Search Documents

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By R. M. Wilson

Concentrating plants, in common with other types of industrial plants, cannot operate without lectric power. The elctric distribution system and utilization equipment; therefore, must be carefully considered in all phases of plant design. Two important aspects of proper distribution and usage of electric power are the selection of voltage levels and the methods of system grounding. These are not necessarily the most important design considerations, but are perhaps more controversial than other major points, Modern plants demand increasing amounts of power which, since electric power is the product of voltage and current means higher voltages or currents. Higher voltages require more insulation, higher currents more conductor. The equipment designer?s problem is to obtain in his transformer, cable, switchgear, controller, motor, etc a balance of insulation and conductor to obtain a satisfactory design at lowest cost. To provide the most economical system, both in initial and operating costs requires the system designer to select the proper voltage level. Adequate voltage also permits expansion to meet future requirements, and results in better operation of utilization equipment, Relatively little advancement has been made in recent years in improving conductors; however, great progress has been made in improving insulation. Thus modern plants, in general, now find it more economical to use higher voltages than they did previously. For example plants which only a few years ago would have used 2400 volts as a system voltage often find nowdays that 4160 volts is their proper choice. If the plant requires 10,000 kva br more, then an even higher voltage, such as 13,800 volts, will prove economical. However, for the average concentration plant, with less than 10,000 kva demand, the choice of distribution voltages is between 2400 and 4160 volts, and 480 volts will be used for the low voltage utilization system.

Jan 1, 1958

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this study is to assess the impact of different reagents, such as limestone, lime, magnesium oxide, and sodium hydroxide, in experiments carried out in the single purification step and in two consecutive purification steps by raising the pH of a rare earth sulfuric liquor with the aim to remove or reduce the impurity concentrations in the rare earth sulfuric liquor. The choice for the best purification condition was made based on the minimum loss of rare earth elements (REEs), reagent consumption, and residue generation. The exploratory experiments show that it takes place in the two consecutive purification steps, the first one consists in dosing the limestone pulp until it reaches a pH of 3.5 followed by an addition of a lime pulp reaching a pH of 5.0. Under this condition, the results were a total removal of Fe3+, PO4 3− , and Th4+ ions and a reduction of 99%, 87%, and 37% w/w in the Al3+, UO2 2+, and SO4 2− concentrations, respectively, in the purified rare earth liquor. Furthermore, the lowest REE losses (8.3% w/w) and reagent consumption (4.3 kg/m3 ) and also a low residue generation (7.5 kg/m3 ) were observed in this condition. Despite reaching similar results regarding impurity removal, the experiments done with the addition of limestone, lime, magnesium oxide pulps, and sodium hydroxide solution in the single purification step, where the pH was raised to 5.0, presented higher REE losses (64.9%, 42.5%, 44.8%, and 60.9% w/w, respectively) and a higher residue generation (43.2, 25.1, 11.1, and 13.6 kg/m3 , respectively). This occurred due to the co-precipitation of salts containing rare earth elements in their composition. The experiments conducted with limestone, lime, and MgO resulted in a higher consumption of reagents, while the same result was observed when NaOH was used (4.3 kg/m3 ). In the experiments carried out with the addition of magnesium oxide and sodium hydroxide, the respective purified rare earth liquors presented a high concentration of magnesium, sulfate, or sodium, which could impact the quality of the marketable rare earth salts, whereas the salts obtained under the best condition observed in this study seem to be amenable for use as raw material in an attempt to obtain rare earth products with an acceptable chemical quality.

By Sufi Md Gulzar, L B. Roy

Rock engineering tasks like tunnelling, dam and building construction, and rock slope stability rely heavily on properly estimating the rock’s uniaxial compressive strength (UCS), a crucial rock geomechanical characteristic. As high-quality specimen are not always possible, scientists often estimate UCS indirectly. The primary objective of this paper is to assess the efficacy of long short-term memory (LSTM), K-nearest neighbour (KNN), a combination of particle swarm optimisation (PSO) with an artificial neural network (ANN), and adaptive neuro-fuzzy inference system (ANFIS) to estimate the UCS of sandstones from Jharia, Dhanbad, India. Point load index (PLI), porosity (n), P-wave velocity (Vp), density (ρ), and moisture content (%) are the parameters used for the present study. Finally, a comparison was made between the various prediction algorithms outputs. The findings of the study validated the effectiveness of computational intelligence methods in forecasting UCS compared to other models used in this paper. The KNN achieves overall the best results, with an R2 of 0.95 for training, 0.94 for testing, and an RMSE of 0.03 for training and 0.05 for testing.

Nov 23, 2023

By S. K. Kawatra, H. J. Haselhuhn

"Fine-grained hematite ore can be concentrated by the process of selective flocculation and dispersion, which relies on proper reagent selection and control of water chemistry. While many previous studies have been performed analyzing the effects of different reagents on this process in a laboratory environment, this paper focuses on investigating the water chemistry within the process in a pilot-scale continuous deslime thickener.The pH, sodium concentration, calcium concentration and magnesium concentration were varied to determine their effects on the iron concentrate grade and recovery, and the phosphorus concentrate grade and rejection in the pilotscale selective deslime thickener. The ideal pH for the iron grade and recovery of the process using a starch selective flocculant was found to be 10.5. Phosphorus rejection, however, was increased at lower pH values. Minimization of sodium concentration was shown to improve iron grade, iron recovery and phosphorus rejection. Calcium acted as a nonselective flocculant showing higher iron recovery, lower iron grade and lower phosphorus rejection with increasing concentration. Conclusions could not be drawn from the experiments that varied magnesium concentration.The zeta potential of the solid-liquid interface of particles in each sample taken was also analyzed to show relationships between zeta potential and process performance. In all cases, a maximization of the magnitude of zeta potential correlated with increased iron grade and recovery. This supports the hypothesis that a higher level of dispersion enhances the selective flocculation and separation process.IntroductionThe United States produced 53.2 million metric tons out of the 3,000 million metric tons of concentrated iron ore produced worldwide in 2012 (Tuck, 2013). With this in mind, there has been a large increase in iron ore processing research (Bolen, 2014; Carlson and Kawatra, 2008, 2013; Halt and Kawatra, 2014; Halt et al., 2014; Haselhuhn et al., 2012a,b, 2013a,b; Liu et al., 2014; Manouchehri, 2014; Sandvik and Larsen, 2014; Semberg et al., 2014). Of the 53.2 million metric tons produced, roughly 8 million metric tons of hematite (Fe2O3) concentrate were produced using a process known as selective flocculation and dispersion (Cliffs Natural Resources, 2011). This process is the only economically viable method for concentrating low grade (< 40% Fe) fine grain (< 25µm liberation size) hematite ores. It is scarcely used due to difficulty in controlling the surface chemistry of the ore and high reagent costs (Department of Energy, 2001; Haselhuhn et al., 2013a). The process is highly dependent upon both reagent selection and precise control of the water chemistry during separation. This study shows the dependence of the process performance of a pilot-scale deslime thickener on the water chemistry in the feed slurry."

Jan 1, 2015

By Sai Phaninder Reddy Chaganti, Corrina D. Beaven

This study investigates the effect of reagent type, dosage, and pH on flotation kinetics and copper recovery for secondary sulfide ore with elevated clay content. The primary objective was to determine whether Xanthate performs comparably to or better than the currently used primary collector, Thiophosphate. Approximately 80 kg of ore was collected from three blast holes and systematically prepared through drying, crushing, grinding, and flotation testing. Grinding tests were conducted to establish optimal grinding time and lime consumption for pH control, achieving a target particle size distribution in 13 minutes and 30 seconds. Elemental and mineralogical analyses using X-ray Fluorescence (XRF) and X-ray Diffraction (XRD) identified a copper content of 0.36% and significant clay presence, affecting flotation performance. Fifteen flotation tests were performed under controlled conditions, with variations in reagent dosages. Control tests confirmed reproducibility, with recoveries around 80–82%. Increasing the pH did not improve kinetics or recovery, making higher pH adjustments economically unjustifiable. Adjusting the Thiophosphate dosage yielded the best recovery of 83%. Xanthate collectors, tested both as tertiary additives and as replacements for Thiophosphate, delivered comparable or superior recoveries—up to 91.5% in plant tests—and demonstrated faster flotation kinetics, even under high-clay conditions. These findings highlight Xanthate’s reduced sensitivity to clay, potential for lower dosage requirements, and operational benefits such as improved selectivity and circuit efficiency, validating its role as a cost-effective and alternative for processing complex sulfide ores.

Feb 22, 2026

By S. S. Peng

This paper presents a computer program package for predicting surface movement and deformation caused by under-ground coal extractions. It is capable of: predicting final surface movement and deformation over underground openings; predicting dynamic surface movement and deformation process associated with underground lingual mining operations; processing and bookkeeping subsidence survey data; recommending subsidence parameters for those new coal mines where no subsidence data are available; and deducting subsidence parameters from collected subsidence data.

Jan 1, 1986

By David Newman

"Horizontal stress can have a profound effect on the stability of an underground limestone mine. The presence of horizontal stress is usually determined once the mine has been developed and the orientation of headers and crosscuts are well established. Multiple attempts are typically made to control roof falls without re-orienting the mine. Once the decision has been made to change the orientation, pillar centers, mine opening widths, and the question of how to determine the correct orientation must be answered.A case history is presented to illustrate how geologic structure, ground conditions and roof falls in adjacent mines, the World Stress Map (Heidbach et al., 2016), in-mine measurement of “cutter” roof orientation, the orientation of strata offset (cats eyes) within borescope holes, and the diametral deviation method of determining horizontal strain from drill core were used to establish the most likely range of horizontal stress.The main headers were re-orientated in a direction parallel to the median of the range of horizontal stress. The crosscuts were angled 60° to the headers to avoid being perpendicular to the horizontal stress direction. Pillar centers and opening widths were increased in the favorable stress direction of the mains and decreased in the less favorable crosscut orientation. The major principal horizontal stress magnitude was estimated using the strain measurements from the diametral deviation method and elastic modulus obtained through testing.INTRODUCTIONOver the past decade, there has been a significant increase in the number of underground stone mining operations in the United States. As stripping ratios at surface quarries become uneconomical and reach the extent of the mineral boundary, coupled with the encroachment of urban development on previously rural mining operations, the remaining mine reserves are best accessed through underground development.Although the majority of underground limestone mines in the Midwest are in relatively flat lying deposits with minimal geologic structure, many Appalachian mines are in folded and faulted environments. Tectonic horizontal stresses associated with multiple orogenic episodes are locked in the formation and are released as the underground mine is developed.A common misconception is that horizontal stress impacts are more prevalent at shallow depths where the ratio of horizontal to vertical stress may be high. However, field observations and academic research indicates that horizontal stress conditions may be encountered at any depth due to the tectonic compression of the limestone formation (Esterhuizen et al., 2007; Dolinar and Esterhuizen, 2007; Iannacchione et al., 2003; Slaker, Murphy, and Miller, 2017; Kuhnhein and Ramer, 2004). This paper outlines mine design and layout guidelines for the mitigation of horizontal stress impacts on underground stone mining operations through a case history example. This approach to mine planning and the ability to anticipate horizontal stress can significantly improve future production of multiple levels (Newman and Newman, 2019). As underground stone production continues at deeper depths and in more geologically and geometrically complex mining conditions, an emphasis on ground control and the anticipation of horizontal stress can provide safer and more productive single and multiple level mining operations."

Jan 1, 2019

By Chenxi Ding, Chenglong Xiao, Guoli Shi, Zhiwei Zhao

This study investigates the directional blasting of a 90° slit charge structure using laboratory experiments and field tests. A 90° slit charge suitable for the corner of roadway is proposed. After the slit charge blasting, two long main cracks along the slit, and several short secondary cracks in other directions. The slit charge not only significantly reduces damage to the surrounding rock, but also improves the quality of the roadway contour. In addition, a comprehensive damage evaluation system of the roadway contour and the surrounding rock is constructed using digital image analysis, borehole televiewer, and CT scanning.

May 23, 2024

By Yuanhong Qi, Xun Fu Wang, Tao Fu, Kunkun Cui, Yingyi Zhang, Jie Wang, Junmao Qie

With the sharp decrease of sulfide nickel resources, the nickel laterite is becoming more attractive as nickel oxide, nickel matte, and nickel-iron. This study investigated the mineral phase structure, chemical analysis, thermal properties, and element distribution characteristics of the rotten rock layer deposited in the Southeast Sulawesi Ophiolite Belt. The results show that the nickel laterite deposited in Southeast Sulawesi Island, Indonesia, belongs to the typical high-nickel and low-iron garnierite-type laterite. The concentrations of nickel and iron of the nickel laterite are 1.99 wt% and 17.55 wt%, respectively. The serpentine, olivine, clay, chlorite, hematite, and magnetite are the major minerals, and the pyroxene, actinolite, limonite, and chromite are the minor minerals in the nickel laterite in Southeast Sulawesi, Indonesia. Serpentine and olivine are the main nickel minerals with an average nickel concentration of 3.65 wt% and 1.73 wt%, respectively. The Fe and Ni have homogeneity and symbiosis in the serpentine and olivine, and their concentrations are often positively correlated.

By Yi Yang, CHENGLONG XU, HAORAN LI, YALI FENG, JINRONG JU

Steel slag is an industrial byproduct of steelmaking that is mainly composed of calcium, iron, silicon and magnesium. In addition, depending on the different raw materials entering the furnace, steel slag contains a certain amount of vanadium that is the main source of vanadium production, accounting for 69 percent of the species of the total vanadium raw material [1]. From experience, the production of one ton of steel will generate 1.0 to 1.5 tons of steel slag [2]. However, the utilization efficiency of steel slag is less than 30 percent, and a large amount of steel slag is identified as waste and stacked in tailings. The random stacking of steel slag not only wastes large amounts of limited steel and land resources but also exerts pressure on the environment [3], making it imperative to research the effective utilization of steel slag and recycling of metal resources.

By James R. Evans

Forecasting demand is an art as well as a science, and much personal judgment is required. National forecasts made for sand and gravel, crushed stone, and/or aggregate may be misleading or unhelpful locally. This is because of significant variation in demand within different geographic and/or political areas in the United States, and/or the use of an inadequate data base and forecasting methodology. The best forecasts may be made for local or regional market areas, irrespective of geographic or political boundaries, provided a proper data base is available. The Bureau of Mines compiles detailed statistics on commodities sold or used in the construction industries and, therefore, is in an advantageous position to make national aggregate demand forecasts.

Jan 1, 1978

By Kraig W. Grubaugh

Rapid growth in the rate of surface mining for coal has caused many states to increase the rigor and complexity of their surface mining codes. The promulgation of Federal surface mining standards may cause those states containing Federal land to amend their codes also. Presented is an up-to-date review of these codes with tabular summaries that divide the codes into operative functions. These summaries will be of use to new operators, multiple-state operators, and state officials. Suggestions are made for industrial efforts to present workable and acceptable amendments to these codes.

Jan 1, 1977

By David Wright, Jerome Chamfray, Anthony Harding, Brian Boye

Conway’s Law states that unless we intentionally design automation tools around what we need, we will simply replicate our existing processes. While we may achieve some savings this way, there is an opportunity for greater benefits if we re-imagine the way we, as an industry, perform design. This paper examines current technology and shows how even small departures from merely encoding what we currently do could reap significant benefits. From these examples a framework is developed for a new and innovative approach tvo automation that will allow us to design more quickly, to a higher quality, and communicate outcomes more effectively.

Dec 1, 2022

By James Wm. White

Calculation of consistent steady-state mass balances in operating metallurgical plants and pilot plants is of interest for many reasons. In general, enough data can - and should - be collected to overdefine the system, i.e., permit calculation of nonmeasured quantities via more than one path. In such cases, resulting steady-state metallurgical mass balances rarely close due to sampling, analysis and/ or instrument error. Indeed, determination of a valid calculational sequence for complicated process flowsheets with multiple recycle streams can prove quite difficult. Here we present and discuss a method that has proven useful in analysis of numerous grinding circuit flowsheets of varying-degrees of complexity our technique requires only a consistent process flowsheet with appropriate associated data and arbitrary numbering of streams and equipments. Process topology and user data are decoded to yield a set of "search" or base variables and a set of "calculated" variables in solids, water, particle size and splitter parameter space. This procedure greatly speeds subsequent actual mass balance adjustment calculations since perturing certain variables (e.g., a solids value) does not require recalculation of other variables (e.g., the water balance). Finally, internal search and calculated variables are back converted to User units and used in a Sum-of-Squares criterion. Global minimization of this performance functional then yields a consistent mass balance in a least, squares sense. Weighting factors of choice can be used. Examples illustrate application of these methods.

Jan 1, 1979

By Peter Zhang, Todd Minoski, Gabriel Esterhuizen, Jack Trackemas, Berk Tulu, Morgan Sears

Roof stability in the belt entry is critical for safe and continuous production of coal during longwall mining. Previous studies of roof falls that occurred in belt entries have shown that the roof falls were largely associated with high in situ and longwall-induced horizontal stresses [1,2,3,4]. To properly support the roof in a belt entry, it is important to understand how longwall-induced horizontal stress changes can affect roof stability in the belt entry. Monitoring of horizontal stress changes was conducted in the belt entries of two Pittsburgh seam longwall panels oriented unfavorably to the major horizontal stress. Numerical models were also set up to investigate how horizontal stress concentrates and relieves in the belt-entry roof near the face as panel orientation changes. Both measurements and modeling results show that high horizontal stress concentrates in the belt entry roof within about 15 m outby the face. The study demonstrates that longwall-induced differential horizontal stress can be used to evaluate the horizontal stress concentration factors. The horizontal stress concentration factors change with panel orientation, resulting in high stress concentrations at orientations between 20 and 110° and low stress concentrations between 130 and 180°. Roof support strategies are given for the belt entries under the influence of high horizontal stress. For unfavorably oriented panels in weak roof conditions, supplementary support should be installed during development, and cable bolts should be anchored into a stable roof horizon. The bolting pattern should be designed to cover both entry corners and the entry center to prevent potential roof cutters and sagging.

Jan 1, 2023

By Sandeep Kumar Jeripotula, Govinda Raj Mandela, Aruna Manglapady

The main aim of this work is to evaluate whole-body vibration (WBV) of dozer operators based on three sitting postures (i.e., with 15° lean forward inclination posture, vertically erect posture with no inclination, and with 15° lean backward inclination posture) in Indian surface coal mines. A seat pad tri-axial accelerometer was used to collect WBV data from six dozer operators for three different sitting postures. Results showed that except for Dozer-1, 2, 4, and 5 operators during lean forward sitting posture and Dozer-4 operator during vertical erected posture, no other dozer operators have exceeded an exposure limit value (ELV) of 1.15 m/s2 in any of the considered sitting postures. Similarly, the vibration dose value (VDV) based on exposure action value (EAV) of 9.1 m/s1.75 has surpassed for all the dozers. But no dozer operator has exceeded an exposure limit value of 21 m/s1.75. The outcome of the study infers that based on “above health guidance caution zone (HGCZ)” for daily vibration exposure, i.e., A(8) measurements, for the operator sitting in lean backward postures the vibration amplification was reduced by 32.89% less compared with lean forward posture and 16.23% less when compared with vertically erected posture. Similarly, based on VDV(8), the exposure to vibration for the lean backward posture was reduced by 33.34% when compared with lean forward posture and 17.11% less when compared with vertically erected posture. Based on the above observation, it is concluded that lean back inclination with a trunk flexion of 15° is a favorable sitting posture, as it exposes the dozer operators to minimum vibration.

By J. Hanna, I. J. Anazia

The Mineral Resources Institute (MRI) has developed a unique process for selective fatty-acid flotation of phosphate minerals from siliceous ores. The process takes advantage of preferential adsorption (over silica surfaces) and high reactivity of fatty-acid collectors toward apatite under slightly acidic conditions (pH 5 - 6.5). The process was successful in upgrading various Florida and North Carolina phosphate samples containing 7.7% to 15.3% P205 and 62.3% to 77.2% siliceous gangue (Insol). The resulting concentrates assayed 28.1 % to 33.1 % P205 and 4.1 % to 9.9% Insol, with high P205 recoveries of 81.8% to 92.2%. Depending on the degree of surface contamination of the silica particles in the flotation feed, one or more cleaning steps, with or without sodium silicate, would be required to achieve higher-grade phosphate concentrates.

Jan 1, 1994

By Leslie G. McMillion

A field project to develop and demonstrate a method for alleviating problems of highly-mineralized ground water where they occur as isolated zones or pockets in fresh-water aquifers is being conducted in the Ogallala Aquifer of eastern New Mexico by the Robert S. Kerr Water Research Center. Removal of contaminated water is by a large-capacity well and the pumped poor-quality water is used locally for secondary recovery of oil, Benefits of the operation are threefold in that the aquifer is being reclaimed for future fresh water production, contaminated water is being used beneficially, and fresh water which otherwise would have been used for waterflooding is available for other purposes. Ground-water quality in the site has improved markedly after 21 months of operation. Water quality in 15 specially-drilled monitoring wells has returned to the original quality level of the aquifer, and chloride concen¬trations in the pumping well have dropped to half the maximum level recorded thus far. Project results are very favorable and provide guidelines for initiation of similar undertakings in localities where needed.

Jan 1, 1970

By J. Gonzales

For this paper, blending is conceived as a linear process that takes a proportion from one stockpile or location and mixes it with another proportion from another stockpile or location, with the aim of obtaining a set of attributes in the final combination that satisfies a given quality standard. A blending class is the combination of ore attributes and grade limits that should be stockpiled in order to achieve the target quality for the process Plant. Current literature considers the number of blending classes in the Open Pit Scheduling Problem as fixed; however, this paper shows how to define specific blending classes for a given deposit so that the schedule can be solved with Sequential Linear Programming. Finally, a practical application in a Peruvian copper mine is shown, involving four ore attributes: alteration code, arsenic, oxide content and copper grade. INTRODUCTION In copper ore deposits, blending for quality has not been a typical issue as it was for coal and iron ore; however, current copper deposits in the world are becoming geologically and chemically more complex than in the past and is not uncommon to have quality standards involving up to four attributes, introducing an additional complexity to the mine scheduling process [1]. In order to solve the Open Pit Scheduling Problem with multiple ore quality constraints, two assumptions are necessary [2]: - Grade constraints are defined only by specifying an upper and lower limit; - Ore attributes in stockpiles are pre-determined, i.e., the upper and/or lower grade limits defining each stockpile are already known at the time of setting the schedule. Assuming each ore attribute is classified as high, medium or low, and there are four attributes to be controlled in the target ore quality, the number of possible blending classes would be 3^4 = 81. This number is impractical to manage in Operations, and increases the complexity at the time of running the schedule; therefore, a more efficient way of classifying ore is required. Note that in practice, one blending class can be split into more than one stockpile location due to physical capacity constraints. Therefore, the number of stockpiles could even be more than 81. BLENDING CLASSES DETERMINATION For a given set of ore grades with lower and upper limits to be achieved, one has to find all feasible ore classes such that when blended, their grades will lie within those limits.

Jan 1, 2019