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By D. B. Dreisinger, M. Mokmeli, B. Wassink

Dissemination of selenium and tellurium in sulphide minerals results in the contamination of pregnant leach solutions and electrolytes in the hydrometallurgical treatment of sulphide ores and residues. The selenium and tellurium content of the copper sulphate-sulfuric acid solution may be reduced into insoluble precipitates of copper selenides and tellurides using cuprous ion. This study presents the use of the thermodynamics and kinetics for the removal process of selenium and tellurium in real life application. Dominant species of selenium and tellurium in acidic copper sulfate solutions were identified and the reduction rates of species were compared. The findings were applied to industrial conditions by modeling the Vale’s CRED (Sudbury, Canada) plant’s selenium and tellurium purification circuit. Rate reducing factors on selenium and tellurium removal were identified and discussed.

Jan 1, 2014

By E. L. Jones

THE concentration of tin in the tailing from Sullivan ore has been de-scribed by H. R. Banks, superintendent of the Sullivan concentrator, in a paper presented at the annual meeting of the B.C. Division of the Institute in October, 1941(1). The reduction of the concentrate EARLY EXPERIMENTAL WORK Experimental work on the smelting of Sullivan tin concentrate was done in Trail. Preliminary tests in the laboratory indicated that the concentrate could be successfully treated in an electric furnace. A small electro-thermic pilot plant was built and, at the same time, reduction tests were made in an oil-fired reverberatory furnace. Both types of treatment gave satisfactory results. It developed that no fluxes, other than those already in the ore and in the ash of the reducing agent (either coke or coal), were needed. By using an excess of iron, a complete recovery of the tin in the slag was obtained, but with 20 to 30 per cent iron in the tin. A counter-current treatment was thus indicated, viz., the primary slag was first treated with hard-head (iron-tin alloy) from the refining and final slag smelting, producing tin with 2 to 4 per cent Fe. This secondary slag was subsequently treated with scrap iron to produce tin-iron alloy, and a final slag low enough in tin to waste. By following this line of endeavour, a tentative flow-sheet was drawn up and a successful operation was established. Without resorting to electrolytic refining, a metal comparable in purity to standard tin was produced. Metallurgical results and operating costs were found to be very similar with an electric furnace or a fuel-fired furnace. 'However, electric furnace smelting was chosen because the furnace required was smaller, and because some doubt existed as to the cleaning of the final slag in the reverberatory furnace reduction.

Jan 1, 1944

By D. G. F. Hedley, F. Grant

"In 1958, the Ontario Department of Mines appointed a committee to study the accident situation and mining methods used in the uranium mines in the E1liot Lake district. This committee reviewed the existing knowledge on mine design, pillar support and roof spans and came to the conclusion that scientific knowledge had not yet reached the stage of producing rational design procedures which would reduce the dependence on trial-and-error methods. Since that time, the Mining Research Centre has made numerous stress measurements in two mines to define the pre-mining and pillar stresses. A comprehensive series of tests has been done in the laboratory to measure the compressive strength of the rock; a geological survey of the region has been made to evaluate tectonic stresses; and a survey was done on mining conditions with regard to stable and unstable pillar configurations. This information has been used to evaluate pillar design as effected by pillar width and height, depth below surface, extraction and pre-mining stress fields. The resultant design of pillar widths and corresponding extraction as the depth increased is in line with past and present experience in these mines. The information available on roof stability is still insufficient to design stable stope spans with the same degree of confidence; experience and trial-and-error methods are still required."

Jan 1, 1972

By K. C. Marsden, B. Pesic

"Interest in the efficient production and recycling of rare earth elements has increased in recent years along with the prices of these elements. The molten LiCl-KCl eutectic is one ionic solvent which can be utilized for these purposes. The LiCl-KCl eutectic has also been selected as the electrolyte for focused research for advanced pyrochemical recycling processes for used nuclear fuel in several nations. Rare earth elements are fission products with notable neutron absorption characteristics, and thorough understanding of the properties and behavior of these elements is critical to their successful partition from the electrochemically-similar actinide elements. The number of research papers investigating individual rare earth elements has greatly expanded in the approximately 35 years since the last review. These research papers are presented in a variety of languages and technical formats, making data difficult to compare, and are sometimes contradictory. A review and summary of diffusion properties of rare earths in LiCl-KCl eutectic was performed, and the data translated to a common format for evaluation. INTRODUCTIONThe rare earth elements have experienced growing importance in recent decades due to their application in high technology, including optical lenses, lasers, high-temperature superconductors, improved alloys, high energy-density batteries, and powerful magnets for compact electronic devices. Their historic production methods and uses are detailed in several texts (Hampel 1971; Bautista &Jackson 1992; Gupta & Krishnamurthy 2005). A s the p rice o f these e lements has r isen in r ecent years, so has interest in their efficient production and possible recycling options. Rare earth oxides are concentrated through hydrometallurgical techniques, but the high thermochemical stability of their oxides precludes production of rare earth metals in aqueous systems. However, the wide electrochemical window and better control of pO2- in fused salt systems allows the production of these reactive metals from their halides or oxides. The high ionic conductivity and diffusivity of the molten ionic electrolyte allow high currents with limited resistive losses (Fray 1980). Electrolytic methods in fused salts are commonly adopted for the production of bulk rare earths in a variety of molten salt systems. Fluorides are sometimes proposed for oxide electrowinning processes due to ability to dissolve the rare earth oxide, reduced hygroscopic behavior, and the wider electrochemical separation between O2 and halide gas evolution (Mohan Das, Damodaran et al. 1988; Gibilaro, Pivato et al. 2011). However, in most electrolytic production processes, such as that for mischmetal, the rare earth oxides are converted to chloride prior to electrolysis in a chloride bath (Gschneidner Jr. & Eyring 1978; Sharma 1987). Of the chlorides, the LiCl-KCl eutectic is one specific medium in which metal production and production-related investigations have been conducted (Gschneidner J r. & Eyring 1978; Driscoll & Fray 1993). L iCl-KCl eutectic has the advantages o f h igh conductivity, but relatively low viscosity and operating temperature. The low operating temperature allows simpler design, with reduced energy consumption, salt volatility and cell corrosion."

Jan 1, 2012

By Kaiwen Xia, Bibhu Mohanty, Per Svedensten, Sheng Huang

"The mechanics of crushing and grinding operations in mining and excavation processes has been investigated in a laboratory simulation study. It employs a multi-particle bedded rock target, which is subjected to multiple impacts. The impact set-up consists of a Hopkinson pressure bar and a Piston-holder system. The apparatus, employing a 38 mm diameter pressure bar, was used to apply varying but calibrated dynamic loading force on the rock particles. The energy consumed by the sample during fragmentation was determined by considering the energy carried by the incident wave and the reflected wave. The Pistonholder system is used to hold rock samples and to recycle fragments after each test for particle size analysis, for single as well as multiple impacts. The feed size selected was in the range of 9.5 to 12.7 mm for all rock samples, and the impact velocity was set at 14 m/s. Two strong granitic rocks and a relatively weak limestone were the target rocks. The resulting particle size distribution after each set of impacts, ranging from single to 10 consecutive impacts, were analyzed, and various size distribution functions (i.e. Rosin- Rammler, Swebrec, Grady and Gilvarry functions) were fitted to compare their suitability in predicting the fragment size distribution for each rock type. INTRODUCTIONCrushers are widely used in the mining industry all over the world. Understanding fragmentation behaviour of rock under crushing process is fundamental to improved productivity and efficiency in mining operations. This is particularly so as all subsequent size reduction processes such as crushing and grinding are far more energy intensive than the initial blasting process employed in breaking of in situ rock. A considerable body of experimental studies exists on the behaviour of rock crushers for specific rock types in order to aid in the design of various types of crushers. However, these studies are mainly site specific, that is, the results are largely empirical, and the fundamentals of fracture process that lead to size reduction have not been dealt with adequately. Most such studies have attempted to link the input parameters, such as feed size and crusher parameters, with output particle size, and global energy expended in the process. However the physical mechanism of crushing process is still not well understood. First of all, the energy consumed by the rock sample is hard to calculate during standard crushing or grinding tests; secondly, multi-particle test is hard to perform in the laboratory due to irregular shape of the subject rock sample. In This paper, describes a laboratory crushing apparatus for multi-particle rock samples, with sufficient control of the energy expended in the process, with a view to relate creation of new fracture surfaces in the size reduction process."

Jan 1, 2015

By S. V. Ulianov, A. Y. Senchenko, E. M. Kurchevskaya

"A process sample of old copper-containing tailings (-2.0+0 mm) from an iron-ore plant was tested in TOMS institute in order to develop a process for copper concentrate production. The study of tailings material composition indicated that -0.2+0 mm fraction was efficient and contained 97.26% of copper. Copper is predominantly concentrated in chalcopyrite which is present both in free form and in intergrowth with ore and rock-forming minerals. Study of chalcopyrite using an optical microscope and Qemscan SEM determined that the most grains surface was covered with oxide films. Additionally, a lot of grains had micropores on their surfaces that indicated a partial mineral leaching. The oxide films did not make it possible to float copper minerals from head material. It was recommended to apply an attrition operation to restore chalcopyrite floatability. In order to increase selectivity a regrinding stage for a primary copper concentrate was introduced to obtain P80 26 um. Taking these recommendations into account a flotation flowsheet was developed to process the old Cu-containing tailings. The flowsheet allowed us to obtain a concentrate with 23.5% Cu content at 71.5% recovery.INTRODUCTIONStudy of material composition is an important prerequisite for development of a minerals processing technology. Mineralogical study contributes to search for an efficient technology to recover valuables and for prospective methods of minerals processing.The use of such up-to-date analysis methods and equipment as Qemscan and Mineral-C7 allows one to determine minerals size, liberation degree, and mineral associations. Mineralogical data can reveal reasons for hard processing of minerals prior to development of the process.The advanced process mineralogical methods used to study Cu-bearing pond tailings indicated several factors that influenced development of the process. The first one is a barren size fraction which is to be removed from the process in order to considerably reduce the costs connected with grinding. The second is the presence of films on chalcopyrite surface; in this context, a preliminary attrition of the material was recommended. The third factor is finely disseminated Cu minerals in sulphide and in the rock, which predetermined selection of particle size for flotation. All these data led to significant decrease in time required to develop the process technology. The developed process flowsheet based on the obtained mineralogical data is present in Figure 1."

Jan 1, 2016

By Murray W. Grabinsky

The in situ performance of Cemented Paste Backfill (CPB) systems can be monitored to improve understanding of the paste?s behaviour and therefore optimize the geomechanical design of the cemented paste backfill system (i.e., minimize binder content, minimize fill barricade complexity, maximize fill rate-of-rise during backfilling, and minimize cure time before resuming production blasting in proximity). However, undertaking such a monitoring program is inherently complex, because the rate-of-rise and accompanying self-weight induced stresses occur at a time rate that is similar to the rate of hydration and associated increase in the paste?s stiffness and strength. In addition, arching within the stope complicates the overall stress distribution. Therefore, to obtain a complete picture of the CPB?s response, it is necessary to measure several variables (3-D total pressures, water pressures and suctions, hydration rates, and blasting induced vibrations) at a given ?point?, and take all such measurements at many points throughout the fill mass as well as at barricade locations. The overall testing program can therefore be logistically difficult to implement and have an apparent high cost. However, if the program is successful, the benefits arising from improved mine design can significantly outweigh the seemingly high initial capital and labour costs of the monitoring program. A case study involving an instrumented paste fill in a tall and narrow Alimak stope is briefly outlined. Plans for a similar experiment in a large long-hole stope are then considered.

May 1, 2008

By D. Stone, N. J. Aslin, W. Webb

In today's modem copper electro-refineries, increasingly higher average current densities are being employed. With these increases many refineries are approaching their limiting current density. The nearness of the average operating current density to the limiting current density has placed increasing emphasis on the need to maintain an even current distribution. This paper explores the importance of maintaining even current density and discusses the factors, processes and practices that are necessary to achieve and maintain high quality production at high operational intensity.

Jan 1, 2005

By Songgen He, Jianchun Guo

With the development of complex, unconventional and deep reservoirs, it shows that many rocks behave plastically with the influence of clay and confining pressure. Traditional linear elastic hydraulic fracturing initiation models are not good predictors for elastic-plastic reservoirs. With the deformation theory of plasticity, a power hardening constitutive equation was developed in piecewise approximation method. Based on the nonlinear constitutive equation, a model of the stress field around the wellbore was developed considering fracturing fluid penetrating effect and in-situ stress anisotropy. At last, coupled with the maximum tensile strength criterion and Mohr-Coulomb criterion, a new elastic-plastic hydraulic fracturing initiation model was built. The following conclusions were summarized in the paper: (1)The piecewise power hardening constitutive equation based on the deformation theory of plasticity can accurately describe the nonlinearity of elastic-plastic deformation. (2)Whether the rock is yielded or not is determined by in-situ stress, yield stress, Biot coefficient and pore pressure. (3)Plastic yield has little influence on radial stress but significant impact on circumferential stress. The radius of the plastic zone is positively correlated with in-situ stress but negatively correlated with yield stress, power hardening index, pore pressure and Biot coefficient. (4)Initiation modes include tensile failure and shear failure when rock is yielded. (5) For elastic-plastic reservoir, the initiation pressure predicted by linear elastic model is much lower if the rock is yielded.

Jan 1, 2015

By Z. D. Hora

Sedimentary phosphate-bearing rocks are found over a considerable area of so utheastern British Columbia that extends from Fernie east to the Alberta-British Columbia boundary and from the International Boundary northward to the headwatei: s of the Elk River. Phosphatic beds occur at the following four stratigraphic levels: 1. lower part of the Banff-Exshaw sequence of Mississippian age; 2. lshbel Formation of Permian age; 3. base of the Fernie Group of Jurassic age; 4. belemnite bed within the Rock Creek Member of the lower part of the Fernie Group. To date, considerable tonnages of phosphate rock have been proven in the area. However, no commercial production has been initiated because of a relatively low P2O5 grade. Data on assays and thicknesses of the phosphatic beds are in part recalculated from the paper by Telfer (I 933) and in part from assessment reports filed at the British Columbia Ministry of Energy, Mines and Petroleum Resources.

Jan 1, 1984

By A. Demers, M. Chapman, N. Reynier, R. Lastra, M. Courchesne, C. Laviolette

Historic medical isotope production at Canadian Nuclear Laboratories (CNL) in Chalk River involved the dissolution of irradiated isotope targets prior to extraction of Mo-99. This process generated liquid waste that was cemented in 5-gallon containers and transferred to an outdoor waste-management facility for intermediate storage. Research was undertaken to develop an innovative method for uranium, mercury and cesium recovery from the radioactive cemented waste (RCW). Regulations prohibit the removal of active radioactive waste from the Chalk River facility. Thus, CanmetMINING produced surrogate material following the same procedures and conditions to those used at CNL. The selective recovery of the uranium from the surrogate radioactive cemented waste (SRCW) could offer CNL more disposition options for the resulting wastes. Leaching tests were performed using four different SRCW at 1 kg scale. Different conditions, operating parameters, and the presence of plastic and corrosion products were evaluated on solubilization. The research investigated the use of potassium iodide with the sulphuric acid leach to increase metals recovery. Iodine improves the solubilisation of metals and the U dissolution reached 99%. The increase of leaching time reduces the U solubilization due to silica gel formation. Therefore, it will be important to control leaching time to avoid the loss of U during the pilot scale experiments. For Hg, the solubilization ranged from 60 to 80% due to the presence of metallic mercury and mercury sulphide found in SRCW cured at 60°C and/or aged for 30 months. Ion exchange (IX) was found the best method to separate the uranium from the impurities and produce a purified and concentrated uranium solution suitable for yielding a uranium product (yellow cake).

Jan 1, 2020

By V. V. Severov, Z. Lafhaj

The flotation separation of salt type calcium minerals is problematic, due to the similarities in their formation properties and the same active Ca2+ related site for interaction with anionic collectors and similar physicochemical characteristics such as solubility, point of zero charge, surface speciation, Ca-site density. The work was performed to achieve effective and selective separation of the calcium-minerals using pure minerals samples: four calcite, two fluorite, and two apatite samples. The effect of pure and mixing anionic collectors such as oleic and linoleic acid to different ratio (2:1; 1:1; 1:2) as well as the role of nonionic collectors on the selective separation of Ca minerals were studied. All flotation tests were performed in self-aspirated flotation cell. The results obtained with the blend of anionic collectors with the molar ratio of 2:1 show a separation between apatite and calcite at pH 5 and a ratio 1:2 at pH 9. The enhancing of separation contrast using the sodium silicate as a depressant for calcite and apatite is also examined as a function of oleate/linoleate ratio. Additionally, this paper discusses the enhancing of the selective separation of Ca minerals when anionic collectors were blended with nonionic reagents. The surface reactions in aqueous mineral suspensions and the adsorption of anionic collectors blended with nonionic reagents were studied by FTIR spectroscopy. An unexpected synergistic effect was observed for some ratios between anionic and nonionic reagents. The mixture of fatty acids and nonionic reagent showed very high flotation efficiency in comparison with fatty acid alone for the flotation of an igneous low-grade phosphate ore.

Jan 1, 2016

By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By A. H. Lang

"The great interest taken in uranium in Canada during the past few years has resulted in the discovery of a very large number of occurrences, and in much research that has added to the knowledge of the mineralogy and geology of uranium deposits. The object of this paper is to present that information in condensed form. Some of it has been published before, but the writer has been asked to bring it together and to add more recent, unpublished data. The paper therefore contains short accounts of the mineralogy of uranium and of the types and distribution of occurrences; brief regional descriptions, including information on some of the characteristic deposits; and conclusions regarding prospecting and development possibilities.The writer has access to much confidential information supplied in compliance with regulations of the Atomic Energy Control Board. He has used this only for making broad generalizations that could not affect individual interests, and only where the owners of properties have agreed to its use.Much of the information on mineralogy and geology is derived from the work of others. The writer is particularly indebted to M. H. Haycock and S. Kaiman of the Mines Branch; H. V. Ellsworth, S. C. Robinson, E. J. Brooker, H. R. Steacy, W. E. Hale, and A. M. Christie of the Geological Survey; and E.W. Nuffield, J. S. Stevenson, and other officers of provincial Departments of Mines. For information and many courtesies he is greatly indebted to so many officers of Eldorado. Mining and Refining (1944), Limited, and owners and staffs of private properties, that it is impossible to mention them individually."

Jan 1, 1950

By Lorant B. Geller

Sixteen miners died tragically at the Paymaster gold mine at Timmins, Ontario in February, 1945, when a badly corroded hoist rope broke. The investigation of the Royal Commission that followed arrived at a number of recommendations (Investigations, 1947) aimed at avoiding future disasters of this kind. One consequence was the development, and legislated use in Canada, several decades ago, of powerful electromagnetic (EM) instruments for the nondestructive testing of mine shaft wire ropes. The authors have been involved for many years in the design, production, and testing of EM instruments (Geller and Udd, 1990 and 1992, Geller and Kitzinger, 1991, Geller et al., 1993). Since the mid-1990s particular attention was paid to the design and operational results obtained from the computer- controlled portable MagnographJ II wire rope tester (Geller et al., 1995 and 1998). In the present article the authors summarize further hardware- and software-related developments of this instrument. Further, an account is given of the results obtained from the most recent design known as the PermaScanJ testing system. This is also a computerized dual-function system. In it, however, the sensor head is designed primarily, if not solely, for permanent installation and for remotely controlled operation. This represents a basic departure from traditional designs, which were intended for ad hoc temporary installations. The remotecontrolled instrument described in this paper has now been in operational use for more than 4 years.

May 1, 2003

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By M. Abumiya, N. Onodera

"The synthesis of large scorodite particles in non-ferrous metallurgical industries usually requires a high-cost operation involving heating and high-pressure autoclaving. To overcome these obstacles, an atmospheric-pressure process for scorodite synthesis (DMSP®) was developed, in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. This process gives scorodite of good crystallinity with particle sizes as large as 15-20 µm. The solutions used for scorodite synthesis in the DMSP® are prepared from various residues containing arsenic from non-ferrous smelters. The solutions may be contaminated with Cu, Sb, and Bi, for example, and therefore the effects of such impurities on the formation of crystalline scorodite need to be investigated. In this study, the effects of Cu, Sb, and Bi contaminants on the formation behaviors of scorodite particles in the DMSP® were investigated systematically.INTRODUCTIONThe synthesis of crystalline scorodite (FeAsO4·2H2O) is a suitable method for arsenic (As) stabilization and storage of As-containing by-products such as flue gas dusts in non-ferrous smelters. It is expected that the formation of large, highly-crystalline scorodite particles would be an ideal method for avoiding the release of arsenic to the environment. Generally, autoclave methods under pressurized oxidation conditions at temperatures above 100°C have been used for the formation of arsenic minerals such as scorodite. However, the autoclave method requires sealed vessels that are resistant to high pressure, heat and acids. This process is also unfavorable on account of the high construction expenses, and high running costs as a result of vapor heat loss. Processes for synthesizing scorodite under atmospheric conditions at temperatures below 100°C which do not need an autoclave have therefore been extensively investigated (Demopoulos, Droppert, & VanWeert, 1994; Demopoulos, 1996; Demopoulos, Lagno, Wang, & Singhania, 2003; Droppert, Demopoulos, & Harris, 1996; Filippou & Demopoulos, 1997).Recently, Fujita et al. (Fujita, Taguchi, Abumiya, Matsumoto, Shibata, & Nakamura, 2008a, 2008b, 2009; Fujita, Taguchi, Kubo, Shibata, & Nakamura, 2009; Fujita, Taguchi, Shibata, & Nakamura, 2009) developed a new method for producing large scorodite crystalline particles with improved filtration and washability properties at normal atmospheric pressure and temperatures below 100°C. In the new method, oxygen gas (O2) is blown into solutions containing a high concentration of arsenic ions (As(V)) and ferrous ions (Fe(II)). The Fe(II) ions were subsequently oxidized to ferric ions (Fe(III)), resulting in the formation of large scorodite particles. High supersaturation of solutes such as Fe(III) will result in excessive nucleation, and the formation of poorly crystalline phases. The scorodite formation must therefore be conducted in a manner that avoids the critical supersaturation level being exceeded. It is supposed that the oxidation of Fe(II) to Fe(III) by O2 gas in the new method suppressed the supersaturation of Fe(III) during scorodite formation. The low Fe(III) supersaturation resulted in formations of highly crystalline scorodite particles of size of around 20 µm. In June 2008, based on the developed process described above, DOWA began experiments to verify the industrial capability of a plant with a capacity of 30 MT/month of As. It was successfully proven that it is possible to produce crystalline scorodite industrially on a commercial scale. This process was named and trademarked as DMSP® (Kubo, Abumiya, & Matsumoto, 2010)."

Jan 1, 2012

By A. A. Tytko, T. S. Golosinski

"The paper discusses the accuracy of magnetic inspections of corroded hoist ropes. It quantifies the error of measured LMA (loss of metallic area) caused by presence in the rope of ferromagnetic products of corrosion. The paper concludes that in mining practice this error is not significant. Hoist Rope Corrosion and its AssessmentCorrosion is one of the most common forms of wire rope wear. For ropes working in wet mine shafts, ropes used by the fishing industry and, in general, ropes working in humid and chemically active environments, corrosion wear is usually the prime reason for rope discard. In most mining applications, rope corrosion is accompanied by fatigue cracking of wires, abrasion of external wires, internal nicking and other forms of wear.Quantification of corrosion damage in ropes using standard inspection procedures and examination methods is very difficult. Qualitative comparisons are sometimes used to describe the degree of rope corrosion to compensate for the lack of quantitative measures (SABS 0293, 1996). If available, the results of magnetic examinations of ropes may be of help in assessing their corrosion weakening.Magnetic rope examination requires that the rope first be magnetized. After that, the rope magnetic flux and the leakage flux along the rope are measured. The first is assumed to be directly proportional to rope metallic area (LMA) and its changes are indicative of the rope’s loss of breaking strength (LBS). Existence of the second indicates existence of local faults (LF) in the inspected rope. As the corrosion of rope results in development of corrosion cracks and in loss of rope metallic area, both the LF and the LMA should be used to quantify the level of rope corrosion. More specifically, the changes to the amplitude of the LF signal are considered to provide qualitative information on rope corrosion (Hansel et al., 1990), while those of the LMA signal are believed to provide quantitative information (Geller and Rousseau, 1990; Golosinski, 1996)."

Jan 1, 1999

By I-H. Jung, J. Kim, B. Konar

"The usage of FeNdB permanent magnet, containing Rare earth elements (REEs), is steeply increasing with its demand for wind-turbine and electrical vehicle. The improvement and recycling of the permanent magnet require good understanding of chemistry of all constituent elements. In order to understand the chemical interactions between REEs and Fe, all Fe-RE binary systems have been critically assessed and optimized based on reliable literature data. The Modified Quasichemical Model and Compound energy formalism is employed to model the liquid phase and the solid solutions present in the binary systems respectively. The enthalpy of the liquid and the intermetallic phases showed a systematic trend along the lanthanide series. This helped to mitigate the discrepancies in literature data and also to predict the binary interactions between some less well investigated Fe-RE binary systems. INTRODUCTIONRare Earth elements (REEs) are a group of seventeen elements (including Scandium, Yttrium and the lanthanide series) that exhibit same characteristic chemical and physical properties. These properties make them valuable to the electronic, appliance, green technology, weapon and medical device manufacturing industries. Compounds of REE with other metals (like Co, Fe, Ni etc.) have unique properties of luminescence, thermal and electrical conductivity, magnetism and ability to act as catalysts and polishing compounds (Gschneidner ,2011).They are not only indispensable for some electronic gadgets of today, like computers, music systems, mobile devices, televisions and MRI machines, but also holds a key to more greener technology of the future. They contribute to the development of more efficient and environment friendly version of everyday products such as cars and light bulbs. REE compounds revolutionized the magnet industry by making them smaller and more powerful with increased longevity, and high temperature workability, which are used in motors and generators that power electronics, telecommunications, electric automobiles and turbines(Humphries, 2011)."

Jan 1, 2012

By Bai-ru Xia, Cang-qin Jia, Qi-wu Huang

Limit Analysis Theorems has revealed to be a powerful tool for the development of numerical models aiming the determination of the load bearing capacity of structures reached by plastic collapse. This work presents a numerical formulation for the computation of strict upper bounds of the collapse loads of rigid-perfectly plastic mechanical systems, derived within the kinematical theorem framework. A key advance of this present method is that the problem is described only in terms of nodes and discontinuities connecting those nodes rather than element or bodies. The alternative approximation procedure to the traditional finite element method might involve discretization of a given body using a suitably large number of nodes laid out on a grid, with the failure mechanism comprising the most critical subset of potential discontinuities interconnecting these nodes. Potential discontinuities which interlink nodes laid out across the problem domain are permitted to crossover one another, giving a much wider search space than when such discontinuities are located only at the edges of finite elements of fixed topology. Highly efficient interior point method solvers can be employed when certain popular failure criteria are specified (e.g. Mohr-Coulomb). By adopting this processing approach it is possible to solve very large problems which normally exceed the memory capacities of a single computer. The developed numerical tool reveals to be robust and versatile, able to solve a wide range of 2D problems. Velocity singularities are automatically identified and visual interpretation of the output is straightforward. Several numerical examples including rock slope are studied by the new method, and the results are very close to those calculated by using analytical method and FEM.

Jan 1, 2015