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By Parker A. J, Muir D. M

Solutions of acetonitrile in water dissolve water soluble copper(I) chloride. Removal of volatile acetonitrile from the resulting solutions, by distillation with low grade steam, precipitates pure copper(I) chloride. This is used to purify a crude copper chloride sublimate from the chlorination of nickel matte but is applicable to other sources of copper(I) chloride. The pure product can be converted to pure copper(I) oxide, copper(II) oxychloride or pure copper metal directly.

Jan 1, 1980

By C Barton, B Randall, T Weldon, M Lefler

FLSmidth-Summit Valley Technologies has been a leader in gold processing equipment for nearly two decades. Over the past several years an extensive research and development effort has led to improvements in Mercury Abatement systems and process efficiency in Adsorption Desorption and Regeneration (ADR) or "Carbon" plant operations. Two technologies will be discussed that are focused on efficiency improvements followed by an explanation of Mercury Abatement systems. Gold and silver can be desorbed from carbon in several ways. FLSmidth has made significant improvements to the Pressure ZADRA process allowing for lower energy consumption and lower capital costs. This patented process is known as the Split-ZADRA Strip method. Split-ZADRA allows a plant to elute loaded carbon in a semi-continuous fashion. This increases the grade of the Pregnant Strip Solution, improves electrowinning efficiency, reduces capital equipment costs, and reduces energy requirements. During desorption and electrowinning for the Pressure ZADRA process, the pressure and temperature of the circulating strip solution is changed multiple times. A self-contained heating and cooling system has been developed which decreases the energy requirements for elution. Mercury Abatement technology has become increasingly important in recent years. Along with FLSmidth Summit Valley Technologies' complete Mercury Retorting Systems, FLS-SVT has developed systems for the capture and removal of mercury from electrowinning cell and strip solution exhaust, Carbon Regeneration exhaust, and the dore furnace exhaust. This paper describes each of the technologies introduced above and their success in operational gold and silver mines. Case studies will be discussed showing the advantages of each specific technology as it applies to operations around the world. CITATION:Lefler, M, Weldon, T, Barton, C and Randall, B, 2013. Improvements in the mercury abatement and process efficiency of adsorption, desorption and regeneration gold processing operations, in Proceedings MetPlant 2013 , pp 468-478 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

Many mining operations are uncertain of what costs they should be achieving. The majority of cost estimates are based on historical costs that have added contingency factors. Historical costs are a valuable source of information but a more precise costing method is necessary. There are several alternative methods for predicting costs. A methodology which provides the best indication of the achievable costs is one using a standard inventory list and a bill of quantities. The model is termed a Basic Principles model and addresses basic design principles and engineering constraints.

Jan 1, 1990

In presenting this address I am conscious of the honour that has been paid me in my election to this important office, and I am very aware that I follow, in the position of President, many distinguished men who have led the Institute over the 70 years since its inauguration in Broken Hill in 1893.It is perhaps appropriate tonight that I intend to talk about a metal which recalls the birth-place of the Institute, and is also one with which I have had a direct association throughout the whole of my working career. This metal is Silver.Silver is associated traditionally in everyone's mind with money and silverware, and has always been prized for its natural beauty and elegance. It is today one of the few metals in which world consumption has outstripped production, and the events which have occurred to bring about this situation make an interesting story.In telling this story, I propose firstly to indicate our development as a silver producing country, give an historical review of the metal, trace its use as currency and the factors influencing its price, and then say something of the old and new uses of silver. Finally I shall give some comments on silver production in Australia today.Australia, with 6-5 per cent of the world's output of silver, ranks sixth among the producer countries and over the years has contributed 892.5 million ounces to the world's supply which, based upon production since the discovery ofAmerica, is estimated to have been 22,150 million ounces or nearly 680,000 tons.Although our production appears relatively small by...

Jan 1, 1963

Observed mineral assemblages in the Mt. Lyell copper deposit can be correlated with phase equilibrium investigations in the systems Cu-Fe-S and Fe-Zn-S. The trend of crystallization (or paragenetic sequence) of the ores is reflected in a progressive increase in the Cu: Fe and metal: sulphur ratios of the assemblages. This trend agrees with the regional zoning of the district. Tentative relationships between the paragenetic sequence, sulphur vapour pressure, and temperature are presented graphically. The absence of a suitable geological thermometer prevents precise elucidation of the range of temperatures and pressures which existed during crystallization.INTRODUCTIONRecent phase equilibrium investigations of metal-sulphur systems at the Geophysical Laboratory, Washington, D.C. provide valuable information on the stability relations of a number of important sulphide minerals. This data, when applied to natural ore deposits, may be expected to clarify two special problems which confront the ore petrologist seeking to interpret observed data in terms of a particular physical and chemical environment of ore deposition. These two problems are the sequence of formation of sulphide minerals (commonly designated the paragenetic sequence) and an elucidation of the range of temperatures and pressures which existed during crystallization. The object of this paper is to make such an interpretation of the copper mineralization of the Mt. Lyell district, Queenstown, Tasmania.The following abbreviations are used in this paper:py = pyrite, cp = chalcopyrite, en = cubanite, bn = bornite,cc = chalcocite, cv = covellite, dg = digenite, id = idaite,po = pyrrhotite, v = sulphur vapour.GEOLOGICAL SETTING AND MINERALIZATIONThe general geology of the Mt. Lyell district is well known through the recent work of Wade and Solomon (1958). The host rocks are a series of quartz-chlorite-seri-...

Jan 1, 1963

Various influences determine how an Environmental Management System (EMS) for a mining or petroleum project is developed and administered. These influences include the environmental and resource legislation applying to the project, the culture of the organisation, the environmental sensitivity of the area, and the administrative policies of the regulatory agencies involved. While financial penalties and even imprisonment may be imposed for non-compliance with environmental legislation, there are other compelling reasons for the establishment of an effective EMS. If a company wishes to be considered by Governments for the grant of exploration or mining rights, it is important that it can demonstrate environmentally responsible operations at existing facilities. The development of an effective EMS requires commitment from the Board of the company and the issue of an Environmental Policy to empower all levels of the staff and workforce to achieve environmentally responsible operations. This must be supported by the provision of appropriate human and financial resources, and environmental training of staff at all levels from the Board to the mine site, workshop and office. A regular environmental auditing programme is essential to ensure that the EMS is in place and is effective in achieving compliance with regulatory requirements, corporate policies and protection of the environment. An EMS can be developed on the basis of existing management systems, quality management systems, existing and emerging environmental management standards (such as BS7750 and ISOI4000), or sophisticated computerised systems which may incorporate international experience, standards, and codes of practice.

Jan 1, 1995

The flolation behaviour of some Australian uranium ores was investigated. Although uraninite and pitchblend float readily with fatty acids, selective concentration to produce an economically discardable tailing has not yet been achieved. This is attributed to the presence in the ores of a quantity of uranium mineral in finely dispersed form which is very difficult to liberate. For some of the ores, at least, the proportion of this material decreases with increase in head assay.Flotation may be a useful concentrating method for some Australian ores if uranium oxide is to be sold in a free competitive market.

Jan 1, 1967

By P A. Tilyard

There have been enormous changes in mineral processing in the past four decades. For example grinding mill power has increased by an order of magnitude, regrinding is done to -10 microns and flotation machines are 100 times bigger. Operating staff have unprecedented opportunities for online monitoring and performance control of mineral processing plants. Sophisticated instruments can provide a plethora of data characterising the mineralogy and surfaces of particles. Digital computers allow complex calculations on huge amounts of data including modelling and simulation of machine and plant performance. However, all these changes have not necessarily lead to better metallurgical results. An analogy can be drawn with the thoroughbred racing industry in Australia. Significant advances in scientific knowledge in animal genetics, physiology, biomechanics and nutrition applied to the business have resulted in only a two per cent reduction in winning times for the Melbourne Cup and Caulfield Cup since the 1920s. A critical look at some mineral processing metrics suggests similar failures to improve performance despite putting in more resources. In fact certain parameters such as operating times and plant start-up performance are considered to have remained static or even deteriorated. There has been an emphasis on 'process' at the expense of 'outcomes'. The industry's strength has been in finding technical (or 'hardware') solutions while its weakness has been at the people end of the business in maximising and consolidating the gains from the technologies. Some trends in plant design over these years have exacerbated the apparent deskilling of operating and technical staff. Despite unparalleled options for communications, some staff are embarrassingly uninformed about technical developments in their fields. The 'boom and bust' cycles of the industry, together with trends in tertiary education and the effects of fly-in, fly-out (FIFO) operations, raise serious questions about the sustainability of human capital in the mineral processing sector. This paper by two experienced mineral processing engineers, with contributions from other senior practitioners, reviews these trends. While there may be an element of 'the older we are, the better we were', it is an attempt to identify the issues and propose solutions.

Jan 1, 2009

By A B. Phillips

This paper details the approach adopted to upgrade the current metallurgical facilities at both the Driefontein and Kloof Gold Mines in the Republic of South Africa. Goldfields Ltd operates eight metallurgical plants within South Africa of which three have recently been upgraded to replace the older technology previously installed, with modern equipment. This upgrade was undertaken with a view to improving extraction efficiencies and to reduce operating costs. The upgrade was undertaken in a phased approach with the first phase focused on the replacement of the filtration/zinc precipitation processes with modern pumpcell carbon-in-pulp technology. Included in this upgrade phase was the installation of an automated hands-free electrowinning cell, which represents the first commercial application of its kind in the industry. The second phase of the upgrade entailed replacement of the multiple comminution stages previously installed with large SAG and SAG/Ball mill combinations. Due to the rapid return on these projects, a fast-track approach was adopted which necessitated the purchase of available good conditioned second-hand mills from both within South Africa as well as in Australia. Goldfields Ltd is a large mining house with gold mining operations in South Africa, Australia and Ghana. A well advanced PGM exploration project is underway in Finland- Arctic Platinum.

Jan 1, 2003

A Good Product Range - So What! While in terms of water, waste management and environment protectrion, the Gippsland Basin may appear to have a good product range, what does this really mean? What it means is that, like any product range, the virtues of the product range must be sold and accepted by a majority of the public. The social, economic and environmental benefits of any enterprise using these products must be sold and accepted by the regional population. Many a budding entrepreneur has failed because he assumed that the public would accept his product, so good did it appear to be! However, we know that such an assumption must be avoided and that a great deal of time and effort needs to be invested in promoting and gaining acceptance of a product to ensure a long term and viable market.

Jan 1, 1992

The leaching characteristics of a number of Australian uranium ores were determined under acid and alkaline conditions. Ores from the Ranger, Nabarlek and Koongarra deposits in the Northern Territory were readily leached in dilute sulphuric acid. Suitable processing conditions were: leaching at 35-40°C, pH 1·52·0 and redox potential -475 mV for periods of 16-24h with ore ground to 50 per cent -200 mesh CB.S.S.). Ore from the Roxby Downs deposit in South Australia required leaching at 55°C and a redox potential of -650 mV to achieve a satisfactory recovery. All ores contained refractory minerals which were not leached under conventional conditions, limiting uranium extraction to 86-96 per cent.Carbonate leaching of carnotite in calcrete ores from Yeelirrie and Lake Way in Western Australia yielded uranium extractions of at least 98 per cent. Leaching rates were considerably faster than those reported for other applications of alkaline leaching as the slow oxidation step was not required.

Jan 1, 1979

By Ralph B. S

Bacterial leaching of low grade quartz felspar porphyry copper ore was studied in large-scale laboratory percolation leaching columns.Limitations in the release of soluble copper showed up before fifty per cent recovery, due to occluding precipitates of iron oxides and hydroxides. Precipitates were removed by increasing the acidity of irrigation feed four-fold with respect to sulphuric acid. However, irrigation at low pH (pH 1.5) inhibited copper leaching. Resumption of bacterial leaching at pH2 was achieved by introducing a period of non-irrigation. The results suggest a 'direct' attack by bacteria on the chalcopyrite substrate rather than an 'indirect' ferric-leach mechanism.

Jan 1, 1981

By P L. McCarthy

To design and operate a successful mine the technical specialists must agree on what is ore, what is not ore, and how quickly the orebody is to be mined and processed. These seemingly simple questions defy easy analysis and can push mining engineers, geologists, metallurgists and others to the limit of their capabilities. The questions are rarely addressed adequately in feasibility studies or in operational planning. To optimise the mine and processing plant requires proper determination of cut-off grades or values, prediction of feed variability on an hourly, daily or longer basis, right-sizing the mining rate for optimum product quality, understanding the cost of capital and the expectations of investors, and many other considerations that involve geology, geotechnical engineering, mining, metallurgy, environmental effects and economics. This paper addresses the key matters that should be considered as inputs to the practical issues of metallurgical plant design and operation.CITATION:McCarthy, P L, 2015. Integrated mining and metallurgical planning and operation, in Proceedings MetPlant 2015, pp 35–45 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

The observation of lower-than-predicted Fe/Cu ratios in the cementation of copper on iron in tests at elevated temperatures indicated that some other reaction was contributing to the reduction of cupric sulphate in addition to the reduction by elemental iron. Experiments showed that the copper sponge, which initially formed on the iron, subsequently reduced the cupric sulphate giving the products cuprous oxide and sulphuric acid.Tests were undertaken to determine the rate and equilibrium conditions of the reduction reaction with variations in the types of the reducing agent and solution parameters. The reaction first became apparent at temperatures above 50°C and as it ceased at pH 1·8 it was possible to induce further reaction by alkali addition.

Jan 1, 1974

By Gibbs R

The objective of this paper is to provide a broad qualitative perspective of the needs and costs of infrastructure associated with typical mining projects. Infrastructure may be defined as anything necessary for the development and operation of a project, which is peripheral to the basic extraction, handling and processing of material. As depicted in Figure 1, infrastructure acts as the link between the technological heart of a project and the outside world.

Jan 1, 1990

By I Ross, C deWolfe

Block caving has been the favoured mining method for large underground hard rock mines for the last few decades. The orebody must be of a size large enough to cave and generally amenable to a caving method. Typically, these mines ranged from 15 000 to 50 000 tonnes per day (50 kt/d) and have been some of the largest and most productive underground mines in the world.Now mining companies, in the quest for improved shareholder return, are looking for higher production rates from new underground mines. Whether a ‘Greenfields’ development, or a replacement for ageing large open pit mines, minimising capital and maximising production has been a focus of project teams. These new block cave mines are what have become known as ‘super caves’. These caves range from 80 kt/d to over 150 kt/d and are being planned or constructed by several major mining companies including Codelco, Freeport-McMoRan, Newcrest and Rio Tinto.Issues facing these super caves include high initial capital costs, very long development periods and significant technical challenges. These issues tend to make it difficult to present an attractive business case for such a project.This paper will discuss some of the potential benefits as well as the technical challenges and risks of operating a mine with the block or panel caving method at these very high tonnage rates. Considerations including geotechnical conditions, development rates, panel widths and ore column heights are discussed. The risks associated with these technical challenges and potential benefits for successful approaches will also be discussed.CITATION:deWolfe, C and Ross, I, 2016. Super caves – benefits, considerations and risks, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 51–58 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

Various steps, and complete sequences, for the recovery of lead and zinc from a mixed sulphide concentrate, high in silica and pyrite, have been tested.Oxidation steps of roasting in air or in a sulphating atmosphere and use of aqueous acidic, ammoniacal, and near neutral oxidation media were compared. Oxidation roasting or use of acidic media appeared most useful. Procedures for dissolution of zinc from calcines using sulphuric and sulphurous acid to avoid silica gelation problems are compared and a direct leaching procedure with sulphuric 'acid at controlled pH shown to be the most useful.Methods for the removal of germanium, nickel, and magnesium from zinc sulphate solutions prior to zinc electrodeposition were tested. The recoveries of zinc from ammoniacal solutions by electrolysis and distillation are compared.The dissolution of lead compounds from the residue of zinc extraction by amine and ammoniacal ammonium sulphate (AAS) solutions Was tested. Lead, sulphide was precipitated in filtera'ble form from AAS solutions. The reduction of lead sulphate to lead sulphide with sulphur was difficult, but possible. The various steps were used to deveiop five complete processing sequences, of which two were shown to be technically feasible and have potential economic viability.

Jan 1, 1975

There are no large rivers in Western Australia capable of supplying water for processing magnetite ores. If sea water is used there are severe corrosion issues and the requirement to wash the concentrates with potable water. If groundwater is used there is a need to treat the water and sustainability is an issue for large projects because of potential drawdown of the aquifer.If sea water is desalinated the cost of the water is high because of the power requirement. At the same time the necessity to conserve water has lead to flow sheets where all of the tailings have to be filtered to minimise the water requirement.Managing the various water qualities and optimising water recovery and quality has resulted in optimising the water balance and issues meeting environmental obligations. Reverse flotation is a critical final step in reducing the silica level in the final concentrate and requires good quality water.

Jan 1, 2009

Present roof bolting practices in the collieries of Australian Iron and Steel Pty. Ltd. are outlined. Roof support has been improved since introducing roof bolts and it is hoped to increase the reliability of the bolts still further.Expansion-shell, and split and wedge roof bolts five to eight feet long are placed by "Atlas Falcon" and "Fletcher" roof bolters. Both anchorage and tightening have presented some problems.Good panel supervision is required if systematic roof bolting is to be properly co-ordinated with coal production without unnecessary delay to either. Successful roof bolting can only be the product of conscientious men and supervisors who are all convinced of its value. A rigid operational code should be established early and maintained.INTRODUCTIONRoof bolting is a method of support which is permanent and reduces or eliminates the need for other support; The method was pioneered in America and was first experimentally investigated in Australian collieries at Elrington in 1949 (McKensey, 1953). Pneumatic installation methods were employed. Subsequently, a method of using standard hand-held electric coal drills was developed at John Darling Colliery (Horseman, 1954). Pneumatic roof bolting equipment was first operated in the collieries of Australian Ironand Steel Pty. Ltd (A.I. &. S.) in 1951. Since then various hydraulically operated mobile machines have been installed in Australian collieries and these, together with improved pneumatic equipment, form the two present basic methods of placing ,roof bolts. Roof bolt anchorage is achieved by either split and wedge or expansion-shell bolts.The two broad types of roof bolting are 1. consolidation of strata, and 2. suspension support.

Jan 1, 1961

A research project was commissioned by the Australian Coal Association Research Program (ACARP) to improve the understanding of tailgate strata mechanics and to provide a more rigorous engineering basis for tailgate support design. A deformation mechanism termed æskew roofÆ was defined which relates the regional influence of differential horizontal strata movement (shear) about longwall extraction to gateroads. Confirmation of the mechanism was achieved by field investigations which included measurement of the shear displacement along weak interfaces. Under geological and mining conditions where the skew roof mechanism operated, strata units were found to move progressively further towards the goaf with height into the roof. 3D numerical modelling was used to assess the major geotechnical factors controlling the mechanism and to determine appropriate support strategies within a æskew roofÆ environment including the role of cables versus standing supports. The skew mechanism is considered relevant to; all roadways in the vicinity of longwall extraction including the faceline itself, chain pillar design, and support design.

Jan 1, 2005