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By J. Hong, K. Han, C. Park, C. Yoon, H. Yoon, N. Kim

The contents of three platinum group metals (PGM-platinum, palladium and rhodium), from the spent automotive catalyst, and two NIST SRM (National Institute of Standard and Technology Standard Reference Material, Used Auto Catalysts) were determined by the X-ray fluorescence (XRF) spectrometry. The XRF technique has been proven to be a fast, effective and accurate method in determining not only PGM but also other solid materials of less soluble for wet digestion analysis. The detection limit of the XRF analysis is better than that of the inductively coupled plasma mass spectrometry which usually requires significant dilution to avoid high dissolved solid concentration. However, the XRF technique suffers from a strong matrix dependent problem. The objective of this study was to examine the applicability of the XRF analysis where the sample matrix was not exactly the same as the standard materials with particular reference to PGM analysis. This study enabled to compare the effect of various matrices including alumina, iron, copper and nickel on determination of the contents of PGM.

Jan 1, 2004

By L. E. Baker, M. J. Leck

OSIRIS is a continuous monitoring system for respirable dust which has been specifically designed for mining and related industries. By using the latest microprocessor technology, OSIRIS provides a sophisticated dust measuring system which is a cost effective alternative to regular gravimetric sampling. The system is certified intrinsically safe for use underground. Up to eight underground OSIRIS sensors can be controlled and monitored by a single IBM PC computer located at the mine surface. This computer provides continuous and instantaneous information about the dust concentrations at the sites being monitored. Information is available in tabular and graphical form. The paper gives details of proving trials of the OSIRIS system in some UK coal mines. During these trials, adjacent OSIRIS sensors placed on the same underground roadway cross-section gave virtually identical results. Throughout a good correlation was obtained with conventional gravimetric dust samples. The OSIRIS equipment proved both reliable and easy to operate. OSIRIS was designed and developed by the Safety Engineering Laboratory of the UK Health and Safety Executive. It is now available commercially and is being

Jan 1, 1987

By M. Prasad, A. K. Majumder, T. C. Rao

The depletion of high-grade phosphate ores is bringing about a search for a suitable, economically viable technique that con process the abundant low-grade phosphate reserves. About 75% to 80% of the world's low-grade phosphate reserves are associated with carbonate gangue that is not amenable to treatment by the simple techniques of physical separation. The processing of sedimentary dolomitic/calcareousphosphate ore has numerous problems, including similar surface properties of the carbonate and phosphate. Two-stage reverse anionic flotation of carbonates (dolomite/calcite) has appeared to be a promising separation technique ,for the removal of carbonates from sedimentary rock phosphate. In reverse fatty-acid anionic flotation, the depression of phosphate mineral with orthophosphoric acid produces satisfactory results for calcareous as well as dolomitic phosphate ores from several locations of sedimentary origin.

Jan 1, 2000

By Bruce Congleton

The Florida phosphate industry is a leader in environmental control, both in terms of dollars spent and significant achievements. For instance, since 1960 the phosphate industry has spent over $71 million for air pollution and control devices, including installation, research and development and maintenance. Water pollution control expenditures also total in the millions, with over $69 million spent in the same 10 year period. The industry also is a leader in water conservation measures, having spent nearly $ 18 million since 1966 for conservation devices. Since phosphate is mined by strip mining, land reclamation plays an important part in the environmental control picture. Here again, the phosphate industry has met the challenge with a voluntary program of reclamation which accounts for over 20,000 acres of land useable after mining has taken place. In terms of progress in environmental control, the industry has been able over the years to solve within the limits of technology the fluoride emission problems it once had, and is currently at work solving sulfur dioxide and particulate problems. In just the past year the industry also has been extremely successful in limiting phosphorus and nitrogen discharges into area streams. The industry continues to cooperate with state and local pollution control officials on matters of environmental control, and future plans include even closer cooperation and assistance, as well as increased expenditures.

Jan 1, 1972

By N. K. Davé

Water quality impacts of shallow water submersion of partially weathered and oxidized waste rock containing reactive sulphide minerals were investigated in laboratory column lysimeter studies. The waste rock investigated was highly reactive, contained oxidation reaction products from previous exposure and weathering, and had a low sulphur content of approximately 2 % S, mostly as pyrite. The submerged waste rock, though previously weathered, had high oxygen consumption, resulting in rapid depletion of dissolved oxygen in its pore water, within a shallow depth of ~2?5 cm from the surface. The surface and pore water qualities of the submerged waste rock were significantly impacted by the dissolution and release of previous-oxidation-reaction products, which contributed to their rapid acidification and having increased concentrations of dissolved SO4, Fe total and other metals: Al, Mn, Ca, Cu, Ni, Zn and Pb. Despite the high porosity and permeability of the waste rock, the diffusion controlled mass transfer from the submerged waste rock to the overlying water cover was relatively low for most ionic species. Additional surface oxidation of the sub-merged, partially weathered waste rock was on-going, but its impact on the overall surface water quality was low and masked by the dissolution and release of previous oxidation reaction products to both surface and pore water regimes.

Jan 1, 2006

By H. Sis, S. Chander

The beneficial effect of a series nonylphenol polyethylene glycol ether surfactants were tested in the flotation of phosphate ores in which the mixture of sodium oleate and dodecane was used as collector. The performance of nonionic surfactants was first tested in the microflotation of pure apatite mineral. Microflotation experiments showed that the recovery of apatite depends on the number of ethoxylation of the nonylphenol surfactants and decreased with higher ethoxylation. The nonionic surfactant with the smallest ethoxylation group used in this research (NP-4) was then tested in batch flotation of phosphate ores. The flotation of three different size phosphate ores was carried out in the absence and presence of NP-4 surfactant. The beneficial effect of nonionic surfactant was obtained for fine size (-35+150 mesh) and very fine size (-150+400 mesh) phosphate ores at different collector dosages studied. But, in the flotation of coarse size (-16+ 35 mesh) phosphate ore the beneficial effect of nonionic surfactant was obtained only at high collector dosages.

Jan 1, 2002

By Jaroslav Vicek, Alois Adamus

In the Czech Republic nitrogen was first used for the fight against the mine fire in 1949 (Hajek,1969). In the years 1949¬1996 the consumption of nitrogen in the Ostrava-Karvina Coal Basin /OKB/ reached more than 220 mil. m-3. The main source of nitrogen in the OKB is a central pipeline now. Gas nitrogen is used for the prevention of spontaneous combustion in gobs of longwall faces. The nitrogen infusion technology (Froger,1985), often called "franca technology", has been applied in the Czech coal mines since 1982. The aspects of the nitrogen infusion technol¬ogy can be theoretically solved by the calculation of mixing two gas streams in the filtration space. Longwall faces are parts of the ventilation network of the coal mine. The intake airflow of the longwall face is divided into the airflow passing through the face and a part of air losses passing through the gob. Air leakages through the gob and nitrogen in¬jected into the gob mix there. There is the main problem to solve air leakages in the gob. Usually, the principles of the gob aerody¬namics were used by many authors (Glusberg,1988;Voracek, 1994; Sulkowski,1993; Michailov, 1995; Dziurzynski, 1995; Kolarczyk, 1995; Saghafi, 1995; Sedlaty, 1993) that are applied to our case as well.

Jan 1, 1997

By Lynn I. Kelley

Industrial-mineral production contributes on the order of CDN$1.5 billion per year to the economy of Saskatchewan, Canada. Potash is the primary industrial mineral produced in the province, followed by aggregate, sodium sulphate, salt, potassium sulphate, peat, clays, silica sand, calcium-chloride brine, and "clinker." Potentially economic deposits of kaolin, diamond, and building stone are under evaluation. All of the major deposits of commodities discussed here are located south of lat 56°30'N. Most of the locations are presented on Figure 1 POTASH Saskatchewan supplies approximately 30% of the world's demand for potash. Eight conventional underground mines and two solution mines produced an all-time high of more than 13 million metric tonnes of potash (KC1) (8 million tonnes K2O equivalent) in 1997, valued at over CDN$1.4 billion. All of the mines exploit the middle Devonian Prairie Evaporite. The four potash-bearing members of the Prairie Evaporite underlie much of southern Saskatchewan and extend southward into North Dakota and Montana and east- ward into Manitoba (Fig. 2). Halite and anhydrite separate the potassic members. The evaporite beds locally are interrupted by solution structures (anomalous ground). Some of the structures may be related to deep-seated tectonic features.

Jan 1, 1999

By I. Iwasaki, H. Dho

The role of sodium silicate in the anionic flotation of a Florida phosphate ore was investigated using laboratory continuous flotation tests, frothabiliry tests and SEM observations. In the absence of sodium silicate, Ca I+ promoted the unwanted activation of quartz by forming calcium bearing precipitates. The addition of sodium silicate enhanced the flotation efficiency through: 1) the removal of impurity minerals and calcium-bearing precipitates from quartz surfaces by dispersion, 2) drier and more persistent froths stabilized by oily droplets containing calcium silicate precipitates, and 3) higher specific flotation rates of phosphate relative to quartz, leading to faster flotation rates and increased selectivity of separation.

Jan 1, 1991

By S. B. Patton, T. Novak, R. L. Sanford

A comprehensive approach to the development and organization of an expert system designed to assist electricians in diagnosing electrical faults in mining machinery is discussed. The system includes diagnostic, reference, and tutorial programs. The diagnostic portion of the system is based on a causal-reasoning approach, which is used to establish a hierarchy of symptoms and the subsequent production rules for identifying component-level failures in the motor-control circuit of a shuttle car. With this approach, conclusions are developed directly from knowledge of the circuit and its behavior (in both working and failure modes) based on first principles, rather than the heuristics of a domain expert. The symptoms and their hierarchal structure are formulated by creating "what if' scenarios and performing a qualitative circuit analysis for each fault. Techniques for incorporating interactive graphical displays of the circuit schematic into the diagnostic portion of the system are also presented. Supportive computer programs that provide reference material and tutorials on the circuit are also described.

Jan 1, 1990

By J. Finch, J. Yianatos, N. W. Johnson, R. Espinosa-Gomez

A method of determining the maximum concentrate solids rate or carrying capacity is described for given column operating conditions. The method requires alteration of the feed rate of solids to the column at a fixed residence time by manipulation of the % solid of the column feed pulp or the bias rate. The carrying capacity was measured for five streams at the Mt. Isa Mines Pb/Zn and Cu concentrators. As a potential scale up parameter, the mass of solids per unit time per unit column cross section (Ca, g/min.cm2) is explored. Ca is tentatively related linearly to the 80% passing size (d80) of the concentrate. For d80 < 15 pm Ca was less than 4 g/min.cm2 (8 lb/min.ft2) which makes it a critical consideration in scale-up for such fine feeds. An alternative carrying capacity parameter, mass of solids per unit volume of gas Cg was not as useful as Ca since Cg varied inversely with gas rate.

Jan 1, 1988

By Gun Berglund, Eric Forssberg

Sulphide mineral flotation is known to be affected by oxidation-reduction conditions in the pulp, although there is some doubt as to whether it is the oxidizing environment or the type of oxidant which influences flotation. Variations in the oxidizing conditions of the pulp and their subsequent effect on flotation were examined for two types of natural sulphide ore, a galenasphalerite ore and a complex pyrite ore. Different gas mixtures ranging from pure nitrogen to pure oxygen were used to control the oxidizing conditions. Zinc recovery increased with a more oxidizing environment, and nitrogen gas acted almost as a depressant for sphalerite in the flotation of the Pb-Zn ore. For the complex pyrite ore, the selectivity between chalcopyrite and both gangue and pyrite improved when the environment was oxidizing, resulting in higher Cu recovery in the copper rougher concentrate. The use of an oxygen rich flotation gas was found to be a suitable method for changing the oxidizing conditions and improving flotation under controlled conditions. The flotation results were correlated to the oxygen content and the redox potential, parameters which describe the pulp chemistry conditions.

Jan 1, 1989

By A. Foscolos

Land reclamation and rehabilitation of depleted coal mines in the wider area of Ptolemais-Amynteon is practiced by the Division of Mines of the Public Power Corporation of Greece in order to conform to the concept of environmentally sustainable economic development of its operations. Detailed chemical and mineralogical studies were performed on reclaimed soils and their crops in order to evaluate the results of land reclamation and rehabilitation while similar studies were undertaken in adjacent, regularly cultivated, soils. Results indicate that trace element concentrations as well as concentrations of elements of environmental concern to be higher in regularly cultivated soils than the reclaimed ones. However, the concentration of the elements in wheat grains harvested from both, regular and reclaimed, group of soils is the same. The reason for this behavior is the very low water solubility, of the elements in the soils, due to their high pH values and the nature of their occurrence. As a result, wheat crops produced from reclaimed-rehabilitated soils developed on depleted lignite mines in the wider area of Ptolemais-Amynteon do not pose any health problem on either humans or animals when consumed.

Jan 1, 2003

By Henrique Garcia Pereira

In a large scale mining project, the global feasibility study must take into account the interdependence of three sub systems: the geological subsystem, represented by the orebody model; the technological subsystem, consisting .of mining and ore dressing models; and the economic subsystem, including the selling price of final product, production costs and investments. In cases where the ore is heterogeneous, the interdependence between geological and technological subsystems may be assessed by a Data Analysis technique such as Correspondence Analysis (CA). This technique was applied by David and Dagbert (1975) on examples of data from geochemistry and geology. In the approach used in this paper, CA is used to create the basic framework for defining different types of ore. The final definitions of ore types take into account the mi¬ning method and the results of applying beneficiation processes to the ore.

Jan 1, 1982

By H. Zhu, A. G. Journel

Qualitative and interpretive information as obtained from geological and/or geophysical studies, in addition to precise measurement, is incorporated into the estimation process through an indicator variable. The indicator conditioned estimator is formulated as a cokriging, and its expression is data value dependent as opposed to that of the traditional kriging estimators. The solution of the dual cokriging system provides simultaneously an estimate of the unknown and an estimate of the conditional probability that the unknown belongs to a specific population or class. Being an unbiased and minimum-error-variance estimator by construction, the indicator conditioned estimator is better in the least square sense than the ordinary kriging estimator because it uses additional information carried by the indicator data. A case study using a large reference database is presented; the indicator conditioned estimates have a smaller conditional bias and a smaller error variance than the ordinary kriging estimates. The results also showed that the indicator conditioned estimator is more efficient for selection in mining.

Jan 1, 1990

By Norm Steenson

Rapid excavation includes rapid support and is the central theme of this paper. Over the last few years, enormous strides forward have been made in the excavation and material handling aspects of underground excavation. However, the technology necessary to support these rapidly created openings has lagged behind the other aspects. This paper would attempt to bring you up-to-date on the progress made in bringing ground support using shotcrete into the same productivity rates as the other cyclic operations. Shotcrete has become an acceptable material for temporary and permanent support for undergound openings. However, coarse aggregate shotcrete has been an expensive construction material. It has been confined in the main to difficult ground conditions where conventional methods of support have proved to be even slower and more expensive than shotcrete. There are two main factors influencing the productivity of shotcrete equipment. (1) Structural shotcrete as opposed to gunite requires 40% to 45% rock minus 3/4" in the mix design. The equipment to handle such aggregate content has been difficult to develop on a volume basis owing to the attritional nature of the material which causes intense wear problems on

Jan 1, 1974

By Michel David

Once a mineralized body has been delineated, drilled and estimated from surface samples, it often happens that before the final go-no-go decision is taken, an underground sampling program is decided, very often via a ramp which hopefully will be later used to extract the ore. The cost of such a program can be close to a million dollars. On other occasions, when a property changes hands and is reexamined maybe 20 years after the original drilling program, a "check sampling" program is carefully, designed to make "sure" that the old assays are "correct". One may fear poor sampling practice in old days, or deliberate highgrading by promoters. Again one may be talking of resampling cost which may be in the six-figures range. Other similar situations include the drilling of a few large diameter holes to ascertain the validity of a majority of small diameter drill holes, or auger drilling, or back-rimming. In uranium checking radiometric information is also a problem related to the above ones.

Jan 1, 1979

By Kenneth F. Lane

In most industries it is normal commercial policy to try to gear production to the market. In times of scarcity output is pushed to its maximum and in times of glut output is reduced. Because of the effects of supply and demand, these times correspond to times of high and low prices respectively so the policy results in maximising long run total profits. Stockpiling is often an integral part of the policy. Stocks are accumulated during depressed market conditions and sold off when demand revives. This further increases the long run total profits. However, such policies cause violent fluctuations in short term profitability and impose severe financial strains. Indeed planning and implementing the policies are a central management concern which is often critical to the success of the industry. The mining industry is no exception and, for many raw materials, trying to balance supply with demand is an international problem. Stockpiling and restricted production agreements are common elements of policy. But very little attention has been paid to the one additional control which is unique to the mining industry, namely, the cut off grade. This neglect is apparent at all levels from individual mines to national economies.

Jan 1, 1979

By Adolf J. Jonaitis

Outokumpu developed TankCell flotation cell technology beginning in 1990, following 35 years of successful flotation cell experience and application. In 1994, Outokumpu proved favorable operating success of 100-m3 (3,500-ft3) TankCells for porphyry copper and zinc flotation. In 1995, evaluation of a 150-m3 TankCell led to the successful application of these large cells in several operations. More than 350 TankCells of 100 m3 and larger in volume have been installed and are in operation. Key features of the Outokumpu TankCell design will be described. In addition, discussion of operating data from various metallic mineral flotation operations worldwide will be presented. Large flotation cell development continues today, with operating cell volumes of up to 160 m3 (5,500 ft3) in operation.

Jan 1, 1999

By W. K. Utt, C. C. Woodward, W. L. Howie, G. G. Miller

The process of roof drilling and bolting is one of the most dangerous jobs in underground mining. In the United States, roof drilling and bolting results in about 1,000 accidents with injuries each year. Researchers, from the Spokane Research Laboratory of the National Institute for Occupational Safety and Health are studying the feasibility of using a drill-monitoring system to estimate the strength of successive layers of rock and assess the integrity of a mine roof. Such a system would allow roof drill operators to be warned when a weak layer is being drilled. Using measurements taken during drilling, a neural network can classify mine roof strata in terms of relative strength. The concept has been proven in principle. This research project was undertaken to increase the safety of underground miners, especially those involved in roof bolting. The system should be applicable to the mobile drills now used in underground mines, and the system would likely find wider application as well.

Jan 1, 2003