrigation and very shortly a situation will arise where the entire low winter flow will be utilised. Fresh groundwater will then be exploited to supplement the surface supplies, and at the same time a drainage system, mainly based on wells will be used to stabilise the water-table at safe depths. This paper discusses some of the methods used to ensure optimum-economic development of the fresh groundwater and describes the general design philosophy evolved by the authors firms for both irrigation and drainage wells, with respect to both well configuation and operation. Water quality standards are discussed in as much as they affect subsequent use of the groundwater. A few particular aspects are considered, including that of the values of the relevant aquifer constants, the construction of wells and the determination of screen losses. A major problem solved during the Lower Indus Project investigations has been the design of wells to-produce fresh water from layers overlying saline water. This solution is also discussed.

Jan 1, 1967

By James Y. Oldshue, Paul M. Kubera

Ore processing requirements in the gold industry are similar to those in other sectors of the minerals industry. In all cases, the processes revolve around the handling of large volumes of ore slurry, incorporating either physical processing or chemical processing steps which are related to distinct mixing application classes as defined in Table 1. From this standpoint, the complexity of the applications range from the simple (blending, solid suspension, etc.) to the complex (e.g., multi-phase reactor systems). The large volume of material to be processed dictates the large equipment size which is characteristic of this industry, and the often remote locations place a premium on both mechanical and process reliability.

Jan 1, 1992

By V. Carabias-Hütter, A. J. Basu

The paper aims at promoting sustainability assessment and reporting into practice using a globally acceptable set of guidelines and a common framework for internal and external reporting at a project/site level. Indicators are used for measuring performance, and this paper addresses development and implementation of performance indicators for sustainability assessment and reporting at local as well as global levels. The selection of a proper set of indicators is a challenging task. The indicators selected should provide the expected information for making right decisions. Relevant and credible sustainability reporting supported by a consistent performance indicator system can be the starting point for benchmarking environmental and social performance for the natural resources sector.

Jan 1, 2004

By Donald R. Williamson

Statistical studies at Cyprus Pima Mine indicate that samples from 22 blastholes are necessary for determining average copper grades, within a desired range of precision, for mine-model blocks by arithmetic averaging. The average number of holes in such blocks is 14. Many considerations show that more holes will not be drilled for sampling. A way to determine block grades more reliably than by" arithmetic averaging was sought. Thus far arithmetic averaging has proven to be the best procedure for the particular operation characteristics despite the small number of samples. It naturally follows that expenditure of great effort in sampling blasthole cuttings is unwise.

Jan 1, 1977

By William Gleason

There was a time, not too long ago, when the most daunting challenges facing those in the mining and mineral processing industries could be solved through better technologies and better practices. But now the challenges that come from the actual acts of mining and processing are just part of the bigger picture. SME?s Colorado Section of the Mineral Processing Division (MPD) hosted its 63rd annual meeting at the Broadmoor Hotel in Colorado Springs, April 25-27 and, while the conference had its fair share or mineralolgy and processing presentations that were heavy on the technical side of things, this year?s conference was also focused on the issues of permitting, regulation compliance and legislative issues. The so-called ?softer? issues, that, if not addressed, can lead to very real and very hard challenges. Under the theme ?Mine your own business - permits, startups, expansions and resources,? even the most dedicated metallurgists were drawn into the discussions of politics and legislation, and how those issues affect their business. Fittingly, Colorado Mining Association (CMA) president Stuart Sanderson was honored with the Arthur C. Daman Lifetime Achievement Award. Sanderson, an outspoken proponent for the mining industry in Colorado and beyond, also presented the keynote address to the lunch crowd where he spoke about framing public opinion toward mining and the efforts of the CMA to move the public opinion dial in a direction more favorable to mining. Sanderson explained that Colorado, once a Republican stronghold, turned after 2002 and now is controlled by Democrats who are traditionally less supportive of the mining industry. Sanderson said the deciding factor in the power shift was money, as supporters of Democrats outspent Republicans in the most recent election cycles. CMA has done its part to keep mining going in the state with a broad marketing campaign that was outlined by Sanderson.

Aug 1, 2013

By Caroline L. Herzenberg

Recently, neutron-induced gamma spectrometry has been introduced and gained provisional acceptance as a method for continuous automated analysis of coal. Instrumentation based on this technique has been under development for and in testing at coal preparation plants and a coal gasifier. To provide a deeper understanding of, and extended capability in applying this method, theoretical calculations have been performed of the absorption of thermal neutrons by various coal compositions, and the thermal neutron capture prompt gamma emission spectra produced by these compositions have been calculated. Selected results of these computer calculations and the computer generated spectra are presented.

Jan 1, 1984

It is widely accepted that particles stabilise flotation froths and that stable froths result in improved flotation performance. Predicting the effect of particle addition on froth stability is, however, challenging. Dynamic surface tension measurement using maximum bubble pressure presents an attractive technique to investigate the effect of surfactant and particles at the air-water interface. The range of bubble lifetimes that can be studied (typically 0.1 to 60 s) is analogous to variations in air rate in flotation cells, and the corresponding changes in surface tension give an indication to the diffusion and adsorption rates of particles at the interface. In this paper, we use dynamic surface tension measurements to investigate the effect of particles on bubble surfaces at the microscale and link this to bulk froth stability measurements carried out using a froth column. Using the maximum bubble pressure method, the results show that the addition of particles results in lower surface tension, both at the dynamic (i.e. short) bubble lifetimes and towards equilibrium (i.e. 60 s bubble lifetime). This corresponds with the bulk froth stability measurements, where the three-phase system yielded more stable froths than the surfactant only system. Furthermore, increased particle loading at the air-water interface, whether through higher surfactant concentrations or lower air rates (longer bubble lifetimes), gave lower surface tension and higher froth stability. This demonstrates the link between bubble loading and froth stability. It is proposed that the maximum bubble pressure technique can be used to predict froth stability for two- and three-phase systems, enabling the effect of particle loading to be accounted for and quantified. Moreover, the technique has the potential to allow rapid determination of particle and surfactant diffusion at the air-water interface and prediction of the corresponding effect on bulk froth behaviour.

By James C. Cobb

Middle Pennsylvanian (Desmoinesian) coals of certain areas of the Illinois and Forest City Basins contain epigenetic sphalerite and associated minerals in veins, clastic dikes, cleat, and other small-scale structural features. The presence of sphalerite in these coals records information about the geology of coals and coal basins, and represents a potential source for zinc as a byproduct of coal production. Origin of Sphalerite in Coal The origin of sphalerite in coal suggested by Cobb (1) involves sphalerite precipitation from zinc-bearing ?Na-Ca-Cl brines upon contact with sources of sulfur in the coal bed, e.g., pyrite, H2S, and organic sulfur. These brines were essentially at the temperature of the host coals as determined by fluid-inclusion thermometry and vitrinite-reflectance studies. The migration of these brines into coal beds may have been caused by compaction of sediments due to continued sediment loading of the coal basins. Zones of high permeability such as sandstones and the coals themselves presumably acted as conduits for the movement of the brines. The open spaces where sphalerite was deposited resulted from minor deformation associated with differential compaction and cleat formation enhanced by volume shrinkage during coalification.

Jan 1, 1982

By Andrew B. Cecala, Robert J. Timko, Christopher J. Pritchard

As mine venti1ation systems become more complex, it is increasingly difficult to supply fresh air to the working face. A high percentage of the fresh air entering a mine never reaches the working face because it short circuits through stoppings and doors, exiting the mine without being utilized. When ventilation limits are reached, the only option presently available to most U.S. mines is to sink a new shaft - an extremely expensive undertaking that many companies cannot afford. Reusing or recirculating a percentage of ventilating airflow may make it possible for some mines to remain operational while maintaining a safe environment for workers. Such a study was performed at a trona mine in Granger. Wyoming. A vane axial fan was used to recirculate approximately 9.4 m /s (20,000 cfm), 25% of the total ventilating airflow, back to the working face area of a three-entry continuous miner section. This study involved two evaluations: the first when the face was 305m (1,000 ft) from the recirculation fan, the second when the face was 610m (2,000 ft) from the fan. The evaluation consisted of monitoring the mine atmosphere for respirable dust, methane (CH4). carbon monoxide (CO), and nitric oxide (NO), at various locations in the intake and return entries. Several shifts were monitored, with and without the recirculation system in operation. With the recirculation system in operation. there was an increase in measured respirable dust concentrations in the intake along with a slight increase in the mine temperature (1.67°C). There were also some minor changes in CO and NO levels in the intake entry, but this seemed to depend on the proximity of the instruments to the turn-around point for the diesel haulage vehicles, than to whether the recirculation system was or was not in use.

Jan 1, 1989