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By S. Khoshjavan

In this investigation, the effects of different coal chemical properties were studied to estimate the coal Hardgrove Grindability Index (HGI) values index. An artificial neural network (ANN) method for 300 data-sets was used for evaluating the HGI values. Ten input parameters were used, and the outputs of the models were compared in order to select the best model for this study. A threelayer ANN was found to be optimum with architecture of five neurons in each of the first and second hidden layers, and one neuron in the output layer. The correlation coefficients (R2) for the training and test data were 0.962 and 0.82 respectively. Sensitivity analysis showed that volatile material, carbon, hydrogen, Btu, nitrogen, and fixed carbon (all on a dry basis) have the greatest effect on HGI, and moisture, oxygen (dry), ash (dry), and total sulphur (dry) the least effect. Keywords coal chemical properties, Hardgrove Grindability Index, artificial neural network, back-propagation neural network.

Jun 1, 2013

[Council for 1994/95 President J.A. Cruise President Elect D.A.J. Ross-Watt Vice Presidents Senior P.D.K. Robinson Junior Dr N.A. Barcza Immediate Past President Dr H. Scott-Russell Honorary Treasurer D.A.J. Ross-Watt Members of Council J.P.W. Bennie Dr L.A. Cramer Prof. R.J. Dippenaar J.R. Dixon A.A.B. Douglas F.M.G. Egerton Prof. R.H. Eric B.R. Fleetwood Dr M.A. Ford Dr R.V.R. Handfield-Jones P.J. Knottenbelt R.P. Mohring K.C. Owen M.H. Rogers K.A. van Gessel P.M.T. White]

Jan 1, 1995

By L. S. Bicalho, W. J. Rodrigues, P. M. A. Rollo, P. R. G. Brandão, W. C. da Silva

Quadrilátero Ferrífero is an important mineral province located in Minas Gerais state, responsible for a substantial amount of iron production in Brazil. Among the concentration methods for iron ore practised by the mining companies in this region, the most important is the reverse cationic flotation. Dolomite iron formations, with the presence of hematite, quartz and dolomite, occur in several areas of mining and, with the deepening of the deposits, this type of ore, with low iron content and more complex mineralogy occurs frequently. Carbonaceous minerals, mainly dolomite, present a technological challenge for the concentration of iron ore by flotation. In the present study, the concentration of iron ore with 6% of dolomite content was evaluated. Bench flotation trials indicated that conventional iron ore flotation is not selective to float dolomite, thus compromising the iron content in the final concentrate. Alternative flotation routes were evaluated, and a selective condition was reached to float both quartz and dolomite using the combination of the cationic collector Flotigam 16424 with an anionic collector Flotinor 16551. It was demonstrated that the flotation of dolomite was improved with the combined use of both collectors in the cleaner stage, and by a previous quartz flotation in the rougher stage. Zeta potential analysis indicated specific adsorption as the adsorption mechanism between Flotinor 16551 and dolomite, confirming the high selectivity observed in the bench flotation tests. Keywords: Flotation, iron ore, dolomite

Jan 1, 2020

By B. K. Loveday

A Colloquium on 'Control and Simulation in the Minerals Industry' was held at the Holiday Inn, Milner Park, on 20th September, 1984, in conjunction with the Electra Mining Exhibition. A total of 170 persons attended the very full morning programme, which began with an opening address by the President, The South African Institute of Mining and Metallurgy, Mr l.D. Austin. He outlined the reasons why computers were being used to an ever-increasing extent for control and simulation in the minerals industry. The computer was even used to check, among other things, the validity of the signals it was receiving by mass-balance calculations.

Jan 1, 1985

By N. B. Strydom, P. L. Jooste, H. F. Kotze, W. H. Van Der Walt

Note: A revised method of heat acclimatization by N. B. STRYDOM, W. H. VAN DER WALT, P. L. JOOSTE, and H. F. KOTZE INTRODUCTION Climatic-room acclimatization was introduced in the gold-mining industry in 1965 and was rapidly adopted by all mines because it reduced the number of days required for heat acclimatization from 12 to 8. The method has been adequately described in previous papers1, 2 but, briefly, requires four hours of heat exposure per day while the work rate is progessively increased from 35 W on Day 1 to 70 W on Days 7 and 8. Several attempts to shorten

Jan 6, 1976

By H. T. Kaiser, P. De Waal

The Alusaf aluminium smelter at Richards Bay by H. T. KAISER, B.Sc. (Pta), M.B.L. (Unisa) (Visitor) and P. DE WAAL, B.Sc., B.lng. (Mech.) (Stell.) (Visitor) A description is given of the aluminium smelter at Richards Bay, which operates on the Hall-Heroult electrolysis principle. The annual output of metal (average 99,7 per cent aluminium) is approximately 7S 000 tons. Since its commissioning in 1971, the plant has fulfilled South Africa's total demand for low-alloy rolling slabs, extrusion billets, remelt ingots, and electrical conductor rod. The plant layout allows for sufficient expansion of its capacity to meet longterm increases in demand.

Jan 7, 1977

This paper describes the operating practice and design features of an intensive-cyanidation plant at the East Gold Plant of Vaal Reefs Exploration and Mining Company Limited (V.R.E.M.). After the development oh cyanidation route for the treatment of gold-plant gravity concentrates by the Anglo American Research laboratories (A.A.R.L.), a full scale plant was commissioned at Western Holdings (Welkom Division) Gold Mine in March 1977, and the V.R.E.M. plant was commissioned in August 1981. Although the gravity-concentration route does not now enjoy the prominence of former times, in an existing conventional plant the intensive-cyanidation route can successfully replace mercury amalgamation.

Jan 1, 1984

By I. V. Samarasekera, E. B. Hawbolt

A review of recent work being conducted at the university of British Columbia on the modeling of the microstructural evolution during the hot rolling of steel is presented. A mathematical model of heat transfer was developed to describe the thermal field in a slab during rough and finish rolling. The model for rough rolling, discussed in this review, also simulates the growth of oxide scale on the slab surface. To quantify the heat transferred from the slab to the work rolls, instrumented samples of MSI3O4 L stainless steel, 0,05 per cent carbon steel, and 0,05 per cent carbon steel with 0,025 per cent

Jan 1, 1995

By A. L. Painting

A study of the end effects in specimen cores under compression tests, with a view to the elimination of these effects by A. L. PAINTING (Student) It is well known that a cylindrical rock specimen tested under uniaxial compression in conventional fashion is subject to end effects; that is, towards the end of the core, the stress and strain distribution becomes non-uniform. The experiment described illustrates such end effects with an aluminium core between steel platens. An attempt was then made to nullifythese effects by compressing the core between pads of mercury. The resulting stress and strain distribution was significantly more uniform, but a slight over-correction was introduced.

Jan 4, 1974

By B. Steyn

AngloGold Ashanti?s Obuasi Mine, in Ashanti Province, Ghana, operates a plant utilizing bacterial oxidation technology. The mineralization consists predominately of arsenopyrite with gold associated in the sulphides. The plant was commissioned in 1994, at that time was the largest BIOX® plant in the world, and has been operated by AngloGold Ashanti since 2004. The constraints identified in the plantwere the flotation capacity, BIOX® feed size and disruptions to the BIOX® process. This paper focuses on the practical steps that were followed in order to increase the recovery of the plant. The original plant design was based on a head grade of 10 g/t and an overall recovery of 86.5%. In 2007 the plant was operating at an overall recovery of 79.2% at a head grade of 5.6 g/t and this has improved to 80.6% at a head grade of 5.8 g/t during the last quarter of 2008. Additional improvement to 81.5% are expected by the end of April 2009. Improvements that have been implemented include: ?Replacement of the regrind mill ?Installation of additional float capacity ?Installation of a scavenging circuit ?Installation of a complete water treatment plant. In addition we have focused on the effect of the water circuit on the BIOX® process and the steps involved in correcting this problem. The water circuit was originally designed as an open circuit and through environmental considerations the circuit was closed towards the end of 2007. The bacteria in the BIOX® are particularly sensitive to cyanide and cannot tolerate levels above 0.05ppm (free cyanide), this required extensive modifications to the water circuit. The plant improvement project is ongoing and the current scope of work should be complete by the end of April 2009. Further research and development work is being planned, which includes a ?white rot bacteria? that can consume the preg-robbing carbon and oxidize the sulphide in a single pass.

Jan 1, 2009

By L. A. Abichequer

ROM grade variability is one of the most important factors influencing plant product recovery. Due to the influence of grade variability on mine profits, it is deemed important to guarantee a proper homogenization of the ore through a well-planned blending and homogenization pile system from which the ore is reclaimed at an acceptable grade fluctuation. This study tests geostatistical simulation efficiency in predicting in situ grade variability. The methodology is illustrated using a data-set from a large phosphate mine in central Brazil. Additionally, real data obtained at the mine site during January and February 2007 were used to derive the actual grades of each pile formed during this period. Each pile was formed by a selection of blocks within a dig line and these lines mined along the year 2007 were also made available. Given the real grades, it was possible to reconciliate and validate the results predicted by the proposed methodology. The main outcome of this study is the opportunity to check the geostatistical simulation as a tool to quantify the variability of the homogenization system.

Jan 1, 2009

By M. Thurston

This case study shows that for a set of lognormal data with a low coefficient of variation the semi-variogram of the logs has almost the same shape as the semi-variogram of the raw data. This means that the variogram of the logs, which is numerically more stable, can be used to krige the raw data. This technique is tested on samples from a sedimentary gold deposit and the results compared to those obtained from ordinary and simple lognormal kriging.

Jan 1, 1987

By Q. G. Reynolds

The dual-electrode direct current (DC) arc furnace uses two graphite electrodes, one connected as cathode and one as anode. Such an arrangement avoids some of the design difficulties associated with the anode hearth traditionally used in single-electrode and twin-cathode DC furnaces, but can introduce other design and operational difficulties including deflection of the arcs toward the furnace walls. Counter-intuitively, both arc jets in a dual-electrode furnace travel from the electrode down to the bath surface, despite carrying electric current in opposite directions?this is suggested in the theory of the governing equations of arc formation, and confirmed by experiments using high-speed photography. The dual-electrode arc system at small pilot-plant scale is studied using a transient magnetohydrodynamic model capable of predicting arc deflection and interaction from first principles, and the results are compared to the behaviour of twin-cathode systems at similar power. Finally, a simple arrangement of the furnace busbars, M configuration, is shown to provide some passive protection against arc deflection.

Jan 1, 2011

By J. Rowe

The attrition of activated carbon, and the loss of gold associated with it, is of significant economic importance to the operation of a CIP/CIL circuit The focus of this study was on activated carbon recovered from an elution circuit which was deemed too fine for reuse. Results of cyclosizer and laser particle size analysis identified that most of the carbon was contained in the larger size fraction suggesting formation by abrasion. Digestion and AAS analysis of the individual size fractions identified a disproportionate concentration of gold in the finer size fractions which was identified by scanning electron microscopy to be due to the presence of fine metallic gold formed as a result of the acid washing process. Attempts to strip the remaining gold using sodium hydroxide or sodium sulphide based solutions proved unsuccessful due to poor elution efficiencies and re adsorption of gold. Upgrading of the material by froth flotation was also investigated using various conventional flotation reagents which had some success in concentrating the free metallic gold, however, grade and/or recoveries were considered less than desirable. Greater success was ultimately found in the transfer of gold from the fine carbon material onto coarser virgin activated carbon using a caustic cyanide solution. Sodium sulphide, sodium chloride and ammonium chloride based solutions were also trialled but proved less successful owing to their inability to mobilise metallic gold or gold cyanide species. Repetition of the transfer process proved capable of stripping 97% of the gold contained on the carbon fines for abed volume ratio of 6:1.

Jan 1, 2009

2nd CONGRESS OF THE INTERNATIONAL SOCIETY FOR ROCK MECHANICS The 2nd Congress of the International Society for Rock Mechanics will be held in Belgrade, 21-26 September, 1970. The Congress will include: working sessions, study tours, receptions, excursions introduced in the working sessions and post-congress excursions and special programme for accompanying persons. Anyone interested in rock mechanics and its applicarion may take part in the 2nd Congress. Official languages of the Congress are: English, French and German. Simultaneous translation service will be provided during the Congress. All the correspondence concerning the 2nd Congress of the International Society for Rock Mechanics should be addressed to: Sekretarijat 2. kongresa Medjunarodnog drustva za mehaniku stena Institut za vodoprivredu "Jaroslav Cerni" Bulevar vojvode Misica 43, Postanski fah 530 Beograd - Jugoslavija NINTH INTERNATIONAL SYMPOSIUM TECHNIQUES FOR DECISION MAKING IN THE MINERAL INDUSTRY The Symposium which is to be held in Montreal during the week of June 14-19, 1970, follows the Computer Symposium held in Salt Lake City this year. The purpose of the Symposium is to define the role of decision making techniques within the mineral industry and to stimulate the development of specific applications. The subject of the Symposium-mathematics, operations research and computers as applied to the mineral industry-allows a complete picture of the mineral industry in its public policy, corporate, financial and technological environment to emerge. This is another of the series of symposia on this and related subjects started in the early 1960's at the University of Arizona. Sponsorship has included a number of Universities and the Society of Mining Engineers of the American Institute of Mining. This 1970 symposium is the first to be held outside of America, and is being sponsored by the Canadian Institute of Mining, McGill University and Ecole Polytechnique. A number of delegates from South Africa have participated in these symposia and several have already arranged to attend this symposium in Montreal. Enquiries should be directed to: Secretariat, The 9th International Symposium, Department of Mining Engineering, Ecole Polytechnique, P.O. Box 50l, Snowden, Montreal 248, Quebec, Canada. 24th INTERNATIONAL GEOLOGICAL CONGRESS This Congress is to be held in Montreal, Canada, from August 21 to 30, 1972. A very detailed and extensive programme has been proposed, and includes a number of excursions. Copies of the first circular are obtainable from: The Organizing Committee, 24th International Geological Congress, 601 Booth Street, Ottawa 4, Ontario, CANADA. SYMPOSIUM ON THE RECOVERY OF PYRITE The proceedings of the Symposium on the Recovery of Pyrite, held in Johannesburg on 12th to 13th June 1969 are now available. Copies may be ordered from the Secretary, S.A.I.M.M., P.O. Box 61019, Marshalltown, Transvaal at a cost of R10.00. Papers and addresses presented at the Symposium were: Opening Address by Mr J. K. E. Douglas (President). 'The world sulphur position,' by W. C. J. van Rensburg (Member). 'The South African sulphur position,' by D. L. Taylor (Member). 'The recovery of pyrite at Government Gold Mining Areas Limited,' by R. J. Westwood (Member), G. S. Stander (Affiliate) and H. R. Carlisle (Member). 'Recovery of pyrite concentrates from colliery-waste discards-A preliminary assessment,' by W. A. Gilbert (Visitor) and E. A. Nugent (Member). 'The role of pyrite in upgrading the uranium content of Witwatersrand conglomerate ores by means of the heavy-medium separation process,' by D. J. Tutt (Associate Member). 'Pyrite recovery by jigs at Durban Roodepoort Deep Limited,' by E. J. Dominy (Affiliate), F. Diamond (Affiliate) and A. D. Graham (Affiliate). 'The storage of pyrite concentrates,' by Joan C. Campkin (Visitor) and P. J. Lloyd (Member). 'The flotation plants of the Anglo- Transvaal Group,' by L. A. Bushell (Member). 'Pyrite flotation with amines and cyanidation of the products,' by E. H. D. Carman (Member). 'Gold recovery by cyanidation from mill products obtained after pyrite flotation,' by P. G. Mrkusic (Graduate), M. Sciarone (Visitor) and H. E. Simonsen (Visitor). 'The influence of sulphydral and cationic flotation reagents on cyanidation of native gold,' by K. G. Ashurst (Visitor) and W. P. Finkelstein (Member). 'Laboratory tests on the flotation of pyrite from Witwatersrand gold ores by cationic collector,' by J. Levin (Member), and M. L. Veitch (Visitor). Closing Address, by Dr R. E. Robinson (Director, National Institute for Metallurgy).

By W. J. Jordaan

The ability of soils to retain and hold cations is called the cation exchange capacity (CEC). Adsorbed cations, however, can be replaced by other cations through the process of cation exchange. Heavy mineral deposits contain a significant portion of slimes including the very fine clay minerals. In most circuits the slimes fraction hampers efficiency and has to be removed during early stages of the process. Being a nonvaluable process stream, the processing of the slimes is a costly exercise. In thickening applications it might be possible to manipulate the ability of clay minerals to retain and hold positively charged cations in order to optimize flocculation and therefore reduce flocculation costs. The CEC value of the slimes could be a measure of this possibility. To investigate this hypothesis, different slimes samples were characterized for size, chemical composition and clay minerals present. The CEC value of each sample was determined and explained in terms of the mineral phases present. Settling tests were conducted and an attempt was made to explain the CEC characteristics of the clay minerals in terms of settling rate. The scope of this investigation was to test the hypothesis and should not be seen as an in-depth study of the subject matter. A greater number of samples and detailed analyses to identify and quantify minerals and phases present would be required to investigate further the relationships between clay minerals in the deposit, CEC and settling rates. Location and geological setting Exxaro KZN Sands is mining a heavy minerals deposit at Hillendale mine located at Richards Bay, South Africa. The orebody consist of a dune some 8 km inland from the coast to the north of eSikhawini. A geological synopsis undertaken by Botha1 concluded that the Hillendale mining area represents a coastal dune sequence that accumulated north of the Tugela River. The northward movement of sediment by long shore drift currents result in a high sand budget on the beaches north of the river youth and is the dominant contributing factor to the accretion of the coastline and development of parallel dune systems along the coastal zone in this area. Beach swash zone processes and enrichment of the fine sand fraction occurs during wind transport off the beach by ascending parabolic dunes that form the coastal barrier dunes. This process results in heavy mineral concentration on the windward dune face and localized enrichment parallel to the dune forms. The aeolian sedimentary facies processes result in the primary concentration of higher grades in the upper silt-enriched reddish brown horizons of the profile. The synopsis by Botha1 further showed that an additional component of heavy mineral concentration can be ascribed to the post-depositional relative enrichment of heavy minerals due to weathering. Therefore, it is likely that the Hillendale orebody protolith was pedogenically weathered to form the homogeneous, silt-enriched, clayey reddish brown to dark red, palaeosol profile that grades downwards into yellowish brown, less clay-enriched sand. Slimes characterization Samples The Hillendale orebody was divided into geochemically discretized zones based on the concentration of ilmenite and other specific minerals and/or phases. Six composite samples were made up from exploration samples taken from Zone 9, Zone 11 and Zone 12. The red and orange horizons within these composite samples were separated and test samples were prepared to conduct test work and analyses. The test samples were submitted for preparation and analysis to characterize the slimes properties. Each test sample was deslimed at 45 µm representing the slimes fraction (-45 µm) and dried at 40°C. The -45 µm slimes samples were then split to conduct size analysis, chemical analysis, XRD and to determine the CEC. Size analysis The size distribution of the composite samples is shown in Table I. The size analysis shows that there is a difference in size distribution between the orange and red horizons of each zone. The orange horizons contain less 850 µ material as well as less slimes (-45 µm). The red horizons contain yore slimes (-45 µm). The size distribution of the slimes fraction (-45 µm) was determined using Malvern size analysis. The cumulative particle size distribution of the slimes is shown in Figure 1. The red horizons of the different zones show similar size distributions. The orange horizons show some differences. However, there is a difference in size distributions between the red and orange horizons.

Jan 1, 2007

By Sönke Schmachtel

Several possible physico-chemical properties of composite electrodes for oxygen evolution are presented to describe experimental data for which a mathematical model had been developed. On this basis, local electrical and electrochemical properties of a composite electrode were investigated with conductive atomic force microscopy (CAFM) and scanning electrochemical microscopy (SECM). It could be shown by CAFM measurement that the boundary between matrix and catalyst particles seemed to have special advantageous electrical properties. The SECM measurements showed the presence of mass transport phenomena with increased surface concentrations, whilst the thickness of the Nernst diffusion layer was very small. An intermediate was detected and assigned to be hydrogen peroxide. From all species involved in the oxygen evolution reaction (H2O2, H+ and O2), it was concluded that local active spots exist on the electrode on which hydrogen peroxide reacts to oxygen and protons. A two?step two-material process was suggested to explain the whole oxygen evolution mechanism.

Jan 1, 2008

By J. H. Viljoen, A. Heyns, J. F. Morrison, C. H. Wyndham, N. B. Strydom

Discussion M. J. Martinson* (Associate Member): This is another interesting paper in the series which the Human Sciences Laboratory is publishing on the physiological cost of the more strenuous manual tasks performed underground. As a mining engineer-albeit presently an academic one -this contributor is more concerned with the practical significance of the study in the field of stope cleaning than with physiological niceties, but before discussing some of the practical issues raised by the paper perhaps the authors would care to reply to lay comment on three physiological matters. Firstly, in two places the authors make statements to the effect that the maximum oxygen intake of 'average' (sic) Bantu mine workers is 3.0 l/min. What do the authors mean by 'average'? Maximum oxygen intake in the individual is probably some function of inter alia age, physical fitness, state of health, ambient partial pressure of oxygen, diurnal and/or seasonal changes in metabolism, and possibly cumulative exposure to dust and other occupational contaminants. Since maximum oxygen intake is apparently such an important quality in manual labourers we ought to have a clear picture of its distribution in the entire labour force, and also know precisely how the individual's quantum is affected by factors such as those mentioned above. Secondly, arising out of the same statements and ignoring the reservation implicit in the previous paragraph, is it correct to say that the 'average' Bantu mine worker has a maximum intake of 3.0 l/min? In the August 1966 issue of the South African Journal of Science four of the present co-authors reported the mean maximum oxygen intake of a random sample of 338 Bantu recruits of different tribes to be 2.63 l/min with a standard deviation of 0.542 l/min, and these figures were repeated in a paper published in the November 1968 issue of this Journal. Admittedly the mean maximum oxygen intake of the six subjects used in the present study was 3.05 l/min, but since they were selected on the grounds of previous shovelling experience they can hardly be regarded as being 'average' recruits. Thirdly, it seems to me that the authors are perhaps a little uncritical in their acceptance of the '50 per cent of maximum oxygen intake' level of activity for endurance work. I am not unmindful of the evidence upon which this level is based, but I suggest that the evidence is at best tenuous and that the whole topic of fatigue and 'optimum' levels of productivity under conditions of high muscular activity and considerable psychological stress is a lot more complicated than would appear from the authors' ready acceptance of the 50 per cent level. Under present working conditions the question is largely rhetorical because it would need an army of supervisors to ensure that all members of a typical gang work at 'optimum' levels throughout the shift, but if individual performance should ever become more readily determinable the issue might become crucial to management and malayisha alike. So much for physiological matters; now a few random thoughts on some wider, practical issues raised by the paper. In the paragraph headed Material the statement is made that 'The mixture (of fine, medium-sized and bigger rocks) was considered to be representative of an average underground rock sample'. Elsewhere in the report the authors specifically draw attention to the effect of particle size on the oxygen consumption of men shovelling graded material, and intuitively one imagines that the size distribution of the material being shovelled would be highly significant in a study such as this. Presumably the authors were forced to assess size distribution subjectively because of the lack of objective data on the subject, and possibly the necessity for this assumption highlights how little we know quantitatively about any of the variables in stope cleaning systems. In this connection it may be remarked that although the present study was largely designed to show how dip and stoping width effect energy expenditure in shovelling, no data are given-nor, probably, are they available-to show how the industry's stoping tonnage is distributed in terms of these two factors. It seems to me that if the mining industry seriously hopes to improve stope productivity it must start by measuring the basic variables in existing systems. Elaborating somewhat on the previous paragraph, there also seems to be a tremendous gap between the present study-and its predecessors-and the prospect of gainfully using the information so carefully garnered by the authors. It would be reassuring to hear from the authors that their work on the physiological aspects is being integrated in some master plan for increasing productivity of manual labour. This I fear is not the case, and if productivity has changed at all in recent years I would hazard a guess that the change has been brought about by random factors rather than by systematic engineering design. The Human Sciences Laboratory has worked extensively in stopes in the past, and possibly the time has come when it should widen the ambit of its operations to include engineering-type analyses of cleaning systems, with particular emphasis on the economics of rapid cleaning by manual labour. Perhaps experiments could be conducted with stakhanovite-type gangs consisting of men selected for their high maximum oxygen intake and superior motivation; these men might be offered special incentives in the shape of extra pay

Jan 10, 1969

By J. P. Beukes

The production of ferrochrome alloy from chromium bearing chromite ores is conducted at high temperature under highly reducing conditions. However, albeit completely unintended, it is impossible to completely exclude oxygen from all high temperature process steps, with the corresponding possibility arising for the generation of small amounts of Cr(VI) species. Certain Cr(VI) species are regarded as a carcinogenic, with specifically airborne exposure to these Cr(VI) species being associated with cancer of the respiratory system. With approximately three-quarters of the world?s viable chromite ore reserves located in South Africa, and annual ferrochrome production approaching almost half of total annual global output, aspects of Cr(VI) generation and control are of particular relevance and importance to the local industry, and naturally to the global industry at large. This paper seeks to examine theoretical and practical aspects associated with Cr(VI)generation (based largely on experience within the local South African industry, but considered to be generally encountered in the broader global industry context), together with mitigating measures that can be applied within the context of the production processes. From the discussions it is clear that significant improvements in various Cr(VI)-related aspects have been made by the South African ferrochrome industry. However, it is also evident that several areas of uncertainty still exist, which require further research in order to better quantify risks and enhance the efficacy of mitigating steps. Keywords Hexavalent chromium, Cr(VI), ferrochrome production, South Africa.

Jan 1, 2010

By B. Geelhoed

A generalization of Gy?s 1979 model for the variance of the fundamental sampling error has been proposed at WCSB2?2005 by Geelhoed. This generalized model can potentially lead to a better correspondence with actual sampling processes. However, a new parameter is required by the new model: ?the parameter for the dependent selection of particles?(Cij). It is important that this new parameter, which is at the basis of the new theory, is well understood in the sampling and blending community. In order to clarify the meaning of Cijand to prevent potential misinterpretation of Cij, we discuss the difference between Cij and an intuitively associated, but different, parameter: ?the parameter for the dependent selection of particle types?(Mij). In this contribution, the theoretical difference between both parameters is clarified. Simulations demonstrate that, numerically, the difference between Cij and Mij can be large. Some additional advantages of the approach which uses Cij are discussed: (i) the approach based on Cijis more general; (ii) in all cases where Mij is known, Cij can be determined as well, while the reverse is not true; (iii) an equation already exists that relates the sample variance to the value of Cij.

Jan 1, 2009