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By F. P. Hassani, A. Hara, M. Momayez

To be competitive on the international market, the Canadian mining industry must reduce its costs, increase its productivity and maintain a high standard of safety. There is a great need today for improved methods that would allow the detection of geological structures in advance of mining to reduce dilution and the monitoring of underground structures to increase safety. This will facilitate planning for optimum exploitation of the mine and to increase production at lower costs. This paper discusses two examples of more efficient mine planning using new technologies such as Ground Probing Radar (GPR). In Kidd Creek mine, GPR technology was used at the 2500and 2600 levels to (1) monitor the stability of the sill pillar; (2) locate the presence of disseminated sulphide pockets in the sill pillar for extracting the mineral content; (3) monitor the stope backs and wall structures to evaluate the effect of on-time filling sequences; and (4)assess rockfill quality in terms of the presence of voids and fractures within the rockfilled areas. In the New Brunswick coal mine in Minto, GPR was used along with core log data to map and construct a 3D block of a section of the bench showing the relative position of different layers overlying the coal seam.

Jan 1, 1996

By A. Dahi Taleghani, A. Shojaei

Continuum damage mechanics (CDM) of rocks is studied together with their elastic and plastic behaviors to develop simulation tools for hydraulic fracturing jobs in naturally fractured formations. The model is constituted based upon pressure sensitive inelastic deformation of porous rocks and their damage mechanisms in the cases of drained and undrained conditions. The CDM model is formulated within Fracture mechanics framework. The performance of the developed elastoplastic and CDM models are compared with the available test data of a specific shale play. The hydraulic fractures growth in the reservoir scale is then simulated; in which the effect of fluid viscosity, natural fractures characteristics and differential stresses on induced fracture network is studied. The simulation results are compared with the available solutions in the literature. The developed CDM model outperforms the traditional fracture mechanics approaches by removing stress singularities at the fracture tips and simulation of progressive fractures without any essential need for remeshing.

Jan 1, 2015

By X. G. Zhao, M. Cai, L. K. Ma, P. F. Li

"Crack initiation stress is one of the characteristic stress thresholds in the rock deformation process under compression. By analyzing AE responses of brittle rocks in uniaxial compression, a new method which is called cumulative AE hit (CAEH) method is proposed for determining the crack initiation stress. An advantage of the CAEH method is that the method removes the user's subjective judgment. To verify the CAEH method, uniaxial compression tests with AE measurement using 77 crystalline rock specimens were conducted. The test specimens cover eight rock classes with different mineral grain distributions. Crack initiation stresses of these specimens were determined by the proposed CAEH method and the LSR method, and the resulting mean crack initiation stresses determined using the two methods were comparable. In addition, taking one rock class with 20 specimens for example, the mean crack initiation stresses determined using the CAEH method and those from several established strain-based and AE-based methods were similar. Hence, the CAEH method can be used as an alternative method for crack initiation stress determination.INTRODUCTIONExperimental observations indicate that the failure process of brittle rocks is associated with crack initiation, crack propagation, crack damage and final strain localization (Brace et al., 1966; Bieniawski, 1967; Lockner, 1993; Wawersik & Fairhurst, 1970). Compression tests on cylindrical specimen are often used to characterize the crack development process. The crack initiation stress (sci), crack damage stress (scd), and peak stress (sc) represent important stress thresholds during the failure process of brittle rocks. Among the three characteristic stress magnitudes, sci is difficult to be determined objectively, directly from examining the stress–strain curves. Some researchers argued that sci obtained from laboratory compression tests is an important parameter for estimating the spalling failure observed in brittle rocks around underground excavations (Andersson et al., 2009; Diederichs, 2007; Martin, 1997). sci can also be used to estimate rock tensile strength and Hoek-Brown failure criterion parameter mi (Cai, 2010). Over the last 40 years, various strain-based methods have been proposed to determine the crack initiation stress in compression tests (Brace et al., 1966; Diederichs, 2007; Eberhardt et al., 1998; Lajtai, 1974; Martin & Chandler, 1994; Stacey, 1981). Nicksiar and Martin (2012) proposed a Lateral Strain Response (LSR) method for establishing sci for low-porosity rocks. Meanwhile, they also used different strain-based methods to evaluate sci of Äspö diorite, and the results showed that all strain-based methods gave acceptable crack initiation stress values. Subsequently, they utilized the LSR method to further investigate the crack initiation stresses in igneous, metamorphic, and sedimentary rocks in compression tests (Nicksiar & Martin, 2013). Compared with previously proposed strain-based methods, an advantage of the LSR method is that it removes the user judgment when interpreting sci. However, the use of the LSR method relies on accurate determination of scd and on having a polynomial fitting equation to find the maximum LSR value."

Jan 1, 2015

By Donald F. MacDonald

METAL PRICES RISE WITHIN the past nine months, the mining industry of the world has been revivified by a spectacular price advance for the metals. ln fact, practically all geological raw materials have been marked up during this period. Reviving industry started the price rise, but the armaments race among the nations has intensified it. These factors, coupled with our decided building shortage, which must be made up, will probably maintain metal prices at decidedly favourable levels over the next two or three years, or longer. OUR MINERAL CIVILIZATION It is interesting to recall that in the past hundred years, while the white population of the world increased some three ta three and a half fold, the consumption of minerals increased seventy-five fold. In other words, ours is a mineral civilization. If we disregard short slumps, which we will occasionally experience, it seems certain that the bread upward trend in mineral consumption will be maintained for many decades into the future. Nations without reasonably abundant and diverse mineral deposits will eventually become nations without much power. Canada is blessed with a splendid store of minerals. Its mineral industry is now facing an exceptionally rosy future. What of the mineral industry of Nova Scotia? GEOLOGICAL RESEARCH ALLOWED TO LAG RN NOVA SCONA Many years ago, when geological science was in? its infancy, much geological study was carried on in Nova Scotia. In 1827, Francis Alger began work on the iron ores in the Bay of Fundy region. In 1886, E. R. Faribault began his series of remarkable papers on Nova Scotia geology. Between these dates, many others published papers on the geology of the Province. The most outstanding of this early group of geologists was Sir William Dawson, whose published works on Nova Scotian geology extended over the period from 1845 to 1891.

Jan 1, 1937

By A. Majumdar, B. Servière, H. Persson

The CCR refinery, which was built in 1931, treats both internal and third party copper anodes to produce 325,000 mt of copper as cathodes. These anodes contain high levels of impurities, such as Ni, As, Sb and Bi, that reports to the electrolyte during the refining step and need to be removed in order to maintain cathode quality and operating efficiencies. In the purification plant, the electrolyte is de-copperized via electrowinning in three stages. In the last stage, the copper content of the electrolyte is reduced to below 1 gpl in order to maximize the co-deposition of As, Sb and Bi with the Cu. This is accomplished with minimum arsine gas generation by using periodic reversal of the current and by controlling the final copper content of the electrolyte. Nevertheless, the possibility of exposure to arsine is treated as a major risk and controls have been implemented to reduce this risk. This paper describes the controls in place at the purification plant, which are being continuously improved through periodic risk assessments and audits. INTRODUCTION The CCR Refinery, which is a part of Glencore Canada Corporation and located in Montreal-East, Quebec, is a custom copper and precious metal refinery, with a capacity to refine 325,000 tonnes of copper anodes per year. Copper anodes are received from the Horne smelter in Rouyn-Noranda, Quebec, Altonorte smelter in Chile and other 3rd party smelters. CCR anodes are produced using the spent anodes from the tankhouse along with purchased spent anodes and copper scrap. The precious metal plant treats the tankhouse anode slime, purchased anode slime, precious metal ingots and Doré anodes from Glencore’s Brunswick lead smelter in Belledune, New Brunswick. CCR products include copper cathodes, silver and gold bullion, a platinum-palladium concentrate, selenium, tellurium dioxide and nickel sulfate. In 1975 an accident occurred at CCR where two employees were exposed to fatal levels of arsine emitted from the then existing purification cells. This process was therefore shut down immediately. Research and development work was then initiated to determine the optimum electrowinning conditions whereby arsine gas generation would be minimized while maintaining high copper and impurity removal efficiencies. It was found that the application of periodic reversal of current (PRC) during the last stage of electrowinning retarded the onset of arsine formation while at the same time allowing the copper concentration to be reduced to less than 1 gpl (Houlachi & Claessens, 1978). A new purification plant was designed based on the PRC technology and was started up in 1976. In addition to the use of PRC electrowinning, the new plant is located in a fully enclosed section of the tankhouse. A special effort was made to design a ventilation system to evacuate the acid mist in addition to any arsine gas. Arsine monitors were installed to measure the emissions from the stack along with arsine levels in the workroom. The arsine monitors and the ventilation system were interlocked with the rectifiers (Thiriar et al., 1983).

Jan 1, 2019

By J. Contreras

In the period 2003-2004, the situation of the copper concentrate market was unfavourable for smelters and refineries, with low TC/RC values and euro-dollar parity affecting European companies negatively. Within this scenario, Atlantic Copper decided to develop a plan to increase its competitiveness and to improve its results in these market circumstances. The plan affected all departments in the Company and was based mainly on cost reduction in energy and manpower. A general analysis of the Complex's overall efficiency was carried out and, based on this analysis, two major Projects emerged, "Primavera" and "KF". Each Project consisted of smaller sub-projects which aimed at improving the areas which could perform better according to our general analysis. The paper describes how this entire project developed and the final results obtained by the Company.

Jan 1, 2007

By A. F. Laurin, A. L. Dorr

"Because of its wide areal extent, its numerous lithological facies and its high degree of metamorphism, the Quebec portion of the Grenville province has only partly been explored and prospected. Rock types that are economically among the most interesting in the Grenville are those of mafic and ultramafic compositions, because of their great potential for coppernickel and chromium-platinum. The peculiar mode of occurrence and the distribution of these igneous masses in which copper-nickel mineralization is known to occur indicate' two common geological features: (1) aerial photographs and/or topographic maps strongly' suggest close spatial (and possibly temporal and genetic) association of most of these mineralized mafic and ultramafic intrusions with circular structures; (2) when plotted on a large-scale map comprising the Quebec portion of the Grenville, these circular structures fall along two lines which could correspond to major tectonic features. Even though the genetic links among the mineralized mafic-ultramafic masses, the circular structures and the linear features are not yet fully understood, their associations are believed to be empirically valid and should therefore be used as geological tools by those interested in exploring the Grenville for copper-nickel and possibly chromium-platinum deposits. It should be noted that these mafic and ultramafic bodies do not appear to be spatially related to anorthosite complexes."

Jan 1, 1971

By Mayumi Ito

Mineral processing of rare-earth ore from the Dong Pao deposit, Vietnam, was investigated. The ore contained bastnaesite, (REE (rare earth element)) CO3F, as the valuable mineral and barite, quartz, and fluorite as gangue. To establish a mineral processing flowchart, selective comminution, size classification, and magnetic separation were tested. Bastnaesite shows brittle properties and selective comminution was applied to improve the purity of products. The crushed products were classified by decantation, and the overflow product showed high purity of bastnaesite indicating that bastnaesite becomes fines by crushing and that selective crushing can be used to concentrate the bastnaesite. Magnetic separation for the sink product was carried out and the mag-product showed high recovery rates of bastnaesite, indicating that the combination of size classification and magnetic separation is effective.

Aug 1, 2013

By M. Maeda, H. Sasaki

Dissolution characteristics of metals vary significantly when they form alloys with other elements. Because hydrometallurgical processes are essential in separation and refining of non-ferrous metals, it is important to study behaviors of alloys in aqueous solutions. The authors have studied dissolution characteristics of precious metals in acid solutions using electrochemical measurement. When precious metals are alloyed with Zn, its dissolution is promoted by an increase in surface area caused by the preferential dissolution of this metal. The electrochemical study also revealed that precious metals dissolved from some alloys at unusually negative potentials; the underpotential dissolutions are explained by activations of these metals in the dealloying.

Jan 1, 2014

By Judith S. Chan

With the increasing awareness of the need for the reduction of carbon emissions globally, geothermal energy, which offers a potential for cleaner energy generation, is one potential new source. In Alberta, these geothermal resources are likely to be found in the sedimentary basin, or in the deeper crystalline basement rocks. Alberta exhibits a very low geothermal gradient compared to other existing geothermal fields located in areas of volcanic and tectonic activity. To mitigate this effect, the focus in Alberta will involve the development of engineered geothermal systems (EGS) in the target resource. The first goal for EGS research and development is to develop a detailed geological-geophysical characterization of selected sites to delineate potential geothermal reservoirs in Northern Alberta. One of the selected sites is in the Fort McMurray area. The deepest well drilled in the oilsands areas of Northern Alberta is located just west of Fort McMurray. It has a depth of 2363 m and as such can provide details on the physical properties of the rocks, the state of stress, and the existence of fracture porosity toward geothermal investigations. To date, we have acquired temperature logs to study the change in geothermal gradient with depth, and a series of petrophysical logs to study the finer scale structure of the rock formations with vertical resolutions in the range of 0.05 cm to 80 cm. Our aim is to identify geological features such as zones of fractures in the basin and/or basement that could provide an indication of enhanced fluid flow potential ? a necessary component for any geothermal systems to be viable. Zero offset and walkaway vertical seismic profiles (VSP) were also conducted to measure the seismic responses at the borehole. VSP data can be used to delineate the structural and stratigraphic features surrounding the borehole that could not be resolved from surface seismic reflection data that are also available near the borehole. The full integration of well logs, VSP data and surface seismic reflection data are expected to provide a detailed characterization of the sedimentary basin and crystalline basement rocks of the Canadian Shield in Northeastern Alberta and will assist in future planning for drilling.

Jun 1, 2012

By E. S. Moore

Introduction The geology of the Sudbury nickel field has been studied extensively, but there are few reports dealing with the structure of the interior of the basin. It was not until the Treadwell-Yukon zinc-lead deposits were discovered that attention was strongly directed toward the large-scale faulting that has split the basin parallel to its long axis. This faulting has been responsible for the , ore deposits in the basin and it may be regarded in many ways as the most important geological event, next to the intrusion and differentiation of the nickel eruptive sheet, that has occurred in the Sudbury region. The early reports on the nickel region by Bell, and Barlow, were chiefly concerned with the nickel-copper ores and with the formations of the region. Coleman was the first geologist to map the nickel eruptive as a continuous sheet around the belt and to emphasize its basin character. On the map accompanying his later report, he shows an important offset in the nickel eruptive at its southwest end, where the large fault cuts this portion of the basin, but the fault was not traced into its interior, as little detailed work was clone in the basin at that time. No ore-bodies had been developed outside of the nickel-copper deposits associated with the norite when the map was prepared, and attention was mostly concentrated on the nickel eruptive. Coleman did, however, map and name the various formations found within the basin and, in general, his delineation of these has remained the standard for prospectors and other workers in the field until the present day.

Jan 1, 1930

By T. L. Lee, D. Y. Tan, J. Mi

Considerable progress has been made in studying the mechanism and effectiveness of using ultrasound waves to manipulate alloy solidification microstructure, However, uncertainties remain in both the underlying physics of how microstructure evolve under ultrasonic waves, and the best technological approach to control the final microstructure and properties. We used the ultrafast synchrotron X-ray phase contrast imaging facility housed at the Advanced Photon Source, Argonne National Laboratory, USA to study in-situ the highly transient and dynamic interactions between the liquid metal and ultrasonic waves/bubbles. The dynamics of ultrasonic bubbles in liquid metal and their interactions with the solidifying phases were captured in-situ for the first time. The experiments were complemented by the simulations of the acoustic pressure field, the pulsing of the bubbles and the associated forces acting onto the solidifying phases, providing more quantitative understanding for using ultrasound to control the growth of dendritic grains and to enhance grain multiplication effects for grain refinement.

Jan 1, 2014

By Guichao Wang, Geoffrey M. Evans, Graeme J. Jameson

"In this paper we present a new method for studying the detachment of particles from bubbles in a rotating turbulent eddy. The eddy is formed in a wall cavity in a two-dimensional water tunnel with transparent walls. When water flows through the tunnel, a vortical flow field develops in the cavity. The properties of the eddy can be modulated by changing the free-stream velocity of the water in the tunnel. Bubbles are pre-loaded with one or more particles in a fluidized bed flotation device located beneath the vortex cavity. Loaded bubbles are released one at a time into the cavity, and the motion of the bubbleparticle aggregate is studied using a high-speed video camera. The diameters of the particles and the bubbles, and the number of particles initially attached to the bubble, can be varied. The trajectories taken by the bubbles are quite complicated. In some cases, the bubble moves to the centre of the eddy, and particles rotate around its axis. If the rotational speed is sufficient, particles may detach due to centrifugal force. However, other modes were observed, including inertial detachment due to rapid changes in direction of the surface of the bubble, because of changes in trajectory of the bubble as a whole, or because of pulsations and oscillations of the bubble surface. Clusters of bubbles held together by particles were seen to form and reform. In the traditional explanation for the detachment of particles in flotation cells, it is assumed that particles detach from bubbles rotating in an eddy due to centrifugal force (Schulze, 1977). Although the conditions assumed in Schulze's theory may exist, it is only one of a range of phenomena that can lead to the detachment of particles from bubbles in a turbulent vortex.INTRODUCTIONThe recovery of particles by flotation methods is dependent on the particle size. The recovery in the existing flotation machines reaches a peak for particle size, typically in the range of 20 to 100 µm. This size range varies as a function of the particle’s properties (type and composites). For coarser particles, the recovery drops very quickly (Gaudin, Groh & Henderson, 1931; Jowett, 1980). If the upper size limit can be increased for flotation, dramatic savings in the grinding energy can be achieved."

Jan 1, 2016

By Glenville A. Collins

IN 1932, Horace Onyett at Oroville, California, built a practical floating washing plant along the general lines as now known, using a 24 in. by 12 ft. trammel; it was fed with a ½ yard dragline bucket, rated then at 200 yards per day. Onyett dubbed his plant a 'Doodlebug' which name has clung to this type of operation ever since. In general, the 'Doodlebug' dredge is the outgrowth of the depression of 1929, wherein many dirt contractors had surplus idle equipment and a few of them ventured to use it for placer mining. Many such plants were impractical and poorly designed and adapted often to locations not suited to the purpose. However out of the general idea came refinements until today dragline dredging has a very definite place in the gold production of the world. Many of the early operators, being mainly contractors without mining experience or technical knowledge of gold saving, geology, or mechanical design, naturally went through stages of trial and error until a workable unit became standard practice. Credit should be given Bodenson Iron Works of San Francisco, who did a notable job of pioneering and building of floating washing plants; also, to Lord and Bishop, contractors of Sacramento, who were among the early operators, and to several others who built and rebuilt their plants until the weak spots were strengthened to take the beating required, and yet deliver a high degree of efficiency.

Jan 1, 1945

"A numerical procedure based on Smoothed Particle Hydrodynamics (SPH) is developed for rock blasting phenomena involving multiple intersecting joints. In this procedure, an elasto-plastic damage constitutive model has been applied in the framework of SPH to simulate yielding response of the surrounding rock medium. In this paper, a square shape rock medium with centrally located emulsion explosive in a borehole is numerically blasted with and without the presence of two diagonal rock joints. The model is simulated by assuming all four sides of the rock medium as free surfaces. The paper elaborates the propagation of stress wave, expansion dynamics of gaseous products, and development of fracture, fragmentation of the medium and dissipation of energy due to damage.INTRODUCTIONDamage prediction of rock mass and its mean fragmentation size are of important to design blast parameters for a given explosive. Current blasting practice solely depends on empirical relationships between fragmentation sizes to those blast design parameters while mathematical descriptions of the physical laws governing the process of rock blasting are limited. A constitutive relationship based on properties of explosives and rock mass is of special interest because of its capabilities in describing the key features of rock fracture and fragmentation, resulting in understanding of the physical process involved in rock blasting. It is well known that blast-induced damage and fragmentation of rock mass occur due to detonation induced stress wave and product gas driven fracture propagation. Nevertheless, the fundamental mechanism of the failure process and the behavior of rock characteristics under these two different loading are not well understood in many cases, which are closely related to growth of fractures and interaction of cracks under different loading conditions.Continuum damage mechanics is considered to be appropriate to describe the failure process under such high-amplitude stress wave. Based on this approach, several theoretical models have been developed to analyze the dynamic damage of brittle material such as rock and concrete with microstructure (Chen, 1999; Taylor et al., 1986; Wu et al., 2004; Yazdchi et al., 1996). These models are mostly based on the theory of damage mechanics or fracture mechanics with some statistical treatment to incorporate random distribution of microcracks. In the application of fracture mechanics theory, sometimes it is difficult to estimate the micromechanical parameters such as crack density and fracture toughness in different modes. In this study, damage in rock material is evaluated according to the earlier model developed by Grady and Kipp (1980), which is a fracture model coupled with a material description for stress wave propagation to predict quantitatively fracture and fragmentation under explosive loading conditions."

Jan 1, 2015

By H. Wotruba, J. Heizmann

"The use of shotcrete is a mandatory means for rock support and therefore for safety in many underground mining operations. If shotcrete gets into the flotation feed though, it can negatively influence the flotation process. This especially occurs when sublevel stoping, cut-and-fill or room-and-pillar methods are applied because as the mining face moves on, formerly applied shotcrete layers are mined together with the ore.As shotcrete does not differ significantly from fluorspar ore in its physical properties it gets moved through the comminution process and is fed to the flotation plant like the ore. To prove the influence of shotcrete on the flotation process, a laboratory test series was conducted at the Unit of Mineral Processing (AMR) of the RWTH Aachen University. The shotcrete grade of the flotation feed was varied between 0 and 10% through addition of pure shotcrete. Flotation parameters and also reagent dosage were held constant apart from the addition of the pH regulator, which was dosed to reach a constant pH of 8 at the flotation start. Results showed that with increasing shotcrete grades in the flotation feed the fluorspar recovery as well as general mass recovery decreased. The enrichment factor of Fluorspar also decreased with increasing shotcrete grades in the feed.In an effort to eliminate the shotcrete contamination of the flotation feed, a feasibility study for use of sensor-based sorting prior to the comminution process was conducted. Rock sorting not only reduces the bad influence of shotcrete on the flotation process, but also reduces comminution costs. INTRODUCTIONShotcrete is used in underground mining on a regular basis. It is used for rock support and therefore to increase safety in the underground mining environment. In mineral processing the presence of shotcrete can cause difficulties for example in the concentration processes. In flotation the highly sensitive reagent mixtures can be disturbed by the chemical activity of shotcrete and therefore recovery rates and selectivity of the process can suffer.Shotcrete is a special form of concrete which is applied pneumatically with high velocities and is compressed by its impact energy. Since the process is especially suitable for work in difficult environments and overhead areas, it is established in underground mining for many years. Shotcrete is not only applied in pre-processing of the mines, but particularly of use for cut and fill, as well as room and pillar mining methods. There it is used to secure excavation chambers. When the mine face is secured with shotcrete and subsequently the mining continues, the applied shotcrete will automatically be mixed with the ore."

Jan 1, 2016

By J. Nsasi Bakambu

This paper describes an autonomous platform for exploration and navigation within networks of tunnels, as those typically found in underground mines and caves. In the exploration mode, a remotely located supervisor instructs the platform to move through successive sections of the network, gathering range data that is, then, concatenated into 2D/3D survey maps of the environment. In the navigation mode, the supervisor specifies high-level missions on the previously acquired survey maps. A motion planner, then, translates each mission into a set of consecutive navigation actions, separated by natural landmarks. Mission execution consists of detecting landmarks, self-localizing and performing the planned navigation actions.

May 1, 2003

By Mark B. Thorpe

Golden Star Resources started gold mining operations in Africa in 1999 after 15 years of exploration in South America. At the time, the approach to local assistance was through "alternative livelihood" programs and the donation of infrastructure to local communities. This was initially successful with local community support. However, with time and on reviewing the implemented projects, it became evident that the success was limited and many if the projects were either poorly used or in disrepair. Through a review of the options, we decided to develop a community assistance model driven by the communities themselves, while keeping control of the finances and the actual construction of the projects. Through the formation of the Golden Star Development Foundation, we began to support community driven projects for local economic development. The evolution of economic development projects continued over the next several years with the addition of project requirements for partnerships with government, and finally an evolution to a partnered turn-key piece of infrastructure that we hand over to an agency for operation and ongoing maintenance. We are currently working with outside partners to further our economic development activities in Ghana to the benefit of our stakeholders.

May 1, 2011

By M. Leroux, C. J. Martin, S. R. Rao, J. A. Finch

"The effect of nitrogen on the flotation separation of sulphides from complex ores from Brunswick Mining and Smelting (New Brunswick) and Mattabi Mines (Ontario) was investigated. The most significant finding was enhanced pyrite floatability after as little as 3 minutes nitrogen conditioning. This was used in a novel sphalerite/pyrite separation process developed on the Brunswick ore. After aeration and Cu/Pb bulk flotation in air using xanthate the slurry was nitrogen conditioned, xanthate added and the pyrite floated in nitrogen. As an example up to 70% pyrite recovery with about 20% sphalerite recovery was achieved. Sphalerite was recovered from the pyrite tailings and the pyrite concentrate by copper-activation, raising the pH to 10 and floating in air. About 65-70% recovery at 35-40% Zn grade was achieved compared to 25% Zn grade by the conventional route. The process offers a promising alternative to current practice which seeks to depress pyrite at all stages. A possible mechanism of the effect of nitrogen is presented. INTRODUCTIONUse of gases other than air in froth flotation has been reported from time to time. [Podobnik and Shirley, 1982; Lin and Metzer, 1975]. Of all the gases, nitrogen would appear to hold the greatest practical promise because of its easy availability and chemical inertness. It is used in froth flotation in chalcopyrite-molybdenite separation [Redfearn, 1983]. The use of nitrogen in polysulphide chalcopyrite. this case is mainly to reduce the oxidation of a compound (Nokes reagent) used as a depressant for There is no reported use of nitrogen in the flotation of other sulphide minerals."

Jan 1, 1988

By K. P. Plucknett, Z. Memarrashidi

WC-Co ‘hard metals’ are widely used in a variety of industrial applications due to their resistance to abrasive wear, in addition to their high hardness and toughness. However, in contrast to their mechanical properties, the corrosion response of these materials is relatively poor. In the current work the corrosion mechanisms of two WC-Co cermets are analysed, with 10 and 30 vol. % of the Co metal binder, in a 3.5 wt.% NaCl aqueous solution. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential, potentiodynamic polarisation and cyclic polarisation, together with systematic analysis of the post-corrosion solution chemistries using inductively coupled plasma optical emission spectroscopy. The corrosion potential and current density were determined, following Tafel extrapolation, allowing the calculation of the corrosion rates. It is demonstrated that continuous dissolution of the cobalt phase occurs during corrosion, which is a result of poor cermet passivation behaviour, and this response increases with the amount of binder in the cermet.

Jan 1, 2015