Search Documents

By J. W. Baker

"The Kerr-Addison mine is on the northeast shore of Larder Lake in the township of McGarry, District of Timiskaming, Ontario. It lies just south of the highway leading to the town of Kirkland Lake, 25 miles to the west.The property was first staked in the summer of 1906, by a party of prospectors led by a Dr. Reddick of Ottawa. Subsequent assessment work resulted in the erection of a 20-stamp mill in 1908. Gold from this mill was used in the first gold coins to be minted in Canada. The operation did not prove successful, however, and mining was suspended. In 1914 a consider-able amount of underground development was undertaken by the Associated Goldfields Co., without success.In 1936 Kerr-Addison Gold Mines Co. carried out large-scale sampling from four adits driven into the hillside at the mine. Results were not satisfactory, but it was decided to drill one last deep diamond drill hole from surface. The hole cut a wide section of gold ore. With this encouragement, further development outlined a large tonnage of ore, and a 500-ton mill was put into production in May, 1938. In 1939, its first full year, the mine produced 54,480 ounces of gold and 2,732 ounces of silver. By 1955 the mill had been expanded to a rate of 4,549 tons daily, and in this year 427,193 ounces of gold and 23,490 ounces of silver were produced.From 1938 to the end of 1955 the total production, from 17,473,797 tons milled, has been 3,607,462.74 ounces of gold (0.2064 ounces per ton), and 182,278.56 ounces of silver, with a total value of $131,073,037."

Jan 1, 1949

By C. Gravel, A. Fathi, P. Rivard, G. Ballivy, Z. Moradian, M. Quirion

Knowing shear mechanism of discontinuities under monotonic and cyclic loading conditions is a key factor in stability analysis of rock slopes and rock foundations. In this paper, the effect of cyclic loads on the shear mechanism of joint asperities is described. For this purpose, a fresh tension-split joint from a granite block was used as a reference and thirty five mortar replicas were fabricated. Cyclic shear tests were conducted on replicas under low values of constant normal load (CNL) using a servo-controlled loading system. Tests were performed in two consecutive steps; load-controlled and then displacementcontrolled. In the load controlled part, after initial increase of shear stress to 0.25 MPa, the test was stopped for 2 minutes, then increased to 0.5 MPa, and finally decreased to 0.25 MPa. This process was repeated ten times. At the end, the test was continued up to 10 mm shear displacement under displacement-controlled loading in order to pass the peak shear strength and reach the residual strength. Characterizing joint surface and modeling of involved asperities during the tests was undertaken using a Matlab code developed with new mathematical expressions. The algorithm used in the code is based on three-dimensional coordinates of the scanned joints’ surfaces before and after the test. It was found that a high percentage of degradation happens during the first cycle of loading and during the other cycles, degradation occurs gradually. While comparing tests conducted in monotonic and cyclic loading conditions, it was observed that under low number of cycles, the pronounced mechanism is consolidation of the joint surfaces. This consolidation increases contact areas and, therefore, shear strength parameters.

Jan 1, 2015

By C. E. Cairnes

The Slocan mining camp in Kootenay district; British Columbia; has long been noted for the great number of its silver-bearing deposits; and for the success that has; in many instances; attended their development. The orebearing area lies east of Slocan lake and mainly within a radius of 6 to 8 miles of the mining town of Sandon. Within this limited area 135 or more properties have shipped ore in quantities of from 100 tons or less to more than 500; 000 tons; and with a total value in silver; lead; and zinc ranging from a few hundred dollars to well over $10; 000; 000. Of the three metals; silver has easily ranked first in value; with lead second and zinc third. Zinc production; however; made slow progress in the early years; and with . the exception of the Lucky Jim mine; and a few others where high-grade ore could be readily hand-sorted; was a detriment to the silver-lead ores until improved methods of separation enabled it to take an important place in the mineral production of the Slocan.

Jan 1, 1954

By C. W. MacLeod

LOCATION The Goudreau gold area in Ontario extends from a point a short distance south of the main line of the Canadian Pacific railway, at Lochalsh, in a south-westerly direction to the Magpie river. It crosses the Algoma Central & Hudson's Bay railway at Goudreau station, 177 miles north of Sault Ste. Marie. The area is roughly 25 miles in length by 6 miles in width. The potential gold formation is much more extensive but little prospecting has been done outside of the limits mentioned. The actual continuous area of Keewatin formation, in which gold has been found, is one of the largest in Ontario. ACCESSIBILITY Probably no mining area in a similar stage of development has had the excellent transportation facilities which Goudreau enjoys. This field is traversed in part by the main lines of the Canadian Pacific and Algoma Central railways. The Provincial Government has constructed 22 miles of road through the heart of the camp. Sixteen miles of this road is suitable for motor car traffic and several cars and trucks are in constant service.

Jan 1, 1926

Aur Resources is Canada's leading copper mining company with producing mines and development projects in North, Central and South America. Copper production from Louvicourt Mine in Quebec, Quebrada Blanca and Andacollo Mines in Chile was a record 245 million pounds in 2001. Located 600 km North of Montreal, Louvicourt Mine is a joint venture between Aur Resources (30%), Novicourt Inc (45%) and Teck-Cominco (25%). Aur Resources is the mine operator with 280 employees working to produce a copper and zinc concentrate. In operation since 1994, the mine has produced a total of 12,606,000 metric tonnes of ore grading 3.6% Cu, 1.5% Zn, 26 gr./m.t. Ag and 0.9 gr./m.t. Au. This highly mechanized mine reached full production in August 1995 at 4,000 tpd. From 1996 to 2001, the average mine production rate was more than 4,300 tpd. The Louvicourt Mine continued its record of solid performance in 2002 and is expected to continue to do so for the balance of its 2.5 years mine life.

May 1, 2003

By Barry D. Simmons

"A well-defined approach is essential to ensure the long-term success of a regional exploration program. Teck's approach in eastern Canada is designed to fulfill corporate objectives while recognizing certain unique parameters for exploration in the area. The elements of this approach include clearly defined objectives, technical considerations and personnel policies, all of which are equally important. The goal is a significant discovery before the mid-l990s and the company is confident that this target will be achieved.IntroductionAs one of Canada's oldest continuously operating mining companies, Teck Corporation traces its roots to Kirkland Lake, Ontario, with the development of the Teck-Hughes gold mine in 1913, later supplemented by production from the Lamaque gold mine in Val d'Or, Quebec. Control of the company was acquired by Temagami Mining Company, part of the Keevil Mining Group, in 1959. Credited as one of the first discoveries made using airborne geophysics, the Keevil Group had recently found the small but very high-grade copper deposits at Temagami, Ontario. These developments in eastern Canada formed a foundation for remarkable growth and Teck's present status as one of Canada's most successful and respected mining companies.Teck currently operates successful mining ventures across Canada and has international exposure through its association with Cominco Ltd., M.I.M. Holdings Limited and Metallgesellschaft AG. Operations in eastern Canada, however, remain an important component of Teck's ongoing success. The David Bell and Williams mines at Hernlo, Ontario, are Canada's lowest cost and largest gold operations, respectively. The Niobec Mine at Chicoutimi, Quebec, is North America's only significant producer of niobium. Teck maintains a 45070 interest in Golden Knight Resources Inc., part owner of the successful gold mining operation in the Casa Berardi area of northwestern Quebec. As a significant shareholder in Aur Resources Inc. and as a part owner, Teck is participating in the development of the Louvicourt deposit, a major base metal discovery at Val d'Or, Quebec."

Jan 1, 1992

By Y. Nishida, Y. Nara, T. Ishida

Understanding time-dependent deformation and fracturing in rock is essential, because the information of the long-term stability of rock is required for many sub-surface structures excavated in a rock mass. Time-dependent fracture propagation has been invoked as a potential key mechanism responsible for the increase in seismicity preceding earthquake ruptures. In engineering projects and in preventing natural hazards, the study of time-dependent fracturing is necessary. Subcritical crack growth is one of the main causes of time-dependent fracturing in rock. For silicate rocks, subcritical crack growth has been investigated by various researchers. It has been clarified that surrounding environmental conditions (temperature, humidity, and existence of water) have strong influence on subcritical crack growth in silicate rocks. Therefore, the information of subcritical crack growth in silicate rocks has already been enough. On the other hand, information of subcritical crack growth in carbonate rocks is not enough. Especially, the influence of surrounding environment on subcritical crack growth in carbonate rock has not been clarified yet. In this study, we investigate subcritical crack growth in carbonate rock experimentally using a fracture mechanics testing method. Marble obtained in Skopje in Macedonia is used as a carbonate rock sample. The Double Torsion method is used to measure the crack velocity and stress intensity factor. Especially, influence of water on subcritical crack growth in Macedonian marble is investigated. It was shown that the crack velocity in water is much higher than that in air at the same temperature. Based on the results of subcritical crack growth measurements, the long-term strength is evaluated for marble. It was clarified that the long-term strength in water is lower than that in air in marble. It is concluded that water has a remarkable influence on subcritical crack growth in marble. It is also considered that the long-term stability of carbonate rock masses should be ensured in a dry environment.

Jan 1, 2015

"The Dome Mine, located in South Porcupine Ont. has been in operation since 1910 and is owned and operated by Placer Dome Inc. The current milling facilities were constructed in two phases with the first being commissioned in 1982. It consists of a grinding, gravity separation, thickening, and leaching circuits. The second phase was commissioned in 1988 with the addition of the CIP, stripping, electrowinning, and carbon regeneration circuits.It is now common practice in the gold processing community to add liquid oxygen to leach circuits to increase both recovery and kinetics. Along with these benefits the metallurgical group at the Dome realized the potential to replace compressed air with liquid oxygen as a source of oxygen for the dissolution of gold. A plant trial of liquid oxygen was undertaken during the fall of 1991. The results of this first test were favourable enough to warrant further investigation, and a second plant trial was conducted in December 1991.The data generated as a result of each trial revealed that oxygen could be economically substituted for compressed air as a source of dissolved 02. The energy savings in required horsepower enabled a rapid payback period. Thus the project was approved in the spring of 1992 and l should be operational during the final quarter of 1992. INTRODUCTIONIn a continuing effort to reduce operating costs and improve recovery at the Dome mill it was decided to investigate the feasibility of adding liquid oxygen (02) to the leach circuit. It is now common practice in the gold processing community to add 02 to the leaching process to increase both kinetics and recovery. It was anticipated that an increase in kinetics would allow us to eliminate one or more leach tanks while maintaining acceptable recoveries. The metallurgical group felt that along with these benefits, the potential was also there to reduce power consumption through the reduction in the processing of compressed air which is quite costly (12 cents/1000 cubic feet per minute in 1991)."

Jan 1, 1993

By F. Musuka, D. Jenkins, A. Keyes

BHP Olympic Dam operates a Direct-to-Blister copper flash smelting Furnace (DBF) and an Electric Slag Cleaning Furnace (ESCF). Tapping blister copper from these furnaces via tapholes is a routine task carried out by trained personnel. Blister tapping is a high-risk activity with personnel operating in close proximity to molten metal. BHP’s risk management framework has identified taphole integrity as key to managing the potential for loss of molten metal containment and molten metal – water steam explosion, both of which have the potential to cause multiple fatalities. As part of the focus on managing this risk, since 2017, a dedicated Taphole Development Team has been embedded in the operation to run an accelerated improvement program focused on safely and sustainably embedding an improved taphole design with greater integrity. The program of works includes selecting and testing of new materials as well as improving operating discipline by collaborating with tapping personnel to convert their knowledge into codified condition monitoring and operating strategies. Computational fluid dynamics (CFD) is being used to derive critical risk controls, and to develop live-alerts to infer excessive refractory insert wear. To date, improving DBF blister taphole mudgun clay has led to more consistent drilling depths and subsequently reduced oxygen lancing requirements, resulting in improvements in taphole insert service life. On the ESCF, insert performance testing and development of a new taphole condition monitoring strategy, is being used to increase taphole insert tonnages to more sustainable levels. Operations personnel have been closely involved in different phases of the change management, this has led to standardization of tapping practices for both furnaces, and improved ownership of the proposed changes. The paper discusses the maturity in taphole integrity risk management as a result of recent and ongoing developments. It then provides an overview of future taphole developments proposed at Olympic Dam. INTRODUCTION Tapping operations at Olympic Dam and learning from significant events The Direct-to-Blister furnace (DBF) at Olympic Dam was built with a conventional design blister taphole, which was designed for manual oxygen lancing and clay stopper bar plugging tapping operations (Campbell, 2005). Manual tapping is a high-risk activity, where personnel work in close proximity to molten metal, and molten metal personal protective clothing and equipment must be used. Opening tapholes by oxygen lancing is a skilled activity and unintentional damage to the taphole inserts can occur. Since 2008, a Mudgun and Drill unit has been developed and trialled and is now in use on the DBF blister tapholes, to remove personnel from the line of fire when opening and closing tapholes. This has the additional benefit of reducing lancing damage to taphole inserts. A new taphole design labelled the Modular Blister Taphole (MBTH) was developed at Olympic Dam for the Mudgun and Drill operation. The intent of the design was for mudgun clay to fill the entire tapping channel when plugging after a tap. The drill would then drill through this clay plug to open the taphole.

Jan 1, 2019

By H. W. McGerrigle

The St. Lawrence Valley of Quebec lies in an earthquake danger zone, the main centers of which appear to be Murray Bay, Montreal and Quebec City. This paper compares conditions in this "earthquake zone" with those of other, currently more active, earthquake zones of the Earth, deals briefly with the mechanics of earth movements and outlines the means by which earthquakes are re-corded. An account is then given of the earthquakes which have occurred in the Province of Quebec -from that of 1534-35 to the earthquake of 1925. A 50-year frequency cycle is implied. The general conclusion is that the 11robability of future earthquakes should be given more consideration in the construction of buildings in the St. Lawrence Valley region.

Jan 1, 1966

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By M. Boher, J. Lehmann, M. C. Kaerlé

"In the production of high quality steel, the understanding of the interactions between liquid steel and refractories and of their effect on steel purity and cleanness are becoming more and more important.An experimental study has been per-formed in order to estimate the importance of the reaction between a MgO-based tundish refractory and an Al-killed steel. The results show a pollution of the liquid steel:•the silicon content of the liquid steel increases due to the reduction of the silica of the refractory by the aluminum contained in the steel; and•a reoxidation of the steel occurs and the formation of an oxide layer on the refracto-ry, mainly composed of spinel crystals and of Ca-aluminates is observed.The transfer mechanisms of the various elements are analyzed."

Jan 1, 1997

By The Satff

"TEXADA Island is situated in the Strait of Georgia, about 100 miles northwest of Vancouver. The property of Texada Mines Ltd. lies on the southwest coast of the northern end of the Island. A part of the ""Sunshine Coast,"" the climate is moderate, with about 30 inches of rain during winter months and relatively dry summers. Texada has been shipping high-grade magnetite concentrate continuously since 1952 to Japanese ore buyers. In 1959, a 3,000-foot tunnel was driven just above sea level to explore the possible downward extension of known orebodies then being mined by open pit. In January of 1961, because the open-pit operations had a limited life, C. C. Huston and Associates were brought in as mining consultants to do a feasibility study on the possibility of going underground for production. This study was completed in March, 1961. With the completion of the report, the Company went to Japan seeking a ,long-term contract to justify the capital outlay necessary for setting up an underground operation. Concurrently, underground diamond drilling revealed more ore, and the Company planned some modifications to the concentrator for increasing the copper recovery. By November, 1961, a ten-year contract was signed with Japanese ore buyers for the sale of 450,-000 long tons of concentrates beginning in October, 1963. Since that time, the Company has built its own 65 000-ton ore carrier and an additional three-year contract has been negotiated, with an annual tonnage increase of from 450,000 to 550,000 tons."

Jan 1, 1967

By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By M. H. Allan

"This paper presents the geographic and geological setting of Saskatchewan Power Corporation's Poplar River Mine in south-central Saskatchewan, about 8 miles from the U.S. border. Generally the mine, which is being expanded to four million tons per year, is in an extremely disturbed geological area with severe dewatering problems. The lignite coal, which is strip mined, is supplied directly to an electric power generating station by means of a 7-mile unit-train private railroad.A number of unique reclamation and socio-economic problems were encountered because of the proximity to the U.S. border and because of the lack of experience of the regulatory authorities in projects of this kind. These are described in some detail, as well as the performance of one of the largest draglines in Canada. IntroductionThe Saskatchewan Power Corporation is a publicly owned utility which has the franchise to supply electricity and natural gas to all customers within the boundaries of Saskatchewan.Saskatchewan is a province which can almost be divided in two: the populated southern portion, principally devoted to farming, and the northern portion which is mostly on the Precambrian Shield and consists of lakes, rocks and muskeg. This portion is largely uninhabited except for a number of small villages. However, in the last few years there has been considerable mineral exploration and development, notably for uranium. This has helped considerably in the diversification of the basic agricultural economy of the province.Saskatchewan consists of 251,700 square miles, 761 miles north to south and an average of 335 miles east to west. It has a population of approximately 960,000, giving a population density of four persons per square mile. The Saskatchewan Power Corporation supplies 357,249 electrical arid 221,378 natural gas customers."

Jan 1, 1982

The control of AG mills fed by ores with harder and softer components can be challenging due to the sensitivity of the mill to the ratio of hard to soft components. The mills at LKAB?s iron ore operations are generally well controlled, but there are periods when the throughput falls off dramatically, due to a loss of mill filling. As the ore is upgraded in the sorting plant through magnetic separation prior to milling, this presents an opportunity to manipulate the feed blend in advance. In order to assess this opportunity, a fullscale mill charge was dumped and assayed by size to quantify the build-up of competent waste in the mills. This was supplemented by pilot and locked-cycle laboratory tests at a wide range of feed blends in order to facilitate the development of an appropriate multi-component AG mill model. This paper reports the experimental campaign requirements and methodologies, as well as the major outcomes from analysis and modelling exercises using the industrial, pilot and laboratory multi-component data.

Jan 1, 2012

By J. E. Dutrizac, J. M. Zinck

Ferrihydrite is often the initial precipitate resulting from the rapid neutralization of Fe(III) sulphate solutions, and it seems to be a major constituent of zinc plant neutral leach residues. The most important parameters affecting ferrihydrite precipitaton are temperature, solution pH and the neutralization rate. Low temperatures and rapid neutralization rates yield poorly filterable ferrihydrite, whereas higher temperatures and slower neutralization rates produce readily filterable precipitates; in all instances, however, the precipitates are two-line ferrihydrite. Significant amounts of Zn are incorporated in the ferrihydrite precipitates, and the Zn contents increase with increasing Zn concentration, pH or temperature. Generally, the sulphate contents of the precipitates decrease as the Zn contents increase, and this may indicate that the Zn is adsorbed on the ferrihydrite. Discrete Zn phases were not detected. Neither Cd nor Tl is precipitated with ferrihydrite, although thallium jarosite co-precipitates with ferrihydrite at high Tl concentrations and elevated temperatures. Virtually all of the Sn added to the solution precipitates with the ferrihydrite, but the tin is believed to be present as intimately admixed amorphous SnO2.nH2O. Although selenite extensively precipitates with the ferrihydrite, selenate remains mostly in solution, likely because of the close similarity of the SeO4 2- ion to the SO4 2- ion which is present in high concentrations and saturates the available sites for anion adsorption.

Jan 1, 1998

By Y. P. Wu

Steeply dipping seam refers to the coal seam with dipping angle in the range of 35?55°, which is well recognized to be very hard to mine by the mining industry all the world. In the last two decades, some fundamental researches were focused on the strata behavior of long-wall panel, complicated rock mass breaking process of the steeply dipping seam, overburden stress field developing and evolution, rock strata breaking and moving process, rock structure stability mechanism and control. Results show that it?s presenting macro stress arch-shell (MSAS) of the stress distribution of the overlying rock in steeply dipping seam. The MSAS is the spatial distribution of intensity envelope line under the strength criterion and has the geometry shape asymmetry as well as the stress distribution heterogeneity. The arch- shell base will forward as the working face mine forward and the shell roof will extend to higher overlying strata above the gob. In this paper, the stress arch-shell analysis model and coordinate system were established and analyzed the inclined masonry structure at different zone. Analysis results show that the rock damage at the key part of the arch-shell is the main factor which causes whole overlying rock structure failure. The rock structure instability modes have tension instability of the shell roof, compression-shear instability of the shell shoulder and composite instability of the shell base, meantime, instability coefficient is proposed to determine instability condition. The above research results enrich the complex coal seams mining theory and provide a theoretical basis for mining safely and efficiently in steeply dipping seam.

Aug 1, 2013

"THE Canadian Advisory Committee on Coal Research, which is commonly known as CACCR, has been in existence for the past five years and has held annual meetings during that period. This Committee is comprised of representatives from: the Mines Branch, Fuels and Mining Practice Division, Ottawa; the Geological Survey of Canada; the Dominion Coal Board; and the Provincial Research Councils and Foundations. It embraces all coal research in Canada that is sponsored, for the most part, by Government funds.To bring the country's coal research activities to the notice of the Canadian coal industry, the Coal Research Committee of the Coal Division, C.I.M., passed a resolution at the 1964 business meeting in favour of recommending the publication of an annual research report prepared by the CACCR. The first such report was published in the September, 1964, issue of the C.I.M. Bulletin; the second appeared in the November, 1965, issue of the same publication."

Jan 1, 1966

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016