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By S. Liu

With the development of global economy, the demand of mineral?s quantity and quality are in-creased, valuable minerals are more and more finer and poorer, and the capacity of concentration plant are more and more high. Using large-scale flotation cells can obviously enhance the capacity of treating the mineral, reduce the cost, and increase the economic benefit and competitive ability for the enterprise. BGRIMM advanced advisable technical scheme with optimally parameter and route for the feature of dynamic in large scale flotation machine, and developed the KYF Large Scale Flotation Cells, which have used more than 400. The paper advanced the history, the design principle, the operating principle, the structure feature and the application of KYF flotation ma-chine.

Jan 1, 2014

By J. Y. ` Xie

The paper introduced bio-oxidation plants of refractory gold concentrate in China and CCGRI cultures. CCGRI cultures are composed of bacteria and archaea. Archaea Ferroplasma acidiphilum is very thick and fills whole mineral surface. It plays a more dominant role in CCGRI process. Several years of practice has proved that the operating temperature in bioreactors between 38~52?,gold recovery is almost same. Pulp concentration has been increased each year and reached to 25%.

Jan 1, 2014

By A. Qaredaqi, M. Mohammadi

Wet High Intensity Magnetic Separators, for short, WHIMS are used for recovery of Iron ores with low magnetic susceptibility. A Jones patent WHIMS with "grooved plates" matrix is being used in Dry Tailing processing line in Hematite Recovery Plant at Golgohar mining & Industrial Co. for recovery of Hematite. In this kind of separators Matrices are used for increasing the Magnetic field intensity and providing high magnetic field gradient. The laboratory WHIMS in Golgohar Iron Ore and Steel research Institute is capable to provide a background magnetic field strength up to 0.85 Tesla and in presence of ‚expanded metal? matrix, magnetic field intensity could increase up to 0.9 Tesla. More than 50% of feed particles in this separator were finer than 36 micron and recovery of these particles needs more magnetic field intensity. Hence, ‚Grooved Plates? matrices with Js= 2 Tesla and 3.8 mm gap were constructed. Measurements indicated that magnetic field intensity around the matrix will increase to 1.25 Tesla. Graph of Magnetic field intensity around the matrix to background magnetic field intensity was plotted and a model with Rsquare= 0.9 was offered. In addition, magnetic field gradient and magnetic force were calculated. In WHIMS with feed top size of 150 micron, the main effective forces on separation process are the magnetic force and the hydrodynamic drag force. With assuming that the particles are smooth and spherical and the flow is laminar, Recovery of fine magnetic particles is problematic in this separator because of drag force. Considering these facts and mentioned model, finest particles that are recoverable in different magnetic field intensities were calculated. Computations illustrated that with magnetic field intensity more than 0.8 Tesla, particles as fine as 4 micron are theoretically separable but it should be noted that in practice a larger attractable particle size would be expected.

Jan 1, 2014

By W. S. Eu

Reduction of weathered mineral ores can initiate phase transformation which can affect either their activation or deactivation, subsequently influencing the extent of extraction of desired metals in a leaching reagent. The reduction of ilmenite ores for one occurs as a series of parallel, solid state reactions which at present has no known mechanisms, although the evidence of their effects is abundant. Understanding these reactions may well be the key to uncovering the mechanism of ilmenite activation, hence enabling precise control of its reaction process to maximize yield of TiO2 extraction. However, documenting the solid state reactions in the reduction of ilmenite is challenging due to the ore complexity, the number of simultaneous reactions and the difficulty of capturing critical intermediate reactions and phase transformations during processing. The phase transformations of ilmenite minerals reduced at temperatures up to 850°C were investigated in this study. Mineral transformations were studied in-situ using synchrotron radiation based X-ray powder diffraction with temperature resolved tests. The effect of the extent of reduction and specific mineral transformations were verified by leaching reduced ore with sulphuric acid. The re-sults suggest that transformation of major mineral phases occurs within of specific window of operation and thermal treatment appears to influence the extent of activation and leachability of ilmenite minerals.

Jan 1, 2014

By Chen Dong, Yang Wenwang, Liu Zhineng, Tan Ming

"To meet the requirement of production expanding of a certain potash ore dressing plant in Xinjiang province of China, industrial test of XCF/KYF-50 flotation machine was performed to process potash ore. The tank of XCF/KYF-50 flotation cell is in U shape, 50m3 of volume. This flotation cell is able to suck slurry by itself, and can be arranged on the same base level without high difference. In this paper, two sets of XCF/KYF-50 flotation cells were adopted to replace 8 sets of 8m3 flotation cell in original flow sheet of flotation. Aeration rate, slurry suction capacity, power consumption and slurry suspension are investigated. The measuring results show the slurry suction capacity of the flotation cell is larger than 12.80m3/min and solid particles disperse evenly in the tank without deposition. Industrial test result indicates that the final grade of concentrate is 26.69% at the recovery of 90.95%, which is up to expected performance. XCF/KYF-50 flotation cell has advantages of high flotation efficiency, significant energy saving and reasonable configuration of automatic control system, this kind of flotation cell can meet the requirement of production expanding of this potash ore dressing plant well."

Jan 1, 2014

By X. M. Yu

A large amount of polluted sludge is produced by a nonferrous metal factory after treating waste water with lime/ferrous salt. The concentration of arsenic in the dried sludge is high to 5.84%, a toxicity test is taken on the sludge according to GB5085.3-2007 and the extraction content is 15.75mg/L, which surpasses the arsenic extraction standard [As]=5mg/L, the sludge is categorized as hazardous waste. If put outside without disposal, it would be very harmful to environments. Here we report an optimum protocol to extract arsenic; S2- alkaline liquor is utilized to treat the arsenic sludge. At 85?, 10L 7% S2- liquor is added into 1kg dried sludge and the resulting mixture is stirred for 120min at 250r/min, then separated by centrifugation and the compressed waste residue dried naturally. The average arsenic content is 1.40mg/L, lower than GB5085.3-2007 Standard and arsenic-free residue is consistent with GB18598-2001 Standard, which can be bury safely. The extracted arsenic is transferred into copper arsensite for use as addictive in copper electrolysis and the waste water can be recycle after calcium is removed.

Jan 1, 2014

By Michael Young, Rodrigo Araya, Cesar Gomez, Le Huynh, James Finch

The performance of flotation machines is closely related to the gas dispersion characteristics achieved in their operation. It is known that frothers play a major role not only in the size distribution of the generated bubble population, but also on the swarm rise velocity. A program to characterize frother effects on two-phase hydrodynamics (air-water) of Jameson cells was undertaken in a fully instrumented pilot unit installed at McGill University. Gas dispersion parameters (gas velocity, gas holdup and bubble size distributions) of the gas-liquid mixture generated in the downcomer were measured after its release into the separation chamber. The unit was operated under different conditions including gas velocity, liquid jet velocity and frother concentration (MIBC). Bubble size distributions for concentrations above the critical coalescence concentration (CCC) were narrow with Sauter mean diameter between 0.6 to 1.3 mm. The bubble size followed the general trend as encountered in other types of flotation machines, i.e., rapid decrease with increasing frother concentrations below 10 µL/L, and almost no change in size for concentrations above 30 µL/L. The CCC was between 10 and 15 µL/L. Strong correlations were found between bubble size and air-to-liquid flow ratio (APR), and between the bulk density of the aerated solution in the separation tank and the vacuum inside the downcomer. An equation is proposed to estimate gas holdup in the separation tank from vacuum and bulk density readings.

Jan 1, 2014

By A. V. Kurkov

The secondary action reagents (SAR) are organic diphilic compounds capable of altering ac-id-base and donor-acceptor properties of the main collector and consequently the energy of collector interaction with the mineral?s surface, its hardness and fixation forms ratio through associates formation via the hydrogen bonds. When the basic flotation conditions are being established, convergence of the electronic structure of the collector and the mineral being extracted due to minerals surface preconditioning with modifiers and the most efficient collector choice. At the next stage of the selective flotation condition establishment SAR is selected for a more precise adjustment of the energy of the collector fixation on the mineral. Such an approach makes it possible to solve efficiently various issues of flotation separation of non-sulfide minerals. In particular neutral organic substances containing groupings C==O, S==O, P==O (ethers of carboxylic and phosphonic acids, amides of carboxylic, phosphonic and sulfonic acids) were proposed as SAR. In order to enhance the flotation process selectivity in the conditions of water recycling including the selectivity of carboxylic collectors especially in the environment of high hardness water flotation, it was proposed to use SAR with long hydrocarbonic radical and groups with enhanced electronic density within the molecule: N-methylolamides of alkylphosphoric acids and ethers of methylphosphonic acid. Introduction of small amounts of these compounds alongside with the main fatty-acid collector enhance the performance of fatty-acid flotation of fluorite, beryl, columbite etc., lowers the collector consumption, and completely compensates the depressive effect of recycled water. Di-2-ethylhexyl ether of methylphosphonic acid?CH3P(O)(OC8H17-i)2 (hexarane) was more thoroughly researched as such an agent within fatty-acid flotation process. Following aspects of the flotation system were studied: interaction of oleic acid and sodium oleate with hexarane in the liquid phase (infrared spectroscopy); heat emission under the interaction of hexarane-oleic acid ? sodium oleate ? calcium salts (isoperiboric diathermic colorimeter); colloid-disperse state of the collector influenced by hexarane (nephelometric analysis); dynamics of the mineral surface hydration due to the agents (method of indicator negative adsorption); hexarane effect upon the interaction of fat-ty-acid collector with calcium salts (complexometric method with Trilon-B); floatability of pure minerals (quartz, microcline, beryl, columbite) in Hallimond tube; hexarane effect upon oleic acid (sodium oleate) adsorption (nephelometric method for identification of the residual content of oleic acid and its forms within the solution). Upon the research it can be definitely concluded that the adjusting effect of such compounds as hexarane within the non-sulfide minerals flotation process is mainly determined by their interaction with the main collector both within the pulp and at the mineral surface with associates formation due to the hydrogen bond. The consequence is calcium oleates destruction with the release of the most active collector under flotation in hard water environment which determines the efficiency of hexarane joint application with fatty-acid collector under recycled water supply. Therefore the introduction of the class of secondary action reagents is supported by their operation mechanisms and flotation process function and determines a new approach to the development of efficient conditions of selective flotation separation of non-sulfide minerals.

Jan 1, 2014

By X. Tong

Flotation researches of indium-beard marmatite from the Dulong multi-metallic ore in the Yunnan Province of China has been studied in order to improve the grades and recoveries of zinc and indium of the zinc concentrate in the Dulong concentration plant. The experimental results have shown that copper sulfate mixed with a chemical reagent X-1 as the activator in the marmatite flotation produced a much better beneficiation than copper sulfate alone, increasing the zinc and indium recoveries of 10% and 6%, respectively, while the concentrate grades were unchanged. Also, the new activator acted well around pH 10, allowing large savings on lime consumption in the marmatite flotation. In addition, it has been found that a sufficient activated time of activator with ore slur-ry in the flotation is needed to achieve good beneficiation of the marmatite ore.

Jan 1, 2014

By C. S. Gundewar

Indian National Steel Policy envisages ambitious three fold rise in steel production by the year 2020. This paper covers the iron ore industry in India which cater to the need of iron ore requirement of Indian iron and steel sector as well as export commitment in addition to addressing the industry?s key concern to attain the same. The main contents are (i) resources and its exploitation; covering status of exploration, reserves and resources, province wise occurrences, distribution, nature of mineralization and generation of fines, etc ; (ii) use of iron ore in iron and steel making, covering physical and chemical requirements for pig iron and sponge iron production; (iii) ore characteristics and beneficiation practice in vogue; (iv) projected steel demand and requirement of quality iron ore and provision thereof; (v) recovery of iron values from in situ low-grade ores and stacked fine rejects (-10/-6 mm) inclusive of slimes (-0.15 mm) from tailing ponds; (vi) agglomeration of fine concentrates preferably by pelletization; (vii) measures to augment iron ore availability for future requirements.

Sep 1, 2012

By Gorki Davila, Irineu Brum

"Brazil has large reserves of coal (32 billion tons) located predominantly in the south of the country. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently the country's strategic planning aims to minimize the gap between coal and resources traditionally used in the Brazilian energy matrix. In this scenario the processing of Brazilian coal by flotation appears as a promising alternative, having been successful in mineral systems containing fine particles This paper aims to study the overall process of flotation for a specific Brazilian coal. The material used in this study consists of fine coal that is usually discarded as waste and deposited in the tailings dam. The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The variables analyzed were the influence of size particle, solids concentration in the pulp, the concentration of surfactants and frothers to be used. The results showed that it is possible, from a feed with around 65% of ashes, to obtain products with approximately 35% ashes with mass recoveries about 40%. The types of collector reagent and foaming employees result in different concentrates. This study also presents a preliminary analysis of the effect of water recovery in concentration parameters."

Jan 1, 2014

By J-P Franzidis, P. O. Gyebi

"Coal-water mixtures (CWM) of concentrated fine coal may be transported in pipelines but this is influenced by both CWM rheology and stability. Here, a low viscosity is required to reduce power requirements, as well as good stability for transport and storage. The objectives of this study are to investigate the importance of surface charge, solids concentration and dispersant addition on the rheology and stability of a fine Witbank coal-water mixture (<75 m). Zeta potential, rheology and stability were measured with a Malvern Zetasizer, a AR1500EA rheometer and a static rod penetration test, respectively. Sendep 30D, Sendep 30F and Norilose 8058, all supplied by Senmin International, were used as dispersants, at dosages of between 0.1 to 0.5% dry coal (w/w). Solids concentration was varied from 10 to 58% (w/w). The zeta potential was found to be positive at low pH and decreased sharply with increasing pH to a minimum of -50 mV at pH 10. The zeta potential decreased with increasing dispersant concentration for all dispersants. The lowest zeta potential of -63 mV was obtained for Norilose 8058 at a dosage of 0.3%. CWM rheology was Newtonian at lower solids concentrations but became non-Newtonian at solids concentrations over 40% (w/w), with an initial yield stress and pseudo plastic behavior. The yield stress decreased sharply with increasing dispersant concentration for all dispersants. The lowest yield stress was obtained for Norilose 8058. The addition of dispersants resulted in significant improvements in stability. A penetration ratio of over 70% was obtained for Norilose 8058 after 10 days. In summary, the addition of dispersants resulted in a decrease in the zeta potential which increased the electrostatic repulsive forces between particles, thus improving both CWM rheology and static stability.INTRODUCTION Coal Water Mixtures South Africa’s energy economy depends heavily on coal. It accounts for about 70% of primary energy consumption, 93% of electricity generation and 30% of liquid petroleum fuels (Eberhard, 2011). The transportation of coal to export markets and power generation stations is a problem in the South African coal industry due to ageing and inefficient rail infrastructure. This problem is intensified by the long distance of coal haulage, delays in the time required to load and unload wagons, and environmental challenges related to air pollution and water contamination. Fine coal may be transported more efficiently and economically in a pipeline as a highly concentrated coal water mixture (CWM). Typically a fine coal CWM will contain 60-75% coal, 25-40% water and nearly 1% of dispersing additives (Atesok et al., 2005; Dincer et al., 2003). However, the transport of CWMs in pipelines is strongly influenced by both CWM rheology and stability. Here, a low viscosity is required to reduce power requirements, as well as good stability for transport and storage. These quantities are affected by the coal composition/mineralogy, solids concentration, particle size and size distribution, particle shape, inter-particle forces and dispersant type and dosage (Laskowski, 2001)."

Jan 1, 2018

By P. Vijay Kumar

Phosphate minerals are conventionally concentrated by flotation process using soap or soap- light diesel oil emulsion as collector. Some plants use detergents such as sodium petroleum sulfonate or alfa olefin sulfonate to enhance efficiency of soap flotation. It is reported that urea a known hydrotrope enhances flotation efficiency of soap as efficiently as alfa olefin sulfonate or linear alkyl benzene sulfonate at bench scale tests. In the present study tri sodium citrate also a known hydrotrope is tested as promoter in the flotation of phosphate mineral from Eshidiya ore.

Sep 1, 2012

By S. K. Kawatra, T. C. Eisele

"Coal-fired electrical power generation plants produce 56% of all the electricity in the U.S., burning approximately 860 million tons of coal annually. This results in the production of 58 million tons of fly-ash; 19 million tons of bottom ash and boiler slag, and 23 million tons of desulfurization sludge.s annually. These are a considerable disposal problem, and it would therefore be very valuable to be able to sell these residues and by-products as useful materials, rather than paying to dispose of them in landfills. However, utilization rates are currently very low, below 32% even for the most thoroughly commercialized combustion byproduct (fly-ash). This poor utilization rate is a result of the high impurity content of combustion byproducts, which makes them unsuitable for existing markets.Mineral processing techniques are useful for upgrading and utilizing combustion by-products. Fly-ash can be processed to remove unburned carbon, or utilized as a binder component in ore pelletization and agglomeration processes; bottom ash can be processed to produce certain aggregate grades; CO2 emissions can be sequestered using modified leaching techniques; and many scrubber sludge’s require processing before they can be used for producing gypsum products.The experiments described in this paper were carried out to study the application of mineral processing techniques to upgrading combustion by-products, particularly flue-gas scrubber sludge. A process was developed for upgrading unoxidized Flue-Gas Desulfurization (FGD) sludge’s by removing the primary impurity (unreacted limestone). A combination of hydrocycloning followed by froth flotation reduced the limestone concentration to as little as 1.7%, while recovering 66% of the sludge weight as a clean product. The recovered limestone was sufficiently concentrated that it could be recycled to the scrubber for more complete utilization."

Jan 1, 2003

By Stoyan N. Groudev, Ioannis Paspaliaris, Irena I. Spasova, Kostas Komnitsas

"Acid mine drainage waters generated in the uranium deposit Curilo, western Bulgaria, were treated by means of a constructed wetland located in the deposit. The waters had a pH in the range of about 2.5 - 4.1 and contained uranium, radium, some heavy metals (iron, manganese, copper, zinc, cadmium, cobalt, nickel, lead), arsenic and sulphates in concentrations much higher than the relevant permissible levels for waters intended for use in the agriculture and/or industry. The wetland covered an area of about 140 m2 and was characterized by an abundant water and emergent vegetation and a diverse microflora. Typha latifolia, Typha angustifolia and Phragmites australis were the prevalent plant species in the wetland but species of the genera Juncus, Eleocharis, Scirpus, Carex and Poa as well as different algae were also well present.The water treatment was started in July 2001 and until now (August 2002) the wetland effluents were characterized by pollutants concentrations decreased below the relevant permissible levels. The water flow rate through the wetland during this period varied in the range of about 0.2 - 1.0 l/s. The water clean-up markedly depended on the temperature but was efficient even in the cold winter months at air and water temperatures close to 0oC. The removal of pollutants was due to different processes but the microbial dissimilatory sulphate reduction and the sorption of pollutants on organic matter (viable and dead plant and microbial biomass) and clay minerals played the main role. Negative effects of the pollutants on the growth and activity of the indigenous plant and microbial communities were not observed."

Jan 1, 2003

By Mario Gerards, Sergej Podkow, Marco Steinberg

"The JONES® WHIMS technology is based on the magnetic separation process and is widely used for the recovery of magnetically susceptible iron ore particles. The conventional machine design is well-known within the iron ore beneficiation industry for more than 50 years and recognized to be highly reliable, robust and extremely compact with the advantages of high capacity and selectivity. In 1981 Rana Gruber AS, Norway bought 14 JONES® WHIMS DP 317 separators when the magnetic separation plant was built and erected. Today, 11 of these old machines are still operating profitably and efficiently. The former supplier was the coal and minerals division of Klöckner-Humboldt-Deutz (KHD) which is today MBE Coal & Minerals Technology GmbH (MBE). This paper outlines a detailed description of the project of revamping the above mentioned old machines and describes the challenge of incorporating enhanced and newly developed technology into an existing processing plant. Further it gives an overview of the recent developments on the design of the JONES® WHIMS. In order to meet modern product requirements and to increase and secure plant productivity, in 2012 Rana Gruber AS settled a contract covering two new designed JONES® WHIMS DP 317 HFR separators to be implemented into the existing building and the upgrading of all 11 older JONES® WHIMS under the use of as many refurbished items as possible. The two new machines were fully developed by the product specialists of the supplier in cooperation with the operator Rana Gruber AS, thereby taking advantage of their great experience. The design of the new machine is based on the conventional design, i.e. the general operating mode as well as the overall dimensions are identical. Finally this paper gives an overview about the erection and commission phase of the two new machines and gives a detailed comparison between conventional and enhanced WHIMS technology."

Jan 1, 2014

By Ventsislav Stoilov, Angel Angelov, Ivan Korolev, Antti Remes, Todor Pukov, Stoyan Gaydardzhiev

"The process modeling and simulation studies aim for better process operation and favorable environmental impact. The objective of this work is to set up a simulation model of the Assarel copper flotation circuit for planning and optimization of the process with the aim of increased metal recovery. The model is parameterized based on laboratory flotation tests of ore samples from the Assarel mine together with mineralogical studies by X-ray diffraction (XRD) and Mineral Liberation Analysis (MLA). A combination of several techniques allows reliable identification of mineralogical composition of the selected samples. The changes in the proportion between sulfide minerals in various products along the circuit have been also documented. Further, this information is used in the simulation model and in data reconciliation procedures for establishing mass balance. The simulation accuracy is studied by comparing the simulations with the plant survey based mass balance. Constructed simulation model can be used to run alternative process scenarios. As an example, the flotation circuit performance with different reagent regimes is simulated based on data from batch flotation tests. Two reagents were considered for this purpose, dithiocarbamate-based one and xanthogen formate/mercaptan blend. It has been revealed that these reagents do not have the same influence on the selective flotation. The one improves flotation of gold and overall recovery but without notable selective action. In contrast, the other showed better selectivity towards copper, rejecting more gangue and lowering gold recovery. The model is also applicable for process optimization studies with different feed compositions, flowrates and circuit configurations. INTRODUCTION In the pursuit for elevated technological indicators, finding an optimal set of process parameters fully utilizing the potential of the equipment is a key factor to success. Over the past decades, there has been a substantial development in flotation circuit optimization through performance benchmarking using metallurgical modelling and steady-state computer simulation. Practical simulation engineering tools are based on experimental data obtained from laboratory tests and from plant surveys and operation data. With the help of flotation models, it is possible to study grade-recovery response with different feed compositions and throughputs, and with various cell-operating parameters, as well as to evaluate and design different flowsheet configurations. Outotec’s HSC Chemistry® software, which incorporates simulation and mass balancing modules alongside with several other tools, can assist with this optimization (Mattsson et al., 2015)."

Jan 1, 2018

By Adam Jordens, Olga Kuzmina, Christopher Marion, Kristian Waters

"In order to meet the growing demand for non-Chinese rare earth suppliers many new rare earth (RE) mineral deposits are currently under development, however these deposits typically include many minerals for which there is little processing information available. One of these deposits is the Nechalacho deposit located in the North West Territories of Canada. This deposit contains multiple RE minerals including bastnäsite, zircon, fergusonite, allanite and monazite. The work presented here investigates the use of different classes of flotation collectors (carboxylic acids, hydroxamic acids, phosphoric acids) typically used in RE mineral flotation to float the Nechalacho ore directly. Flotation tests are also conducted as the final step in a beneficiation process incorporating centrifugal gravity concentration and magnetic separation. This combination of centrifugal gravity concentration and magnetic separation rejects low specific gravity gangue minerals such as K-feldspar and plagioclase and concentrates high specific gravity minerals such as magnetite and hematite. The removal of low specific gravity gangue helps to improve flotation and the removal of ferromagnetic iron oxides is important prior to flotation using certain chelating collectors."

Jan 1, 2014

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By V. V. Zakopaylo, M. V. Lukyantseva, V. A. Ignatkina, V. A. Bocharov, L. C. Khachatryan, D. M. Altynamanov, A. A. Kayumov, R. H. Sharipov

"This research was aimed to explain the reasons of low floatability of tennantite from refractory pyrite ores of non-ferrous metals and to create a reagent regime for selective increasing a recovery of copper sulfide minerals from arsenic-containing copper pyrite ore. ?opper-zinc ore of the Uzelga deposit has 89% of pyrite, some part as melnikovite; copper is assayed as 3.58% of tennantite and 0.25% of chalcopyrite; there is 2.19% sphalerite. Sulfide minerals are very finely disseminated. Tennantite is genetically related to primary copper sulfides. Graphene was identified on the surface of tennantite by a transmission electron microscopy (TEM) method. The recovery of tennantite was rose up by using the collector M-TF. M-TF is the mixture of diisobutylditiophosphate (DTF) and O-isopropyl-N-methyl (ethyl) (TC) in the certain ratio. M-TF change up a kinetic of copper sulfide flotation in a slightly alkaline medium, but pyrite has slowly floatability at this moment. A depressing effect of thiosulfate ions in a liquid phase of pulp flotation tennantite from pyrite ore has been established. A copper recovery up 14.2% (from 67.7 to 82.0%) into a copper concentrate level off copper grade of 18.65% (butkx) and 18.68% (M-TF) has been increased by the new technology with M-TF compared to a standard technology with butkx. A main copper recovery up to 50 % in an inter-cycle copper concentrate assaying 19-21% Cu in case of using M-TF was gotten. A zinc concentrate with recovery of 50% and a zinc assay of 41.76% by a standard flow sheet with butyl xanthate was obtained. A zinc recovery of 70.3% with a zinc grade of 44.17% by the M-TF technology was achieved.INTRODUCTION The pyrite copper-zinc ores of the Urals region are considered refractory. The distinctive features of these ores include a high content of pyrite (90-95%), the presence of arsenopyrite and arsenical pyrite, and the simultaneous presence of chalcopyrite, bornite, tennantite with the predominance of the latter (Andreasen et al.,2008;.Dobrotsvetov, 2009; Chanturiya et al. 2016). The flotation properties of tennantite differ from those of chalcopyrite (Xumeng Chen, Yongjun Peng, Dee Bradshaw. 2014), which is the reason why a comprehensive study was under taken of the flotation activity of tennantite and a process for its recovery was developed. The proposed agent treatment and flotation process make it possible to produce salable copper and zinc concentrates."

Jan 1, 2018