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By Y. W. Pan, Y. R. Liu

The disturbed natural rock mass tends to equilibrium state accompanying with non-equilibrium evolution process which has significant influence on the long-term stability of engineering structure. The deformation development in the non-equilibrium evolution is determined by two intrinsic processes, trend to equilibrium and damage development, which can be illustrated by evolution of excavated tunnel. Thus the creep and damage must be taken into account in study of non-equilibrium evolution process. Within Rice’s irreversible thermodynamics with internal state variable (ISV), the conjugate force function which equals to zero is a convex surface which divide the stress space into two parts, called equilibrium and nonequilibrium stress space respectively. The concept of effective stress of non-equilibrium has been proposed, in which the stress difference (d - d ) are the effective driving forces of non-equilibrium evolution process with hardening and damage effective. The formulations of inelastic strain rate and energy dissipation rate have been recast in the form of effective stresses. The inelastic complementary energy (ICE) is proposed to measure intensity of non-equilibrium evolution of material system. The specific equations of conjugated forces and kinetic equations of internal state variables are presented. The ICE and rate of energy dissipation are all calculated to be used to evaluate long-term stability of geo-engineering. The results show that rate of energy dissipation may be more convenience and flexible than ICE for internal state variable constitutive equation of rock mass.

Jan 1, 2015

By F. Rivard, M. G. Drouet, W. S. Ruff, P. Carabin

"In both the hot rotary-salt-furnace (RSF) treatment of aluminum dross and the cold ball-millsieving (BMS) treatment of zinc dross, enormous amounts of energy and recoverable metal are wasted and large amounts of greenhouse gas are produced. Such wastes and the environment pollution could be avoided by using the DROSRITE PLUS™ technology. Economic and GHG production comparisons between the presently used industrial treatment processes and DROSRITE PLUS™, supported by over one hundred tests conducted in Canada, the US and Europe, are presented. The savings, with DROSRITE PLUS™, would be about $191 and $418 per MT of aluminum and zinc dross, respectively.INTRODUCTIONDross is a material, which forms on the surface of molten non-ferrous metal, such as aluminum or zinc, during melting, metal holding and handling operations when the molten metal is in contact with a reactive atmosphere. Dross normally consists of metal oxides entraining a considerable quantity of molten free (unreacted) metal, and for economic reasons it is desirable to extract the free metal before discarding the residue. In the case of aluminum dross, recovery of the metal is usually carried out by treating the dross in a furnace at a high temperature (Peterson et al., 2002). By contrast, cold zinc dross is crushed in a ball mill followed by sieving to separate the coarse metal portion from the fine oxide residue.The conventional aluminum dross treatment process, using gas or oil-heated rotary salt furnaces (RSF), is thermally inefficient and environmentally unacceptable because of the salt slag and CO2 produced from the combustion of fossil fuels. In the past several years, a number of salt-free processes have been developed and some of these have found limited commercial use (Gripenberg et al., 1994; Lavoie et al., 1990). In all these dross treatment processes, heating of the cold dross in a rotary furnace requires an external energy input that varies between 375 and 2,500 kWh per (metric) tonne of dross. Molten metal separated during processing of the heated dross is tapped, and the remaining solid residue is discharged from the furnace."

Jan 1, 2012

The most expensive unit operation in the beneficiation of ores is grinding. The correct design of the grinding circuit is crucial to prevent unnecessary use of energy. Proper design and evaluation of SAG grinding circuits require the specific grinding energy, which is determined experimentally. The most common tests in SAG grinding are the Drop Weight Test, from the Julius Kruttschnitt Mineral Research Center (JKMRC) in Australia, and the SAG Power Index, from MinnovEX Technologies in Canada. The application of these tests to the same ore sample commonly produces different results. The work reported here aims at comparing the application of these two tests in the determination of the specific grinding energy for sulfide copper ores from Sequeirinho and Sossego deposits, Sossego Project, Companhia Vale do Rio Doce - CVRD, in Para state, Brazil.

Jan 1, 2007

By Hamid-Reza Manouchehri

Coarse particles flotation is controlled by detachment (particle hydrophobicity and flotation cell turbulence) For composite particles (the bubble may attach to good hydrophobic region, but the expansion of the three phase line of contact is limited. Hence, the equilibrium contact angle, characteristic of the hydrophobic region, may never be attained, and the force of attachment is decreased relative to that possible for homogenous hydrophobic surfaces.

May 1, 2013

By M. Saghaeian, R. Hejazi, Fakoor Sanat Tehran Company, H. Abedini, M. Zare

"Dewatering of final tailings is one the biggest issues in iron ore processing plants. Because of the fine and hydrophilic particles in the iron ore tailings, dewatering of such material is difficult and, in most of the cases, needs to be processed using expensive and complicated equipment. In this study, a novel method based on classification of small and large particles has been proposed to improve the dewatering performance of iron ore tailings. In the proposed method, a hydrocyclone has first been used to separate the fine and coarse fraction of iron ore tailings. Then, the coarse fraction (hydrocyclone underflow) is easily dewatered by using vacuum belt filter. Then, the fine fraction (hydrocyclone overflow) is primarily dewatered by using a high rate thickener. Finally, the thickener underflow is added to the bed of solids on the same belt filter, which is used for dewatering of hydrocyclone underflow. The efficiency of this method has been compared with other solutions for tailings dewatering including changing vacuum filtration parameters, using fabric with larger pore size, and using pressure filtration, all through laboratory scale experiments on the tailings of an iron ore processing plant in Iran. The results indicated the superiority of this method compared to the other ones, which increased the specific filtration capacity of the tailings by around 46%.INTRODUCTIONWet beneficiation of minerals requires a substantial amount of water to enhance the efficiency of the process. Used water should be recovered at the end of process to minimize shipping costs, meet contract specifications, and reuse process water (Wills and Napier-Munn, 2006). Dewatering equipment is usually divided into sedimentation (thickening) and filtration (pressure and vacuum) equipment, the choice of which depends on particle size, solid content of slurry, and material nature (Mular et al., 2002)."

Jan 1, 2016

By Somasundaran P., M. Vasudevan, Z. Dai, D. R. Nagaraj, T. Bhambani, P. Patra

Historically, efficient beneficiation of ultramafic ores has been challenging, partly due to a lack of clear scientific understanding of the effects of Mg silicates, particularly fibrous serpentines, on selective Ni recovery. Recent research at Columbia-Cytec as a part of a Vale JDP project has led to new insights into the mechanistic aspects of the adverse effects of Mg silicates. Our research has provided strong evidence to support the hypothesis that the adverse effects of Mg silicates are mediated through their large influence on pulp rheological properties, far more than any other pathway. The severity of the effect of Mg silicates is predominantly dependent on the aspect ratios of Mg silicates. For example, the pulp viscosity increases dramatically with increase in the fibrous nature of the gangue mineral leading to poor Ni separation. Various ways by which the suspension rheology affects flotation sub-processes, with implications for remedy are discussed. The insights and results have served to develop (or construct) a phenomenological model to adequately explain all of the ore flotation data, particularly the Mg silicate transport to the froth phase and the concentrate.

Jan 1, 2011

By Boris Yacksic, R. W. Bruce

"The flotation of a cassiterite ore with oleic acid will recover primary or rougher concentrates assaying over 10 per cent Sn, with a recovery of 80 to 90 per cent. These rougher concentrates cannot be up-graded to a marketable grade by normal reflotation. Experiments were conducted on low-grade tin ores, and a process was developed for up-grading the rougher flotation concentrates by a reverse flotation technique. The process was tested on a number of samples of ore from the Catavi mine in Bolivia. The results of these tests showed that a concentrate assaying 40 to 60 per cent Sn could be readily produced, with a recovery of 60 to 75 per cent of the tin in the ore."

Jan 1, 1967

By Shin-Kun Ryi

The world nowadays faces many challenges associated with excessive utilization of fossil, fuels, such as poor air quality and greenhouse gas emissions. Hydrogen appears to be an attractive alternative to the conventional, fossil, fuels with better energy efficiency and less environmental, impact. Pd and Pd-based alloy are the most often used membranes for hydrogen separation due to their superiority over other membranes. However, the stability of the commonly-used thin Pd-based composite membranes at high temperatures still, remains a big challenge. In this presentation, we will, report our progress on thin Pd-Ru alloy composite membrane by electroless plating high temperature applications.

Jan 1, 2010

By A. A. Brant

"Improving geological and geophysical evaluation should serve to reduce the early-stage risk assessment and there-by contribute to exploration expenditure stimulation. The limitations of present-day methods are reviewed, particularly as to anomaly causes, depth penetration and quantitative physical interpretative abilities. Some of the problems now under study are discussed. Future developments expected include the treatment of quantitized geologic and geophysical data, as well as continuing attempts toward computerized interpretation."

Jan 1, 1967

By Robert B. Parsons

"The February 18, 1987, Federal Budget contains a proposed amendment which would simplify somewhat the ""successor corporation"" rules in the Income Tax Act. Despite this amendment, though, the important successor rules will continue to be relatively complex.IntroductionThe February 18, 1987, Federal Budget papers propose an income tax amendment whereby the so-called ""successor corporation"" rules would be revised by removing the present provision which limits the application of these rules to a maximum of two ""successions"". The successor corporation rules represent one of the most complicated sets of rules in the Income Tax Act. This month, Tax Notes seeks to explain these rules and the proposed amendment in simplified terms.Basically, the successor rules provide a mechanism for transferring unused exploration and development expenses from one taxpayer to another , in specified circumstances. The aforementioned limitation of two successions refers to the rule which allows a maximum of two such transfers with respect to any particular pool of deductions."

Jan 1, 1987

By F. Mallozzi

"With the requirements of air pollution codes becoming more and more critical, the role of the ventilation engineer in industry has become an extremely important one. The ventilation engineer must provide the expertise for the selection of equipment and the design of systems which will reduce pollution to an acceptable level. Because pollution control systems involve considerable capital and operating expense, he must have the ability to select, from a wide range of products, the collector which will provide the required performance with a minimum of down time for maintenance. This paper discusses the principles of wet collection and the forces used to separate particulate matter from a gas stream. Important factors in the selection of equipment, such as collection efficiency, horsepower requirements and water consumption for the various types of collectors, are discussed in detail, as well as the construction features normally incorporated to circumvent potential problems."

Jan 1, 1971

By K. Sun

The exothermic behavior of the intermetallic reactions inside an Al-Mn metallic powder compact and its assimilation fundamentals in molten aluminum were examined. In this study cylindrical compacts were manufactured and tested. The experimental work involved simultaneous temperature measurements of three thermocouples as well as detection of the apparent weight of the cylindrical specimen during its assimilation in liquid aluminum. The details of the intermetallic reactions prior to the compact complete disintegration were investigated by microscopically studying the morphology and local composition in a partially reacted compact. The variation of manganese concentration in the melt was determined by chemically analyzing the samples taken from the molten aluminum at specific time intervals. The exothermic reaction increases the compact's temperature above that of the liquid aluminum. In tandem with this exothermic reaction, the compact is suffering a swelling action. This swelling action disintegrates the cylindrical specimen, which is assimilated into the liquid aluminum. The intermetallic reactions proceed in a stepwise manner. Both the bath temperature and the compact composition impact on the exothermicity of the intermetallic reactions. However, when the amount of Mn in the compact is greater than 75-wt%, the maximum centerline temperature rise is slightly reduced as Mn amount increases.

Jan 1, 2004

By F. Cheuk, E. Krause, V. G. Papangelakis, G. A. Moldoveanu, S. Abendschein

Systematic studies have been conducted at the University of Toronto in order to evaluate lanthanide extraction from clay minerals from different geographical regions. It was found that rare earth elements (REE) are easily recovered into an aqueous solution via an ion exchange mechanism by leaching with electrolyte solutions containing monovalent cations under ambient conditions. In this study we assessed extraction levels of individual REEs as a function of initial clay composition and leaching conditions. It was found that, in spite of variations in clay origin, all clays consistently reached peak REE extraction levels with fast kinetics. However, terminal extractions were clay-specific. The feasibility of using seawater as a leaching solution and potential synergies with ammonium sulphate as a lixiviant was also investigated. Seawater was found to be inferior to using ammonium sulphate, and provided no observable synergy in leaching performance when used together. The aqueous phase trapped in leached clays was shown to contain significant amounts of REE, as demonstrated in clay washing tests. Techniques to improve the REE concentration in leachate through process variations were investigated. However, it was found that most techniques capable of increasing REE concentrations in the resultant leachate also resulted in reduced REE extraction.

Jan 1, 2014

By A. J. Neale, B. C. Flintoff

"A review of the dynamic rod mill-ball mill grinding circuit simulator developed at the University of Alberta, highlighting the modular structure and open-ended design, demonstrates the ease with which classical feedback control strategies can be designed and implemented. Various open loop simulations are presented to demonstrate the highly interactive nature of the grinding circuit and to indicate where potential control problems may be encountered. Closed loop simulations are examined, beginning with the basic SISO classical feedback control of circuit product size. Further improvement in the grinding circuit performance in the presence of various disturbances is realized through the application of a classical MIMO feedback controller. As an example of advanced (multivariable) control, static decoupling is implemented and shown to provide additional improvement in overall circuit performance.INTRODUCTIONIt has long been recognized in the processing industries that a dynamic process simulator is an indispensable tool in the design and evaluation of automatic control schemes. In mineral processing the lack of these simulators is felt to have been a major hindrance to the widespread implementation of effective process control systems. In particular dynamic simulation is a necessary precursor to any study of modern (as opposed to classical) process control methods. This paper discusses the development of a dynamic simulator that can be used to study various feedback control strategies. The simulation software provides a powerful educational tool for those individuals interested in grinding circuit control."

Jan 1, 1988

By N. Hwang

There has been increasing interest in the use of robotic machines, and several prototype robotic machines have been developed to automate the grit-blasting process for the purpose of steel bridge maintenance. To utilize such a robotic grit-blast machine effectively, the first consideration is automating the determination of the rust surface area to blast, on the basis of standards of practice, in a rapid manner. This study aims to propose a method to rapidly and accurately determine the rust surface area on steel bridges to blast, with consideration for the standards of practice, from images acquired via a blasting machine. The first step is to perform a color space conversion to transform the input image from a red/green/blue (RGB) color space to a hue/saturation/intensity (HSI) color space. The next step is to detect the presence of rust, using pixel-level classification via the C4.5 decision tree algorithm. Then it is necessary to confirm the blasting area by verifying whether the rust detection result satisfies the specified criteria on the basis of standards of practice. The proposed method was validated on 39 test images with various characteristics with respect to the degree of rusting and rust distribution type. The experimental results showed that the average accuracy rate of rust area classification was about 97.63%, and the success rate of the final decision of blasting area determination was 100.00% for 39 test examples. The whole processing time took an average of only 0.86 seconds per image. The preliminary results demonstrated that the proposed method not only determined whether rust was present in an image and the amount of rust but also indicated whether blasting was necessary, and, if necessary, it rapidly specified the rust surface area that should be blasted on the basis of standards of practice. The proposed method could be successfully incorporated into a robotic grit-blast machine.

Aug 1, 2013

By W. E. Roscoe

The probability of making an exploration discovery in Canada can be calculated from Derry's (1970) data on exploration expenditures and number of discoveries over the last nineteen years. Considering an average exploration "try" to be $30,000, the probability of a discovery with one try has decreased tenfold from about 0.01 in 1951 to 0.001 in 1969. A plot of these probabilities can be extrapolated to the future, giving a 1969-71 three-year average probability of 0.00096 with 90 per cent confidence limits of 0.00042 and 0.00153. Using this probability, various calculations can be made, such as (1) the probability of making at least one discovery for any given exploration expenditure, (2) the probability of ultimate ruin or survival of the exploration investment process and (3) the expected value of an exploration investment. There is a critical minimum amount per discovery that must be re-invested in exploration, no matter how large the original investment is, for exploration to survive at all in the long run. Currently, this critical minimum is $31,200,000 with 90 per cent confidence limits of $19,600,000 and $71,400,000.

Jan 1, 1971

By Jan E. Nesset, L. Paul Staples

"High Gradient Magnetic Separation (HGMS) technology, although developed over 2 decades ago, has not been widely applied to the separation of sulphide minerals. Under conditions of strong magnetic field gradients, weakly magnetic minerals such as chalcopyrite (CuFeS2) and marmatite (Zn(Fe)S, sphalerite with iron in solid solution) behave paramagnetically and can be effectively separated from diamagnetic minerals such as galena (PbS). The application of this technology to the separation of Cu-Pb and Zn-Pb bearing streams in the treatment of fine grained complex sulphides may in some cases be more effective than separation by flotation. A 2 TPH Sala HGMS pilot plant was operated at Brunswick for a nine month period, ending in March 1995. The testing demonstrated the mechanical reliability of the technology, the consistency of operating results and the scale up from laboratory testing. HGMS is seen as a complimentary technology to flotation, best suited to performing those separations of galena (and other diamagnetics) which flotation does not do as well.IntroductionBackgroundSince the turn of the century, the magnetic character or magnetic susceptibilities of minerals have been determined with increasing precision and accuracy. Figure 1 illustrates specific magnetic susceptibilities of some common minerals. As long as susceptibility ranges do not overlap, separation is possible.In 1937, the principle of using a magnetizable matrix material in a magnetic field to increase both magnetic flux density gradients and number of capture sites for susceptible minerals was first applied (Frantz). It was not until the 1970's, however, that the genuine development of wet high gradient magnetic separation began with the introduction of very fine matrix materials to the magnetized volume of large solenoid magnets. Today, dozens of HGMS units purify, filter and separate minerals, primarily for the removal of iron stained minerals from clays used in the paper coating and china clay industries and for the recovery of fine titanium and iron oxides in the iron ore industry. Only the Garpenburg mill in Sweden is currently applying a continuous HGMS machine to separate complex sulphide minerals; upgrading a lead concentrate since 1988."

Jan 1, 1996

By M. M. C Jiménez, D. C. Buzzi, D. C. R. Espinosa, J. A. S Ténorio, G. F. R Oliveira

In this work the extractive and selective capacities of solvent extraction synergistic systems to recover nickel and cobalt were evaluated. The liquor used was from the high pressure acid leaching process (HPAL). Initially the industrial liquor, processed from lateritic ores, was analyzed to identify the concentrations of the metals. Experiments of synergistic solvent extraction were performed later. The extraction liquid-liquid was carried out with a mixture of Cyanex 272 (CY) and Ionquest 290 (IQ) extractants. The process was executed with the temperature of 65 ºC, pH of 5.2 and the ratio aqueousorganic 2:1. Systems of 80% kerosene and CY 20%, CY 16% - IQ 4%, CY 12% - IQ 8%, CY 8% - IQ 16%, CY 4% - IQ 16%, IQ 20% were studied during 20 minutes. The results of this paper showed that the mixture of these two extractants doesn’t improve significantly the recovery of nickel and cobalt from liquor.

Jan 1, 2014

By Mory Ghomshei

Pebble Creek Geothermal Power project is associated with a massive recent volcanic eruption in Southwestern British Columbia Canada. Slim holes drilled to depths 1100 m in the prospect area, show very high temperature gradients around 80?100?C/km. The temperature and chemistry of the Pebble Creek hot springs indicate the possibility of a steam reservoir in the prospect area. In addition to high temperature gradients, presence of host rocks with high permeability, along with abundance of recharge waters (from the Lillooet River) provides clear signature of a high-grade geothermal power reservoir at depth 2000 to 3000 m. Data show that over five hundred Megawatt of green power can be generated from the prospect area in a commercially viable manner. The generated power will be base-load, which in comparison with large hydro has the advantage of lower capital costs and a significantly smaller footprint. The final hurdle to overcome, before starting the development phase, is deep exploratory drilling for resource confirmation. This paper is a summary of the data available on the Pebble Creek geothermal power prospect, presented in the context of viability of the resource for large-scale commercial power generation.

Aug 1, 2013

By Qing-Xun Low

Ni current collector has excellent electronic conductivity and mechanica, properties. However, nicke, cannot be used in H2S-containing syngas SOFCs due to sulfur poisoning and coking. Copper coated nicke, is prepared by electrochemica, deposition. XRD, SEM, and EDX techniques are used to characterize the samples. After high temperature treatment in syngas containing, the coated samples exhibit high resistance of coke formation and sulfur corrosion compared to pure nickel. Therefore, copper coated nicke, is a promising anode current collector for H2S-containing syngas SOFCs.

Jan 1, 2010