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By P. B. Lorenz

Wettability measurements and laboratory waterflood tests were compared under a wide variety of conditions. Experiments were conducted with synthetic and natural crude oils, treated and untreated outcrop and oilfield sandstone cores, and synthetic brines with and without caustic, detergent, or phosphate additives. Measurements were made on equilibrated and unequilibrated systems at 77° and 150° F. Wettability was evaluated by the Bureau of Mines method from capillary pressure curves determined with a centrifuge. The waterflood data were fitted by empirical curves; the parameters of the curves characterize primary and subordinate production and also give the ultimate oil recovery. Results showed that wettability measurements at 77° F were useful predictors of recovery efficiency in waterflood tests run at both temperatures. Oil recovery in the early stages of waterflooding increased with increasing water wettability; however, the ultimate recovery was highest at a slightly oil-wet condition. The oil displaced at highest speed in the centrifuge was correlated with ultimate recovery in waterflood tests. Chemical additives to the brine sometimes lowered wettability and also sometimes improved waterflood recovery, but wettability and recovery were not correlated with additives present. The effect of additives on recovery in waterflooding was best seen in water-oil ratio curves.

Jan 1, 1974

By W. E. Robinson

Oil-shale samples selected from a core of the Green River Basin (Wyoming) were studied to ascertain differences in the composition and/or chemical structure of the organic material in the samples relative to stratigraphic position within the Green River Formation. This involved a systematic study of the soluble organic material and the insoluble kerogen present in the samples. Emphasis was placed upon the distribution of the alkanes (normal and isoprenoid compounds) in the soluble extract and upon the aromaticity of the kerogen. In general, it was concluded that significant differences exist in the chemical structure of the oil-shale organic material from various strata within the Green River Formation of Wyoming. Most of the compositional and structural changes were not related to burial depth but were related to source material variations, environmental differences, or other factors.

By J. B. Gayle

Numerous investigators have studied the addition of inert4 substances to coking blends. Generally, the results have yielded trends applicable only to the particular coals and inerts studied. Recently, somewhat more general results were obtained for cokes produced from blends containing added inerts, using the sole-heated oven. The present investigation represents an extension of this work to include a wider range of inerts and to determine the applicability of the various conclusions to cokes produced with the Tuscaloosa oven. The results indicated that an increase in dry-coal charge density of 1 pound per cubic foot (p.c.f.) caused a corresponding change in the hardness (1/4-inch tumbler index) of Tuscaloosa oven cokes of 0.9 percentage points. This value compares favorably with the value of 0.7 determined previously for the sole-heated oven and Bureau of Mines-American Gas Association (BM-AGA) retort.

Jan 1, 1961

By W. K. Sawyer

In this Bureau of Mines investigation, one-and two-dimensional gas reservoir simulators were combined in such a manner that pressure distributions both in an induced vertical fracture and in the surrounding formation, could be determined as a function of time for any specified well production rate. The technique used consisted basically of the alternate ust of one-and two-dimensional algorithms for obtaining new pressure distributions in the fracture and in the reservoir, respectively. The pressures at adjacent reservoir and fracture nodes were used to calculate flow rates from the formation into the fracture, which provided source terms for both algorithms. The combination model developed provides the only known means of simultaneously simulating transient gas flow in a vertical fracture and the surrounding formation. Thus, the technique developed would be useful in locating wells in a gas storage field in that the effects of both fracture length and conductivity could be considered prior to drilling and fracturing operations. In addition, it will be helpful in analyzing pressure drawdown tests in a vertically fractured gas well since the entire test can be readily simulated for a wide range of reservoir and fracture properties.

Jan 1, 1974

By James H. Russell

Several solid sorbents were compared for their effectiveness in removing sulfur dioxide from flue gases. The materials were tested for the rate of sorption and capacity at about 300° C, and rate of regeneration around 700° C in thin beds and in 4-inch-diameter fluidized beds. Rates of material loss were also estimated. The sorbents tested included three samples of alkalized alumina, two samples of sodium carbonate-impregnated alumina, and one proprietary sample of porous silica impregnated with copper and iron compounds. The results showed that all the alkalized aluminas had good sorption capacities and rates, required high temperature regeneration, and suffered excessive material loss; the sodium carbonate-impregnated aluminas (1) had high sorption rates but barely adequate capacities, (2) required high temperature regeneration, and (3) suffered excessive material losses; and the copper-iron impregnated silica suffered only slight material loss and could be regenerated at a relatively low temperature, but the sorption rate and capacity were too small. None of the sorbents met all the arbitrary performance criteria that follow: sorption rate constant of 1 min-1, sorption capacity of 0.1 g sulfur per g sorbent, regeneration rate constant of about 0.075 min-1 at a reasonable temperature, less than 0.07 pct per hour material loss during operation, and a chemical life of 500 cycles.

Jan 1, 1971

By Thomas J. Peters

This report is part of the U.S. Bureau of Mines Idaho Land Assesment Program to study the mineral resources of priority roadless areas in Idaho. The results of these mineral inventories provide minerals information needed to make wise decisions regarding future land management practices, and to ensure a dependable supply of minerals at a reasonable cost. The 16,300-acre Lionhead area, studied in 1991, lies along the Montana border north of Henrys lake, 10 mi west of West Yellowstone, Montana. The study area includes much of the rugged Henrys Lake Mountains, and is largely covered with conifer forest. Several peaks are over 10,000 ft in elevation. The Lionhead area has been proposed for Wilderness. No mineral resources were identified within or near the Lionhead study area. Five prospects occur in, or within 1 mi of the area: these include 1) an intermittently used road gravel pit, 2) the Thimbleberry lateritic iron prospect, of geologic and historic interest only, 3) the Tick Heaven talc prospect, 4) the Dry Fork garnet prospect, and 5) the lynx prospect, which appears to be of historic interest only. Talc is seen only as float at the Tick Heaven prospect, but the geology is permissive of talc resources at depth. The garnet prospect, and nearby similar alluvial terrane, mainly outside the study area, appears to be the most likely setting to contain mineable resources. Examined workings include four trenches and pits in rock and one gravel pit.

Jan 1, 1992

Enhance hydraulic fragmentation technology by developing alternative grout sealing methods. Traditional grout scaling methods rely on chemical adhesion and require large contact areas to restrict high-pressure fluids. Fluid injection into rock requires economical and effective seals. With economical and effective seals, rock is easily fractured in tension by high-pressure fluid injection (fig. 1). Approach An innovative grouting technique was developed and tested by the Bureau. Slowly hydrating expanding chemicals are placed within a borehole and around a section of high-pressure tubing. Testing was conducted using 9/16-inch-OD smooth-walled injection tubes in 1.5-inch-ID holes. Seal lengths weir less than 10 inches and curing times were less than 24 hours.

Jan 1, 1989

By Victor E. Kral

"INTRODUCTION The Segerstorm-Heizer property was examined by engineers 3/ of the Bureau of Mines in May and June 1942 and Mach 1943. As a result of these examination, the Nevada State Department of Highways,constructed 9.3 miles of graveled road under the mine access-road program. A magnetometer survey was made by the Geophysical Division 4/ in October 1943, and as a result the Mining Branch set up and conducted a core-drilling,project. Work on the deposit started May 24, 1944, and was suspended on July 31, 1944, but was resumed on December 4, 1944 and continued until completion on March 27, 1945.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as it, primary objective the more effective resource to the end that they make the greatest possible contribution to national security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploration work, and prepares the final report. The Metallurgical Branch, R. G. Kinickerbocker, chief analyses samples and performs beneficiation tests."

Mar 1, 1947

By M. I. Copeland

The investigation of the zirconium-gadolinium equilibrium diagram was part of a program to investigate rare:earth alloys for use as nuclear reactor control materials. Investigation of the zirconium-gadolinium equilibrium diagram revealed a eutectic system with limited terminal solubilities and one peritectoid reaction. The eutectic composition occurs at about 82 percent gadolinium, and the eutectic isotherm, which occurs at 1,220 ±5° C., extends from about 12 to 99+ percent gadolinium. A peritectoid isotherm occurs at 890 ±5° C. and extends from about 2 to 99+ percent gadolinium. The solubility of gadolinium in beta zirconium decreases from about 12 percent at 1,220 ±5° C. to about 2 percent at 890 ±5° C. The solubility of gadolinium in alpha zirconium decreases from approximately 5 percent at 890 ±5° C. to between 2 and 3 percent at 600° C. Vary little solubility of zirconium in gadolinium was indicated. An allotropic transformation of gadolinium was observed at 1,260 ±5° C. A change of the gadolinium transformation temperature on alloying with zirconium was not observed.

Jan 1, 1961

By Bruce T. Olenchuk, Wils L. Cooley

Electrical grounding is essential for the safe operation of power systems. A low-impedance path to ground is necessary to prevent the possibility of dangerously high potentials in human work areas. If for any reason this ground connection becomes faulty, a serious hazard may exist. One reason for faulty ground connections is ground bed corrosion. Corrosion of electrical ground rods has plagued the power industry and appeared in coal mine power systems. This paper will investigate ground rod corrosion, its cause, and possible solutions. Included is an evaluation of various ground rods for their ability to resist corrosion under stray current conditions. -The first known study of X-it3 Rod Corrosion is also presented.

Jan 1, 1979

By Forrest T. Moyer

Injury experience in the mineral mining and processing industries during 1968 was slightly improved in the nonfatal-injury record but worse in the fatality record. The resulting frequency rate of all injuries was slightly better, whereas the injury-severity rate retrogressed appreciably from the figure for 1967. Overall operating activity, as measured by man-hours of worktime, was slightly higher in 1968. However, there were several major segments of the mineral industries in which activity was lower owing to reduced demand for mineral products and to several major work stoppages. These statistics comprise the injury and work experience of all personnel engaged in production, exploration, development, maintenance, repair, and force-account construction work, including supervisory and technical personnel, and working partners and owners at mineral-producing and mineral-processing establishments in the United States. Data concerning officeworkers are excluded except for the oil and gas industry for which such information is not separable. All injury rates and totals are calculated from data before rounding. The data for 1968 are preliminary except for the anthracite, coke, petroleum and natural gas, native asphalt, peat, and slag industries, which are final. The figures represent full coverage for all industries except oil and gas for which coverage is not complete, particularly with respect to small companies.

Jan 1, 1970

By R. V. Ramani, R. Bhaskar

"One of the primary means of control of health hazards from respirable contaminants in mine atmospheres is through design and operation of mines to meet mine health and safety regulations and recommended practices. A U.S. National Academy of Sciences study concluded that for significant progress in coal mine dust control, research should be directed more toward obtaining fundamental understanding of the origin, transport and characteristics of respirable coal mine dust. Theoretical and experimental studies on transport of dust · in mine airways, particularly coordinated efforts to validate theory with practice, are scarce. Some empirical models, developed on the basis of experimental data, are available but these models cannot be applied to new conditions. The purpose of this paper is to present the results of theoretical and experimental studies on the transport and deposition of dust in mine airways. This study is a part of an ongoing research project in the Generic Mineral Technology Center on Respirable Dust.In the paper, the assumptions of the modeling phase of the project and the development of a convectiondiffusion equation for dust transport in mine airways are outlined. The important aspect of the modeling effort is the capture of the deposition phenomenon. The experiments performed under controlled conditions in a typical mine airway, as well as under normal mine operating conditions, are discussed. The comparison of the model predictions with experimental results are made to identify critical areas of agreements and deviations. The implications of the findings and areas for further research and development are presented."

Jan 1, 1990

By A. Visnapuu

The Bureau of Mines investigated carbonyl processing techniques for the recovery of the critical metals Ni, Co, Mn, and Cr from domestic primary and secondary sources. In most cases, the source materials require reductive precarbonylation treatment to metallize the contained Fe, Ni, and Co compounds to render them reactive with CO. The critical metals were recovered either by direct conversion to the respective carbonyls or as upgraded products by carbonyl removal of an undesirable metal. Best metal-to-metal carbonyl conversion was under CO pressure, from 80 atm upward, and at 1400 C. Carbonylation was accelerated by the addition of HzS in small quantities. CO pressure, temperature, promoter and pretreatment trends, and other factors enhancing metal carbonyl formation are presented.

Jan 1, 1987

By Robert J. Willard

This chapter includes tables for 1982 that were not available in time for publication of the 1982 Minerals Yearbook, but does not include corresponding tables for 1983. The value of raw nonfuel minerals produced in the United States during 1988 was estimated at $21.1 billion, an increase of $1.5 billion over the value for 1982. This is a reversal of last year's downturn in value from that of 1981, which was the only decrease noted since 1971; hence, an overall trend of increasing values has been maintained for 12 years, except for 1982. Although the reversal is a basis for cautious economic optimism, it is tempered by continued problems in the domestic mining industry: inadequate funds for capital investment and competition with other countries that have lower production costs. Output of metal commodities in 1983 increased for 8 out of 21 metals, and metal values, in general, increased for 9 of the metals. Output of nonmetal commodities was mixed, with 24 nonmetals showing increases, 20 showing decreases, and 2 unchanged. Nonmetal values were also mixed in 1982: 25 showed increases, 20 declined, and 1 was unchanged. Improvements in the international metals market have not been forthcoming because of the continued depressed prices for major metals. Governments in foreign producing countries have been concerned with maintaining employment and continuing foreign exchange flows through mineral exports. Consequently, the excess of supply in the face of shrinking demand brought downward pressure on metal prices in general, except for the precious metals. On the domestic front, this situation means U.S. mining companies must become even more cost efficient. The major trend in the mining industry in 1983 was to cut costs further, reduce or stabilize total production, reduce outlays for major capital equipment, modify existing systems and equipment, and streamline operations. Most of the accomplishments reported herein reflect this trend.

Jan 1, 1984

By S. J. Page, J. A. Organiscak

Dust surveys were conducted around small truck-mounted rock drills operating at surface coal mines to assess their airborne respirable dust generation and in-service dust control methods. Of four out of seven drills sampled, respirable dust concentrations measured around the drill deck ranged from 8.68 to 95.15 mg/m with3concentrations ranging from 1.37 to 2.69 mg/m at distances 12.2 to 30.5 m downwind of these drills. The other3drills had noticeably lower respirable dust concentrations measured around the drill deck at or below 1.30 mg/m.3Rotoclone-type dry dust collectors were commonly used with dust being emitted from around the drill deck shroud, collector exhaust, and collector fines dumping. Wind speed and direction was also a factor in the dust concentrations measured on the bench. Dust control modifications were made to three rock drills to reduce their airborne dust emissions. Dust controls tested included water injection into the Rotoclone exhaust, Rotoclone exhaust extension, improved sealing of drilling deck shroud, shrouding the Rotoclone hopper dump process, and wet drilling. These control techniques showed noticeable improvement in dust concentrations measured around the drills. Finally, repositioning the drill operator showed that operator dust exposure can be improved by avoiding the dust cloud around the drill.

Jan 1, 1995

By Thomas A. Gray, Lynn M. Crayne, Michael A. Trevits, Phil Glogowski

Mine seals can be remotely constructed in underground coal mines, through vertical boreholes, when direct access to a fire is impossible or considered to be too dangerous. This method has great merit because boreholes can be drilled to specific mine areas and seals can be positioned close to a fire zone. The technology however, can be largely ineffective if the constructed seals do not provide effective barriers to airflow or cannot be used to impound water and other inert materials. Unfortunately, no viable alternatives exist to sealing the entire mine at the ground surface. Full-scale remote mine seal construction research is being conducted at the National Institute for Occupational Safety and Health’s (NIOSH) Lake Lynn Laboratory (LLL). Under this effort, Howard Concrete Pumping Company and GAI Consultants, Inc. have joined forces to evaluate a potentially significant improvement to the current state-of-the-art. This paper will cover development of novel technology for remote mine seal construction, evaluation of the materials used, construction practice, and follow-up testing.

Hang ventilating air curtains so that they can be installed, moved, opened and closed more easily than curtains that are spadded or nailed in place. Approach Low-leakage plastic curtains fitted with grommets along the top were threaded onto a steel cable which is suspended from roof bolt plates. The system was tested in two mines. How It Works The curtains are threaded onto a steel cable which is suspended from roof bolt plates by S-shaped hooks. See Figure 1. The outby end of the cable is reeled off a hand operated winch; the inby end of the cable is anchored to a roof bolt plate by means of a cable grip and an S-shaped hook. To install the curtains the following procedure is used. First, the winch is located at least 5 feet outby the last open cross-cut. The base of the winch can be secured to the mine roof with short roof bolts, only about a foot long.

Jan 1, 1978

By A. N. Styler

As part of its water-jet assisted rock cutting research, the Bureau of Mines has initiated a study into the mechanism of rock fragmentation by water-jet-assisted mechanical tools. The objective of this research is to increase coal extraction efficiency by seeking an improved understanding of the synergistic relationship between mechanical cutters and water jets, enabling the design of more effective cutterheads. Rock chips collected during laboratory traverse speed jet-assisted cutting tests were analyzed with respect to the size distribution of the chips and the forces measured during cutting. As the water-jet pressure was increased, the size distribution of the product became coarser with V-face type cutting tools producing less fine material than conical cutting tools. Fracture mechanics theory accounted for less than 10 pet of the energy consumed during fragmentation of the rock. The energy consumed by processes other than rock breakage decreased with the use of water jets and increasing advance rate.

Jan 1, 1987

By H. E. Peterson

A study was undertaken by the Bureau of Mines to develop a simple, reliable test for field detection of selenium in rocks and soils. Two methods are described for qualitative detection of selenium, dependent upon its form of occurrence and the presence of interfering constituents in the sample. Both methods involve fusion of the sample in a test tube to form elemental selenium that will volatilize and condense as a red deposit on the cooler upper portion of the test tube. The methods are sensitive to 10 parts per million, (p.p.m.) equivalent to 0.001 percent, and can be made semiquantitative by using suitable standard samples. INTRODUCTION Although selenium is widely distributed in the United States, the known deposits are either so small or so low grade that they cannot be processed economically for selenium alone-4/ At present, commercial production is a byproduct of the smelting and refining of base-metal ores, particularly copper.5/ About 0.75 pound of selenium is recovered per ton of electrolytic copper, and small amounts are recovered by special treatment of assorted smelter dusts and fume products. Since selenium is a strategic metal in short supply, new sources are being sought by both Government and private interests.

Jan 1, 1957

By Clarence O. Babcock

This Bureau of Mines report presents the initial development of a two-dimensional method of analysis for inclusions in plates in which the deformed shape of an open hole and the separate structural behavior of inclusion and plate with hole are used to obtain the stresses and strains in the inclusion only. In this report the solution for a circular inclusion is presented because a direct verification of the results with previous solutions was possible. The numerical results were in exact agreement with those obtained with the equations of Sezawa and Donnell. The equations developed are less complex than those of Sezawa and more general, for a circular inclusion, than those of Donnell. Stresses and strains in the inclusion are in terms of the elastic constants of the inclusion and the plate and the biaxial stress field applied far away. The elastic constants can be all different. An important conclusion from this work is that a difference in Poisson's ratios between inclusion and plate may be as important as a difference in Young's moduli between inclusion and plate in producing the inclusion effect. Many problems in mining and rock mechanics can be treated as inclusion problems. The understanding of inclusion behavior on a physical basis should provide the solutions to some of these problems.

Jan 1, 1974