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By W. D. Maier, H. V. Eales

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. A lithological and geochemical study revealed significant lateral variation of the interval over 170 km of strike, from about 30 m at the Union Section to 220 m near Brits. The cumulates also become more evolved and leucocratic with distance from the Union Section both towards the NE (Amandelbult) and SE (Impala, Rustenburg and Brits). It is inferred that the persistent heat flux from a putative major feeder zone near the Union Section impaired deposition of felsic cumulates in the vicinity, delaying crystallisation of successive phases in parts of the chamber near the feeder. New influxes were therefore deposited on a footwall of varying thickness and lithology in response to different degrees of crystallisation and accumulation along strike. The development of cyclic units of chromitite, harzburgite, pyroxenite, norite and anorthosite was interrupted at different stages in different parts of the chamber

Apr 1, 1994

By T. C. Alex, S Srikanth, Premchand

It has been suggested that reduction of the iron and manganese phases as far as FeO and MnO is preferred for the complete liberation and selective reduction of the copper, nickel and cobalt oxides in manganese nodules. The oxygen partial pressure/temperature regime suitable for this purpose has been delineated. Free-energy minimisation and thermogravimetric results indicate that the requisite conditions can be achieved if more than 10% of neutral oil is used at temperatures greater than 923 degrees C. Neutral oil content, temperature and roasting time have been optimised to maximise leaching recoveries of Cu, Ni and Co: up to 96% of Cu and Ni and up to 85% of Co can be recovered if 15% of neutral oil is used as a reductant at 973 K for 90 min

Jun 21, 1905

By G. G. Barbante

Anode slimes produced during copper electrorefining are a valuable source of silver, gold, selenium and tellurium. The conventional pyrometallurgical process for treating slimes involves preliminary leaching in sulphuric acid followed by smelting in a reverberatory furnace with fluxes, but it is slow and has many recycle streams. The chemistry of the phases and the reactions that occur in slimes smelting are poorly understood and and this prevents major improvements to the process. Laboratory-scale experiments were conducted using unleached slimes, with and without the addition of fluxes and under neutral, oxidising and reducing conditions. Results show that selenium is readily removed as gaseous selenium dioxide and that molten Cu-Ag-Se-O phases form when fluxes are added. Oxidation-refining of these phases by air injection and flux addition can result in the formation of silver suitable for further electrorefining

Aug 1, 1995

By A. P. Gize, J. F. W. Bowles, D. J. Vaughan, S. J. Norris

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. Geological evidence from tropical laterites indicates clearly that platinum group metals are taken into solution and precipitated to form grains larger than those in the source rocks. Platinum and palladium move differentially in the surface environment, with Pt partitioning into soils and eluvial or alluvial deposits while Pd remains more mobile in natural waters. Natural organic acids, particularly humic acid, can interact with platinum-group elements and concentrate them even in areas where their content in rocks is very low. Experimental work has confirmed that Pt and Pd can be taken into solution by humic acid at room temperature and in geologically short time-spans. Solubility and deposition may be controlled by physicochemical conditions, reaction kinetics or an adsorption effect, or there may be two competing reactions, solubilisation assisted by organic matter and a kinetically slower metal precipitation

Apr 1, 1994

By V. A. Melezhik, P. K. Skufin, L. P. Nilsson

these factors into account. Theoretical and

Aug 1, 1994

By T. Lenarcic, R. Svrkota, J. M. McNeal, E. Prohic, S. Pirc

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Surface drainage samples, the usual media employed in mapping national territories, cannot be used for the geochemical mapping of carbonate terrains because there is no regular surface-drainage pattern on karst. Suitable sampling media have been studied in Yugoslavia, one-third of which consists of karst terrain. Sampling designs for the work were based on analysis of variance techniques. During initial investigations of various sampling materials in NW Yugoslavia sediment and aquatic moss from karst springs, along with soil, were established as the most appropriate media. Modified sampling procedures were then carefully applied along the entire Yugoslav karst belt, which includes terrains of contrasting topography, climate, pedology and vegetation. The studies indicate that climate and relief do not systematically influence the geochemical composition of soil. Regional and local variability was assessed for 21 chemical elements and the feasibility of producing stable regional geochemical maps was determined for a number of elements on the basis of sampling aquatic moss and sediment from karst springs and soil

Jul 1, 1991

By N. B. J. Kieser

Paper presented at the IAGOD international symposium on mineralization related to mafic and ultramafic rocks, held in Orleans, France, 1-3 September 1993. Platinum-group minerals (PGM) in the enriched zone at Dust Mountain occur in two separate parageneses, the first representing primary magmatic PGM and the second primary magmatic PGM that have been reduced to alloys during serpentinisation. Minerals in the first group were unaffected by hydrothermal alteration on account of their textural setting or stable chemical composition. Despite substantial alteration of the serpentinised assemblage, most evidence points to the dominant role of primary magmatic processes in determining PGM occurrence. Several base metals have nevertheless been introduced hydrothermally. With respect to surficial dispersion the single most important paragenetic factor was the reduction of sulphides to alloys, rendering them more susceptible to mechanical erosion and less so to chemical leaching. The different textural setting of Pd-group and Ir-group phases results in different dispersion characteristics, with major implications for stream sediment sampling

Apr 1, 1994

The reduction of zinc from slags by a molten, carbon-saturated bath was examined in a laboratory study under conditions of continuous slag feeding. The results show that it is possible to reduce the bulk of the zinc from the slag before there is a net reduction of iron. However, the recovery of zinc was not as high as in batch tests performed in an earlier study. Lead in the slag was reduced simultaneously with the zinc to very low levels and was volatilised. Copper in the slag was reduced and dissolved in the alloy. An attempt was made to identify potentially commercial ways of treating zinc slags using an iron bath. The approaches that appear to have the greatest potential are reduction in a batch process using electrical heating and reduction in a continuous process with co- or countercurrent flow of the slag and alloy. In the latter the alloy would be prepared in a separate furnace before being contacted with the slag. The purpose of this would be to superheat and carburise the alloy so that no additional heat or reductant would have to be supplied in the slag-alloy reactor

Jul 1, 1991

By S. P. Godby, S. P. Sharples

Wind-tunnel tests were carried out of the conditions under which nuisance dust particles (100-1 000 micrometres) become entrained by wind. A laser entrainment monitoring system (LEMS) was used, and was found to provide an accurate means of assessing nuisance dust emissions from a surface. Accurate determination of the threshold entrainment velocity of dusts using the LEMS gives a baseline against which the performance of dust control techniques can be evaluated. Minerals tested included coal, petroleum coke, limestone, sand and pulverised fuel ash. Pilot field trials of a portable wind tunnel equipped with the LEMS have been successfully completed, providing a means of validating laboratory results in the field

Jun 19, 1905

By R. Patel, D. R. Taylor, P. M. Varley

In-situ measurements of ground stress were made from surface boreholes, using overcoring and hydrofracturing techniques, to obtain data for the detailed design of the underground works at Pergau. Unexpectedly low stresses were measured and appeared to correlate with apparent hydrofracturing observed during permeability testing. The low values of the minor principal stress had a major impact on design, particularly of the lining for the pressure tunnel and shaft. Additional hydrofracture tests were made underground during construction of the low- and high-pressure headrace tunnels and the pressure shaft, to define the vertical reduction in the minor principal stress with overburden. These data were then used to locate and design the steel and reinforced concrete linings

Jun 19, 1905

By S. C. Tennant, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Immobile-element lithogeochemistry is providing a detailed chemostratigraphy of the submarine Ordo-Silurian volcano-sedimentary sequence. Primary lithologies and magmatic affinities of the sericitised and silicified volcanics are determined from binary plots of Nb, Zr, Y, TiO2 and Al2O3, while mass-change calculations using immobile-element anchors can identify and quantify zones of significant hydrothermal alteration. Stratiform polymetallic mineralisation at the western margin of Parys Mountain, around the Penymynydd fault zone, has been shown to have a distinct hanging-wall and footwall stratigraphy. These ore zones are probably part of a homoclinal, north-younging volcano-sedimentary sequence. The apparent stratigraphic complexity results from primary lithofacies variations and pervasive alteration, with the modifying role of the Caledonian orogeny much less than previously suggested

Jun 19, 1905

By M. T. Styles, E. Condliffe, R. C. Leake, R. J. Chapman, D. J. Bland

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Quantitative point analysis and microchemical mapping identified 52 different types of mineral in inclusions, usually ranging in size from 5 to less than 1 micrometre, inherited from source bedrock. A combination of grain chemistry, heterogeneity and inclusions provides a grain signature reflecting the type and history of source mineralisation. Several grains from an alluvial site are needed, to allow for bedrock variation and the presence of inclusions in only 10-20% of grains. A total of 1 530 grains obtained from 30 localities in Scotland were of ten types, two of them minor variants. Two types in the Highlands may be related to centres of Caledonian igneous activity, but the most widespread is likely to have been of deep-seated origin and structurally controlled. Gold in the Ochil Hills is probably from a source associated with Devonian andesitic activity. In the Southern Uplands, grain types reflect two separate episodes of mesothermal lode gold mineralisation and relationships with Permian red beds/mafic volcanics and with Tertiary dykes

Jun 19, 1905

By T. B. Colman

Paper presented at the MEP '89 conference held in Madrid, 13-15 November 1989. Britain has sustained an important metalliferous mining industry over many centuries. Recently, new geological concepts and exploration techniques have indicated that there is considerable potential for the discovery of a variety of deposit styles, often in previously neglected areas. The recent discoveries at Aberfeldy (Ba-Zn-Pb), Gairloch (Cu-Zn) and Cononish (Au-Ag)in Scotland and Curraghinalt (Au-Ag) and Lack (Au-Ag-Pb) in Northern Ireland are illustrations of this potential. Some of the prospective areas for future exploration are described and an indication is given of the legislative framework within which mineral exploration and development are carried out

Jan 1, 1991

By P. Mousset-Jones, G. Danko

Variations of the temperature and steam/moisture content of the air with distance and time are modelled for a single airway. The input for the simulation is an air temperature that varies with time, together with the moisture/steam content that results, for example, from a fire with a given distribution of heat and of fume concentrations at the beginning of the airway. The transport of heat and moisture to the surface of the wallrock is assumed to be simultaneous. Such multiphase convection may result in evaporation from the moist wall close to the fire and recondensation downstream. The modelling of this non-linear effect is a unique feature of the new simulation. A new analytical solution is used to calculate the conduction of transient heat within the rock mantle, which, in the event of a fire, is typically a short-term process. This allows for an arbitrary variation of surface temperature with time - unlike that permitted by the age function solution, which is limited to stepped temperature changes. An iterative numerical scheme that has recently been developed to simulate mine climate is used to calculate the coupled transient heat conduction and multiphase surface heat transport in successive length increments along the airway. To demonstrate the simulation procedure a numerical example is presented in which a fire with a given distribution of heat and fume concentrations with time is located at the beginning of an airway

May 1, 1991

By V. A. Melezhik, A. H. Green, L. N. Grinenko

Finally, a theoretical model is constructed that takes

Aug 1, 1994

Errors in ore reserve estimation can occur during drilling and sampling, sample preparation and analysis, geological logging and modelling, database construction, statistical or geostatistical evaluation, selection of economic parameters, selection of ore reserve method and assessment of mining constraints. Core sample recovery can be a major source of error, and it is proposed that the modelling of grade, metal accumulation and thickness should be accompanied by the modelling of core recovery (or core loss) so that for each ore block a weighted block recovery factor is obtained. This gives a good indicator of the reliability of a reserve estimate. It is suggested that a resource reliability rating (RRR) system be established to quantify what is meant by geological assurance and to combine this with an estimate of the precision of estimation as gained by geostatistical analysis. Proven and probable minable reserves would be those with an RRR better than 50% and a precision of estimation better than 20%

Dec 1, 1996

By M. Feely, W. G. O'Keefe, C. O'Reilly, M. P. Holdstock

A petrographic and microthermometric study of fluid inclusions in the Kentstown Granite, crosscutting quartz (VI) and calcite+quartz (V 2) veins in the granite and calcite+quartz (V 2) veins in the overlying sediments was performed on samples taken from the borehole. Comparisons of the type 1, type 2 and type 3 fluid inclusion populations recorded in the present study with those from other Irish Caledonian granites strongly suggest a similar fluid evolutionary history. Furthermore, the low-temperature CaC12-rich brines (type 5) of this study, which must be syn- to post-Lower Carboniferous in age, have correlatives both in Irish Caledonian granites and in the Lower Carboniferous base-metal deposits of the Irish midlands

Jun 19, 1905

By L. E. Mordberg, E. N. Nesterova

Geochemical studies of the bauxite deposits show that the primary composition is gibbsitic. Some trace elements were relatively mobile during bauxite formation with the content of Th, U and Zr increasing and that of Rb, Ni and Co decreasing. Y and Pb were relatively immobile during lateritisation; their contents and ratios were inherited from different types of underlying rocks. The supply of Ni and Co took place at the diagenetic or epigenetic stages; their ultimate source was the crystalline basement in the region. The studies support the view that the bauxite was likely to have originated as a result of in-situ lateritisation and not through sedimentary transport and redeposition

Jun 18, 1905

By B. Gazea, A. Kontopoulos, A. Kourtis, K. Adam

Static tests give a measure of the balance between acid-producing and acid-neutralising mineral components in a material, while kinetic tests determine acid generation and neutralisation over a long period. Drill-core samples from the amphibolite and gneiss host rocks of the Stratoni lead-zinc sulphide deposit in Greece and mine/mill waste samples from Stratoni and Olympias were examined by the standard acid base accounting, BCR and net acid production tests. Mineralogical data on the materials and resulting residues were used to illustrate the differences between the methods and establish their ranges of applicability. BCR seems to simulate most closely the conditions prevailing during generation of acid mine drainage but is time-consuming and requires elaborate equipment. Acid base accounting is suggested for standard screening; net acid production might be used in the field or for solids with less than 10% S

Jun 19, 1905

By S. P. Singh

The purpose of the cut is to provide a free face to which the remainder of a development or breasting round can break. The results of field testing in drifts and at a quarry face were used as a basis for a description of the rock breakage and flushing mechanism in the cut. It was concluded that the important features of a cut design are proper hole spacing, sufficient relief volume, drilling accuracy and relief holes slightly longer than the planned length of the round. The void space provided by the relief holes should be about 15% of the cut volume, with more required in weak, highly fissured rocks. The importance of drilling accuracy increases with round length, an error being magnified by the small blasthole spacing. The first hole pulls only about 20% of the round length, 4-6 holes having to be fired before the cut is pulled close to its design depth. The first four blastholes should be fired with a minimum inter-hole delay of 100 ms to provide progressive relief of burden and avoid the superimposition of ground vibrations. The earliest-firing charge should be closest to the relief area and act laterally, while the first of the vertically-fired charges to be detonated should be the uppermost. Problems during cut-pulling include sympathetic detonation, dynamic pressure desensitisation, charge disruption and freezing of the cut

Dec 1, 1995