Search Documents

By Jason J. Ballentine

This case study presents the results of a maintenance review of a soot blower system at a coal fired power generation station. The power generation station was following a ?repair when it breaks? maintenance strategy for its soot blowers. The efficiency losses incurred as a result of failures in the soot blower system and the resulting interruption and out of service time was found to have a significant effect on the plant output. The maintenance strategy for the soot blowers was reviewed using Reliability Cantered Maintenance and lifecycle simulation. This methodology provided visibility to the monetary implications of failures and allowed alternative types of maintenance to be assessed and where justified were added to a maintenance schedule in the Maximo work order management system. By reducing unplanned breakdowns the predicted reduction in efficiency losses was 45%.

May 1, 2007

By Steve W. Ciccone

The Red Dog Mine is both the largest known zinc reserve and the largest zinc producer in the world. The mine started in 1989, and by 1999 had increased production from approximately 300,000 tonnes per year (t/yr) of zinc concentrate to in excess of 900,000 t/yr. The VIP Mill Optimization Project further increased zinc concentrate production to 1.1M t/yr while improving both product quality and zinc recovery. The Mill Optimization project also addressed a number of issues related to risk reduction: power generation capacity, water treatment capacity and concentrate thickening. The project was faced with numerous challenges, the most daunting of which was the schedule. This US$105M project was executed, from conception to completion, inside of two years. Less than nine months elapsed from concept to delivery of materials and equipment to site. The project also faced a 100-day icefree shipping window, the challenges of construction in an Arctic environment, and an extremely tight labour market for qualified craft personnel. These challenges were successfully addressed with several innovative approaches to project execution, including an Alliance contracting arrangement between the owner, engineer and contractor; full integration of the team; construction of modules in Anchorage; and fast-track engineering, procurement and construction. Steve Ciccone, AMEC?s project manager on the Mill Optimization project, works for the Mining & Metals unit of AMEC, a world leader in the provision of engineering and construction services. He obtained his BASc from the University of British Columbia and is currently midway through his MBA program at Simon Fraser University. Steve has 15 years of experience providing engineering and project management services on mining and metals projects, and has been involved in the execution of five capital projects and several studies at Red Dog since 1995. George Hope was responsible for process design and engineering on the Mill Optimization project and has been Manager, Project Development at Teck Cominco since 1995. Prior to this time, he was a project manager and chief metallurgist for Lac Minerals for 14 years and a mill superintendent and metallurgist for Noranda for 5 years. George received his BSc in Mineral Technology from the Royal School of Mines in England.

May 1, 2002

By R. K. Collings

"This paper summarizes research that was done at the Mines Branch, Ottawa, to evaluate samples of phosphogypsum for gypsum products manufacture. The samples were from phosphate fertilizer facilities at: Port Maitland, Ontario ; Valleyfield, Quebec; and Fort Saskatchewan and Redwater, Alberta. All samples were wet-screened, washed, filtered and calcined in a laboratory kettle at atmospheric pressure. Tests were also made at higher pressures in a small autoclave. The gypsum and resulting hemi-hydrate, being acidic, were treated before, during and after calcining with various bases. The hemi-hydrate products were checked for time of set, compressive strength and bond to gypsum wallboard paper. The results of this study indicate that phosphogypsum from each of the sources investigated has potential as a substitute for mined gypsum in gypsum products manufacture. Pilot-scale testing is recommended to confirm that the product would be satisfactory for the manufacture of plaster products on a commercial basis."

Jan 1, 1972

By M. J. Slater

Ion exchange using resins is one of the few processes capable of reducing ionic contaminants in effluents to very low levels. Continuous fluidized-bed ion exchange is an advantageous technique for processing dirty effluents and thin slurries. It also reduces resin inventory and equipment cost compared to fixed packed beds. A simple continuous fluidized-bed unit has been investigated for treating effluents and its performance is described. Breakthrough curves were first obtained from static fluidized fixed beds; these data were then used to determine the required operating conditions for a periodic-flow, countercurrent fluidized-bed ion exchange system. A waste stream, containing about 56 ppm copper, was treated in the continuous system using an extraction fluidized bed depth of 203 cm and a flow rate of 1.22 cm3/ cm2s (900 gph / sq.ft) to yield an effluent containing less than 0.02 ppm copper. A generalized design method is proposed for similar chemical systems.

Jan 1, 1978

By R. N. Chakravorty, K. K. Feng

"There is growing evidence that modern methods of mining coal increase the risk of spontaneous combustion. Seemingly unimportant at this time, this hazard could prove to be a barrier to growth and development of the coal industry in some areas of Canada. The paper presents bedrock knowledge on spontaneous combustion gathered by scanning and evaluating current technical and research literature. Special efforts have been made to identify significant coal and environmental factors and to establish criteria for susceptibility. In addition to the state-of-the-art knowledge, preliminary results from on-going studies are discussed."

Jan 1, 1973

By F. P. Agterberg

"IntroductionTHE KNOWLEDGE about the mineral resources in a region ranges from relatively precise ore-reserve estimates for known deposits to probabilistic estimates concerning the speculative resources which may be discovered in future at greater depths and in the less-explored parts of the region. Previously developed probabilistic methods for regional resource evaluation (1) are based on the following two assumptions.(1) The probability that a specific block of rock, or part of a region close to the topographic surface, contains undiscovered deposits can be estimate d by weighting selected geological, geophysical or geochemical parameters for that block. The weights are computed by considering similar environments which are known to contain deposits.(2) Some of the characteristics of the undiscovered deposits, such as ore tonnages and average grades of metals contained in the ore, can be evaluated by considering probability distributions f or known deposit data. These methods were initially applied to Precambrian deposits in the Abitibi Volcanic Belt of the Canadian Shield (1).Since 1972, statistical methods for quantitative resource evaluation have been applied to the occurrences of the mainly Paleozoic base metal deposits in t he Canadian Appalachian Region. The objectives of this project (Project Appalachia) have been discussed by Leech (2) in a paper that introduces 8 papers with results of the exploratory data analysis. Project Appalachia represents an effort to develop and apply methods of combining information and concepts from regional geology, metallogeny and geomathematics for computer- aided regional mineral resource evaluation."

Jan 1, 1977

By Robert T. McKnight

"Traditional techniques for valuing resource projects companies have been primarily based on discounted cashflow methods (DCF) or by comparison to similar projects with an apparent market capitalization. Many resource projects are really forms of options to invest rather than a future cashflow stream. Employing the DCF method to value a resource project which is really an option to invest, can dramatically underestimate the real value of the project. The analytical tools required to evaluate options, while more complicated than the usual spreadsheets used for DCF, are becoming more easily available and usable by managers. This paper will discuss the background of options valuation and some of the tools which will make it easier for managers to estimate the value of projects and companies which have significant real option values.ResumeBob McKnight is a graduate of the University of British Columbia in Geological Engineering, supplemented by an MBA from Simon Fraser University. Following several years in the oil patch with Cities Service and Brascan, Bob returned to Vancouver in 1979 to work for Wright Engineers. He subsequently went on to work for Cassiar Mining, Getty Resources and Endeavour Financial before joining Pincock Allen & Holt Ltd. in 1998. His experience ranges from exploration to feasibility studies, financial evaluations of mining and oil & gas projects, due diligence, project finance, valuations and mergers and acquisitions. He has extensive international mining experience pertaining to such countries as Chile, Mexico, Uruguay, Thailand, Indonesia, Angola, Papua New Guinea, Kazakhstan.What are Options?Options have been around for centuries. They were familiar to Roman and Phoenician traders who were shipping cargoes from Mediterranean seaports. In the financial world, options are types of contracts that generally include the right, but not the obligation, to buy or sell a share, currency or commodity. The underlying commodity price or share price changes are assumed to be lognormally distributed. In this context, options are of two general types, ""call"" options and ""put"" options. Call options have the characteristic of having the right to buy a tradable commodity or currency at a predetermined price for a specified period of time. For the owner of call options, they become more valuable as the price of the underlying commodity increases. For the seller of call options, these options become an increasing liability as commodity prices rise, since there is the obligation to sell the commodity at a predetermined (perhaps lower-than-market) price. This characteristic of call options recently became high profile with the sharp rise in gold prices last year. The value of gold call options sold by certain producers increased their associated liabilities to the point where margin calls were made."

Jan 1, 2003

By R. A. Frith

"Belts of Yellowknife Supergroup volcanic and sedimentary strata in the Slave Structural Province are separated by granitoid complexes. The strata and most intrusive rocks are 2.7 and 2.5 Ga old, but rocks around 3.1 Ga have been recognized in some of the complexes and are believed to represent a once-extensive sialic crust. Volcanics were erupted along rifts in this crust and the rifts became sites of crustal foundering and the development of troughs that filled with turbidites of volcanic and granitoid provenance. Present margins of the granitoid complexes may be close to the original margins of deposition of volcanics, with associated mineral deposits, and close to the thickest parts of basins of sedimentation.The Hackett River volcanic belt extends 100 kilometres between Mara River and Back River and is crudely S-shaped, with a northern sector surrounding a core of granitoid basement rocks, a northeasterly facin g central sector and a southerly facing southern sector. Up to 8 kilometres of andesitic volcanics with intercalated felsi c volcanic rocks are preserved within the central sector. The f elsic rocks include thick lenses of volcaniclastics with large, quartz-eye-bearing clasts, but the known metal deposits are not associated with these. Both of the deposit areas, the Hackett River area in the northern domal sector and the 'A itch ' Lake area 40 kilometres to the south in the central sector, are near the tops of relatively thin atypical volcanic sequences above suspected basement rocks. The Yava deposit near 'A itch , Lake overlies a unit of subaerially deposited, welded, andesit ic ash flows and the Hack ett River deposits overlie highly metamorphosed volcaniclastic rocks that include suspected ignimbrites.The deposits are notably argentijerous and lead-rich. They consist of stratigraphically zoned sheet-like bodies of iron sulphides, sphalerite, galena and chalcopyrite underlain by altered rocks containing chalcopyrite stringers. The Yava deposit was formed where hydrothermal fluids exuded through the fractured floor of a flooded caldera basin. The Hackett River deposits may have been formed in a similar setting and it is not inconceivable that all the known deposits in the belt were formed in a single large caldera basin, although there is no independent evidence for the required major fault separation between the Hackett River dome and the 'Aitch' Lake area."

Jan 1, 1980

By J. S. Vanderploeg

I WILL begin this presentation by citing the annual per capita use of copper in Canada. This is best calculated by taking refinery domestic sales, plus imports of the products of foreign fabricating mills (very little refinery copper is imported), and deducting the exports of Canadian mills. No attempt has been made to estimate the copper content of imports or exports of machinery, motors, etc., but the trade balance here is probably against Canada. In any event, we find that, though varying somewhat since the war, the estimated yearly per capita figure has reached a high of 18 pounds. This is practically on a par with the United States. The rest of the world uses an average of about 2 pounds per capita, yearly, though this includes some countries, such as Sweden, Germany and England, which consume much better than average quantities. It looks, therefore, as if the Canadian copper industry has not (as has been generally charged) been asleep after all.

Jan 1, 1962

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are in northern Saskatchewan, 11 km west-northwest of the Rabbit Lake mine. Their average grade is 1.8% UJ0 8 and they contain 6,350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende.Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest mineralizing fluids were aqueous and at temperatures of about 200°C. Ar39/ Ar40 laser age determination of illite indicates mineralization began about 1300 m.y, ago and that significant hydrothermal alteration ceased about 1170 m.y. ago though Pb/U data suggest the deposits continued to evolve into the Mesozoic.The deposits are interpreted as the result of oxidizing ground water stripping uranium and other metals from either the Athabasca sandstone, especially the heavy mineral layers, or from the regolith, and precipitating these when encountering a warm reduced fluid emanating from the basement."

Jan 1, 1984

By T S. Cochrane

This paper is based on observations made during a recent visit by the writer to three of the dust research laboratories .in West Germany, each .of which is mainly concerned with studymg the composition and character of the respirable dust produced in mines or at industrial sites. The three institutes are discussed as regards their orgamzat10n and duties, their methods of dust sampling and analysis, and recent trends in research and development. An extensive bibliography completes the paper. Introduction A RECENT trip to Europe to attend international conferences m Austria and m Belgium gave the writer the opportunity to visit a number of research laboratories and mines in Western Europe. The visits to the dust research laboratories in West Germany are the basis of this report. In Germany, cooperative associations formed prior to and since the turn of the 20th Century to promote the safety and welfare of their workers have recognized the effects of airborne dust on the general health of the labour force.

Jan 1, 1964

By A. Romero, M. Carvalho, D. L. Millar

"The number of underground mines replacing diesel by battery powered mobile equipment is growing worldwide. The latter produces locally zero emissions and less heat, improving air quality in the working areas, and can potentially reduce energy costs due to lower ventilation requirements and in the face of higher fuel prices. However, there is a lack of systematic approaches to evaluate the potential economic benefit of switching from diesel mobile technologies to electric ones. This paper presents a method to answer the question of whether a mine with known operating conditions should invest in battery-powered electric equipment to reduce its total costs. Furthermore, this method provides the optimal number of electric and diesel equipment in relationship with their impact on the ventilation system and the total costs of running the mine from the energy perspective. A case study of an underground mine in Northern Ontario (Canada) is presented to validate the method proposed. The scenarios studied include the specific climatic conditions of the region, and the possibility to use heat recovery for the ventilation system. Overall, results show that the use of electric mobile plants is cost competitive, especially so when electricity cost can be lowered through load-shedding strategies.INTRODUCTIONOf the multiple advantages of using electrical vehicles (EV) underground in mining, the potential increase in air quality and comfort is the most significant (Paraszczak, Svedlund, Fytas, and Laflamme, 2014). Until recently, fully battery-powered electrical underground heavy duty machinery (i.e., loaders or trucks) were not available, so that tethered and trolley assisted vehicles were the only electric alternatives to diesel powered vehicles (Bétournay et al., 2011). Today, several commercial battery-based alternatives are available (General Electric Fairchild, 2015; RDH Mining Equipment, 2015; Paraszczak et al., 2014). Operational details can be found in Ewing (2015). The main battery technology used (Lithium Iron Phosphate, LiFePO4, or LFP) was already anticipated in Bétournay et al. (2011) as a good candidate for these types of vehicles. More details on these batteries, along with state of the art and future perspectives can be found in Zubi, Dufo-López, Carvalho, and Pasaoglu, (2018)."

Jan 1, 2019

By J. D. Little

"THE SALMO PROPERTIES of Canadian Exploration, Limited comprise forty-one Crown-granted mineral claims situated on Iron mountain between Sheep creek (on the north) and Lost creek, some eight miles southward from Salmo, in the Nelson mining division (see Figure 1). On these claims there are at present four operating mines. These are, from north to south, the Dodger, Feeney, and Emerald, all tungsten mines, and the Jersey, a lead-zinc mine, about 7,000 feet south of the Dodger. About midway between the Dodger and the Jersey is a fifth mine, the Emerald lead-zinc mine, which was the first producer in the area but has been inactive since 1926. The locations of the mines are shown in Figure 2.Records of prospecting and claim staking on Iron mountain -which owes its name to the presence of large iron-stained outcrops -go back to 1895. The first recorded owner of the claims that form the old Emerald lead-zinc mine was John Waldbeser who, in 1908, did considerable work and produced 426 tons of lead ore valued, at the then price of lead, at $7,000. This ore was chiefly lead carbonate and was taken from the surface outcrops of two bands of ore that form the Emerald orebodies. In 1909, the Emerald was the largest lead producer in the Nelson mining district."

Jan 1, 1953

By C. Gosselin, M. Rheault, M. Benoit, Y. Bouroubi, V. Sarago

The last three decades have seen significant mining development in northern regions of Canada, where the freeze and thaw cycle of permafrost and the corresponding surface subsidence and heave represent a significant challenge to the design and maintenance of infrastructures. Identifying areas at risk is of great assistance to reduce the impact of this issue. Over the past ten years, Synthetic Aperture Radar Interferometry (InSAR) has been widely used to monitor ground surface deformation. With this technique, changes in phase between two SAR acquisitions are used to detect centimeter to millimeter surface displacements over a large area and with high spatial resolution. InSAR can be used as a tool to assist the siting and design of new infrastructure as well as highlighting the risk to existing structures in areas of unstable terrain. This paper presents the results of a project carried out by Effigis, which made use of SAR interferometry in the context of monitoring terrain and infrastructure stability in a northern mining environment that is affected by permafrost seasonal and long term changes. TerraSAR-X images acquired during two periods, August to November 2012 and March to October 2013, were used to measure the deformations and/or movement of ground surface, infrastructure and stockpiles caused by seasonal changes in permafrost extent in and around a mining site located in Nunavik, Quebec. The results showed that spatial and temporal distributions of surface displacements are in accordance with scientific and terrain knowledge. Some displacements were observed in loose soil areas while, as expected, none were detected in bedrock and rock outcrop areas. The areas most affected by active layer changes showed surface subsidence in the thaw settlement period. This study confirms that SAR interferometry has a great potential for operational applications related to risks induced by surface deformation in mining environments. It shows that this technique can be used to produce reliable maps of surface movement and monitor the vertical displacement of important infrastructure.

Jan 1, 2015

By Brian W. Mackenzie

The paper addresses five questions concerning the economic of gold exploration in the western Canadian shield. Can historical footprints be used to project future gold prices for exploration planning? Experience suggests that gold price forecast are too clo ely tied to current market events to provide meaningful guidelines. What range of breakeven gold price will typically be required to ju tify gold exploration in Canada? Minimum price requirements. initially asses ed at $540 to $1080 per ounce, probably lie in the range of $480 to $760 per ounce (expressed in 1985 Canadian dollar). Within Canada, what role do regional conditions and taxation policies play in determining the viability of prospective gold exploration targets? Striking interprovincial differences are found to exist, given the same geological circum tance -Nova Scotia, ew Brunswick, and Quebec rank towards the top in term of motivating exploration, Briti h Columbia provides the least investment incentive, while Saskatchewan and Manitoba place around the middle of the Canadian league. How can minimum acceptable tonnage-grade conditions for gold targets in the western shield be established and, then, constructively applied to provide exploration planning guidelines? Minimum target conditions, realis tically defined in terms of a broad band of doubt, can be used judiciously to help balance the direct costs of uneconomic exploration with the opportunity costs associated with rejecting economic deposits. How does the average cost per ounce of gold discovered in the western shield compare with the overall Canadian experience? Average discovery costs for the we tern shield, apprai ed at $100 per ounce, are shown to compare favourably with the Canada-wide record.

Jan 1, 1986

By Da-Qiang Cang, Qingde Wang, Wei Wang, Wen-Bin Dai, Min Guo, Yu Li

Utilization of both slag and its heat for hot slag is a great challenge for iron and steel industry. Many methods of hot slag modification for directly converting hot slag into value-added materials were researched in recent years, and waste heat of hot slag could thereby be transformed into inner energy or chemical energy of the materials. In this paper, an experiment of converting hot slag directly into glass ceramics by hot slag modification method was conducted. A cooled modifiers mainly composed of fly ash were firstly heated though a cyclone furnace and then fell into a molten bath to mix with hot steel slag. Half of hot slag was used as raw materials and accordingly about half energy consumption, about 5MJ/kg for melting raw materials was saved in the process compared with that of traditional producing method. Frit quenched from the modified hot slag had a higher basicity of 0.6-0.7 than traditional frits in order to reduce the needed amount of cold modifiers and accordingly utilize more hot slag and its waste heat. Glass ceramics were further prepared from the frit and a heat treatment of one-stage method is more suiter to such frit than that of two-stage method. The glass-ceramics with basicity of 0.6 and heat-treated by one stage method had the best performance with bending strength of 146.46 MPa, Vickers hardness of 6.79 GPa, water absorption rate of below 2% and shrinkage rate of around 10%.

Jan 1, 2015

By Kris Inwood

"In 1879, when the Dominion government initiated its controversial program of industrial promotion, iron smelting in Canada was limited to one company producing coke iron on the mainland of Nova Scotia and three small charcoal blast furnaces in Quebec. There was no steel production. By the eve of the First World War, iron and steel were being produced in very large quantities, the companies active in 1879 had disappeared and new centres of integrated iron and rolled steel production at Hamilton, Sydney and Sault Ste. Marie had come to resemble the industry as we know it today. The most dramatic change was that at Sydney, Nova Scotia, where in the early 1900s, two steelmaking companies established works. The Sydney developments have been explained as the result of resource discovery and technical change. W.J. Donald, in his authoritative account of the Canadian iron and steel industry, observes:(1) ""The most rapid growth of the Canadian iron and steel industry has occurred since 1897 ... The remarkable growth has been caused largely by the new conditions of the industry. The discovery and use of Newfoundland ores, together with the availability of Cape Breton coal, has made the Nova Scotia industry not only possible but profitable .... It is a safe conclusion that the Canadian industry would not have been an important one, had it not been for the discovery of the Michipicoten and especially the Wabana (Newfoundland) ores:' Donald also argues that metallurgical progress had been necessary to render the ores valuable. ""Newfoundland ores ... contain a considerable amount of phosphorus, and were made available for steel-making by recent inventions:' The purpose of this paper is to re-examine Donald's story. It will be argued that the origin of steel-making at Sydney is somewhat more complicated than Donald has indicated. The difficulty with Newfoundland ore extended beyond its phosphorus content and a resolution required more than the basic open hearth furnace identified by Donald. Moreover metallurgical change was only one of several developments necessary to induce industrial investment at Sydney. Surprisingly, however, the discovery of iron ore in the late nineteenth century does not appear to be part of the explanation."

Jan 1, 1999

By Tanai Marin

Modelling of pyrometallurgical processes can become extremely challenging when the process involves complex chemical reactions, phase change, multiphase flows, heat and mass transfer and fluid flow. Traditionally modelling involving complex thermodynamic equilibrium and thermochemistry are treated separately from problems in which transport phenomena are dominant, such as CFD and heat transfer studies. The separation is also necessary due to the lack of modelling tools that can effectively couple both solution thermodynamic and transport phenomena or even multiphysics problems. However, there are, quite often, problems in high temperature process metallurgy in which it is not possible to simplify this two modelling approaches. Typical cases of this are for example, the modelling of slag freezing on furnace walls (electric or flash furnaces) to create a protective layer in front of the refractories hot wall, the formation of build up from the matte or metal phases at the hearth of the furnace, calcine smelting from charging piles into slag phase, etc. The problem is even more challenging in nonferrous pyrometallurgy as most, if not all, of the condense phases are highly non ideal solutions involving several components and exhibiting complex crystallization paths and miscibility gaps, such as the Fe-Ni-Cu-S matte, FeO-Fe2O3-SiO2, FeO-MgO-SiO2 slags, etc. In this paper, an approach to model coupled problems involving multiphysics and solution thermodynamic is presented. The approach consists in developing in-house a library containing the Gibbs energy minimization routines and using the local equilibrium concept for process modelling from a multiphysics commercial software (COMSOL). Simple test cases, such as building a non-ideal binary phase diagram on a CFD package is presented, the limitations and of other classic approaches such as equilibrium or Scheil cooling are discussed and compared to this model.

Jan 1, 2015

By J Zhou

Based on the mineralogical characteristics and mineral processing techniques required, gold ores can be classified into 12 types, including gold placers, quartz vein-lode ores, oxidized ores, silver-rich ores, iron oxide copper gold ores, porphyry copper gold ores, iron sulphide ores, arsenic sulphide ores, antimony sulphide ores, bismuth sulphide ores, telluride ores and carbonaceous sulphide ores. The bulk mineralogy and gold deportment of each ore type is different and may have a significant impact on ore processing and metal extraction. This paper summarizes the bulk mineralogy and gold deportment in some major types of gold ores and discusses the potential impact of gold deportment on gold metallurgy.

Jan 1, 2011

By P. West-Sells, B. Wassink, N. Fisher

Gold leaching from a commercial cyanide-amenable gold ore was studied at 25°C using sodium bisulfide-hydrogen sulfide solutions containing elemental sulfur. Gold extraction from the ore using 0.55 M NaSH, 4.1 atm (60 PSI) H2S, 1 g/L S8 and 26% solids by weight was about as good as the best extraction obtained by cyanidation. Maximum extraction was achieved in roughly 48 hours. Sulfur dissolves in the bisulfide solutions to form a mixture of polysulfides. Simple speciation calculations indicate that gold solubility as bisulfide complexes should be roughly ten times higher than in the absence of added zerovalent sulfur. The principal bisulfide complex is believed to be [Au(HS)2]-. Gold dissolution is favoured by increasing HS- concentration and by increasing H25 pressure. Polysulfide complexes of gold are also likely to be formed, and may contribute substantially to gold leaching. Two experiments using pure gold were also performed. Up to 100 mg/L gold was dissolved in 140 hours using 0.55 M NaSH, 1 g/L added elemental sulfur and 6.2 atm H2S.

Jan 1, 2005