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By R. R. Rogers

Introduction The subject of cathodic protection is not new. In 1824 Sir Humphry Davy, in publishing the results of his investigations for the British navy, pointed out that copper could be protected from sea-water corrosion by connecting it electrically with zinc or iron. Since that time much work has been clone in this field, particularly in the protection of metals from the action of sea water, neutral brines, and treated and untreated waters. Special mention should be made of the successful protection of underground pipe-lines which formerly were badly corroded by the water in the ground. So far, magnesium alloy and zinc anodes have been the most popular. However, fairly recent work has indicated that aluminium anodes will give good service under certain conditions. The principle of cathodic protection has been applied extensively in coating steel articles with zinc and in cladding aluminium alloy sheet with pure aluminium. A valuable discussion of the fundamentals and applications of cathodic protection recently was presented in the Corrosion Handbook. A useful list of references was included in the article.

Jan 1, 1949

By G. M. Ritcey, B. H. Lucas

In the conventional alkaline leaching of concentrate containing nickel, copper and cobalt, copper is usually removed from the system, prior to nickel reduction, by sulphide precipitation. A new process is described for the selective extraction of copper and separation from cobalt and nickel, using liquid-liquid extraction. General Mills LIX-63 dissolved in a kerosene diluent is the extractant. Trace amounts of co-extracted cobalt and nickel are easily removed by a scrub treatment, and copper is recovered from the extract by sulphuric acid stripping, thus providing a solution amenable to the oroduction of electrolytic copper. Estimated processing costs are included together with a proposed flowsheet.

Jan 1, 1972

By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

DOME MINES, Limited, is a gold producer situated in the Porcupine area of Ontario, 500 miles north of Toronto. During the year 1960, '71 4,600 tons of ore were milled, yielding gold bullion valued at $6,025,370. Prior to conversion to natural gas, an average of 3,200 tons of coal was consumed annually, one third of which was obtained from Canadian sources with the remainder coming from the United States. Due to the distances involved, the freight charges increased the pithead cost by as much as ISO per cent. Steam is generated at a central boiler plant and used for timber treatment, plant heating and process steam. Until August, 1960, steam was supplied during the winter months by two water tube coal-fired boilers, each rated at 200 boiler horsepower at 100 per cent output. Steam requirement was as high as 150 per cent of boiler rating in the colder periods. The summer load was

Jan 1, 1962

By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company's plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By K. C. Hendrick

The paper will review the significant developments in world copper over the past ten years and their impact on the Canadian industry. It will also examine the outlook for the future.

Jan 1, 1971

By S. Kashani-Nejad

The formation of oxides during the dehydration of MgC12,6H20, Bischofite, was studied by heating the bischofite over a range of time and temperatures in ambient atmosphere. Using a methanol-leaching technique developed by authors, the oxides that formed were isolated, identified and assayed. Three distinct regions of oxide stability were identified. The oxide produced at dehydration temperatures less than 300 °C was Mg2(OH)3C1,2H2O; at 300 °C, mixtures of MgOHC1 and Mg2(OH)3C1.2H2O were formed and at 400 °C, MgOHC1 was the only oxide produced. The presence of MgO observed in the products of the dehydration of bischofite at temperatures above 400 °C was due to the thermal decomposition of the MgOHC1 that was formed while the sample was heating to over 400 °C.

Jan 1, 2006

By Wei Wei

Mining induced ground movement and/or stress redistribution could cause ground instability issues. This is particularly true when the extraction of large stopes is done with one or two large production blasts. Often enough, it is the nearby mine development like haulage drifts and cross cuts that are influenced the most by production blasts. Proper and timely mitigation of ground control issues due to stress redistribution is required. This is usually done by drift rehabilitation involving the installation of secondary support system in the affected areas of the mine development which include; slashing, wire mesh, and in some cases the use of shotcrete liners. It is imperative that such rehabilitation be implemented to the mine infrastructure in a timely manner in order to avoid aggravated ground control problems and production delays. If the real time performance of the support system is captured, it would be possible to determine the timing for rehabilitation job. Birchtree Mine in Thompson, at the Vale Manitoba Operation, has begun mining the 84 Deep Orebody. One of the identified risks is the stability of the crusher room under mining induced stress redistribution. It is proposed to use the U-Cell technology to monitor the primary support system performance (rebar bolts and extension bolts) and monitor the real time performances of the bolt axial loads. The U-Cell technology is a 7-inch long, coupler load cell that is screwed onto the threaded portion of a rock bolt prior to installation. Rehabilitation in the vicinity of the crusher area where U-Cells are installed is recommended when the bolts have reached 70% of their yielding capacity. Catastrophic ground failure can be avoided by adding secondary support in a timely fashion. This paper presents a case study at Birchtree Mine in Thompson Manitoba, where the performance of primary ground support system is monitored and recorded during production.

Jun 1, 2012

By H. A. Hamza

An experimental study of the settling characteristics of a washery effluent originating as tailings from a froth flotation circuit was undertaken by using a systematic approach to select the most appropriate flocculant(s) under predetermined conditions. Selection and evaluation procedures which greatly reduce the effort required to select flocculants are described. The results show that, although different flocculants display superiority at different ranges of dosage. Separan MG 700 (Dow) is the most suitable on absolute economic grounds. Flocculant evaluation is based on a Cost Performance Index (CPI) which expresses the cost of flocculant (¢/ton) required to produce a unit settling rate (in./hr). From experiments carried out with a number of flocculant aid and flocculant combinations, it was concluded that the use of flocculant aids can be economically justified only if the settling rates required are higher than those obtainable at the optimum flocculant dosage. Otherwise, the value of the flocculant aid appears to be limited largely to the reduction of supernatant turbidity.

Jan 1, 1979

By A. S. Dawson

"IntroductionTHE PURPOSE of this paper is to describe the results of a preliminary investigation of a method thought to be useful in interpreting geological structures in un-metamorphosed sedimentary rocks. The writer is not aware of the method having been described or investigated previously, although no thorough search of the literature has been made.The method to •be described is based on the assumption that, in argillaceous sedimentary rocks, certain ceramic properties are diagnostic for certain beds within areas of variable limits.Two ceramic properties• have been investigated: pyrometric cone equivalent (P.C.E.), and bloating characteristics of shales. The enquiry has been directed toward testing the usefulness of these properties in determining the following:A -The correlation of shale beds and, by inference, of coal seams, sandstone beds, or other such structures associated with them.B.-The location of contacts between marine and non-marine shales where lithological, palaeontological, or other evidence is lacking.Limitations of time and facilities have prevented a thorough investigation of this problem. The results given in the present paper are preliminary only. It is hoped, however, that they will occasion discussion or even lead to more thorough investigation of the method by individuals or organizations.There are, admittedly, various limitations to the proposed method. It is thought to show some promise when used in conjunction with the well-known and established methods used in stratigraphic correlation and, more particularly, when the conventional methods are not applicable."

Jan 1, 1952

By F. R. Nogas

"Because of the elements of uncertainty and instabilitp associated with single-enterprise communities, there is increasing interest in the alternatives to developing additional new communities of this nature. Gulf Minerals Canada Limited has chosen a unique alternative means to accommodate employees at a new uranium mine/mill complex at Rabbit Lake in Northern Saskatchewan. Gulf has adopted a fly-in program which moves their staff from a 450-mile radius, in and out of the on-site facilities, on a 7-day rotation."

Jan 1, 1976

By A. Consigny

New "clean technologies" to treat mining and metallurgical effluents containing dissolved metals have been successfully applied at mine sites in North America and Asia, treating water flows up to 24,000 m3/day. These clean technologies offer significant benefits compared to conventional alternatives and provide a sustainable solution that eliminates residual waste sludge, improves water conservation, generates revenues from wastewater, and delivers overall improvements to the environment. This paper will profile these technologies, and provide best practice case study examples of their application at mining operations, including data for water chemistry, flows, water quality, capital and operating costs, and life cycle costs of treatment.

Jan 1, 2011

By J. W. Matousek

The heat content of the waste slag from a typical smelting operation methods for estimating the thermodynamic properties of smelting slags, to include: -- heats of formation -- heat capacities (specific heats) -- heat contents -- melting temperatures -- heats of fusion The techniques are illustrated with the analyses of a nickel reverberatory furnace slag from Copper Cliff, an iron-making blast furnace slag, and a "lateritic" slag from a ferronickel operation in Colombia.

Jan 1, 2007

By J. Font

The RAF or copper fire refining process at the Caletones smelter of CodelcoChile consists of several pyrorefining stages that successively lowers the levels of S, Fe, Pb, As, Sb, Te, Se and to some extent 0 in the copper melt, allowing the production of high quality fire-refined copper of 99.93 % purity (RAF copper). This chemical feature of the RAF copper is only achieved by quite long processing times, and a considerable consumption of fluxes and fuels in the RAF vessels. The main goal of this study was to improve the RAF process performance by thermodynamic considerations and industrial scale tests, i.e., an in situ approach for the process as featured by intensive sampling, characterization and subsequent modifications. Thus, both theoretical and industrial data were derived, and based on kinetic and thermodynamic evaluations, a higher operational standard was achieved for the RAF process. These new operational practices allowed enhancing the overall economic of the RAF process, by reducing the time and operational costs, and consequently increasing the availability of the vessels.

Jan 1, 2007

By W. W. Beaton

The Coxheath copper mine is situated on the north side of the Coxheath hills and opposite the French Vale, at a distance of about 10 miles southwest of Sydney, Cape Breton county. The deposit was discovered in 1880, and the first work on the property was carried out with local capital. Lacer some Boston men became interested and formed a Company to finance the undertaking. This group operated the mine intermittently for approximately 20 years, spending close to one million dollars on the undertaking. Three shafts were sunk to depths of 110, 190, and 340 feet, and further underground workings to the extent of approximately one-half mile were driven. Also, an extensive surface programme was carried out. in which many test pits and hundreds of feet of trenches were dug, Early in the summer of 1928 the Arno Mines, Limited, optioned the property and immediately started an exploration campaign. A series of trenches were dug along the parallel vein system, and over 4,000 feet of diamond-drilling was done. The results obtained were so encouraging that a mining plant was erected in the fall of chat year and No. 2 shaft was drained. A complete new plant was installed, consisting of one 120 h.p. Fairbanks-Morse Diesel engine, direct connected to a Sullivan angle compound, air compressor; an 80 h .p. Leonard boiler, which supplies power for the 7 by 11 Ingersoll-Rand hoist; and a Sullivan class C steel sharpener and oil furnace. Two 250-gallon Cameron pumps, one operated by steam and the other by air, were placed in the mine so that, in case of a break-down, the mine would not be flooded.

Jan 1, 1930

By J. J. Barakso, C. Tarnocai

This paper outlines a method of testing for the mercury content of rocks, soils and plants. Techniques of sample collecting are described and the analytical procedures outlined. Examples are given of mercury determinations in two known mineralized areas in British Columbia - Copper Mountain Mines and Pacific Nickel Mines.

Jan 1, 1970

By F. C. Robles Hernandez

This paper presents the results of the electromagnetic semi-solid treatment of the 319 aluminum foundry alloy, Various levels of structure modification were achieved controlling the AC current used to create the Electromagnetic Field, thus manipulating the intensity of the field, The level of grain refinement, partial modification of the Al-Si eutectic, as well as cellular dendrites were observed, A quantitative analysis of the structure was performed using Image Analysis (IA) techniques. In addition a novel Thermal Analysis methodology was developed for the on-line determination of the microstructure modification level.

Jan 1, 2004

By C. A. Young, H-H. Huang, L. G. Twidwell

Solid particles, especially oxides/hydroxides, develop an electrical charge on their surface when submerged in aqueous solution. Parks was able to relate PZC (point of zero charge) of an oxide to its minimum solubility and isoelectric point. Dzombak has compiled an extensive database for adsorption reactions on ferrihydrite surfaces using the double layer theory. The equilibrium calculational program, STABCAL has been used to extend the considerations of Parks and Stumm. The PZC for many hydroxides, complex oxides, and non-oxides have been investigated and the results are reported in the literature. Removal of arsenic and metals by adsorption on ferrihydrite as the substrate has been computed using ST ABCAL and the computational results are compared to experimental data. Absorbents other than ferrihydrite such as aluminum hydroxide are also discussed.

Jan 1, 2005

By R. M. Kleine

In the fall of 1968, Sheridan Geophysics leased the Renzy Mine property 50 miles northwest of the town of Maniwaki, Quebec. A 500-tpd flotation mill was dismantled at Belleterre, Quebec, trucked into the mine over a winter road and re-erected during extreme winter conditions. Approximately one billion gallons of water were removed from Renzy lake to expose the orebody. A 3,000-hp diesel generating plant and a self-supporting community were set up during the early part of 1969. This was a remark-able achievement considering that most of the work, including the pouring of foundations and the draining of the lake, had to be done during the winter months. Despite this, the project was completed ahead of schedule and one million dollars below budget. The mill is now treating an average of 800 tpd.

Jan 1, 1970

1.Assessment of methane content in coal. Given a naturally low methane content in 11 Coal Seam and the fact that the areas of the 11 Seam adjacent to the tunnelway were degassing for a very, very long time due to previous development and mining, it is conservatively estimated that the remaining in -situ methane is less than 0.5m3/tonne. 2. Continuous miner cutting rate based on the past practice. The best loading rate recorded at the past operations of Smoky River Coal was 45 seconds for a 8 tonnes shuttle car. Using these records, the maximum peak loading rate potential at the face is calculated at 0.178 tonnes per one second or 10.67 tonnes per one minute. 3. Methane release at the face. ?The actual face methane liberation, conservatively assumed at 40% of the total in situ content: 0.20 m3/tonne ?The peak cutting rate: 0.178 t/sec ?The maximum (peak) face methane release: 0.20*0.178 = 0.036 m3/sec

May 1, 2003