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By Yulin Zhou, WenFeng Li, Wen Chen

"In this article, with the help of the X-ray photoelectron Spectroscopy (XPS), a modern test method, all the characteristics of the chlorite,and adsorption collector A6 on the surface of chlorite have been studied. There exist abundant carboxylic C-O and C=O structures in the Carbon XPS atlas with strong adhesive ability after the reaction between new collector A6 and chlorite, which indicates that the ring structure and ether-base functional groups can strengthen the reaction between collector A6 molecule and chlorite surface. The results of XPS analysis indicate that the photoelectron spectroscopy peaks of Mg2p and Al2p moved towards low energy after collector A6 absorbed on chlorite surface, which indicates that chemical bonding through electron cloud transfer happened between collector A6 and Mg, Al ions of chlorite surface. The chemical reaction promoted the adsorption of A6 on chlorite surface and eventually improved the ability of A6 to float and collect chlorite.INTRODUCTIONThere are a large amount of iron-bearing silicate minerals such as chlorite in different types of gangue minerals in iron ore from different areas besides quartz (Yingyong et al, 2012; Qiang et al, 2009). There always exist Mg2+, Al3+ Fe3+ and other metallic ions due the isomorphic replacement among the irons of this kind of minerals. The dissolution often occurs on the surface of minerals with abundant metallic ions during grinding process, and some ions are exposed on the surface, such as Mg2+, Fe3+, Al3+, Si4+, which can increase the surface electrical behaviour of iron-bearing silicate minerals (Wanzhong & Chuanyao, 2002; Yuping et al., 2007), making it easy for the surface to react preferentially with the depressants such as causticizing starch which making it impossible for the surface to reach with conventional anionic fatty acid collector (Mowla et al, 2008). Thus, the beneficiation efficiency is dramatically decreased and the improvement of concentrate grade becomes very difficult. The conventional aliphatic acid collector has some defects such as poor selectivity, poor low temperature resistance, sensitive to water hardness, etc. Thus, the addition of synergist (Liu, & Yu, 2015) or other compound reagents (Zhou et al, 2015) can promote the adsorption of reagents to mineral surface, and improve the collecting capacity and selectivity of aliphatic acid collector to minerals. The addition of polar group to nonpolar group in aliphatic acid can improve the water solubility, dispensability and hard water resistance (Tian et al, 2013). The nitrogen atoms in amid ate aliphatic acid collector can adsorb on mineral surface by itself and supply coordinate electron which can form chelating keys to improve the collecting capacity of collector. There exist coordinate electron in oxygen atoms of ether acid collector, which, along with the oxygen on carboxyl compose chelate with metal (Luo et al, 2015). There are also exist some opinions that the ether acid can arrange into similar crown ether structure which can absorb on mineral surface. A new alicyclic unsaturated ether acid compounds collector A6 is adopted in this paper, the structural formula is listed in Figure 1. The A6 has a strong collecting ability to chlorite with strong water solubility and low temperature resistance."

Jan 1, 2016

By D. A. Beck

The load-deformation response of discontinuous rock under static and dynamic loading conditions has been simulated using Explicit Finite Element models. The intent of the analysis was to investigate the effects of specimen size and confining stress on strength, dilation and comminution. The simulations allow the development of homogenised constitutive material properties for discontinuous rock masses using laboratory scale measurements and representative Discrete Fracture Networks (DFNs). A procedure for this is presented which includes a comparison of measured seismic response in a mine to the Dissipated Plastic Energy (DPE) that is released in the simulated rock masses. The models also show how confinement and scale affect the stress-strain and DPE response of the simulated rock specimens, reproducing a number of known rock phenomena that are often poorly captured in geotechnical modelling. A case study is presented showing a satisfactory match between the model-derived, homogenised material properties and values achieved by calibration of a mine-scale model where many thousands of seismic, displacement and damage measurements were available.

May 1, 2009

By J F. Davies

A review is presented of the fundamental differences between the Superior and Churchill geologic provinces. Structure, lithology, grade of metamorphism and a single recent age determination suggest that the Flin Flon -Snow Lake and Lynn Lake belts are remnant blocks of originally Superior rocks lying within the Churchill province. Major mineral belts occur along the main boundary between the Superior and Churchill provinces (the Thompson -Moak Lake nickel belt) and within the remnant Superior blocks inside the Churchill province (Fiin Flon -Snow Lake and Lynn Lake). During the Hudsonian orogeny, metamorphic gradients must have existed across the Churchill-Superior boundary and between the remnants of Superior rocks and the enclosing gneisses of the Churchill province. It is possible that not only the unusual nickel deposits of the Thompson belt but also the base metal deposits of the Flin Flon -Snow Lake and Lynn Lake districts are due to redistribution, or diffusion and migration of metals to areas of lower-grade metamorphism during the Hudsonian orogeny.

Jan 1, 1964

By B. A. Kjarsgaard, C. J. Mwenifumbo

"Abstract - Natural gamma-ray measurements were made in the GSC Smeaton drillhole as part of the borehole geophysical classification of kimberlite pipe 169. In addition, forty samples of Cretaceous sediments (shales, siltstones, and sandstones) and thirty-five kimberlite samples, selected from the drill core, were analyzed for major and trace elements. These elements included potassium (K), uranium (U), and thorium (Th), which are the main naturally-occurring radioactive elements.Different phases of the kimberlite, and the Cretaceous sediments which show variations in the gamma-ray activity, can be easily delineated on the gamma-ray logs. The gamma-ray logs indicate that the radioactivity in the kimberlite derives mainly from Th, and, to a lesser extent, U. Most of the kimberlite units are enriched in Th and U relative to the Cretaceous sediments, and these radioelements are mainly hosted by accessory apatite and perovskite, and minor zircon. Potassium concentrations are low in the kimberlite. The higher K concentration in the sediments clearly distinguishes the Cretaceous sediments from the kimberlite.The U/K and Th/K ratios show important and distinct differences between the two major types of volcaniclastic kimberlite. Kimberlite lapillistones have higher U/K and Th/K ratios than the olivine crystal tuffs. Furthermore, standardized U/K and Th/K geophysical logs can be used to separate marine reworked olivine shoreface sands from other shallow marine sediments that contain kimberlitic detritus. The identification of different phases and/or stratigraphic facies of kimberlite on the basis of radioelement distributions means that gamma-ray spectrometry can assist exploration, particularly in regard to diamond grade distribution."

Jan 1, 1999

By E. S. Moore

In order that a logical conclusion may be reached regarding the possible occurrence of commercial iron deposits in Canada it is necessary to consider some important producers found elsewhere on this continent. A study of such deposits reveals the fact tl:~at a number of distinct types are producing large tonnages of ore. These types may be classified according to origin and occurrence as follows: (1) Bedded sedimentary deposits. (2) Contact metamorphic deposits. (3) Residual ores. (4) Lenses in metamorphic rocks and m some cases of uncertain origin. In addition to the types listed there are other deposits which have contained or do contain considerable ore and they either have not been worked on a large scale or they have been nearly exhausted. These include the following types: (1) Magmatic segregations. These are mostly titaniferous magnetites. (2) Dikes of magnetite of igneous origin. (3) Bog and lake ores in glacial drift. (4) Black sand placers.

Jan 1, 1925

By Ahmad Ghahremaninezhad, Noelene Ahern, Yeonuk Choi

Arsenic (As) is a toxic element and is a major contaminant in the extraction processes of some metals (e.g. gold and copper). Due to the toxicity of arsenic species, its removal from As-containing streams from extractive metallurgy processes and safe disposal is absolutely necessary. For nearly complete removal of waste arsenic species from metallurgical process streams, it is required to have arsenic in its pentavalent state (As5+ species). This study presents an oxidation process for arsenic species with air or oxygen gas as oxidant. Activated carbon (AC) or other carbon based materials are used to catalyse the oxidation reaction. Air or oxygen gas is the only consumed reagent which makes the economy of the process very attractive. The oxidation reaction can be carried out at ambient conditions (room temperature and atmospheric pressure) in less than 24 hours.

Jan 1, 2014

By C. W. Drury

It is practically fifteen years since stellite was first introduced into industry, and since then the progress made in its manufacture has been so rapid and the number of successful applications so varied that it was considered a review of the more important phases would be of general interest. Stellite is a cobalt-chromium-tungsten alloy, containing approximately 2. 75 per cent carbon. The high percentage of carbon is necessary for the requisite hardness and resistance to wear at ordinary temperatures, whereas the tungsten is essential to impart hardness at a red heat. Chromium imparts hardness and strength, and cobalt renders the alloys more resistant to oxidation. The metals cobalt and chromium are completely soluble in all proportions, both in the liquid and solid state, the equilibrium diagram showing a minimum in the solubility curve at approximately 50 per cent cobalt and l,340°C. Cobalt and tungsten are completely soluble up to 40 per cent tungsten, which is beyond the limit of the; tungsten content of stellite alloys. In the presence of carbon, carbides are formed, which are essential in stellite possessing good cutting or wearing properties.

Jan 1, 1930

By P. Abachi

Cemented carbides or hard metals that generally consist of hard tungsten carbide and a tough metal binder such as cobalt are important in many segments of the world economy, ranging from automobile related components to machining, cutting, and drilling tools. For metal cutting operations such as turning and milling, replaceable cemented carbide inserts are frequently used. The exposure of inserts to very severe conditions (e.g. temperatures as high as 1000°C) in combination with very high loads, limits their lifetime. When the tools and components are scrapped, they are collected with a view to recovering the tungsten carbide and cobalt due to both their environmental aspects and their strategic importance. In this work, a selective electrolysis process was used for recovery of WC powder particles from cemented carbide scraps. The WC-10Co and WC-10Co-VC up to 3 wt.% VC was produced using powder metallurgy route. The mean particle size of WC, Co and VC were selected as 2.5, l.5 and 2.2 µm respectively. Referring to electrochemical curves of WC-10Co cemented carbides in hydrochloric acid solutions with different concentrations, the recovery rate was enhanced in IN acid. Therefore, this solution was selected for recycling of all samples. The surfaces of as-produced and corroded specimens were investigated using a scanning electron microscopy (SEM). Detection of corrosion products was provided by energy dispersive spectrometry (EDS). According to results, the selective electrolysis process could be useful in the recycling of scrap carbide materials, although more studies should be undertaken on economical aspects of the process and the quality of samples produced using recovered powders.

Jan 1, 2005

By So-Yeong Lee, Moosang Lee, Seung Hwan Ahn, Ho-Sang Sohn, Jongshin Chang

It is necessary to understand the characteristics, phase changes and chemical reactions of flue dusts introduced from a furnace to an off-gas line in order to achieve the stable operation and the improvement. This study is to develop the dust reaction model for chemical reactions of dusts in an uptake shaft of smelting furnace and a waste heat boiler. Phase equilibria and reaction paths in this system were determined by thermodynamic calculation with experimental and industrial data. The oxidation reaction rate of dusts was determined by the gas film mass transfer controlling. And the sulfation reaction rate was evaluated by the unreacted shrinking core model. Kinetic parameters were estimated by reference data including industrial ones. The present study with the developed model shows various effects of temperatures, dust particle sizes, and O2 gas partial pressures on dust reactions. INTRODUCTION The flue dusts from a copper smelting furnace move along a furnace off-gas stream into an uptake shaft and a waste heat boiler (WHB) and electrostatic precipitator(s). It is necessary to control the dust quality in order to stabilize the operation because the sticking behaviors differ depending on the phase of dusts. Phase changes of dusts are caused by chemical reactions at given conditions such as temperature and partial pressure of gases. Therefore, it is required to understand the phase changes and chemical reactions of dusts in order to perform the improvement and stable operation. The present study carried out the investigation to understand their fundamental knowledge. Especially, this study was focused on the kinetics of chemical reactions of flue dusts, developed the model. In particular, the scope of development and utilization of the model was defined as the uptake shaft of the Mitsubishi S furnace and the S-WHB radiation section in the Onsan smelter. Information needed for the modeling work referred to data from these processes.

Jan 1, 2019

By Stephen B. Cheeseman

The quantity of data available and the rate at which we access such data are rapidly increasing. Electronic data capture systems, fleet management systems and a host of other technological advancements have created a constant stream of real-time, tactical data. However, are we taking advantage of this data? Are we converting data into useful information to aid in efficient decision-making? Mining operations are struggling with ?information overload?, finding it difficult to extract the benefits from vast stores of data. Without the necessary tools to facilitate a data filtering and information reporting process, most operations revert to old practises such as re-entering data into multiple spreadsheet reports. As a result, the ability to make effective use of data still eludes many mining operations. Some operations have taken audacious steps to rectify this situation. The De Beers Venetia mine in South Africa has implemented an integrated mining information technology solution that transforms their data into practical, usable information allowing staff and management to make decisions that improve efficiencies and reduce costs. In the absence of quantitative justification or ROI, De Beers took a risk in implementing change. Today, they are realising the benefits. This paper will unearth the information technology issues that surfaced during the Venetia implementation, then identify the benefits De Beers has obtained from deploying an integrated mining information technology solution at the Venetia mine.

May 1, 2002

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

By S. Jordanov

The nature of processes that take place on top of copper bearing grains during the suppression of copper acid drainage from mine tailings was studied on a grain model. Cyclic voltammetry (C.V.) was employed as an experimental technique suitable for indirect measuring of copper leaching. Experiments were done in sulfuric acid (pH=2) at electrodes that progressively approach the real situation during acid main drainage, starting with Cu-metal, then with CuO and finally with CuO covered with CaSO4. Oxidation was found to be the only process that takes place on metallic copper electrode anodically polarized up to 2 V vs. Cu/CuSO4 reference electrode. Dissolution is intensive and reaches up to 50 mA.cm-2. When the same was repeated, but on CuO electrode, anodic currents were some 4 times lower than on the bare metallic surface. This indicates that the electrode material is not completely oxidized to copper(II)oxide and the Cu(O) or Cu(I) residues are oxidized during the anodic polarization. This explains the diminished dissolution. Dissolution is further restricted at electrodes covered with CaSO4. It is some 20 times lower than on the bare oxide electrode. When the second layer of CaSO4 was applied, anodic currents were another 15 times lower. Total decrease of anodic currents when transition is made from Cu-metal to CuO covered with 2 layers of CaSO4 reaches up to 7.500 times. C.V. measurements produced a proof that mechanical blockage is the way how lime prevents leaching of copper bearing grains in immobilization experiments referred elsewhere.

Jan 1, 2007

By A. G. Roach

IT IS generally stated that the gold ores of Nova Scotia are free-milling, and for the most part this is true. However, there is a certain proportion of the gold finely disseminated throughout the sulphides, notably arsenopyrite, and this gold is definitely not recoverable as 'free-milling' gold by amalgamation. The proportion of free-milling gold to total gold seems to vary widely in different localities in the Province and is lowest in deposits of the fissure-vein type. The problem of recovery of these relatively recalcitrant values is usually one of economics, in some plac.es a simple gravity concentrate being of such low tenor that its extraction and subsequent disposal will not bear the costs involved. In other cases, such a high percentage of values escapes from the mortars and plates that concentration is definitely indicated. The size of the mining operation is also an important factor. In the large majority of cases, however, some concentrating step is warranted, even if the resulting concentrate is stock-piled until sufficient has accumulated to justify further treatment.

Jan 1, 1940

By D. Kong, A. Klyashtorin, L. McGilp, I. Wilson

This work reports on applying iron oxide coated sands media in an experimental permeable reactive barrier to remove uranium species from uranium containing water. A field experiment was conducted at the legacy Gunnar uranium mine & mill site that was abandoned in the 1960s with limited to no decommissioning. The flooded Gunnar mine pit presently contains about 3.2 million m3 of water contaminated by dissolved U (1.2 mg/l), Ra-226 (0.4 Bq/l), and minor concentrations of other contaminants (As, Se, etc.). The water is seeping over the pit rim into Lake Athabasca posing environmental and health concerns. Iron oxide coated sands can be used to immobilize uranium species through an adsorption process. Methods for preparation of hydrous ferric oxide sorbents and their supported forms onto silica sands are described. Fourier transform infrared spectroscopy (FTIR), and powder X-ray diffraction (pXRD) were used to characterize the physical-chemical properties of the sorbent. The monolayer uranium uptake capacity (Qm) was estimated through the Langmuir adsorption isotherm. Adsorption kinetic experiments were performed in a lab environment before moving to a field trial. Based on these lab results and the input on field-scale appropriate geometries, a pilot permeable reactive barrier was fabricated and a field test conducted near the Gunnar pit in June 2019. This pilot test provided technical data and information needed for designing a full-scale permeable barrier based on the iron oxide coated sands, which may be applied for in-situ water treatment at Gunnar and other legacy uranium sites.

Jan 1, 2020

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

By T. G. Phillips

"This paper gives an inside look at a bulk terminal and describes the preparations that must be made by a company in developing such a terminal and its position in today's traffic pattern. The following headings cover the subject material: (a) Traffic pressures, their detection and measurement, (b) position in the traffic flow -selection of site, (c) transportation connections -present and possible future routes, (d) engineering studies and costs, (e) contracts, the basic material for insured traffic, (f) financing, (g) budgetary control, (h) development of new techniques, (i) growth into new cargoes or cargo-handling methods and (j) consolidation."

Jan 1, 1968

The Red Lake greenstone belt is an irregular mass of lavas sedimentary rocks and intrusives which is approxiately 35 miles long 18 miles wide and 7 miles deep. Basaltic volcamcs are the oldest rocks w1thm the belt. They are believed to have been laid down on an ancient crust which is at least 3 billion (3 x 109) years old and was composed partly of sediments. The basaltic rocks are overlain by acid volcanics and sedimentary rocks which have been complexly folded and are preserved as a down-folded remnant of younger rocks within the older crust. The volcanics and sedimentary rocks of the greenstone belt have been cut by intrusives with a wide range of composition. The emplacement of the intrusives and the accompanying regional metamorph-ism which terminated the orogenic activity in this area are believed to have occurred approximately 2.4 billion years ago. The basalts and many of the basic and ultrabasic intrusives undoubtedly had their source in the sub-crust or mantle. At least some of the granitic intrusives are believed to have had

Jan 1, 1965

By O. Peters, D. Lascelles, R. Caldwell

Ageing tests on a crushed Cu-porphyry ore were conducted to assess the impact of sample oxidation on flotation performance. The objective of the testwork was to simulate ageing of ore that would be blasted through block caving but not milled for possibly several months. Ageing was performed in specially designed columns, using site and deionised water to keep the samples moist over the entire ageing period. Samples from each ageing interval (0, 0.5, 1, 2, 4, and 8 months) were examined for physical and metallurgical changes resulting from the ageing process through chemical analyses, size analyses, and batch flotation tests.

Jan 1, 2009

By T. Purushotham, B. Samanta

ABSTRACT; The shaft bottom junction in a mine ventilation system is an important source of shock loss due to the combined effect of bend and area change. The occurrence of high-volume ?ow rates through this con?guration can potentially result in high energy losses. The current research examines the process of shock loss at a characteristic shaft bottom junction of an underground coal mine. Investigations are per-formed on both laboratory-scale models and three-dimensional computational ?uid dynamics (CFD) simulations, under both exhausting and forcing shaft bottom conditions. The effects of the plat roughness and the shaft bottom length on the shock loss factor values are also examined. The studies show that the combined effect of bend and area changes that occur at the shaft bottom junction results in shock loss factors that are much higher than those values resulting from abrupt area change only. The transition from a smooth wall condition to an unlined rough airway condition (relative roughness, e/d = 0.112) can increase the shock loss factors by 40%. The effect of shaft bottom length on the shock loss factor has not been clearly established due to con?icting results produced by scale model studies and the CFD simulations.

Jan 1, 2010

By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006